Articles | Volume 15, issue 11
https://doi.org/10.5194/gmd-15-4625-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/gmd-15-4625-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
GNOM v1.0: an optimized steady-state model of the modern marine neodymium cycle
Earth Sciences Department, University of Southern California, Los Angeles, CA, USA
now at: School of Mathematics and Statistics, University of New South Wales, Sydney, Australia
Sophia K. V. Hines
CORRESPONDING AUTHOR
Lamont–Doherty Earth Observatory, Columbia University, Palisades, NY, USA
Department of Marine Chemistry and Geochemistry, Woods Hole Oceanographic Institution, Woods Hole, MA, USA
Hengdi Liang
Earth Sciences Department, University of Southern California, Los Angeles, CA, USA
Yingzhe Wu
Lamont–Doherty Earth Observatory, Columbia University, Palisades, NY, USA
Steven L. Goldstein
Lamont–Doherty Earth Observatory, Columbia University, Palisades, NY, USA
Department of Earth and Environmental Sciences, Columbia University, Palisades, NY, USA
Seth G. John
Earth Sciences Department, University of Southern California, Los Angeles, CA, USA
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How do perpetually slower and warmer oceans sequester carbon? Compared to the preindustrial state, we find that biological productivity declines despite warming-stimulated growth because of a lower nutrient supply from depth. This throttles the biological carbon pump, which still sequesters more carbon because it takes longer to return to the surface. The deep ocean is isolated from the surface, allowing more carbon from the atmosphere to pass through the ocean without contributing to biology.
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Modeling the ocean's carbon and oxygen cycles accurately is challenging. Parameter optimization improves the fit to observed tracers but can introduce artifacts in the biological pump. Organic-matter production and subsurface remineralization rates adjust to compensate for circulation biases, changing the pathways and timescales with which nutrients return to the surface. Circulation biases can thus strongly alter the system’s response to ecological change, even when parameters are optimized.
Cited articles
Abbott, A. N., Haley, B. A., and McManus, J.: Bottoms up: Sedimentary control
of the deep North Pacific Ocean's εNd signature, Geology, 43, 1035–1035, https://doi.org/10.1130/g37114.1, 2015a. a
Abbott, A. N., Haley, B. A., McManus, J., and Reimers, C. E.: The sedimentary
flux of dissolved rare earth elements to the ocean, Geochim.
Cosmochim. Ac., 154, 186–200, https://doi.org/10.1016/j.gca.2015.01.010,
2015b. a, b
Adebiyi, A. A., Kok, J. F., Wang, Y., Ito, A., Ridley, D. A., Nabat, P., and Zhao, C.: Dust Constraints from joint Observational-Modelling-experiMental analysis (DustCOMM): comparison with measurements and model simulations, Atmos. Chem. Phys., 20, 829–863, https://doi.org/10.5194/acp-20-829-2020, 2020. a, b, c, d
Adkins, J. F.: The role of deep ocean circulation in setting glacial
climates, Paleoceanography, 28, 539–561, https://doi.org/10.1002/palo.20046, 2013. a
Amakawa, H., Yu, T.-L., Tazoe, H., Obata, H., Gamo, T., Sano, Y., Shen, C.-C.,
and Suzuki, K.: Neodymium concentration and isotopic composition
distributions in the southwestern Indian Ocean and the Indian sector of the
Southern Ocean, Chem. Geol., 511, 190–203,
https://doi.org/10.1016/j.chemgeo.2019.01.007, 2019. a
Anderson, S. P.: Glaciers show direct linkage between erosion rate and chemical
weathering fluxes, Geomorphology, 67, 147–157,
https://doi.org/10.1016/j.geomorph.2004.07.010,
2005. a
Arsouze, T., Dutay, J.-C., Lacan, F., and Jeandel, C.: Modeling the neodymium
isotopic composition with a global ocean circulation model, Chem. Geol.,
239, 165–177, https://doi.org/10.1016/j.chemgeo.2006.12.006, 2007. a, b
Arsouze, T., Treguier, A. M., Peronne, S., Dutay, J.-C., Lacan, F., and Jeandel, C.: Modeling the Nd isotopic composition in the North Atlantic basin using an eddy-permitting model, Ocean Sci., 6, 789–797, https://doi.org/10.5194/os-6-789-2010, 2010. a, b
Bacon, M. P. and Anderson, R. F.: Distribution of thorium isotopes between
dissolved and particulate forms in the deep sea, J. Geophys.
Res.-Oceans, 87, 2045–2056, https://doi.org/10.1029/JC087iC03p02045, 1982. a
Basak, C., Pahnke, K., Frank, M., Lamy, F., and Gersonde, R.: Neodymium
isotopic characterization of Ross Sea Bottom Water and its advection through
the southern South Pacific, Earth Planet. Sc. Lett., 419,
211–221, https://doi.org/10.1016/j.epsl.2015.03.011, 2015. a
Behrens, M. K., Pahnke, K., Paffrath, R., Schnetger, B., and Brumsack, H.-J.:
Rare earth element distributions in the West Pacific: Trace element sources
and conservative vs. non-conservative behavior, Earth Planet. Sc. Lett., 486, 166–177, https://doi.org/10.1016/j.epsl.2018.01.016, 2018a. a
Behrens, M. K., Pahnke, K., Schnetger, B., and Brumsack, H.-J.: Sources and
processes affecting the distribution of dissolved Nd isotopes and
concentrations in the West Pacific, Geochim. Cosmochim. Ac., 222,
508–534, https://doi.org/10.1016/j.gca.2017.11.008, 2018b. a
Bertram, C. and Elderfield, H.: The geochemical balance of the rare earth
elements and neodymium isotopes in the oceans, Geochim. Cosmochim. Ac., 57, 1957–1986, https://doi.org/10.1016/0016-7037(93)90087-D, 1993. a, b, c
Bezanson, J., Edelman, A., Karpinski, S., and Shah, V. B.: Julia: A Fresh
Approach to Numerical Computing, SIAM Review, 59, 65–98,
https://doi.org/10.1137/141000671, 2017. a, b
Blaser, P., Lippold, J., Gutjahr, M., Frank, N., Link, J. M., and Frank, M.:
Extracting foraminiferal seawater Nd isotope signatures from bulk deep sea
sediment by chemical leaching, Chem. Geol., 439, 189 – 204,
https://doi.org/10.1016/j.chemgeo.2016.06.024, 2016. a, b, c
Blaser, P., Gutjahr, M., Pöppelmeier, F., Frank, M., Kaboth-Bahr, S., and
Lippold, J.: Labrador Sea bottom water provenance and REE exchange during
the past 35,000 years, Earth Planet. Sc. Lett., 542, 116299,
https://doi.org/10.1016/j.epsl.2020.116299, 2020. a, b
Bouvier, A., Vervoort, J. D., and Patchett, P. J.: The Lu–Hf and Sm–Nd
isotopic composition of CHUR: Constraints from unequilibrated chondrites and
implications for the bulk composition of terrestrial planets, Earth Planet. Sc. Lett., 273, 48–57, https://doi.org/10.1016/j.epsl.2008.06.010,
2008. a
Brahney, J., Mahowald, N., Ward, D. S., Ballantyne, A. P., and Neff, J. C.: Is
atmospheric phosphorus pollution altering global alpine Lake stoichiometry?,
Global Biogeochem. Cycles, 29, 1369–1383, https://doi.org/10.1002/2015GB005137,
2015. a, b
Byrne, R. H. and Kim, K.-H.: Rare earth element scavenging in seawater,
Geochim. Cosmochim. Ac., 54, 2645–2656,
https://doi.org/10.1016/0016-7037(90)90002-3, 1990. a
Che, H. and Zhang, J.: Water Mass Analysis and End-Member Mixing Contribution
Using Coupled Radiogenic Nd Isotopes and Nd Concentrations: Interaction
Between Marginal Seas and the Northwestern Pacific, Geophys. Res.
Lett., 45, 2388–2395, https://doi.org/10.1002/2017GL076978, 2018. a
Chien, C.-T., Mackey, K. R. M., Dutkiewicz, S., Mahowald, N. M., Prospero,
J. M., and Paytan, A.: Effects of African dust deposition on phytoplankton
in the western tropical Atlantic Ocean off Barbados, Global
Biogeochem. Cycles, 30, 716–734, https://doi.org/10.1002/2015GB005334, 2016. a, b, c
Dai, A.: Historical and Future Changes in Streamflow and Continental Runoff,
chap. 2, 17–37, American Geophysical Union (AGU),
https://doi.org/10.1002/9781118971772.ch2, 2016. a
Dai, A.: Dai and Trenberth Global River Flow and Continental Discharge
Dataset, Research Data Archive at the National Center for Atmospheric Research, Computational and Information Systems Laboratory, https://doi.org/10.5065/D6V69H1T, 2017. a, b, c
Dai, A. and Trenberth, K. E.: Estimates of Freshwater Discharge from
Continents: Latitudinal and Seasonal Variations, J.
Hydrometeorol., 3, 660–687,
https://doi.org/10.1175/1525-7541(2002)003<0660:EOFDFC>2.0.CO;2, 2002. a, b
Dai, A., Qian, T., Trenberth, K. E., and Milliman, J. D.: Changes in
Continental Freshwater Discharge from 1948 to 2004, J. Climate, 22,
2773–2792, https://doi.org/10.1175/2008JCLI2592.1, 2009. a
Danisch, S. and Krumbiegel, J.: Makie.jl: Flexible high-performance data
visualization for Julia, J. Open Source Softw., 6, 3349,
https://doi.org/10.21105/joss.03349, 2021. a
Danisch, S., Krumbiegel, J., Singhvi, A., Freyer, F., Wang, A., Vertechi, P., Holy, T., Widmann, D., Krabbe Borregaard, M., Datseris, G., M. M., Greimel, F., Butterworth, I., Foster, C., Dehaybe, H., Schauer, M., Kilpatrick, L., Byrne, S., kragol, Weidner, J., Hatherly, M., Sharma, A., Micluța-Câmpeanu, S., t-bltg, Herikstad, R., Goretkin, G., TagBot, J., Štih, V., and smldis: JuliaPlots/Makie.jl, Zenodo,
https://doi.org/10.5281/zenodo.3735092, 2021. a
Dausmann, V., Frank, M., and Zieringer, M.: Dissolved Hafnium and
Neodymium data measured on water samples during METEOR cruise M84/5 in the
Bay of Biscay, PANGAEA, https://doi.org/10.1594/PANGAEA.902808, 2019. a
Dausmann, V., Frank, M., and Zieringer, M.: Water mass mixing versus local
weathering inputs along the Bay of Biscay: Evidence from dissolved hafnium
and neodymium isotopes, Marine Chemistry, 224, 103844,
https://doi.org/10.1016/j.marchem.2020.103844, 2020. a
de Baar, H. J. W., Bacon, M. P., and Brewer, P. G.: Rare-earth distributions
with a positive Ce anomaly in the Western North Atlantic Ocean, Nature, 310,
324–327, https://doi.org/10.1038/301324a0, 1983. a
de Baar, H. J. W., Bacon, M. P., Brewer, P. G., and Bruland, K. W.: Rare earth
elements in the Pacific and Atlantic Oceans, Geochim. Cosmochim. Ac., 49, 1943–1959, https://doi.org/10.1016/0016-7037(85)90089-4, 1985. a
DePaolo, D. J. and Wasserburg, G. J.: Nd isotopic variations and petrogenetic
models, Geophys. Res. Lett., 3, 249–252,
https://doi.org/10.1029/GL003i005p00249, 1976. a, b, c
Dessert, C., Dupré, B., Gaillardet, J., François, L. M., and Allègre, C. J.:
Basalt weathering laws and the impact of basalt weathering on the global
carbon cycle, Chem. Geol., 202, 257–273,
https://doi.org/10.1016/j.chemgeo.2002.10.001, 2003. a
DeVries, T.: The oceanic anthropogenic CO2 sink: Storage,
air–sea fluxes, and transports over the industrial era, Global
Biogeochem. Cycles, 28, 631–647, https://doi.org/10.1002/2013GB004739, 2014. a, b
DeVries, T. and Primeau, F.: Dynamically and Observationally Constrained
Estimates of Water-Mass Distributions and Ages in the Global Ocean, J. Phys. Oceanogr., 41, 2381–2401, https://doi.org/10.1175/JPO-D-10-05011.1,
2011. a, b
Du, J., Haley, B. A., and Mix, A. C.: Evolution of the Global Overturning
Circulation since the Last Glacial Maximum based on marine authigenic
neodymium isotopes, Quaternary Sci. Rev., 241, 106396,
https://doi.org/10.1016/j.quascirev.2020.106396, 2020. a, b, c, d
Elderfield, H.: The oceanic chemistry of the rare-earth elements,
Philos. T. Roy. Soc. Lond. A, 325, 105–126,
https://doi.org/10.1098/rsta.1988.0046, 1988. a, b
Elderfield, H. and Greaves, M. J.: The rare earth elements in seawater,
Nature, 296, 214–219, https://doi.org/10.1038/296214a0, 1982. a
Elderfield, H. and Sholkovitz, E. R.: Rare earth elements in the pore waters
of reducing nearshore sediments, Earth Planet. Sc. Lett., 82,
280–288, https://doi.org/10.1016/0012-821x(87)90202-0, 1987. a, b, c
Elderfield, H., Hawkesworth, C. J., Greaves, M. J., and Calvert, S. E.: Rare
earth element geochemistry of oceanic ferromanganese nodules and associated
sediments, Geochim. Cosmochim. Ac., 45, 513–528,
https://doi.org/10.1016/0016-7037(81)90184-8, 1981. a, b
Frank, M.: Radiogenic isotopes: Tracers of past ocean circulation and
erosional input, Rev. Geophys., 40, 1-1–1-38, https://doi.org/10.1029/2000RG000094, 2002. a, b, c
Fröllje, H., Pahnke, K., Schnetger, B., Brumsack, H.-J., Dulai, H., and
Fitzsimmons, J. N.: Hawaiian imprint on dissolved Nd and Ra isotopes and rare
earth elements in the central North Pacific: Local survey and seasonal
variability, Geochim. Cosmochim. Ac., 189, 110–131,
https://doi.org/10.1016/j.gca.2016.06.001, 2016. a
Gaillardet, J., Dupré, B., Louvat, P., and Allègre, C.: Global silicate
weathering and CO2 consumption rates deduced from the
chemistry of large rivers, Chem. Geol., 159, 3–30,
https://doi.org/10.1016/S0009-2541(99)00031-5, 1999. a
Garcia, H. E., Weathers, K., Paver, C. R., Smolyar, I., Boyer, T. P.,
Locarnini, R. A., Zweng, M. M., Mishonov, A. V., Baranova, O. K., Seidov, D.,
and Reagan, J. R.: World Ocean Atlas 2018, NOAA Atlas NESDIS 84, vol. 4:
Dissolved Inorganic Nutrients (phosphate, nitrate and nitrate+nitrite,
silicate), edited by: Mishonov, A., NOAA Atlas NESDIS 84, 35 pp., 2019. a, b
Garcia-Solsona, E., Jeandel, C., Labatut, M., Lacan, F., Vance, D., Chavagnac,
V., and Pradoux, C.: Rare earth elements and Nd isotopes tracing water mass
mixing and particle-seawater interactions in the SE Atlantic, Geochim.
Cosmochim. Ac., 125, 351–372, https://doi.org/10.1016/j.gca.2013.10.009, 2014. a, b
Gardner, W. D., Richardson, M. J., and Mishonov, A. V.: Global assessment of
benthic nepheloid layers and linkage with upper ocean dynamics, Earth Planet. Sc. Lett., 482, 126–134, https://doi.org/10.1016/j.epsl.2017.11.008,
2018. a
Gebbie, G. and Huybers, P. J.: Total Matrix Intercomparison: A Method for
Determining the Geometry of Water-Mass Pathways, J. Phys.
Oceanogr., 40, 1710–1728, https://doi.org/10.1175/2010JPO4272.1, 2010. a
GEOTRACES Planning Group: GEOTRACES Science Plan, Baltimore, Maryland, Scientific Committee on Oceanic Research, https://geotracesold.sedoo.fr/libraries/documents/Science_plan.pdf (last access: 7 June 2022), 2006. a
German, C. R., Masuzawa, T., Greaves, M. J., Elderfield, H., and Edmond, J. M.:
Dissolved Rare Earth Elements in the Southern Ocean: golCerium Oxidation and
the Influence of Hydrography, Geochim. Cosmochim. Ac., 59,
1551–1558, https://doi.org/10.1016/0016-7037(95)00061-4, 1995. a
Goldberg, E. D., Koide, M., Schmitt, R. A., and Smith, R. H.: Rare-Earth
Distributions in the Marine Environment, J. Geophys. Res.,
68, 4209–4217, https://doi.org/10.1029/JZ068i014p04209, 1963. a
Goldstein, S. and Hemming, S. R.: Long-lived isotopic tracers in oceanography,
paleoceanography, and ice-sheet dynamics, in: Treatise on Geochemistry,
edited by: Holland, H. D. and Turekian, K. K., 453–489, Pergamon, Oxford,
https://doi.org/10.1016/B0-08-043751-6/06179-X, 2003. a, b, c, d
Goldstein, S. and O'Nions, R. K.: Nd and Sr Isotopic Relationships in Pelagic
Clays and Ferromanganese Deposits, Nature, 292, 324–327,
https://doi.org/10.1038/292324a0, 1981. a, b
Goldstein, S. L. and Jacobsen, S. B.: The Nd and Sr Isotopic Systematics of
River-Water Dissolved Material: Implications for the Sources of Nd and Sr in
Seawater, Chem. Geol., 66, 245–272, 1987. a
Goldstein, S. L., O'Nions, R. K., and Hamilton, P. J.: A Sm–Nd isotopic study
of atomospheric dusts and particulates from major river system, Earth Planet. Sc. Lett., 70, 221–236, https://doi.org/10.1016/0012-821X(84)90007-4,
1984. a, b, c, d
Greaves, M., Statham, P., and Elderfield, H.: Rare earth element mobilization
from marine atmospheric dust into seawater, Marine Chemistry, 46, 255–260,
https://doi.org/10.1016/0304-4203(94)90081-7, 1994. a, b
Grenier, M., Garcia-Solsona, E., Lemaitre, N., Trull, T. W., Bouvier, V.,
Nonnotte, P., van Beek, P., Souhaut, M., Lacan, F., and Jeandel, C.:
Differentiating Lithogenic Supplies, Water Mass Transport, and Biological
Processes On and Off the Kerguelen Plateau Using Rare Earth Element
Concentrations and Neodymium Isotopic Compositions, Front. Marine Sci., 5, 426, https://doi.org/10.3389/fmars.2018.00426, 2018. a
Gu, S., Liu, Z., Oppo, D. W., Lynch-Stieglitz, J., Jahn, A., Zhang, J., and Wu,
L.: Assessing the potential capability of reconstructing glacial Atlantic
water masses and AMOC using multiple proxies in CESM, Earth Planet. Sc. Lett., 541, 116294, https://doi.org/10.1016/j.epsl.2020.116294, 2020. a, b, c
Haley, B., Klinkhammer, G., and McManus, J.: Rare earth elements in pore
waters of marine sediments, Geochim. Cosmochim. Ac., 68, 1265–1279, https://doi.org/10.1016/j.gca.2003.09.012, 2004. a, b, c
Haley, B. A., Frank, M., Hathorne, E., and Pisias, N.: Biogeochemical
implications from dissolved rare earth element and Nd isotope distributions
in the Gulf of Alaska, Geochim. Cosmochim. Ac., 126, 455–474,
https://doi.org/10.1016/j.gca.2013.11.012, 2014. a
Haley, B. A., Du, J., Abbott, A. N., and McManus, J.: The Impact of Benthic Processes on Rare Earth Element and Neodymium Isotope Distributions in the Oceans, Front. Marine Sci., 4,
https://doi.org/10.3389/fmars.2017.00426, 2017. a
Hartman, A. E.: The neodymium composition of Atlantic Ocean water masses:
implications for the past and present, Academic Commons, Columbia University Libraries, https://doi.org/10.7916/D8DZ077F, 2015. a
Hines, S. K. V., Bolge, L., Goldstein, S. L., Charles, C. D., Hall, I. R., and Hemming, S.: Little Change in Ice Age Water Mass Structure From Cape Basin Benthic Neodymium and Carbon Isotopes, Paleoceanogr.
Paleocl., 36, e2021PA004281, https://doi.org/10.1029/2021PA004281, 2022. a
Høgdahl, O. T., Melsom, S., and Bowen, V. T.: Neutron Activation Analysis of
Lanthanide Elements in Sea Water, in: Trace Inorganics in Water, chap. 19, edited by:
Baker, R. A., American Chemical Society, ACS, Washington, D.C., 73, 308–325, https://doi.org/10.1021/ba-1968-0073.ch019, 1968. a
Holzer, M. and Hall, T. M.: Tropospheric transport climate partitioned by
surface origin and transit time, J. Geophys. Res., 113, D08104,
https://doi.org/10.1029/2007JD009115, 2008. a
Holzer, M. and Primeau, F. W.: The path-density distribution of oceanic
surface-to-surface transport, J. Geophys. Res.-Oceans, 113, C01018,
https://doi.org/10.1029/2006JC003976, 2008. a
Holzer, M., Frants, M., and Pasquier, B.: The age of iron and iron source
attribution in the ocean, Global Biogeochem. Cycles, 30, 1454–1474,
https://doi.org/10.1002/2016GB005418, 2016. a, b
Holzer, M., Kwon, E. Y., and Pasquier, B.: A new metric of the biological
carbon pump: number of pump passages and its control on atmospheric
pCO2, Global Biogeochem. Cycles, 35, e2020GB006863,
https://doi.org/10.1029/2020GB006863, 2021. a
Huang, K. F., Oppo, D. W., and Curry, W. B.: Decreased influence of Antarctic
intermediate water in the tropical Atlantic during North Atlantic cold
events, Earth Planet. Sc. Lett., 389, 200–208,
https://doi.org/10.1016/j.epsl.2013.12.037, 2014. a
Irving, D.: A Minimum Standard for Publishing Computational Results in the
Weather and Climate Sciences, B. Am. Meteorol.
Soc., 97, 1149–1158, https://doi.org/10.1175/BAMS-D-15-00010.1, 2016. a
Jacobsen, S. B. and Wasserburg, G. J.: Sm-Nd isotopic evolution of
chondrites, Earth Planet. Sc. Lett., 50, 139–155,
https://doi.org/10.1016/0012-821X(80)90125-9, 1980. a
Jeandel, C., Arsouze, T., Lacan, F., Téchiné, P., and Dutay, J. C.:
Isotopic Nd compositions and concentrations of the lithogenic inputs into
the ocean: A compilation, with an emphasis on the margins, Chem. Geol.,
239, 156–164, https://doi.org/10.1016/j.chemgeo.2006.11.013, 2007. a, b, c
Johannesson, K. H. and Burdige, D. J.: Balancing the global oceanic neodymium
budget: Evaluating the role of groundwater, Earth Planet. Sc. Lett., 253, 129–142, https://doi.org/10.1016/j.epsl.2006.10.021, 2007. a, b
John, S. G., Liang, H., Weber, T., DeVries, T., Primeau, F., Moore, K., Holzer,
M., Mahowald, N., Gardner, W., Mishonov, A., Richardson, M. J., Faugere, Y.,
and Taburet, G.: AWESOME OCIM: A simple, flexible, and powerful tool for
modeling elemental cycling in the oceans, Chem. Geol., 533, 119403,
https://doi.org/10.1016/j.chemgeo.2019.119403, 2020. a, b, c, d, e, f
Jones, K. M., Khatiwala, S. P., Goldstein, S. L., Hemming, S. R., and van de
Flierdt, T.: Modeling the distribution of Nd isotopes in the oceans using an
ocean general circulation model, Earth Planet. Sc. Lett., 272,
610–619, https://doi.org/10.1016/j.epsl.2008.05.027, 2008. a, b, c
Khatiwala, S.: A computational framework for simulation of biogeochemical
tracers in the ocean, Global Biogeochem. Cycles, 21, GB3001,
https://doi.org/10.1029/2007GB002923, 2007. a
Khatiwala, S., Visbeck, M., and Cane, M. A.: Accelerated simulation of passive
tracers in ocean circulation models, Ocean Model., 9, 51–69,
https://doi.org/10.1016/j.ocemod.2004.04.002, 2005. a
Kim, J., Goldstein, S. L., Pena, L. D., Jaume-Seguí, M., Knudson, K. P.,
Yehudai, M., and Bolge, L.: North Atlantic Deep Water during Pleistocene
interglacials and glacials, Quaternary Sci. Rev., 269, 107146,
https://doi.org/10.1016/j.quascirev.2021.107146, 2021. a
Kok, J. F., Adebiyi, A. A., Albani, S., Balkanski, Y., Checa-Garcia, R., Chin, M., Colarco, P. R., Hamilton, D. S., Huang, Y., Ito, A., Klose, M., Leung, D. M., Li, L., Mahowald, N. M., Miller, R. L., Obiso, V., Pérez García-Pando, C., Rocha-Lima, A., Wan, J. S., and Whicker, C. A.: Improved representation of the global dust cycle using observational constraints on dust properties and abundance, Atmos. Chem. Phys., 21, 8127–8167, https://doi.org/10.5194/acp-21-8127-2021, 2021a. a, b, c
Kok, J. F., Adebiyi, A. A., Albani, S., Balkanski, Y., Checa-Garcia, R., Chin, M., Colarco, P. R., Hamilton, D. S., Huang, Y., Ito, A., Klose, M., Li, L., Mahowald, N. M., Miller, R. L., Obiso, V., Pérez García-Pando, C., Rocha-Lima, A., and Wan, J. S.: Contribution of the world's main dust source regions to the global cycle of desert dust, Atmos. Chem. Phys., 21, 8169–8193, https://doi.org/10.5194/acp-21-8169-2021, 2021b. a, b, c, d
Lacan, F. and Jeandel, C.: Tracing Papua New Guinea imprint on the central
Equatorial Pacific Ocean using neodymium isotopic compositions and Rare Earth
Element patterns, Earth Planet. Sc. Lett., 186, 497–512,
https://doi.org/10.1016/S0012-821X(01)00263-1, 2001. a
Lacan, F. and Jeandel, C.: Neodymium isotopic composition and rare earth
element concentrations in the deep and intermediate Nordic Seas: Constraints
on the Iceland Scotland Overflow Water signature, Geochem. Geophys.
Geosyst., 5, Q11006, https://doi.org/10.1029/2004GC000742, 2004. a
Lagarde, M., Lemaitre, N., Planquette, H., Grenier, M., Belhadj, M., Lherminier, P., and Jeandel, C.: Particulate rare earth element behavior in the North Atlantic (GEOVIDE cruise), Biogeosciences, 17, 5539–5561, https://doi.org/10.5194/bg-17-5539-2020, 2020. a
Lambelet, M., van de Flierdt, T., Crocket, K., Rehkämper, M., Kreissig, K.,
Coles, B., Rijkenberg, M. J. A., Gerringa, L. J. A., de Baar, H. J. W., and
Steinfeldt, R.: Neodymium isotopic composition and concentration in the
western North Atlantic Ocean: Results from the GEOTRACES GA02 section,
Geochim. Cosmochim. Ac., 177, 1–29, https://doi.org/10.1016/j.gca.2015.12.019,
2016. a, b
Lambelet, M., van de Flierdt, T., Butler, E. C. V., Bowie, A. R., Rintoul,
S. R., Watson, R. J., Remenyi, T., Lannuzel, D., Warner, M., Robinson, L. F.,
Bostock, H. C., and Bradtmiller, L. I.: The Neodymium Isotope Fingerprint of
Adélie Coast Bottom Water, Geophys. Res. Lett., 45, 11247–11256,
https://doi.org/10.1029/2018GL080074, 2018. a
Laukert, G., Frank, M., Bauch, D., Hathorne, E. C., Rabe, B., von Appen,
W.-J., Wegner, C., Zieringer, M., and Kassens, H.: Ocean circulation and
freshwater pathways in the Arctic Mediterranean based on a combined Nd
isotope, REE and oxygen isotope section across Fram Strait, Geochim. Cosmochim. Ac., 202, 285–309, https://doi.org/10.1016/j.gca.2016.12.028, 2017. a, b
Laukert, G., Frank, M., Bauch, D., Hathorne, E. C., Rabe, B., von
Appen, W.-J., Wegner, C., Zieringer, M., and Kassens, H.: Neodymium
isotopes and rare earth elements measured on water bottle samples during
POLARSTERN cruise ARK-XXVII/1, PANGAEA, https://doi.org/10.1594/PANGAEA.871516, 2017a. a
Laukert, G., Frank, M., Bauch, D., Hathorne, E. C., Rabe, B., von
Appen, W.-J., Wegner, C., Zieringer, M., and Kassens, H.: Rare earth
elements measured on water bottle samples at BATS, PANGAEA,
https://doi.org/10.1594/PANGAEA.871518, 2017b. a
Laukert, G., Frank, M., Bauch, D., Hathorne, E. C., Rabe, B., von
Appen, W.-J., Wegner, C., Zieringer, M., and Kassens, H.: Rare earth
elements measured on water bottle samples at BATS, PANGAEA,
https://doi.org/10.1594/PANGAEA.871519, 2017c. a
Laukert, G., Frank, M., Bauch, D., Hathorne, E. C., Rabe, B., von
Appen, W.-J., Wegner, C., Zieringer, M., and Kassens, H.: Neodymium
isotopes and rare earth elements measured on water bottle samples during
cruise TDXXI and TDXXII, PANGAEA, https://doi.org/10.1594/PANGAEA.871517, 2017d. a
Laukert, G., Makhotin, M., Petrova, M. V., Vesman, A., Frank, M.,
Hathorne, E. C., Bauch, D., Böning, P., Kassens, H., and
Ivanov, V.: Dissolved neodymium (Nd) isotope compositions and rare earth
element (REE) concentrations along with stable oxygen isotope compositions
measured on water bottle samples collected during PU2014 to the Barents Sea
in 2014, PANGAEA, https://doi.org/10.1594/PANGAEA.895123, 2018. a
Laukert, G., Makhotin, M., Petrova, M. V., Frank, M., Hathorne, E. C., Bauch,
D., Böning, P., and Kassens, H.: Water mass transformation in the Barents
Sea inferred from radiogenic neodymium isotopes, rare earth elements and
stable oxygen isotopes, Chem. Geol., 511, 416–430,
https://doi.org/10.1016/j.chemgeo.2018.10.002, 2019. a
Luijendijk, E., Gleeson, T., and Moosdorf, N.: Geospatial data and model
results for a global model study of coastal groundwater discharge, PANGAEA,
https://doi.org/10.1594/PANGAEA.907641, 2019. a, b
Luijendijk, E., Gleeson, T., and Moosdorf, N.: Fresh groundwater discharge
insignificant for the world's oceans but important for coastal ecosystems,
Nat. Commun., 11, 1260, https://doi.org/10.1038/s41467-020-15064-8, 2020. a, b, c
McCulloch, M. T. and Wasserburg, G. J.: Sm-Nd and Rb-Sr Chronology of
Continental Crust Formation, Science, 200, 1003–1011,
https://doi.org/10.1126/science.200.4345.1003, 1978. a, b
Mogensen, P. K. and Riseth, A. N.: Optim: A mathematical optimization package
for Julia, J. Open Source Softw., 3, 615,
https://doi.org/10.21105/joss.00615, 2018. a
Morrison, R., Waldner, A., Hathorne, E., Rahlf, P., Zieringer, M., Montagna,
P., Colin, C., Frank, N., and Frank, M.: Limited influence of basalt
weathering inputs on the seawater neodymium isotope composition of the
northern Iceland Basin, Chem. Geol., 511, 358–370,
https://doi.org/10.1016/j.chemgeo.2018.10.019, 2019. a
Morse, P. M., Feshbach, H., et al.: Methods of theoretical physics, McGraw-Hill
New York, 1953. a
Najjar, R. G., Jin, X., Louanchi, F., Aumont, O., Caldeira, K., Doney, S. C.,
Dutay, J.-C., Follows, M., Gruber, N., Joos, F., Lindsay, K., Maier-Reimer,
E., Matear, R. J., Matsumoto, K., Monfray, P., Mouchet, A., Orr, J. C.,
Plattner, G.-K., Sarmiento, J. L., Schlitzer, R., Slater, R. D., Weirig,
M.-F., Yamanaka, Y., and Yool, A.: Impact of circulation on export
production, dissolved organic matter, and dissolved oxygen in the ocean:
Results from Phase II of the Ocean Carbon-cycle Model Intercomparison Project
(OCMIP-2), Global Biogeochem. Cycles, 21, GB3007, https://doi.org/10.1029/2006GB002857,
2007. a
Nocedal, J. and Wright, S. J. (Eds.): Numerical optimization, Springer Verlag, 35,
7, https://doi.org/10.1007/b98874, 1999. a
O'Nions, R. K., Carter, S. R., Cohen, R. S., Evensen, N. M., and Hamilton,
P. J.: Pb, Nd and Sr isotopes in oceanic ferromanganese deposits and ocean
floor basalts, Nature, 273, 435–438, https://doi.org/10.1038/273435a0, 1978. a
Palmer, M. R. and Elderfield, H.: Variations in the Nd isotopic composition of
foraminifera from Atlantic Ocean sediments, Earth Planet. Sc. Lett., 73, 299–305, https://doi.org/10.1016/0012-821X(85)90078-0, 1985. a
Pasquier, B.: F-1 Method: A julia package for autodiff through a steady-state
solver, Zenodo, https://doi.org/10.5281/zenodo.2667835, 2020b. a, b
Pasquier, B.: Post-IDP17 Nd data, Figshare [data set], https://doi.org/10.6084/m9.figshare.15058329.v1, 2021. a
Pasquier, B. and Holzer, M.: Inverse-model estimates of the ocean's coupled phosphorus, silicon, and iron cycles, Biogeosciences, 14, 4125–4159, https://doi.org/10.5194/bg-14-4125-2017, 2017. a
Pasquier, B. and Holzer, M.: The number of past and future regenerations of iron in the ocean
and its intrinsic fertilization efficiency, Biogeosciences, 15, 7177–7203, https://doi.org/10.5194/bg-15-7177-2018, 2018. a
Pasquier, B., Hines, S. K. V., Liang, H., Wu, Y., Goldstein, S. L., and John, S. G.: GNOM: An optimized steady-state model of the modern global marine neodymium cycle (v1.0.2), Zenodo [data set], https://doi.org/10.5281/zenodo.6118414, 2022a. a, b
Pearce, C. R., Jones, M. T., Oelkers, E. H., Pradoux, C., and Jeandel, C.: The
effect of particulate dissolution on the neodymium (Nd) isotope and Rare
Earth Element (REE) composition of seawater, Earth Planet. Sc. Lett., 369, 138–147, https://doi.org/10.1016/j.epsl.2013.03.023, 2013. a, b
Pena, L., Goldstein, S., Hemming, S., Jones, K., Calvo, E., Pelejero, C., and
Cacho, I.: Rapid changes in meridional advection of Southern Ocean
intermediate waters to the tropical Pacific during the last 30 kyr, Earth Planet. Sc. Lett., 368, 20–32, https://doi.org/10.1016/j.epsl.2013.02.028,
2013. a
Pena, L. D. and Goldstein, S. L.: Thermohaline circulation crisis and impacts
during the mid-Pleistocene transition, Science, 345, 318–322,
https://doi.org/10.1126/science.1249770, 2014. a
Peng, R. D.: Reproducible Research in Computational Science, Science, 334,
1226–1227, https://doi.org/10.1126/science.1213847, 2011. a
Piepgras, D. and Wasserburg, G.: Strontium and neodymium isotopes in hot
springs on the East Pacific Rise and Guaymas Basin, Earth Planet. Sc. Lett., 72, 341–356, https://doi.org/10.1016/0012-821X(85)90057-3, 1985. a
Piepgras, D., Wasserburg, G., and Dasch, E.: The isotopic composition of Nd in
different ocean masses, Earth Planet. Sc. Lett., 45, 223–236,
https://doi.org/10.1016/0012-821X(79)90125-0, 1979. a
Piepgras, D. J. and Jacobsen, S. B.: The behavior of rare earth elements in
seawater: Precise determination of variations in the North Pacific water
column, Geochim. Cosmochim. Ac., 56, 1851–1862,
https://doi.org/10.1016/0016-7037(92)90315-A, 1992. a
Piepgras, D. J. and Wasserburg, G.: Neodymium Isotopic Variations in
Seawater, Earth Planet. Sc. Lett., 50, 128–138,
https://doi.org/10.1016/0012-821X(80)90124-7, 1980. a, b, c
Piotrowski, A. M., Goldstein, S. L., Hemming, S. R., and Fairbanks, R. G.:
Intensification and variability of ocean thermohaline circulation through the
last deglaciation, Earth Planet. Sc. Lett., 225, 205–220,
https://doi.org/10.1016/j.epsl.2004.06.002, 2004. a
Piotrowski, A. M., Goldstein, S. L., Hemming, S. R., and Fairbanks, R. G.:
Temporal Relationships of Carbon Cycling and Ocean Circulation at Glacial
Boundaries, Science, 307, 1933–1938, https://doi.org/10.1126/science.1104883, 2005. a
Piotrowski, A. M., Goldstein, S. L., Sidney, R. H., Fairbanks, R. G., and
Zylberberg, D. R.: Oscillating glacial northern and southern deep water
formation from combined neodymium and carbon isotopes, Earth Planet. Sc. Lett., 272, 394–405, https://doi.org/10.1016/j.epsl.2008.05.011, 2008. a
Piper, D. Z.: Rare earth elements in the sedimentary cycle: a summary,
Chem. Geol., 14, 285–304, https://doi.org/10.1016/0009-2541(74)90066-7, 1974. a
Pöppelmeier, F., Blaser, P., Gutjahr, M., Süfke, F., Thornalley, D.
J. R., Grützner, J., Jakob, K. A., Link, J. M., Szidat, S., and Lippold,
J.: Influence of Ocean Circulation and Benthic Exchange on Deep Northwest
Atlantic Nd Isotope Records During the Past 30,000 Years, Geochem.
Geophys. Geosyst., 20, 4457–4469, https://doi.org/10.1029/2019gc008271, 2019. a
Pöppelmeier, F., Scheen, J., Blaser, P., Lippold, J., Gutjahr, M., and
Stocker, T. F.: Influence of Elevated Nd Fluxes on the Northern Nd Isotope
End Member of the Atlantic During the Early Holocene, Paleoceanogr.
Paleoclimatol., 35, e2020PA003973, https://doi.org/10.1029/2020pa003973, 2020. a, b, c, d
Pöppelmeier, F., Gutjahr, M., Blaser, P., Schulz, H., Süfke, F., and
Lippold, J.: Stable Atlantic Deep Water Mass Sourcing on Glacial-Interglacial
Timescales, Geophys. Res. Lett., 48, e2021GL092722,
https://doi.org/10.1029/2021GL092722, 2021. a
Primeau, F. W.: Characterizing Transport between the Surface Mixed Layer and
the Ocean Interior with a Forward and Adjoint Global Ocean Transport Model,
J. Phys. Oceanogr., 35, 545–564, https://doi.org/10.1175/JPO2699.1, 2005. a
Rahlf, P., Frank, M., and Hathorne, E. C.: Neodymium isotopes from water
bottle samples measured during METEOR cruise M121 (GEOTRACES cruise GA08),PANGAEA,
https://doi.org/10.1594/PANGAEA.907825, 2019. a
Rahlf, P., Hathorne, E., Laukert, G., Gutjahr, M., Weldeab, S., Frank, M.,
Rahlf, P., Hathorne, E., Laukert, G., Gutjahr, M., Weldeab, S., and Frank,
M.: Tracing water mass mixing and continental inputs in the southeastern
Atlantic Ocean with dissolved neodymium isotopes, Earth Planet. Sc. Lett., 530, 115944, https://doi.org/10.1016/j.epsl.2019.115944, 2020. a
Rahlf, P., Laukert, G., Hathorne, E. C., Vieira, L. H., and Frank,
M.: Neodymium and hafnium isotopes and rare earth element concentrations
from water bottle samples measured during METEOR cruise M121 along the Congo
River plume (GEOTRACES cruise GA08), PANGAEA, https://doi.org/10.1594/PANGAEA.925602, 2020. a
Rahlf, P., Laukert, G., Hathorne, E. C., Vieira, L. H., and Frank, M.:
Dissolved neodymium and hafnium isotopes and rare earth elements in the Congo
River Plume: Tracing and quantifying continental inputs into the southeast
Atlantic, Geochim. Cosmochim. Ac., 294, 192–214,
https://doi.org/10.1016/j.gca.2020.11.017, 2021. a
Rempfer, J., Stocker, T. F., Joos, F., Dutay, J.-C., and Siddall, M.:
Modelling Nd-isotopes with a coarse resolution ocean circulation model:
Sensitivities to model parameters and source/sink distributions, Geochim. Cosmochim. Ac., 75, 5927–5950, https://doi.org/10.1016/j.gca.2011.07.044, 2011. a, b, c, d
Robinson, S., Ivanovic, R., van de Flierdt, T., Blanchet, C. L., Tachikawa,
K., Martin, E. E., Cook, C. P., Williams, T., Gregoire, L., Plancherel, Y.,
Jeandel, C., and Arsouze, T.: Global continental and marine detrital εNd: An
updated compilation for use in understanding marine Nd cycling, Chem. Geol., 567, 120119, https://doi.org/10.1016/j.chemgeo.2021.120119, 2021. a, b, c, d, e, f, g, h, i
Rutberg, R. L., Hemming, S. R., and Goldstein, S. L.: Reduced North Atlantic
Deep Water flux to the glacial Southern Ocean inferred from neodymium isotope
ratios, Nature, 405, 935–938, https://doi.org/10.1038/35016049, 2000. a
Scanza, R. A., Hamilton, D. S., Perez Garcia-Pando, C., Buck, C., Baker, A., and Mahowald, N. M.: Atmospheric processing of iron in mineral and combustion aerosols: development of an intermediate-complexity mechanism suitable for Earth system models, Atmos. Chem. Phys., 18, 14175–14196, https://doi.org/10.5194/acp-18-14175-2018, 2018. a, b
Schijf, J., Christenson, E. A., and Byrne, R. H.: YREE scavenging in
seawater: A new look at an old model, Marine Chemistry, 177, 460–471,
https://doi.org/10.1016/j.marchem.2015.06.010, 2015. a
Schlitzer, R., Anderson, R. F., Dodas, E. M., Lohan, M., Geibert, W.,
Tagliabue, A., Bowie, A., Jeandel, C., Maldonado, M. T., Landing, W. M.,
Cockwell, D., Abadie, C., Abouchami, W., Achterberg, E. P., Agather, A.,
Aguliar-Islas, A., van Aken, H. M., Andersen, M., Archer, C., Auro, M., de
Baar, H. J., Baars, O., Baker, A. R., Bakker, K., Basak, C., Baskaran, M.,
Bates, N. R., Bauch, D., van Beek, P., Behrens, M. K., Black, E., Bluhm,
K., Bopp, L., Bouman, H., Bowman, K., Bown, J., Boyd, P., Boye, M., Boyle,
E. A., Branellec, P., Bridgestock, L., Brissebrat, G., Browning, T., Bruland,
K. W., Brumsack, H.-J., Brzezinski, M., Buck, C. S., Buck, K. N., Buesseler,
K., Bull, A., Butler, E., Cai, P., Mor, P. C., Cardinal, D., Carlson, C.,
Carrasco, G., Casacuberta, N., Casciotti, K. L., Castrillejo, M., Chamizo,
E., Chance, R., Charette, M. A., Chaves, J. E., Cheng, H., Chever, F.,
Christl, M., Church, T. M., Closset, I., Colman, A., Conway, T. M., Cossa,
D., Croot, P., Cullen, J. T., Cutter, G. A., Daniels, C., Dehairs, F., Deng,
F., Dieu, H. T., Duggan, B., Dulaquais, G., Dumousseaud, C., Echegoyen-Sanz,
Y., Edwards, R. L., Ellwood, M., Fahrbach, E., Fitzsimmons, J. N., Russell
Flegal, A., Fleisher, M. Q., van de Flierdt, T., Frank, M., Friedrich, J.,
Fripiat, F., Fröllje, H., Galer, S. J., Gamo, T., Ganeshram, R. S.,
Garcia-Orellana, J., Garcia-Solsona, E., Gault-Ringold, M., George, E.,
Gerringa, L. J., Gilbert, M., Godoy, J. M., Goldstein, S. L., Gonzalez,
S. R., Grissom, K., Hammerschmidt, C., Hartman, A., Hassler, C. S., Hathorne,
E. C., Hatta, M., Hawco, N., Hayes, C. T., Heimbürger, L.-E., Helgoe, J.,
Heller, M., Henderson, G. M., Henderson, P. B., van Heuven, S., Ho, P.,
Horner, T. J., Hsieh, Y.-T., Huang, K.-F., Humphreys, M. P., Isshiki, K.,
Jacquot, J. E., Janssen, D. J., Jenkins, W. J., John, S., Jones, E. M.,
Jones, J. L., Kadko, D. C., Kayser, R., Kenna, T. C., Khondoker, R., Kim, T.,
Kipp, L., Klar, J. K., Klunder, M., Kretschmer, S., Kumamoto, Y., Laan, P.,
Labatut, M., Lacan, F., Lam, P. J., Lambelet, M., Lamborg, C. H., Le
Moigne, F. A., Le Roy, E., Lechtenfeld, O. J., Lee, J.-M., Lherminier, P.,
Little, S., López-Lora, M., Lu, Y., Masque, P., Mawji, E., Mcclain, C. R.,
Measures, C., Mehic, S., Barraqueta, J.-L. M., van der Merwe, P., Middag,
R., Mieruch, S., Milne, A., Minami, T., Moffett, J. W., Moncoiffe, G., Moore,
W. S., Morris, P. J., Morton, P. L., Nakaguchi, Y., Nakayama, N.,
Niedermiller, J., Nishioka, J., Nishiuchi, A., Noble, A., Obata, H., Ober,
S., Ohnemus, D. C., van Ooijen, J., O'Sullivan, J., Owens, S., Pahnke, K.,
Paul, M., Pavia, F., Pena, L. D., Peters, B., Planchon, F., Planquette, H.,
Pradoux, C., Puigcorbé, V., Quay, P., Queroue, F., Radic, A., Rauschenberg,
S., Rehkämper, M., Rember, R., Remenyi, T., Resing, J. A., Rickli, J.,
Rigaud, S., Rijkenberg, M. J., Rintoul, S., Robinson, L. F., Roca-Martí, M.,
Rodellas, V., Roeske, T., Rolison, J. M., Rosenberg, M., Roshan, S., Rutgers
van der Loeff, M. M., Ryabenko, E., Saito, M. A., Salt, L. A., Sanial, V.,
Sarthou, G., Schallenberg, C., Schauer, U., Scher, H., Schlosser, C.,
Schnetger, B., Scott, P., Sedwick, P. N., Semiletov, I., Shelley, R.,
Sherrell, R. M., Shiller, A. M., Sigman, D. M., Singh, S. K., Slagter, H. A.,
Slater, E., Smethie, W. M., Snaith, H., Sohrin, Y., Sohst, B., Sonke, J. E.,
Speich, S., Steinfeldt, R., Stewart, G., Stichel, T., Stirling, C. H.,
Stutsman, J., Swarr, G. J., Swift, J. H., Thomas, A., Thorne, K., Till,
C. P., Till, R., Townsend, A. T., Townsend, E., Tuerena, R., Twining, B. S.,
Vance, D., Velazquez, S., Venchiarutti, C., Villa-Alfageme, M., Vivancos,
S. M., Voelker, A. H., Wake, B., Warner, M. J., Watson, R., van Weerlee,
E., Alexandra Weigand, M., Weinstein, Y., Weiss, D., Wisotzki, A.,
Woodward, E. M. S., Wu, J., Wu, Y., Wuttig, K., Wyatt, N., Xiang, Y., Xie,
R. C., Xue, Z., Yoshikawa, H., Zhang, J., Zhang, P., Zhao, Y., Zheng, L.,
Zheng, X.-Y., Zieringer, M., Zimmer, L. A., Ziveri, P., Zunino, P., and
Zurbrick, C.: The GEOTRACES Intermediate Data Product 2017, Chem. Geol., 493, 210–223, https://doi.org/10.1016/j.chemgeo.2018.05.040, 2018. a, b, c
Sholkovitz, E., Shaw, T., and Schneider, D.: The geochemistry of rare earth
elements in the seasonally anoxic water column and porewaters of Chesapeake
Bay, Geochim. Cosmochim. Ac., 56, 3389–3402,
https://doi.org/10.1016/0016-7037(92)90386-w, 1992. a, b
Sholkovitz, E. R. and Schneider, D. L.: Cerium redox cycles and rare earth
elements in the Sargasso Sea, Geochim. Cosmochim. Ac., 55,
2737–2743, https://doi.org/10.1016/0016-7037(91)90440-G, 1991. a
Sholkovitz, E. R., Piepgras, D. J., and Jacobsen, S. B.: The pore water
chemistry of rare earth elements in Buzzards Bay sediments, Geochim. Cosmochim. Ac., 53, 2847–2856, https://doi.org/10.1016/0016-7037(89)90162-2, 1989. a, b, c
Sholkovitz, E. R., Landing, W. M., and Lewis, B. L.: Ocean particle chemistry:
The fractionation of rare earth elements between suspended particles and
seawater, Geochim. Cosmochim. Ac., 58, 1567–1579,
https://doi.org/10.1016/0016-7037(94)90559-2, 1994. a, b
Siddall, M., Khatiwala, S., van de Flierdt, T., Jones, K., Goldstein, S. L.,
Hemming, S., and Anderson, R. F.: Towards explaining the Nd paradox using
reversible scavenging in an ocean general circulation model, Earth Planet. Sc. Lett., 274, 448–461, https://doi.org/10.1016/j.epsl.2008.07.044,
2008. a, b, c, d
Sigman, D. M., Hain, M. P., and Haug, G. H.: The polar ocean and glacial
cycles in atmospheric CO2 concentration, Nature, 466, 47–55,
https://doi.org/10.1038/nature09149, 2010. a
Stichel, T., Frank, M., Rickli, J., and Haley, B. A.: The hafnium and
neodymium isotope composition of seawater in the Atlantic sector of the
Southern Ocean, Earth Planet. Sc. Lett., 317–318, 282–294,
https://doi.org/10.1016/j.epsl.2011.11.025, 2012a. a, b
Stichel, T., Frank, M., Rickli, J., Hathorne, E. C., Haley, B. A., Jeandel, C.,
and Pradoux, C.: Sources and input mechanisms of hafnium and neodymium in
surface waters of the Atlantic sector of the Southern Ocean, Geochim. Cosmochim. Ac., 94, 1–50, https://doi.org/10.1016/j.gca.2012.07.005,
2012b. a
Stichel, T., Hartman, A. E., Duggan, B., Goldstein, S. L., Scher, H., and
Pahnke, K.: Separating biogeochemical cycling of neodymium from water mass
mixing in the Eastern North Atlantic, Earth Planet. Sc. Lett.,
412, 245–260, https://doi.org/10.1016/j.epsl.2014.12.008, 2015. a
Stichel, T., Pahnke, K., Duggan, B., Goldstein, S. L., Hartman, A. E.,
Paffrath, R., and Scher, H. D.: TAG Plume: Revisiting the Hydrothermal
Neodymium Contribution to Seawater, Front. Marine Sci., 5, 96,
https://doi.org/10.3389/fmars.2018.00096, 2018. a, b, c
Stichel, T., Kretschmer, S., Geibert, W., Lambelet, M., Plancherel, Y., Rutgers
van der Loeff, M. M., and van de Flierdt, T.: Particle–Seawater Interaction
of Neodymium in the North Atlantic, ACS Earth and Space Chemistry, 4,
1700–1717, https://doi.org/10.1021/acsearthspacechem.0c00034, 2020. a
Stichel, T., Kretschmer, S., Geibert, W., Lambelet, M., Plancherel,
Y., Rutgers van der Loeff, M. M., and van de Flierdt, T.: Particulate
Neodymium Isotopes and Concentrations in the Western North Atlantic, PANGAEA,
https://doi.org/10.1594/PANGAEA.922598, 2020. a
Tachikawa, K., Athias, V., and Jeandel, C.: Neodymium budget in the modern
ocean and paleo-oceanographic implications, J. Geophys. Res.-Oceans, 108, 3254, https://doi.org/10.1029/1999JC000285, 2003. a, b
Tachikawa, K., Arsouze, T., Bayon, G., Bory, A., Colin, C., Dutay, J.-C.,
Frank, N., Giraud, X., Gourlan, A. T., Jeandel, C., Lacan, F., Meynadier, L.,
Montagna, P., Piotrowski, A. M., Plancherel, Y., Pucéat, E., Roy-Barman,
M., and Waelbroeck, C.: The large-scale evolution of neodymium isotopic
composition in the global modern and Holocene ocean revealed from seawater
and archive data, Chem. Geol., 457, 131–148,
https://doi.org/10.1016/j.chemgeo.2017.03.018, 2017.
a
Tantau, T., Wibrow, M., Feuersänger, C., et al.: The TikZ and PGF Packages, Manual for version 3.1.9a,
https://github.com/pgf-tikz/pgf, last access: 26 May 2022. a
van de Flierdt, T., Robinson, L. F., Adkins, J. F., Hemming, S. R., and
Goldstein, S. L.: Temporal stability of the neodymium isotope signature of
the Holocene to glacial North Atlantic, Paleoceanography, 21, PA4102,
https://doi.org/10.1029/2006PA001294, 2006. a
van de Flierdt, T., Griffiths, A. M., Lambelet, M., Little, S. H., Stichel, T.,
and Wilson, D. J.: Neodymium in the oceans: a global database, a regional
comparison and implications for palaeoceanographic research, Philosophical
Transactions of the Royal Society A: Mathematical, Phys. Eng.
Sci., 374, 20150293, https://doi.org/10.1098/rsta.2015.0293, 2016a. a, b, c, d, e
van de Flierdt, T., Griffiths, A. M., Lambelet, M., Little, S. H., Stichel, T., and Wilson, D. J.: Global Database from Neodymium in the oceans: a global database, a regional comparison and implications for palaeoceanographic research, The Royal Society [data set], https://doi.org/10.6084/m9.figshare.3980064.v1, 2016b. a
van Hulten, M., Dutay, J.-C., and Roy-Barman, M.: A global scavenging and circulation ocean model of thorium-230 and protactinium-231 with improved particle dynamics (NEMO–ProThorP 0.1), Geosci. Model Dev., 11, 3537–3556, https://doi.org/10.5194/gmd-11-3537-2018, 2018. a
von Blanckenburg, F. and Nägler, T. F.: Weathering versus
circulation-controlled changes in radiogenic isotope tracer composition of
the Labrador Sea and North Atlantic Deep Water, Paleoceanography, 16,
424–434, https://doi.org/10.1029/2000PA000550, 2001. a, b, c
Weber, T., John, S., Tagliabue, A., and DeVries, T.: Biological uptake and
reversible scavenging of zinc in the global ocean, Science, 361, 72–76,
https://doi.org/10.1126/science.aap8532, 2018. a, b
Wilson, D. J., Piotrowski, A. M., Galy, A., and Clegg, J. A.: Reactivity of
neodymium carriers in deep sea sediments: Implications for boundary exchange
and paleoceanography, Geochim. Cosmochim. Ac., 109, 197–221,
https://doi.org/10.1016/j.gca.2013.01.042, 2013. a, b, c, d
Wu, Y.: Investigating the Applications of Neodymium Isotopic Compositions and
Rare Earth Elements as Water Mass Tracers in the South Atlantic and North
Pacific, Academic Commons, Columbia University Libraries, https://doi.org/10.7916/D8-KSTX-XG38, 2019. a
Wu, Y., Pena, L. D., Goldstein, S. L., Anderson, R. F., Hartman, A. E., Bolge,
L. L., Basak, C., Rijkenberg, M. J. A., and de Baar, H. J. W.: Assessing
neodymium isotopes as an ocean circulation tracer in the Southwest Atlantic,
Earth Planet. Sc. Lett., in review, 2022. a
Zheng, X.-Y., Plancherel, Y., Saito, M. A., Scott, P. M., and Henderson, G. M.:
Rare earth elements (REEs) in the tropical South Atlantic and quantitative
deconvolution of their non-conservative behavior, Geochim. Cosmochim.
Ac., 177, 217–237, https://doi.org/10.1016/j.gca.2016.01.018, 2016. a
Short summary
Neodymium isotopes in seawater have the potential to provide key information about ocean circulation, both today and in the past. This can shed light on the underlying drivers of global climate, which will improve our ability to predict future climate change, but uncertainties in our understanding of neodymium cycling have limited use of this tracer. We present a new model of neodymium in the modern ocean that runs extremely fast, matches observations, and is freely available for development.
Neodymium isotopes in seawater have the potential to provide key information about ocean...