Articles | Volume 17, issue 12
https://doi.org/10.5194/gmd-17-5009-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/gmd-17-5009-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Development and technical paper
| 
27 Jun 2024
Development and technical paper |
| 27 Jun 2024
| 27 Jun 2024
A computationally efficient parameterization of aerosol, cloud and precipitation pH for application at global and regional scale (EQSAM4Clim-v12)
ResearchConcepts Io GmbH, Freiburg, Germany
Samuel Rémy
HYGEOS, Lille, France
Jason E. Williams
R and D Weather and Climate modeling, Royal Netherlands Meteorological Institute, De Bilt, the Netherlands
Vincent Huijnen
R and D Weather and Climate modeling, Royal Netherlands Meteorological Institute, De Bilt, the Netherlands
Johannes Flemming
European Centre for Medium-Range Weather Forecasts, Bonn, Germany
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Simon Chabrillat, Samuel Rémy, Quentin Errera, Vincent Huijnen, Christine Bingen, Jonas Debosscher, François Hendrick, Swen Metzger, Adrien Mora, Daniele Minganti, Marc Op de beek, Léa Reisenfeld, Jason E. Williams, Henk Eskes, and Johannes Flemming
EGUsphere, https://doi.org/10.5194/egusphere-2025-1327, https://doi.org/10.5194/egusphere-2025-1327, 2025
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We document the forecasts of the composition of the stratosphere by the Copernicus Atmosphere Monitoring Service. The model's predictions are compared with satellite measurements over a recent period, during polar ozone depletion events, and after the Mount Pinatubo volcanic eruption. The system performs well for sulfate aerosols, ozone and several other key gases but not as well for several nitrogen-containing gases. Chemical processes in aerosols and polar clouds should be improved.
Jason Williams, Swen Metzer, Samuel Remy, Vincent Huijnen, and Johannes Flemming
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2024-188, https://doi.org/10.5194/gmd-2024-188, 2024
Preprint under review for GMD
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One of the main constituents of Particulate Matter at the surface are Secondary Inorganic Aerosols (SIA) which are influenced by both anthropogenic emissions and the acidity of clouds and aerosols. This study shows improvements in introduced into the IFS-COMPO simulating the surface concentrations of SIA and the resulting changes in the total wet deposition for Europe, the US and South-East Asia.
Samuel Rémy, Swen Metzger, Vincent Huijnen, Jason E. Williams, and Johannes Flemming
Geosci. Model Dev., 17, 7539–7567, https://doi.org/10.5194/gmd-17-7539-2024, https://doi.org/10.5194/gmd-17-7539-2024, 2024
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In this paper we describe the development of the future operational cycle 49R1 of the IFS-COMPO system, used for operational forecasts of atmospheric composition in the CAMS project, and focus on the implementation of the thermodynamical model EQSAM4Clim version 12. The implementation of EQSAM4Clim significantly improves the simulated secondary inorganic aerosol surface concentration. The new aerosol and precipitation acidity diagnostics showed good agreement against observational datasets.
Gunnar Myhre, Øivind Hodnebrog, Srinath Krishnan, Maria Sand, Marit Sandstad, Ragnhild B. Skeie, Lieven Clarisse, Bruno Franco, Dylan B. Millet, Kelley C. Wells, Alexander Archibald, Hannah N. Bryant, Alex T. Chaudhri, David S. Stevenson, Didier Hauglustaine, Michael Prather, J. Christopher Kaiser, Dirk J. L. Olivie, Michael Schulz, Oliver Wild, Ye Wang, Thérèse Salameh, Jason E. Williams, Philippe Le Sager, Fabien Paulot, Kostas Tsigaridis, and Haley E. Plaas
EGUsphere, https://doi.org/10.5194/egusphere-2025-3057, https://doi.org/10.5194/egusphere-2025-3057, 2025
This preprint is open for discussion and under review for Geoscientific Model Development (GMD).
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Volatile organic compounds (VOCs) affect air quality and climate, but their behavior in the atmosphere is still uncertain. We launched a global research effort to compare how different models represent these compounds and to improve their accuracy. By analyzing model results alongside observations and satellite data, we aim to better understand the atmospheric composition of these compounds.
Yunqian Zhu, Hideharu Akiyoshi, Valentina Aquila, Elizabeth Asher, Ewa M. Bednarz, Slimane Bekki, Christoph Brühl, Amy H. Butler, Parker Case, Simon Chabrillat, Gabriel Chiodo, Margot Clyne, Peter R. Colarco, Sandip Dhomse, Lola Falletti, Eric Fleming, Ben Johnson, Andrin Jörimann, Mahesh Kovilakam, Gerbrand Koren, Ales Kuchar, Nicolas Lebas, Qing Liang, Cheng-Cheng Liu, Graham Mann, Michael Manyin, Marion Marchand, Olaf Morgenstern, Paul Newman, Luke D. Oman, Freja F. Østerstrøm, Yifeng Peng, David Plummer, Ilaria Quaglia, William Randel, Samuel Rémy, Takashi Sekiya, Stephen Steenrod, Timofei Sukhodolov, Simone Tilmes, Kostas Tsigaridis, Rei Ueyama, Daniele Visioni, Xinyue Wang, Shingo Watanabe, Yousuke Yamashita, Pengfei Yu, Wandi Yu, Jun Zhang, and Zhihong Zhuo
Geosci. Model Dev., 18, 5487–5512, https://doi.org/10.5194/gmd-18-5487-2025, https://doi.org/10.5194/gmd-18-5487-2025, 2025
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To understand the climate impact of the 2022 Hunga volcanic eruption, we developed a climate model–observation comparison project. The paper describes the protocols and models that participate in the experiments. We designed several experiments to achieve our goals of this activity: (1) to evaluate the climate model performance and (2) to understand the Earth system responses to this eruption.
Paolo Andreozzi, Mark D. Fielding, Robin J. Hogan, Richard M. Forbes, Samuel Rémy, Birger Bohn, and Ulrich Löhnert
EGUsphere, https://doi.org/10.5194/egusphere-2025-3790, https://doi.org/10.5194/egusphere-2025-3790, 2025
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
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Aerosols significantly contribute to the Earth’s climate, but models still struggle at representing them. Here we use satellite observations of clouds to improve aerosols in our weather and air-quality model. We show that African wildfires induce too bright simulated clouds and that our model removes too much aerosol from ice-containing clouds. This showcases how our approach effectively targets poorly observed aerosol processes, potentially informing weather forecasting and climate models.
Anam M. Khan, Olivia E. Clifton, Jesse O. Bash, Sam Bland, Nathan Booth, Philip Cheung, Lisa Emberson, Johannes Flemming, Erick Fredj, Stefano Galmarini, Laurens Ganzeveld, Orestis Gazetas, Ignacio Goded, Christian Hogrefe, Christopher D. Holmes, László Horváth, Vincent Huijnen, Qian Li, Paul A. Makar, Ivan Mammarella, Giovanni Manca, J. William Munger, Juan L. Pérez-Camanyo, Jonathan Pleim, Limei Ran, Roberto San Jose, Donna Schwede, Sam J. Silva, Ralf Staebler, Shihan Sun, Amos P. K. Tai, Eran Tas, Timo Vesala, Tamás Weidinger, Zhiyong Wu, Leiming Zhang, and Paul C. Stoy
Atmos. Chem. Phys., 25, 8613–8635, https://doi.org/10.5194/acp-25-8613-2025, https://doi.org/10.5194/acp-25-8613-2025, 2025
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Vegetation removes tropospheric ozone through stomatal uptake, and accurately modeling the stomatal uptake of ozone is important for modeling dry deposition and air quality. We evaluated the stomatal component of ozone dry deposition modeled by atmospheric chemistry models at six sites. We find that models and observation-based estimates agree at times during the growing season at all sites, but some models overestimated the stomatal component during the dry summers at a seasonally dry site.
Simon Chabrillat, Samuel Rémy, Quentin Errera, Vincent Huijnen, Christine Bingen, Jonas Debosscher, François Hendrick, Swen Metzger, Adrien Mora, Daniele Minganti, Marc Op de beek, Léa Reisenfeld, Jason E. Williams, Henk Eskes, and Johannes Flemming
EGUsphere, https://doi.org/10.5194/egusphere-2025-1327, https://doi.org/10.5194/egusphere-2025-1327, 2025
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We document the forecasts of the composition of the stratosphere by the Copernicus Atmosphere Monitoring Service. The model's predictions are compared with satellite measurements over a recent period, during polar ozone depletion events, and after the Mount Pinatubo volcanic eruption. The system performs well for sulfate aerosols, ozone and several other key gases but not as well for several nitrogen-containing gases. Chemical processes in aerosols and polar clouds should be improved.
Takashi Sekiya, Emanuele Emili, Kazuyuki Miyazaki, Antje Inness, Zhen Qu, R. Bradley Pierce, Dylan Jones, Helen Worden, William Y. Y. Cheng, Vincent Huijnen, and Gerbrand Koren
Atmos. Chem. Phys., 25, 2243–2268, https://doi.org/10.5194/acp-25-2243-2025, https://doi.org/10.5194/acp-25-2243-2025, 2025
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Five global chemical reanalysis datasets were used to assess the relative impacts of assimilating satellite ozone and its precursor measurements on tropospheric ozone analyses for 2010. The multiple reanalysis system comparison allows an evaluation of the dependency of the impacts on different reanalysis systems. The results suggested the importance of satellite ozone and its precursor measurements for improving ozone analysis in the whole troposphere, with varying magnitudes among the systems.
Yutao Chen, Ronald J. van der A, Jieying Ding, Henk Eskes, Jason E. Williams, Nicolas Theys, Athanasios Tsikerdekis, and Pieternel F. Levelt
Atmos. Chem. Phys., 25, 1851–1868, https://doi.org/10.5194/acp-25-1851-2025, https://doi.org/10.5194/acp-25-1851-2025, 2025
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There is a lack of local SO2 top-down emission inventories in India. With the improvement in the divergence method and the derivation of SO2 local lifetime, gridded SO2 emissions over a large area can be estimated efficiently. This method can be applied to any region in the world to derive SO2 emissions. Especially for regions with high latitudes, our methodology has the potential to significantly improve the top-down derivation of SO2 emissions.
Mariya Petrenko, Ralph Kahn, Mian Chin, Susanne E. Bauer, Tommi Bergman, Huisheng Bian, Gabriele Curci, Ben Johnson, Johannes W. Kaiser, Zak Kipling, Harri Kokkola, Xiaohong Liu, Keren Mezuman, Tero Mielonen, Gunnar Myhre, Xiaohua Pan, Anna Protonotariou, Samuel Remy, Ragnhild Bieltvedt Skeie, Philip Stier, Toshihiko Takemura, Kostas Tsigaridis, Hailong Wang, Duncan Watson-Parris, and Kai Zhang
Atmos. Chem. Phys., 25, 1545–1567, https://doi.org/10.5194/acp-25-1545-2025, https://doi.org/10.5194/acp-25-1545-2025, 2025
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We compared smoke plume simulations from 11 global models to each other and to satellite smoke amount observations aimed at constraining smoke source strength. In regions where plumes are thick and background aerosol is low, models and satellites compare well. However, the input emission inventory tends to underestimate in many places, and particle property and loss rate assumptions vary enormously among models, causing uncertainties that require systematic in situ measurements to resolve.
Dylan Jones, Lucas Prates, Zhen Qu, William Cheng, Kazuyuki Miyazaki, Takashi Sekiya, Antje Inness, Rajesh Kumar, Xiao Tang, Helen Worden, Gerbrand Koren, and Vincent Huijen
EGUsphere, https://doi.org/10.5194/egusphere-2024-3759, https://doi.org/10.5194/egusphere-2024-3759, 2025
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We evaluate five chemical reanalysis products to assess their potential to provide useful information on tropospheric ozone variability. We find that the reanalyses produce consistent information on ozone variations in the free troposphere, but have large discrepancies at the surface. The results suggests that improvements in the reanalyses are needed to better exploit the assimilated observations to enhance the utility of the reanalysis products at the surface.
Augustin Colette, Gaëlle Collin, François Besson, Etienne Blot, Vincent Guidard, Frederik Meleux, Adrien Royer, Valentin Petiot, Claire Miller, Oihana Fermond, Alizé Jeant, Mario Adani, Joaquim Arteta, Anna Benedictow, Robert Bergström, Dene Bowdalo, Jorgen Brandt, Gino Briganti, Ana C. Carvalho, Jesper Heile Christensen, Florian Couvidat, Ilia D’Elia, Massimo D’Isidoro, Hugo Denier van der Gon, Gaël Descombes, Enza Di Tomaso, John Douros, Jeronimo Escribano, Henk Eskes, Hilde Fagerli, Yalda Fatahi, Johannes Flemming, Elmar Friese, Lise Frohn, Michael Gauss, Camilla Geels, Guido Guarnieri, Marc Guevara, Antoine Guion, Jonathan Guth, Risto Hänninen, Kaj Hansen, Ulas Im, Ruud Janssen, Marine Jeoffrion, Mathieu Joly, Luke Jones, Oriol Jorba, Evgeni Kadantsev, Michael Kahnert, Jacek W. Kaminski, Rostislav Kouznetsov, Richard Kranenburg, Jeroen Kuenen, Anne Caroline Lange, Joachim Langner, Victor Lannuque, Francesca Macchia, Astrid Manders, Mihaela Mircea, Agnes Nyiri, Miriam Olid, Carlos Pérez García-Pando, Yuliia Palamarchuk, Antonio Piersanti, Blandine Raux, Miha Razinger, Lennard Robertson, Arjo Segers, Martijn Schaap, Pilvi Siljamo, David Simpson, Mikhail Sofiev, Anders Stangel, Joanna Struzewska, Carles Tena, Renske Timmermans, Thanos Tsikerdekis, Svetlana Tsyro, Svyatoslav Tyuryakov, Anthony Ung, Andreas Uppstu, Alvaro Valdebenito, Peter van Velthoven, Lina Vitali, Zhuyun Ye, Vincent-Henri Peuch, and Laurence Rouïl
EGUsphere, https://doi.org/10.5194/egusphere-2024-3744, https://doi.org/10.5194/egusphere-2024-3744, 2024
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The Copernicus Atmosphere Monitoring Service – Regional Production delivers daily forecasts, analyses, and reanalyses of air quality in Europe. The Service relies on a distributed modelling production by eleven leading European modelling teams following stringent requirements with an operational design which has no equivalent in the world. All the products are full, free, open and quality assured and disseminated with a high level of reliability.
Jason Williams, Swen Metzer, Samuel Remy, Vincent Huijnen, and Johannes Flemming
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2024-188, https://doi.org/10.5194/gmd-2024-188, 2024
Preprint under review for GMD
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One of the main constituents of Particulate Matter at the surface are Secondary Inorganic Aerosols (SIA) which are influenced by both anthropogenic emissions and the acidity of clouds and aerosols. This study shows improvements in introduced into the IFS-COMPO simulating the surface concentrations of SIA and the resulting changes in the total wet deposition for Europe, the US and South-East Asia.
Samuel Rémy, Swen Metzger, Vincent Huijnen, Jason E. Williams, and Johannes Flemming
Geosci. Model Dev., 17, 7539–7567, https://doi.org/10.5194/gmd-17-7539-2024, https://doi.org/10.5194/gmd-17-7539-2024, 2024
Short summary
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In this paper we describe the development of the future operational cycle 49R1 of the IFS-COMPO system, used for operational forecasts of atmospheric composition in the CAMS project, and focus on the implementation of the thermodynamical model EQSAM4Clim version 12. The implementation of EQSAM4Clim significantly improves the simulated secondary inorganic aerosol surface concentration. The new aerosol and precipitation acidity diagnostics showed good agreement against observational datasets.
Jorge E. Pachón, Mariel A. Opazo, Pablo Lichtig, Nicolas Huneeus, Idir Bouarar, Guy Brasseur, Cathy W. Y. Li, Johannes Flemming, Laurent Menut, Camilo Menares, Laura Gallardo, Michael Gauss, Mikhail Sofiev, Rostislav Kouznetsov, Julia Palamarchuk, Andreas Uppstu, Laura Dawidowski, Nestor Y. Rojas, María de Fátima Andrade, Mario E. Gavidia-Calderón, Alejandro H. Delgado Peralta, and Daniel Schuch
Geosci. Model Dev., 17, 7467–7512, https://doi.org/10.5194/gmd-17-7467-2024, https://doi.org/10.5194/gmd-17-7467-2024, 2024
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Latin America (LAC) has some of the most populated urban areas in the world, with high levels of air pollution. Air quality management in LAC has been traditionally focused on surveillance and building emission inventories. This study performed the first intercomparison and model evaluation in LAC, with interesting and insightful findings for the region. A multiscale modeling ensemble chain was assembled as a first step towards an air quality forecasting system.
Henk Eskes, Athanasios Tsikerdekis, Melanie Ades, Mihai Alexe, Anna Carlin Benedictow, Yasmine Bennouna, Lewis Blake, Idir Bouarar, Simon Chabrillat, Richard Engelen, Quentin Errera, Johannes Flemming, Sebastien Garrigues, Jan Griesfeller, Vincent Huijnen, Luka Ilić, Antje Inness, John Kapsomenakis, Zak Kipling, Bavo Langerock, Augustin Mortier, Mark Parrington, Isabelle Pison, Mikko Pitkänen, Samuel Remy, Andreas Richter, Anja Schoenhardt, Michael Schulz, Valerie Thouret, Thorsten Warneke, Christos Zerefos, and Vincent-Henri Peuch
Atmos. Chem. Phys., 24, 9475–9514, https://doi.org/10.5194/acp-24-9475-2024, https://doi.org/10.5194/acp-24-9475-2024, 2024
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The Copernicus Atmosphere Monitoring Service (CAMS) provides global analyses and forecasts of aerosols and trace gases in the atmosphere. On 27 June 2023 a major upgrade, Cy48R1, became operational. Comparisons with in situ, surface remote sensing, aircraft, and balloon and satellite observations show that the new CAMS system is a significant improvement. The results quantify the skill of CAMS to forecast impactful events, such as wildfires, dust storms and air pollution peaks.
Sören Johansson, Michael Höpfner, Felix Friedl-Vallon, Norbert Glatthor, Thomas Gulde, Vincent Huijnen, Anne Kleinert, Erik Kretschmer, Guido Maucher, Tom Neubert, Hans Nordmeyer, Christof Piesch, Peter Preusse, Martin Riese, Björn-Martin Sinnhuber, Jörn Ungermann, Gerald Wetzel, and Wolfgang Woiwode
Atmos. Chem. Phys., 24, 8125–8138, https://doi.org/10.5194/acp-24-8125-2024, https://doi.org/10.5194/acp-24-8125-2024, 2024
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We present airborne infrared limb sounding GLORIA measurements of ammonia (NH3) in the upper troposphere of air masses within the Asian monsoon and of those connected with biomass burning. Comparing CAMS (Copernicus Atmosphere Monitoring Service) model data, we find that the model reproduces the measured enhanced NH3 within the Asian monsoon well but not that within biomass burning plumes, where no enhanced NH3 is measured in the upper troposphere but considerable amounts are simulated by CAMS.
Claire L. Ryder, Clément Bézier, Helen F. Dacre, Rory Clarkson, Vassilis Amiridis, Eleni Marinou, Emmanouil Proestakis, Zak Kipling, Angela Benedetti, Mark Parrington, Samuel Rémy, and Mark Vaughan
Nat. Hazards Earth Syst. Sci., 24, 2263–2284, https://doi.org/10.5194/nhess-24-2263-2024, https://doi.org/10.5194/nhess-24-2263-2024, 2024
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Desert dust poses a hazard to aircraft via degradation of engine components. This has financial implications for the aviation industry and results in increased fuel burn with climate impacts. Here we quantify dust ingestion by aircraft engines at airports worldwide. We find Dubai and Delhi in summer are among the dustiest airports, where substantial engine degradation would occur after 1000 flights. Dust ingestion can be reduced by changing take-off times and the altitude of holding patterns.
Peng Xian, Jeffrey S. Reid, Melanie Ades, Angela Benedetti, Peter R. Colarco, Arlindo da Silva, Tom F. Eck, Johannes Flemming, Edward J. Hyer, Zak Kipling, Samuel Rémy, Tsuyoshi Thomas Sekiyama, Taichu Tanaka, Keiya Yumimoto, and Jianglong Zhang
Atmos. Chem. Phys., 24, 6385–6411, https://doi.org/10.5194/acp-24-6385-2024, https://doi.org/10.5194/acp-24-6385-2024, 2024
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The study compares and evaluates monthly AOD of four reanalyses (RA) and their consensus (i.e., ensemble mean). The basic verification characteristics of these RA versus both AERONET and MODIS retrievals are presented. The study discusses the strength of each RA and identifies regions where divergence and challenges are prominent. The RA consensus usually performs very well on a global scale in terms of how well it matches the observational data, making it a good choice for various applications.
Adrianus de Laat, Vincent Huijnen, Niels Andela, and Matthias Forkel
EGUsphere, https://doi.org/10.5194/egusphere-2024-732, https://doi.org/10.5194/egusphere-2024-732, 2024
Preprint archived
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This study assesses state-of-the art and more advanced and innovative satellite-observation-based (bottom-up) wildfire emission estimates. They are evaluated by comparison with satellite observation of single fire emission plumes. Results indicate that more advanced fire emission estimates – more information – are more realistic but that especially for a limited number of very large fires certain differences remain – for unknown reasons.
Zhipeng Qu, David P. Donovan, Howard W. Barker, Jason N. S. Cole, Mark W. Shephard, and Vincent Huijnen
Atmos. Meas. Tech., 16, 4927–4946, https://doi.org/10.5194/amt-16-4927-2023, https://doi.org/10.5194/amt-16-4927-2023, 2023
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The EarthCARE satellite mission Level 2 algorithm development requires realistic 3D cloud and aerosol scenes along the satellite orbits. One of the best ways to produce these scenes is to use a high-resolution numerical weather prediction model to simulate atmospheric conditions at 250 m horizontal resolution. This paper describes the production and validation of three EarthCARE test scenes.
Sebastien Garrigues, Melanie Ades, Samuel Remy, Johannes Flemming, Zak Kipling, Istvan Laszlo, Mark Parrington, Antje Inness, Roberto Ribas, Luke Jones, Richard Engelen, and Vincent-Henri Peuch
Atmos. Chem. Phys., 23, 10473–10487, https://doi.org/10.5194/acp-23-10473-2023, https://doi.org/10.5194/acp-23-10473-2023, 2023
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The Copernicus Atmosphere Monitoring Service (CAMS) provides global monitoring of aerosols using the ECMWF forecast model constrained by the assimilation of satellite aerosol optical depth (AOD). This work aims at evaluating the assimilation of the NOAA VIIRS AOD product in the ECMWF model. It shows that the introduction of VIIRS in the CAMS data assimilation system enhances the accuracy of the aerosol analysis, particularly over Europe and desert and maritime sites.
Olivia E. Clifton, Donna Schwede, Christian Hogrefe, Jesse O. Bash, Sam Bland, Philip Cheung, Mhairi Coyle, Lisa Emberson, Johannes Flemming, Erick Fredj, Stefano Galmarini, Laurens Ganzeveld, Orestis Gazetas, Ignacio Goded, Christopher D. Holmes, László Horváth, Vincent Huijnen, Qian Li, Paul A. Makar, Ivan Mammarella, Giovanni Manca, J. William Munger, Juan L. Pérez-Camanyo, Jonathan Pleim, Limei Ran, Roberto San Jose, Sam J. Silva, Ralf Staebler, Shihan Sun, Amos P. K. Tai, Eran Tas, Timo Vesala, Tamás Weidinger, Zhiyong Wu, and Leiming Zhang
Atmos. Chem. Phys., 23, 9911–9961, https://doi.org/10.5194/acp-23-9911-2023, https://doi.org/10.5194/acp-23-9911-2023, 2023
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A primary sink of air pollutants is dry deposition. Dry deposition estimates differ across the models used to simulate atmospheric chemistry. Here, we introduce an effort to examine dry deposition schemes from atmospheric chemistry models. We provide our approach’s rationale, document the schemes, and describe datasets used to drive and evaluate the schemes. We also launch the analysis of results by evaluating against observations and identifying the processes leading to model–model differences.
Anna Agustí-Panareda, Jérôme Barré, Sébastien Massart, Antje Inness, Ilse Aben, Melanie Ades, Bianca C. Baier, Gianpaolo Balsamo, Tobias Borsdorff, Nicolas Bousserez, Souhail Boussetta, Michael Buchwitz, Luca Cantarello, Cyril Crevoisier, Richard Engelen, Henk Eskes, Johannes Flemming, Sébastien Garrigues, Otto Hasekamp, Vincent Huijnen, Luke Jones, Zak Kipling, Bavo Langerock, Joe McNorton, Nicolas Meilhac, Stefan Noël, Mark Parrington, Vincent-Henri Peuch, Michel Ramonet, Miha Razinger, Maximilian Reuter, Roberto Ribas, Martin Suttie, Colm Sweeney, Jérôme Tarniewicz, and Lianghai Wu
Atmos. Chem. Phys., 23, 3829–3859, https://doi.org/10.5194/acp-23-3829-2023, https://doi.org/10.5194/acp-23-3829-2023, 2023
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We present a global dataset of atmospheric CO2 and CH4, the two most important human-made greenhouse gases, which covers almost 2 decades (2003–2020). It is produced by combining satellite data of CO2 and CH4 with a weather and air composition prediction model, and it has been carefully evaluated against independent observations to ensure validity and point out deficiencies to the user. This dataset can be used for scientific studies in the field of climate change and the global carbon cycle.
Stijn Naus, Lucas G. Domingues, Maarten Krol, Ingrid T. Luijkx, Luciana V. Gatti, John B. Miller, Emanuel Gloor, Sourish Basu, Caio Correia, Gerbrand Koren, Helen M. Worden, Johannes Flemming, Gabrielle Pétron, and Wouter Peters
Atmos. Chem. Phys., 22, 14735–14750, https://doi.org/10.5194/acp-22-14735-2022, https://doi.org/10.5194/acp-22-14735-2022, 2022
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We assimilate MOPITT CO satellite data in the TM5-4D-Var inverse modelling framework to estimate Amazon fire CO emissions for 2003–2018. We show that fire emissions have decreased over the analysis period, coincident with a decrease in deforestation rates. However, interannual variations in fire emissions are large, and they correlate strongly with soil moisture. Our results reveal an important role for robust, top-down fire CO emissions in quantifying and attributing Amazon fire intensity.
Sebastien Garrigues, Samuel Remy, Julien Chimot, Melanie Ades, Antje Inness, Johannes Flemming, Zak Kipling, Istvan Laszlo, Angela Benedetti, Roberto Ribas, Soheila Jafariserajehlou, Bertrand Fougnie, Shobha Kondragunta, Richard Engelen, Vincent-Henri Peuch, Mark Parrington, Nicolas Bousserez, Margarita Vazquez Navarro, and Anna Agusti-Panareda
Atmos. Chem. Phys., 22, 14657–14692, https://doi.org/10.5194/acp-22-14657-2022, https://doi.org/10.5194/acp-22-14657-2022, 2022
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The Copernicus Atmosphere Monitoring Service (CAMS) provides global monitoring of aerosols using the ECMWF forecast model constrained by the assimilation of satellite aerosol optical depth (AOD). This work aims at evaluating two new satellite AODs to enhance the CAMS aerosol global forecast. It highlights the spatial and temporal differences between the satellite AOD products at the model spatial resolution, which is essential information to design multi-satellite AOD data assimilation schemes.
Antje Inness, Ilse Aben, Melanie Ades, Tobias Borsdorff, Johannes Flemming, Luke Jones, Jochen Landgraf, Bavo Langerock, Philippe Nedelec, Mark Parrington, and Roberto Ribas
Atmos. Chem. Phys., 22, 14355–14376, https://doi.org/10.5194/acp-22-14355-2022, https://doi.org/10.5194/acp-22-14355-2022, 2022
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The Copernicus Atmosphere Monitoring Service (CAMS) provides daily global air quality forecasts to users worldwide. One of the species of interest is carbon monoxide (CO), an important trace gas in the atmosphere with anthropogenic and natural sources, produced by incomplete combustion, for example, by wildfires. This paper looks at how well CAMS can model CO in the atmosphere and shows that the fields can be improved when blending CO data from the TROPOMI instrument with the CAMS model.
Thomas Drugé, Pierre Nabat, Marc Mallet, Martine Michou, Samuel Rémy, and Oleg Dubovik
Atmos. Chem. Phys., 22, 12167–12205, https://doi.org/10.5194/acp-22-12167-2022, https://doi.org/10.5194/acp-22-12167-2022, 2022
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This study presents the implementation of brown carbon in the atmospheric component of the CNRM global climate model and particularly in its aerosol scheme TACTIC. Several simulations were carried out with this climate model, over the period 2000–2014, to evaluate the model by comparison with different reference datasets (PARASOL-GRASP, OMI-OMAERUVd, MACv2, FMI_SAT, AERONET) and to analyze the brown carbon radiative and climatic effects.
Qirui Zhong, Nick Schutgens, Guido van der Werf, Twan van Noije, Kostas Tsigaridis, Susanne E. Bauer, Tero Mielonen, Alf Kirkevåg, Øyvind Seland, Harri Kokkola, Ramiro Checa-Garcia, David Neubauer, Zak Kipling, Hitoshi Matsui, Paul Ginoux, Toshihiko Takemura, Philippe Le Sager, Samuel Rémy, Huisheng Bian, Mian Chin, Kai Zhang, Jialei Zhu, Svetlana G. Tsyro, Gabriele Curci, Anna Protonotariou, Ben Johnson, Joyce E. Penner, Nicolas Bellouin, Ragnhild B. Skeie, and Gunnar Myhre
Atmos. Chem. Phys., 22, 11009–11032, https://doi.org/10.5194/acp-22-11009-2022, https://doi.org/10.5194/acp-22-11009-2022, 2022
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Aerosol optical depth (AOD) errors for biomass burning aerosol (BBA) are evaluated in 18 global models against satellite datasets. Notwithstanding biases in satellite products, they allow model evaluations. We observe large and diverse model biases due to errors in BBA. Further interpretations of AOD diversities suggest large biases exist in key processes for BBA which require better constraining. These results can contribute to further model improvement and development.
Vincent Huijnen, Philippe Le Sager, Marcus O. Köhler, Glenn Carver, Samuel Rémy, Johannes Flemming, Simon Chabrillat, Quentin Errera, and Twan van Noije
Geosci. Model Dev., 15, 6221–6241, https://doi.org/10.5194/gmd-15-6221-2022, https://doi.org/10.5194/gmd-15-6221-2022, 2022
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We report on the first implementation of atmospheric chemistry and aerosol as part of the OpenIFS model, based on the CAMS global model. We give an overview of the model and evaluate two reference model configurations, with and without the stratospheric chemistry extension, against a variety of observational datasets. This OpenIFS version with atmospheric composition components is open to the scientific user community under a standard OpenIFS license.
Samuel Rémy, Zak Kipling, Vincent Huijnen, Johannes Flemming, Pierre Nabat, Martine Michou, Melanie Ades, Richard Engelen, and Vincent-Henri Peuch
Geosci. Model Dev., 15, 4881–4912, https://doi.org/10.5194/gmd-15-4881-2022, https://doi.org/10.5194/gmd-15-4881-2022, 2022
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This article describes a new version of IFS-AER, the tropospheric aerosol scheme used to provide global aerosol products within the Copernicus Atmosphere Monitoring Service (CAMS) cycle. Several components of the model have been updated, such as the dynamical dust and sea salt aerosol emission schemes. New deposition schemes have also been incorporated but are not yet used operationally. This new version of IFS-AER has been evaluated and shown to have a greater skill than previous versions.
Jason E. Williams, Vincent Huijnen, Idir Bouarar, Mehdi Meziane, Timo Schreurs, Sophie Pelletier, Virginie Marécal, Beatrice Josse, and Johannes Flemming
Geosci. Model Dev., 15, 4657–4687, https://doi.org/10.5194/gmd-15-4657-2022, https://doi.org/10.5194/gmd-15-4657-2022, 2022
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The global CAMS air quality model is used for providing tropospheric ozone information to end users. This paper updates the chemical mechanism employed (CBA) and compares it against two other mechanisms (MOCAGE, MOZART) and a multi-decadal dataset based on a previous version of CBA. We perform extensive validation for the US using multiple surface and aircraft datasets, providing an assessment of biases and the extent of correlation across different seasons during 2014.
Dimitris Akritidis, Andrea Pozzer, Johannes Flemming, Antje Inness, Philippe Nédélec, and Prodromos Zanis
Atmos. Chem. Phys., 22, 6275–6289, https://doi.org/10.5194/acp-22-6275-2022, https://doi.org/10.5194/acp-22-6275-2022, 2022
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We perform a process-oriented evaluation of Copernicus Atmosphere Monitoring Service (CAMS) reanalysis (CAMSRA) O3 over Europe using WOUDC (World Ozone and Ultraviolet Radiation Data Centre) ozonesondes and IAGOS (In-service Aircraft for a Global Observing System) aircraft measurements. Chemical data assimilation assists CAMSRA to reproduce the observed O3 increases in the troposphere during the examined folding events, but it mostly results in O3 overestimation in the upper troposphere.
Joe McNorton, Nicolas Bousserez, Anna Agustí-Panareda, Gianpaolo Balsamo, Luca Cantarello, Richard Engelen, Vincent Huijnen, Antje Inness, Zak Kipling, Mark Parrington, and Roberto Ribas
Atmos. Chem. Phys., 22, 5961–5981, https://doi.org/10.5194/acp-22-5961-2022, https://doi.org/10.5194/acp-22-5961-2022, 2022
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Concentrations of atmospheric methane continue to grow, in recent years at an increasing rate, for unknown reasons. Using newly available satellite observations and a state-of-the-art weather prediction model we perform global estimates of emissions from hotspots at high resolution. Results show that the system can accurately report on biases in national inventories and is used to conclude that the early COVID-19 slowdown period (March–June 2020) had little impact on global methane emissions.
Beatriz M. Monge-Sanz, Alessio Bozzo, Nicholas Byrne, Martyn P. Chipperfield, Michail Diamantakis, Johannes Flemming, Lesley J. Gray, Robin J. Hogan, Luke Jones, Linus Magnusson, Inna Polichtchouk, Theodore G. Shepherd, Nils Wedi, and Antje Weisheimer
Atmos. Chem. Phys., 22, 4277–4302, https://doi.org/10.5194/acp-22-4277-2022, https://doi.org/10.5194/acp-22-4277-2022, 2022
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The stratosphere is emerging as one of the keys to improve tropospheric weather and climate predictions. This study provides evidence of the role the stratospheric ozone layer plays in improving weather predictions at different timescales. Using a new ozone modelling approach suitable for high-resolution global models that provide operational forecasts from days to seasons, we find significant improvements in stratospheric meteorological fields and stratosphere–troposphere coupling.
Antje Inness, Melanie Ades, Dimitris Balis, Dmitry Efremenko, Johannes Flemming, Pascal Hedelt, Maria-Elissavet Koukouli, Diego Loyola, and Roberto Ribas
Geosci. Model Dev., 15, 971–994, https://doi.org/10.5194/gmd-15-971-2022, https://doi.org/10.5194/gmd-15-971-2022, 2022
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This paper describes the way that the Copernicus Atmosphere Monitoring Service (CAMS) produces forecasts of volcanic SO2. These forecasts are provided routinely every day. They are created by blending SO2 data from satellite instruments (TROPOMI and GOME-2) with the CAMS model. We show that the quality of the CAMS SO2 forecasts can be improved if additional information about the height of volcanic plumes is provided in the satellite data.
Song Liu, Pieter Valks, Gaia Pinardi, Jian Xu, Ka Lok Chan, Athina Argyrouli, Ronny Lutz, Steffen Beirle, Ehsan Khorsandi, Frank Baier, Vincent Huijnen, Alkiviadis Bais, Sebastian Donner, Steffen Dörner, Myrto Gratsea, François Hendrick, Dimitris Karagkiozidis, Kezia Lange, Ankie J. M. Piters, Julia Remmers, Andreas Richter, Michel Van Roozendael, Thomas Wagner, Mark Wenig, and Diego G. Loyola
Atmos. Meas. Tech., 14, 7297–7327, https://doi.org/10.5194/amt-14-7297-2021, https://doi.org/10.5194/amt-14-7297-2021, 2021
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In this work, an improved tropospheric NO2 retrieval algorithm from TROPOMI measurements over Europe is presented. The stratospheric estimation is implemented with correction for the dependency of the stratospheric NO2 on the viewing geometry. The AMF calculation is implemented using improved surface albedo, a priori NO2 profiles, and cloud correction. The improved tropospheric NO2 data show good correlations with ground-based MAX-DOAS measurements.
Maria Sand, Bjørn H. Samset, Gunnar Myhre, Jonas Gliß, Susanne E. Bauer, Huisheng Bian, Mian Chin, Ramiro Checa-Garcia, Paul Ginoux, Zak Kipling, Alf Kirkevåg, Harri Kokkola, Philippe Le Sager, Marianne T. Lund, Hitoshi Matsui, Twan van Noije, Dirk J. L. Olivié, Samuel Remy, Michael Schulz, Philip Stier, Camilla W. Stjern, Toshihiko Takemura, Kostas Tsigaridis, Svetlana G. Tsyro, and Duncan Watson-Parris
Atmos. Chem. Phys., 21, 15929–15947, https://doi.org/10.5194/acp-21-15929-2021, https://doi.org/10.5194/acp-21-15929-2021, 2021
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Absorption of shortwave radiation by aerosols can modify precipitation and clouds but is poorly constrained in models. A total of 15 different aerosol models from AeroCom phase III have reported total aerosol absorption, and for the first time, 11 of these models have reported in a consistent experiment the contributions to absorption from black carbon, dust, and organic aerosol. Here, we document the model diversity in aerosol absorption.
Anthony C. Jones, Adrian Hill, Samuel Remy, N. Luke Abraham, Mohit Dalvi, Catherine Hardacre, Alan J. Hewitt, Ben Johnson, Jane P. Mulcahy, and Steven T. Turnock
Atmos. Chem. Phys., 21, 15901–15927, https://doi.org/10.5194/acp-21-15901-2021, https://doi.org/10.5194/acp-21-15901-2021, 2021
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Ammonium nitrate is hard to model because it forms and evaporates rapidly. One approach is to relate its equilibrium concentration to temperature, humidity, and the amount of nitric acid and ammonia gases. Using this approach, we limit the rate at which equilibrium is reached using various condensation rates in a climate model. We show that ammonium nitrate concentrations are highly sensitive to the condensation rate. Our results will help improve the representation of nitrate in climate models.
Jérôme Barré, Hervé Petetin, Augustin Colette, Marc Guevara, Vincent-Henri Peuch, Laurence Rouil, Richard Engelen, Antje Inness, Johannes Flemming, Carlos Pérez García-Pando, Dene Bowdalo, Frederik Meleux, Camilla Geels, Jesper H. Christensen, Michael Gauss, Anna Benedictow, Svetlana Tsyro, Elmar Friese, Joanna Struzewska, Jacek W. Kaminski, John Douros, Renske Timmermans, Lennart Robertson, Mario Adani, Oriol Jorba, Mathieu Joly, and Rostislav Kouznetsov
Atmos. Chem. Phys., 21, 7373–7394, https://doi.org/10.5194/acp-21-7373-2021, https://doi.org/10.5194/acp-21-7373-2021, 2021
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This study provides a comprehensive assessment of air quality changes across the main European urban areas induced by the COVID-19 lockdown using satellite observations, surface site measurements, and the forecasting system from the Copernicus Atmospheric Monitoring Service (CAMS). We demonstrate the importance of accounting for weather and seasonal variability when calculating such estimates.
Harald Flentje, Ina Mattis, Zak Kipling, Samuel Rémy, and Werner Thomas
Geosci. Model Dev., 14, 1721–1751, https://doi.org/10.5194/gmd-14-1721-2021, https://doi.org/10.5194/gmd-14-1721-2021, 2021
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Atmospheric aerosols crucially impact air quality, climate and weather. Thus, global model forecasts of atmospheric constituents are published daily on the ECMWF website and are regularly verified by the CAMS service team. The IFS-AER model is largely able to reproduce observed 3-D distributions of the important particle types over Germany. The particle concentration is mostly captured within several tens of percent, but quantification of some specific processes still remains a challenge.
Wannan Wang, Tianhai Cheng, Ronald J. van der A, Jos de Laat, and Jason E. Williams
Atmos. Meas. Tech., 14, 1673–1687, https://doi.org/10.5194/amt-14-1673-2021, https://doi.org/10.5194/amt-14-1673-2021, 2021
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This paper is an evaluation of the AIRS and MLS ozone (O3) algorithms via comparison with daytime and night-time O3 datasets. Results show that further refinements of the AIRS O3 algorithm are required for better surface emissivity retrievals and that cloud cover is another problem that needs to be solved. An inconsistency is found in the
AscDescModeflag of the MLS v4.20 standard O3 product for 90–60° S and 60–90° N, resulting in inconsistent O3 profiles in these regions before May 2015.
Jonas Gliß, Augustin Mortier, Michael Schulz, Elisabeth Andrews, Yves Balkanski, Susanne E. Bauer, Anna M. K. Benedictow, Huisheng Bian, Ramiro Checa-Garcia, Mian Chin, Paul Ginoux, Jan J. Griesfeller, Andreas Heckel, Zak Kipling, Alf Kirkevåg, Harri Kokkola, Paolo Laj, Philippe Le Sager, Marianne Tronstad Lund, Cathrine Lund Myhre, Hitoshi Matsui, Gunnar Myhre, David Neubauer, Twan van Noije, Peter North, Dirk J. L. Olivié, Samuel Rémy, Larisa Sogacheva, Toshihiko Takemura, Kostas Tsigaridis, and Svetlana G. Tsyro
Atmos. Chem. Phys., 21, 87–128, https://doi.org/10.5194/acp-21-87-2021, https://doi.org/10.5194/acp-21-87-2021, 2021
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Simulated aerosol optical properties as well as the aerosol life cycle are investigated for 14 global models participating in the AeroCom initiative. Considerable diversity is found in the simulated aerosol species emissions and lifetimes, also resulting in a large diversity in the simulated aerosol mass, composition, and optical properties. A comparison with observations suggests that, on average, current models underestimate the direct effect of aerosol on the atmosphere radiation budget.
Dimitris Akritidis, Eleni Katragkou, Aristeidis K. Georgoulias, Prodromos Zanis, Stergios Kartsios, Johannes Flemming, Antje Inness, John Douros, and Henk Eskes
Atmos. Chem. Phys., 20, 13557–13578, https://doi.org/10.5194/acp-20-13557-2020, https://doi.org/10.5194/acp-20-13557-2020, 2020
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We assess the Copernicus Atmosphere Monitoring Service (CAMS) global and regional forecasts performance during a complex aerosol transport event over Europe induced by the passage of Storm Ophelia in mid-October 2017. Comparison with satellite observations reveals a satisfactory performance of CAMS global forecast assisted by data assimilation, while comparison with ground-based measurements indicates that the CAMS regional system over-performs compared to the global one in terms of air quality.
Stelios Myriokefalitakis, Nikos Daskalakis, Angelos Gkouvousis, Andreas Hilboll, Twan van Noije, Jason E. Williams, Philippe Le Sager, Vincent Huijnen, Sander Houweling, Tommi Bergman, Johann Rasmus Nüß, Mihalis Vrekoussis, Maria Kanakidou, and Maarten C. Krol
Geosci. Model Dev., 13, 5507–5548, https://doi.org/10.5194/gmd-13-5507-2020, https://doi.org/10.5194/gmd-13-5507-2020, 2020
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This work documents and evaluates the detailed tropospheric gas-phase chemical mechanism MOGUNTIA in the three-dimensional chemistry transport model TM5-MP. The Rosenbrock solver, as generated by the KPP software, is implemented in the chemistry code, which can successfully replace the classical Euler backward integration method. The MOGUNTIA scheme satisfactorily simulates a large suite of oxygenated volatile organic compounds (VOCs) that are observed in the atmosphere at significant levels.
Cited articles
Fagerli, H., Tsyro, S., Jonson, J. E., Nyíri, Á., Gauss, M., Simpson, D., Wind, P., Benedictow, A., Klein, H., Mortier, A., Aas, W., Hjellbrekke, A.-G., Solberg, S., Platt, S. M., Yttri, K. E., Tørseth, K., Gaisbauer, S., Mareckova, K., Matthews, B., Schindlbacher, S., Sosa, C., Tista, M., Ullrich, B., Wankmüller, R., Scheuschner, T., Bergström, R., Johanson, L., Jalkanen, J.-P., Metzger, S., Denier van der Gon, H. A. C., Kuenen, J. J. P., Visschedijk, A. J. H., Barregård, L., Molnár, P., and Stockfelt, L.: Transboundary particulate matter, photo-oxidants, acidifying and eutrophying components, EMEP Status Report 1 “, Norwegian Meteorological Institute, https://emep.int/publ/reports/2019/EMEP_Status_Report_1_2019.pdf (last access: 26 June 2024), 2019. a, b
Flemming, J., Huijnen, V., Arteta, J., Bechtold, P., Beljaars, A., Blechschmidt, A.-M., Diamantakis, M., Engelen, R. J., Gaudel, A., Inness, A., Jones, L., Josse, B., Katragkou, E., Marecal, V., Peuch, V.-H., Richter, A., Schultz, M. G., Stein, O., and Tsikerdekis, A.: Tropospheric chemistry in the Integrated Forecasting System of ECMWF, Geosci. Model Dev., 8, 975–1003, https://doi.org/10.5194/gmd-8-975-2015, 2015. a, b
Friese, E. and Ebel, A.: Temperature Dependent Thermodynamic Model of the System H+-NH
Guo, H., Xu, L., Bougiatioti, A., Cerully, K. M., Capps, S. L., Hite Jr., J. R., Carlton, A. G., Lee, S.-H., Bergin, M. H., Ng, N. L., Nenes, A., and Weber, R. J.: Fine-particle water and pH in the southeastern United States, Atmos. Chem. Phys., 15, 5211–5228, https://doi.org/10.5194/acp-15-5211-2015, 2015. a
Guo, H., Sullivan, A. P., Campuzano-Jost, P., Schroder, J. C., Lopez-Hilfiker, F. D., Dibb, J. E., Jimenez, J. L., Thornton, J. A., Brown, S. S., Nenes, A., and Weber, R. J.: Fine particle pH and the partitioning of nitric acid during winter in the northeastern United States, J. Geophys. Res.-Atmos., 121, 10355–10376, https://doi.org/10.1002/2016JD025311, 2016. a
Guo, H., Liu, J., Froyd, K. D., Roberts, J. M., Veres, P. R., Hayes, P. L., Jimenez, J. L., Nenes, A., and Weber, R. J.: Fine particle pH and gas–particle phase partitioning of inorganic species in Pasadena, California, during the 2010 CalNex campaign, Atmos. Chem. Phys., 17, 5703–5719, https://doi.org/10.5194/acp-17-5703-2017, 2017. a
Guo, H., Otjes, R., Schlag, P., Kiendler-Scharr, A., Nenes, A., and Weber, R. J.: Effectiveness of ammonia reduction on control of fine particle nitrate, Atmos. Chem. Phys., 18, 12241–12256, https://doi.org/10.5194/acp-18-12241-2018, 2018. a
Huijnen, V., Le Sager, P., Köhler, M. O., Carver, G., Rémy, S., Flemming, J., Chabrillat, S., Errera, Q., and van Noije, T.: OpenIFS/AC: atmospheric chemistry and aerosol in OpenIFS 43r3, Geosci. Model Dev., 15, 6221–6241, https://doi.org/10.5194/gmd-15-6221-2022, 2022. a
Koo, B., Metzger, S., Vennam, P., Emery, C., Wilson, G., and Yarwood, G.: Comparing the ISORROPIA and EQSAM Aerosol Thermodynamic Options in CAMx, in: Air Pollution Modeling and its Application XXVI, series Title: Springer Proceedings in Complexity, edited by Mensink, C., Gong, W., and Hakami, A., Springer International Publishing, Cham, 93–98, ISBN 978-3-030-22054-9 978-3-030-22055-6, https://doi.org/10.1007/978-3-030-22055-6_16, 2020. a, b
Metzger, S.: The EQSAM Box Model (for eqsam4clim-v12), Zenodo [code and data set], https://doi.org/10.5281/zenodo.10276178, 2023. a, b
Metzger, S., Dentener, F., Pandis, S., and Lelieveld, J.: Gas/aerosol partitioning: 1. A computationally efficient model, J. Geophys. Res.-Atmos., 107, ACH 16-1–ACH 16-24, https://doi.org/10.1029/2001JD001102, 2002. a
Metzger, S., Steil, B., Xu, L., Penner, J. E., and Lelieveld, J.: New representation of water activity based on a single solute specific constant to parameterize the hygroscopic growth of aerosols in atmospheric models, Atmos. Chem. Phys., 12, 5429–5446, https://doi.org/10.5194/acp-12-5429-2012, 2012. a, b, c, d
Metzger, S., Steil, B., Abdelkader, M., Klingmüller, K., Xu, L., Penner, J. E., Fountoukis, C., Nenes, A., and Lelieveld, J.: Aerosol water parameterisation: a single parameter framework, Atmos. Chem. Phys., 16, 7213–7237, https://doi.org/10.5194/acp-16-7213-2016, 2016b. a, b, c, d, e, f, g, h, i, j, k
Metzger, S., Abdelkader, M., Steil, B., and Klingmüller, K.: Aerosol water parameterization: long-term evaluation and importance for climate studies, Atmos. Chem. Phys., 18, 16747–16774, https://doi.org/10.5194/acp-18-16747-2018, 2018. a, b, c, d
Metzger, S., Remy, S., Williams, J. E., Huijnen, V., Meziane, M., Kipling, Z., Flemming, J., and Engelen, R.: Representing acidity in the IFS using a coupled IFS-EQSAM4Clim approach, EGU General Assembly 2022, Vienna, Austria, 23–27 May 2022, EGU22-11122, https://doi.org/10.5194/egusphere-egu22-11122, 2022. a
Metzger, S., Rémy, S., Huijnen, V., Williams, J., Chabrillat, S., Bingen, C., and Flemming, J.: Impact of pH computation from EQSAM4Clim on inorganic aerosols in the CAMS system, EGU General Assembly 2023, Vienna, Austria, 24–28 April 2023, EGU23-16085, https://doi.org/10.5194/egusphere-egu23-16085, 2023. a
Peuch, V.-H., Engelen, R., Rixen, M., Dee, D., Flemming, J., Suttie, M., Ades, M., Agusti-Panareda, A., Ananasso, C., Andersson, E., Armstrong, D., Barre, J., Bousserez, N., Dominguez, J. J., Garrigues, S., Inness, A., Jones, L., Kipling, Z., Letertre-Danczak, J., Parrington, M., Razinger, M., Ribas, R., Vermoote, S., Yang, X., Simmons, A., de Marcilla, J. G., and Thepaut, J.-N.: The Copernicus Atmosphere Monitoring Service: From Research to Operations, B. Am. Meteorol. Soc., 103, E2650–E2668, https://doi.org/10.1175/BAMS-D-21-0314.1, 2022. a, b
Pye, H. O. T., Nenes, A., Alexander, B., Ault, A. P., Barth, M. C., Clegg, S. L., Collett Jr., J. L., Fahey, K. M., Hennigan, C. J., Herrmann, H., Kanakidou, M., Kelly, J. T., Ku, I.-T., McNeill, V. F., Riemer, N., Schaefer, T., Shi, G., Tilgner, A., Walker, J. T., Wang, T., Weber, R., Xing, J., Zaveri, R. A., and Zuend, A.: The acidity of atmospheric particles and clouds, Atmos. Chem. Phys., 20, 4809–4888, https://doi.org/10.5194/acp-20-4809-2020, 2020. a, b, c, d, e, f, g, h, i, j
Rémy, S., Kipling, Z., Huijnen, V., Flemming, J., Nabat, P., Michou, M., Ades, M., Engelen, R., and Peuch, V.-H.: Description and evaluation of the tropospheric aerosol scheme in the Integrated Forecasting System (IFS-AER, cycle 47R1) of ECMWF, Geosci. Model Dev., 15, 4881–4912, https://doi.org/10.5194/gmd-15-4881-2022, 2022. a, b
Shi, X., Nenes, A., Xiao, Z., Song, S., Yu, H., Shi, G., Zhao, Q., Chen, K., Feng, Y., and Russell, A. G.: High-Resolution Data Sets Unravel the Effects of Sources and Meteorological Conditions on Nitrate and Its Gas-Particle Partitioning, Environ. Sci. Technol., 53, 3048–3057, https://doi.org/10.1021/acs.est.8b06524, 2019. a
Wexler, A. S. and Clegg, S. L.: Atmospheric aerosol models for systems including the ions H+, NH4+, Na+, SO42−, NO3−, Cl−, Br−, and H2O, J. Geophys. Res.-Atmos., 107, ACH 14-1–ACH 14-14, https://doi.org/10.1029/2001JD000451, 2002. a
Williams, J. E. ., Huijnen, V., Bouarar, I., Meziane, M., Schreurs, T., Pelletier, S., Marécal, V., Josse, B., and Flemming, J.: Regional evaluation of the performance of the global CAMS chemical modeling system over the United States (IFS cycle 47r1), Geosci. Model Dev., 15, 4657–4687, https://doi.org/10.5194/gmd-15-4657-2022, 2022. a
Williams, J. E., Rémy, S., Metzger, S., Huijnen, V., and Flemming, J.: An evaluation of the regional distribution and wet deposition of secondary inorganic aerosols and their gaseous precursors in IFS-COMPO 49R1: the impact of aerosol and cloud pH, in preparation, 2024. a
Short summary
EQSAM4Clim has recently been revised to provide an accurate and efficient method for calculating the acidity of atmospheric particles. It is based on an analytical concept that is sufficiently fast and free of numerical noise, which makes it attractive for air quality forecasting. Version 12 allows the calculation of aerosol composition based on the gas–liquid–solid and the reduced gas–liquid partitioning with the associated water uptake for both cases, including the acidity of the aerosols.
EQSAM4Clim has recently been revised to provide an accurate and efficient method for calculating...
