Articles | Volume 6, issue 5
https://doi.org/10.5194/gmd-6-1407-2013
© Author(s) 2013. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/gmd-6-1407-2013
© Author(s) 2013. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Model description paper
| 
09 Sep 2013
Model description paper |
| 09 Sep 2013
The SOCOL version 3.0 chemistry–climate model: description, evaluation, and implications from an advanced transport algorithm
A. Stenke
Institute for Atmospheric and Climate Science, ETH Zurich, Switzerland
M. Schraner
Institute for Atmospheric and Climate Science, ETH Zurich, Switzerland
now at: MeteoSwiss, Zurich, Switzerland
E. Rozanov
Institute for Atmospheric and Climate Science, ETH Zurich, Switzerland
Physical-Meteorological Observatory/World Radiation Center, Davos, Switzerland
T. Egorova
Physical-Meteorological Observatory/World Radiation Center, Davos, Switzerland
Institute for Atmospheric and Climate Science, ETH Zurich, Switzerland
T. Peter
Institute for Atmospheric and Climate Science, ETH Zurich, Switzerland
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In spring, winds the Arctic stratosphere change direction – an event called final stratospheric warming (FSW). Here, we examine whether the interannual variability in Arctic stratospheric ozone impacts the timing of the FSW. We find that Arctic ozone shifts the FSW to earlier and later dates in years with high and low ozone via the absorption of UV light. The modulation of the FSW by ozone has consequences for surface climate in ozone-rich years, which may result in better seasonal predictions.
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Frost point hygrometers are the most reliable instruments for measuring water vapor in the upper troposphere and lower stratosphere. Their greatest source of uncertainty arises from controller instabilities, which have been poorly investigated to date. The “Golden Points” and nonequilibrium correction is a new chilled mirror processing technique that enables existing instruments to measure the water vapor mixing ratio from the ground to the middle stratosphere with an unprecedented 4 % accuracy.
Ales Kuchar, Timofei Sukhodolov, Gabriel Chiodo, Andrin Jörimann, Jessica Kult-Herdin, Eugene Rozanov, and Harald H. Rieder
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Sandro Vattioni, Rahel Weber, Aryeh Feinberg, Andrea Stenke, John A. Dykema, Beiping Luo, Georgios A. Kelesidis, Christian A. Bruun, Timofei Sukhodolov, Frank N. Keutsch, Thomas Peter, and Gabriel Chiodo
Geosci. Model Dev., 17, 7767–7793, https://doi.org/10.5194/gmd-17-7767-2024, https://doi.org/10.5194/gmd-17-7767-2024, 2024
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We quantified impacts and efficiency of stratospheric solar climate intervention via solid particle injection. Microphysical interactions of solid particles with the sulfur cycle were interactively coupled to the heterogeneous chemistry scheme and the radiative transfer code of an aerosol–chemistry–climate model. Compared to injection of SO2 we only find a stronger cooling efficiency for solid particles when normalizing to the aerosol load but not when normalizing to the injection rate.
Sandro Vattioni, Andrea Stenke, Beiping Luo, Gabriel Chiodo, Timofei Sukhodolov, Elia Wunderlin, and Thomas Peter
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We investigate the sensitivity of aerosol size distributions in the presence of strong SO2 injections for climate interventions or after volcanic eruptions to the call sequence and frequency of the routines for nucleation and condensation in sectional aerosol models with operator splitting. Using the aerosol–chemistry–climate model SOCOL-AERv2, we show that the radiative and chemical outputs are sensitive to these settings at high H2SO4 supersaturations and how to obtain reliable results.
Christina V. Brodowsky, Timofei Sukhodolov, Gabriel Chiodo, Valentina Aquila, Slimane Bekki, Sandip S. Dhomse, Michael Höpfner, Anton Laakso, Graham W. Mann, Ulrike Niemeier, Giovanni Pitari, Ilaria Quaglia, Eugene Rozanov, Anja Schmidt, Takashi Sekiya, Simone Tilmes, Claudia Timmreck, Sandro Vattioni, Daniele Visioni, Pengfei Yu, Yunqian Zhu, and Thomas Peter
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The aerosol layer is an essential part of the climate system. We characterize the sulfur budget in a volcanically quiescent (background) setting, with a special focus on the sulfate aerosol layer using, for the first time, a multi-model approach. The aim is to identify weak points in the representation of the atmospheric sulfur budget in an intercomparison of nine state-of-the-art coupled global circulation models.
Jan Clemens, Bärbel Vogel, Lars Hoffmann, Sabine Griessbach, Nicole Thomas, Suvarna Fadnavis, Rolf Müller, Thomas Peter, and Felix Ploeger
Atmos. Chem. Phys., 24, 763–787, https://doi.org/10.5194/acp-24-763-2024, https://doi.org/10.5194/acp-24-763-2024, 2024
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The source regions of the Asian tropopause aerosol layer (ATAL) are debated. We use balloon-borne measurements of the layer above Nainital (India) in August 2016 and atmospheric transport models to find ATAL source regions. Most air originated from the Tibetan plateau. However, the measured ATAL was stronger when more air originated from the Indo-Gangetic Plain and weaker when more air originated from the Pacific. Hence, the results indicate important anthropogenic contributions to the ATAL.
Rolf Müller, Ulrich Pöschl, Thomas Koop, Thomas Peter, and Ken Carslaw
Atmos. Chem. Phys., 23, 15445–15453, https://doi.org/10.5194/acp-23-15445-2023, https://doi.org/10.5194/acp-23-15445-2023, 2023
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Paul J. Crutzen was a pioneer in atmospheric sciences and a kind-hearted, humorous person with empathy for the private lives of his colleagues and students. He made fundamental scientific contributions to a wide range of scientific topics in all parts of the atmosphere. Paul was among the founders of the journal Atmospheric Chemistry and Physics. His work will continue to be a guide for generations of scientists and environmental policymakers to come.
Yaowei Li, Corey Pedersen, John Dykema, Jean-Paul Vernier, Sandro Vattioni, Amit Kumar Pandit, Andrea Stenke, Elizabeth Asher, Troy Thornberry, Michael A. Todt, Thao Paul Bui, Jonathan Dean-Day, and Frank N. Keutsch
Atmos. Chem. Phys., 23, 15351–15364, https://doi.org/10.5194/acp-23-15351-2023, https://doi.org/10.5194/acp-23-15351-2023, 2023
Short summary
Short summary
In 2021, the eruption of La Soufrière released sulfur dioxide into the stratosphere, resulting in a spread of volcanic aerosol over the Northern Hemisphere. We conducted extensive aircraft and balloon-borne measurements after that, revealing enhanced particle concentration and altered size distribution due to the eruption. The eruption's impact on ozone depletion was minimal, contributing ~0.6 %, and its global radiative forcing effect was modest, mainly affecting tropical and midlatitude areas.
Franziska Zilker, Timofei Sukhodolov, Gabriel Chiodo, Marina Friedel, Tatiana Egorova, Eugene Rozanov, Jan Sedlacek, Svenja Seeber, and Thomas Peter
Atmos. Chem. Phys., 23, 13387–13411, https://doi.org/10.5194/acp-23-13387-2023, https://doi.org/10.5194/acp-23-13387-2023, 2023
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The Montreal Protocol (MP) has successfully reduced the Antarctic ozone hole by banning chlorofluorocarbons (CFCs) that destroy the ozone layer. Moreover, CFCs are strong greenhouse gases (GHGs) that would have strengthened global warming. In this study, we investigate the surface weather and climate in a world without the MP at the end of the 21st century, disentangling ozone-mediated and GHG impacts of CFCs. Overall, we avoided 1.7 K global surface warming and a poleward shift in storm tracks.
Gabriel Chiodo, Marina Friedel, Svenja Seeber, Daniela Domeisen, Andrea Stenke, Timofei Sukhodolov, and Franziska Zilker
Atmos. Chem. Phys., 23, 10451–10472, https://doi.org/10.5194/acp-23-10451-2023, https://doi.org/10.5194/acp-23-10451-2023, 2023
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Stratospheric ozone protects the biosphere from harmful UV radiation. Anthropogenic activity has led to a reduction in the ozone layer in the recent past, but thanks to the implementation of the Montreal Protocol, the ozone layer is projected to recover. In this study, we show that projected future changes in Arctic ozone abundances during springtime will influence stratospheric climate and thereby actively modulate large-scale circulation changes in the Northern Hemisphere.
Marina Friedel, Gabriel Chiodo, Timofei Sukhodolov, James Keeble, Thomas Peter, Svenja Seeber, Andrea Stenke, Hideharu Akiyoshi, Eugene Rozanov, David Plummer, Patrick Jöckel, Guang Zeng, Olaf Morgenstern, and Béatrice Josse
Atmos. Chem. Phys., 23, 10235–10254, https://doi.org/10.5194/acp-23-10235-2023, https://doi.org/10.5194/acp-23-10235-2023, 2023
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Previously, it has been suggested that springtime Arctic ozone depletion might worsen in the coming decades due to climate change, which might counteract the effect of reduced ozone-depleting substances. Here, we show with different chemistry–climate models that springtime Arctic ozone depletion will likely decrease in the future. Further, we explain why models show a large spread in the projected development of Arctic ozone depletion and use the model spread to constrain future projections.
Tatiana Egorova, Jan Sedlacek, Timofei Sukhodolov, Arseniy Karagodin-Doyennel, Franziska Zilker, and Eugene Rozanov
Atmos. Chem. Phys., 23, 5135–5147, https://doi.org/10.5194/acp-23-5135-2023, https://doi.org/10.5194/acp-23-5135-2023, 2023
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This paper describes the climate and atmosphere benefits of the Montreal Protocol, simulated with the state-of-the-art Earth system model SOCOLv4.0. We have added to and confirmed the previous studies by showing that without the Montreal Protocol by the end of the 21st century there would be a dramatic reduction in the ozone layer as well as substantial perturbation of the essential climate variables in the troposphere caused by the warming from increasing ozone-depleting substances.
Anand Kumar, Kristian Klumpp, Chen Barak, Giora Rytwo, Michael Plötze, Thomas Peter, and Claudia Marcolli
Atmos. Chem. Phys., 23, 4881–4902, https://doi.org/10.5194/acp-23-4881-2023, https://doi.org/10.5194/acp-23-4881-2023, 2023
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Smectites are a major class of clay minerals that are ice nucleation (IN) active. They form platelets that swell or even delaminate in water by intercalation of water between their layers. We hypothesize that at least three smectite layers need to be stacked together to host a critical ice embryo on clay mineral edges and that the larger the surface edge area is, the higher the freezing temperature. Edge sites on such clay particles play a crucial role in imparting IN ability to such particles.
Arseniy Karagodin-Doyennel, Eugene Rozanov, Timofei Sukhodolov, Tatiana Egorova, Jan Sedlacek, and Thomas Peter
Atmos. Chem. Phys., 23, 4801–4817, https://doi.org/10.5194/acp-23-4801-2023, https://doi.org/10.5194/acp-23-4801-2023, 2023
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The future ozone evolution in SOCOLv4 simulations under SSP2-4.5 and SSP5-8.5 scenarios has been assessed for the period 2015–2099 and subperiods using the DLM approach. The SOCOLv4 projects a decline in tropospheric ozone in the 2030s in SSP2-4.5 and in the 2060s in SSP5-8.5. The stratospheric ozone increase is ~3 times higher in SSP5-8.5, confirming the important role of GHGs in ozone evolution. We also showed that tropospheric ozone strongly impacts the total column in the tropics.
Andrey V. Koval, Olga N. Toptunova, Maxim A. Motsakov, Ksenia A. Didenko, Tatiana S. Ermakova, Nikolai M. Gavrilov, and Eugene V. Rozanov
Atmos. Chem. Phys., 23, 4105–4114, https://doi.org/10.5194/acp-23-4105-2023, https://doi.org/10.5194/acp-23-4105-2023, 2023
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Periodic changes in all hydrodynamic parameters are constantly observed in the atmosphere. The amplitude of these fluctuations increases with height due to a decrease in the atmospheric density. In the upper layers of the atmosphere, waves are the dominant form of motion. We use a model of the general circulation of the atmosphere to study the contribution to the formation of the dynamic and temperature regimes of the middle and upper atmosphere made by different global-scale atmospheric waves.
Kristian Klumpp, Claudia Marcolli, Ana Alonso-Hellweg, Christopher H. Dreimol, and Thomas Peter
Atmos. Chem. Phys., 23, 1579–1598, https://doi.org/10.5194/acp-23-1579-2023, https://doi.org/10.5194/acp-23-1579-2023, 2023
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The prerequisites of a particle surface for efficient ice nucleation are still poorly understood. This study compares the ice nucleation activity of two chemically identical but morphologically different minerals (kaolinite and halloysite). We observe, on average, not only higher ice nucleation activities for halloysite than kaolinite but also higher diversity between individual samples. We identify the particle edges as being the most likely site for ice nucleation.
Ilaria Quaglia, Claudia Timmreck, Ulrike Niemeier, Daniele Visioni, Giovanni Pitari, Christina Brodowsky, Christoph Brühl, Sandip S. Dhomse, Henning Franke, Anton Laakso, Graham W. Mann, Eugene Rozanov, and Timofei Sukhodolov
Atmos. Chem. Phys., 23, 921–948, https://doi.org/10.5194/acp-23-921-2023, https://doi.org/10.5194/acp-23-921-2023, 2023
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The last very large explosive volcanic eruption we have measurements for is the eruption of Mt. Pinatubo in 1991. It is therefore often used as a benchmark for climate models' ability to reproduce these kinds of events. Here, we compare available measurements with the results from multiple experiments conducted with climate models interactively simulating the aerosol cloud formation.
Arseniy Karagodin-Doyennel, Eugene Rozanov, Timofei Sukhodolov, Tatiana Egorova, Jan Sedlacek, William Ball, and Thomas Peter
Atmos. Chem. Phys., 22, 15333–15350, https://doi.org/10.5194/acp-22-15333-2022, https://doi.org/10.5194/acp-22-15333-2022, 2022
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Applying the dynamic linear model, we confirm near-global ozone recovery (55°N–55°S) in the mesosphere, upper and middle stratosphere, and a steady increase in the troposphere. We also show that modern chemistry–climate models (CCMs) like SOCOLv4 may reproduce the observed trend distribution of lower stratospheric ozone, despite exhibiting a lower magnitude and statistical significance. The obtained ozone trend pattern in SOCOLv4 is generally consistent with observations and reanalysis datasets.
Nikou Hamzehpour, Claudia Marcolli, Sara Pashai, Kristian Klumpp, and Thomas Peter
Atmos. Chem. Phys., 22, 14905–14930, https://doi.org/10.5194/acp-22-14905-2022, https://doi.org/10.5194/acp-22-14905-2022, 2022
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Playa surfaces in Iran that emerged through Lake Urmia (LU) desiccation have become a relevant dust source of regional relevance. Here, we identify highly erodible LU playa surfaces and determine their physicochemical properties and mineralogical composition and perform emulsion-freezing experiments with them. We find high ice nucleation activities (up to 250 K) that correlate positively with organic matter and clay content and negatively with pH, salinity, K-feldspars, and quartz.
Nikou Hamzehpour, Claudia Marcolli, Kristian Klumpp, Debora Thöny, and Thomas Peter
Atmos. Chem. Phys., 22, 14931–14956, https://doi.org/10.5194/acp-22-14931-2022, https://doi.org/10.5194/acp-22-14931-2022, 2022
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Dust aerosols from dried lakebeds contain mineral particles, as well as soluble salts and (bio-)organic compounds. Here, we investigate ice nucleation (IN) activity of dust samples from Lake Urmia playa, Iran. We find high IN activity of the untreated samples that decreases after organic matter removal but increases after removing soluble salts and carbonates, evidencing inhibiting effects of soluble salts and carbonates on the IN activity of organic matter and minerals, especially microcline.
Marina Friedel, Gabriel Chiodo, Andrea Stenke, Daniela I. V. Domeisen, and Thomas Peter
Atmos. Chem. Phys., 22, 13997–14017, https://doi.org/10.5194/acp-22-13997-2022, https://doi.org/10.5194/acp-22-13997-2022, 2022
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In spring, winds the Arctic stratosphere change direction – an event called final stratospheric warming (FSW). Here, we examine whether the interannual variability in Arctic stratospheric ozone impacts the timing of the FSW. We find that Arctic ozone shifts the FSW to earlier and later dates in years with high and low ozone via the absorption of UV light. The modulation of the FSW by ozone has consequences for surface climate in ozone-rich years, which may result in better seasonal predictions.
Clare E. Singer, Benjamin W. Clouser, Sergey M. Khaykin, Martina Krämer, Francesco Cairo, Thomas Peter, Alexey Lykov, Christian Rolf, Nicole Spelten, Armin Afchine, Simone Brunamonti, and Elisabeth J. Moyer
Atmos. Meas. Tech., 15, 4767–4783, https://doi.org/10.5194/amt-15-4767-2022, https://doi.org/10.5194/amt-15-4767-2022, 2022
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In situ measurements of water vapor in the upper troposphere are necessary to study cloud formation and hydration of the stratosphere but challenging due to cold–dry conditions. We compare measurements from three water vapor instruments from the StratoClim campaign in 2017. In clear sky (clouds), point-by-point differences were <1.5±8 % (<1±8 %). This excellent agreement allows detection of fine-scale structures required to understand the impact of convection on stratospheric water vapor.
Irina Mironova, Miriam Sinnhuber, Galina Bazilevskaya, Mark Clilverd, Bernd Funke, Vladimir Makhmutov, Eugene Rozanov, Michelle L. Santee, Timofei Sukhodolov, and Thomas Ulich
Atmos. Chem. Phys., 22, 6703–6716, https://doi.org/10.5194/acp-22-6703-2022, https://doi.org/10.5194/acp-22-6703-2022, 2022
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From balloon measurements, we detected unprecedented, extremely powerful, electron precipitation over the middle latitudes. The robustness of this event is confirmed by satellite observations of electron fluxes and chemical composition, as well as by ground-based observations of the radio signal propagation. The applied chemistry–climate model shows the almost complete destruction of ozone in the mesosphere over the region where high-energy electrons were observed.
Kristian Klumpp, Claudia Marcolli, and Thomas Peter
Atmos. Chem. Phys., 22, 3655–3673, https://doi.org/10.5194/acp-22-3655-2022, https://doi.org/10.5194/acp-22-3655-2022, 2022
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Surface interactions with solutes can significantly alter the ice nucleation activity of mineral dust. Past studies revealed the sensitivity of microcline, one of the most ice-active types of dust in the atmosphere, to inorganic solutes. This study focuses on the interaction of microcline with bio-organic substances and the resulting effects on its ice nucleation activity. We observe strongly hampered ice nucleation activity due to the presence of carboxylic and amino acids but not for polyols.
Debra K. Weisenstein, Daniele Visioni, Henning Franke, Ulrike Niemeier, Sandro Vattioni, Gabriel Chiodo, Thomas Peter, and David W. Keith
Atmos. Chem. Phys., 22, 2955–2973, https://doi.org/10.5194/acp-22-2955-2022, https://doi.org/10.5194/acp-22-2955-2022, 2022
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This paper explores a potential method of geoengineering that could be used to slow the rate of change of climate over decadal scales. We use three climate models to explore how injections of accumulation-mode sulfuric acid aerosol change the large-scale stratospheric particle size distribution and radiative forcing response for the chosen scenarios. Radiative forcing per unit sulfur injected and relative to the change in aerosol burden is larger with particulate than with SO2 injections.
Kseniia Golubenko, Eugene Rozanov, Gennady Kovaltsov, Ari-Pekka Leppänen, Timofei Sukhodolov, and Ilya Usoskin
Geosci. Model Dev., 14, 7605–7620, https://doi.org/10.5194/gmd-14-7605-2021, https://doi.org/10.5194/gmd-14-7605-2021, 2021
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A new full 3-D time-dependent model, based on SOCOL-AERv2, of beryllium atmospheric production, transport, and deposition has been developed and validated using directly measured data. The model is recommended to be used in studies related to, e.g., atmospheric dynamical patterns, extreme solar particle storms, long-term solar activity reconstruction from cosmogenic proxy data, and solar–terrestrial relations.
Arseniy Karagodin-Doyennel, Eugene Rozanov, Timofei Sukhodolov, Tatiana Egorova, Alfonso Saiz-Lopez, Carlos A. Cuevas, Rafael P. Fernandez, Tomás Sherwen, Rainer Volkamer, Theodore K. Koenig, Tanguy Giroud, and Thomas Peter
Geosci. Model Dev., 14, 6623–6645, https://doi.org/10.5194/gmd-14-6623-2021, https://doi.org/10.5194/gmd-14-6623-2021, 2021
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Here, we present the iodine chemistry module in the SOCOL-AERv2 model. The obtained iodine distribution demonstrated a good agreement when validated against other simulations and available observations. We also estimated the iodine influence on ozone in the case of present-day iodine emissions, the sensitivity of ozone to doubled iodine emissions, and when considering only organic or inorganic iodine sources. The new model can be used as a tool for further studies of iodine effects on ozone.
Timofei Sukhodolov, Tatiana Egorova, Andrea Stenke, William T. Ball, Christina Brodowsky, Gabriel Chiodo, Aryeh Feinberg, Marina Friedel, Arseniy Karagodin-Doyennel, Thomas Peter, Jan Sedlacek, Sandro Vattioni, and Eugene Rozanov
Geosci. Model Dev., 14, 5525–5560, https://doi.org/10.5194/gmd-14-5525-2021, https://doi.org/10.5194/gmd-14-5525-2021, 2021
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This paper features the new atmosphere–ocean–aerosol–chemistry–climate model SOCOLv4.0 and its validation. The model performance is evaluated against reanalysis products and observations of atmospheric circulation and trace gas distribution, with a focus on stratospheric processes. Although we identified some problems to be addressed in further model upgrades, we demonstrated that SOCOLv4.0 is already well suited for studies related to chemistry–climate–aerosol interactions.
Ralf Weigel, Christoph Mahnke, Manuel Baumgartner, Antonis Dragoneas, Bärbel Vogel, Felix Ploeger, Silvia Viciani, Francesco D'Amato, Silvia Bucci, Bernard Legras, Beiping Luo, and Stephan Borrmann
Atmos. Chem. Phys., 21, 11689–11722, https://doi.org/10.5194/acp-21-11689-2021, https://doi.org/10.5194/acp-21-11689-2021, 2021
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In July and August 2017, eight StratoClim mission flights of the Geophysica reached up to 20 km in the Asian monsoon anticyclone. New particle formation (NPF) was identified in situ by abundant nucleation-mode aerosols (6–15 nm in diameter) with mixing ratios of up to 50 000 mg−1. NPF occurred most frequently at 12–16 km with fractions of non-volatile residues of down to 15 %. Abundance and productivity of observed NPF indicate its ability to promote the Asian tropopause aerosol layer.
Michael Weimer, Jennifer Buchmüller, Lars Hoffmann, Ole Kirner, Beiping Luo, Roland Ruhnke, Michael Steiner, Ines Tritscher, and Peter Braesicke
Atmos. Chem. Phys., 21, 9515–9543, https://doi.org/10.5194/acp-21-9515-2021, https://doi.org/10.5194/acp-21-9515-2021, 2021
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We show that we are able to directly simulate polar stratospheric clouds formed locally in a mountain wave and represent their effect on the ozone chemistry with the global atmospheric chemistry model ICON-ART. Thus, we show the first simulations that close the gap between directly resolved mountain-wave-induced polar stratospheric clouds and their representation at coarse global resolutions.
Margot Clyne, Jean-Francois Lamarque, Michael J. Mills, Myriam Khodri, William Ball, Slimane Bekki, Sandip S. Dhomse, Nicolas Lebas, Graham Mann, Lauren Marshall, Ulrike Niemeier, Virginie Poulain, Alan Robock, Eugene Rozanov, Anja Schmidt, Andrea Stenke, Timofei Sukhodolov, Claudia Timmreck, Matthew Toohey, Fiona Tummon, Davide Zanchettin, Yunqian Zhu, and Owen B. Toon
Atmos. Chem. Phys., 21, 3317–3343, https://doi.org/10.5194/acp-21-3317-2021, https://doi.org/10.5194/acp-21-3317-2021, 2021
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This study finds how and why five state-of-the-art global climate models with interactive stratospheric aerosols differ when simulating the aftermath of large volcanic injections as part of the Model Intercomparison Project on the climatic response to Volcanic forcing (VolMIP). We identify and explain the consequences of significant disparities in the underlying physics and chemistry currently in some of the models, which are problems likely not unique to the models participating in this study.
Manuel Graf, Philipp Scheidegger, André Kupferschmid, Herbert Looser, Thomas Peter, Ruud Dirksen, Lukas Emmenegger, and Béla Tuzson
Atmos. Meas. Tech., 14, 1365–1378, https://doi.org/10.5194/amt-14-1365-2021, https://doi.org/10.5194/amt-14-1365-2021, 2021
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Water vapor is the most important natural greenhouse gas. The accurate and frequent measurement of its abundance, especially in the upper troposphere and lower stratosphere (UTLS), is technically challenging. We developed and characterized a mid-IR absorption spectrometer for highly accurate water vapor measurements in the UTLS. The instrument is sufficiently small and lightweight (3.9 kg) to be carried by meteorological balloons, which enables frequent and cost-effective soundings.
Michael Steiner, Beiping Luo, Thomas Peter, Michael C. Pitts, and Andrea Stenke
Geosci. Model Dev., 14, 935–959, https://doi.org/10.5194/gmd-14-935-2021, https://doi.org/10.5194/gmd-14-935-2021, 2021
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We evaluate polar stratospheric clouds (PSCs) as simulated by the chemistry–climate model (CCM) SOCOLv3.1 in comparison with measurements by the CALIPSO satellite. A cold bias results in an overestimated PSC area and mountain-wave ice is underestimated, but we find overall good temporal and spatial agreement of PSC occurrence and composition. This work confirms previous studies indicating that simplified PSC schemes may also achieve good approximations of the fundamental properties of PSCs.
Teresa Jorge, Simone Brunamonti, Yann Poltera, Frank G. Wienhold, Bei P. Luo, Peter Oelsner, Sreeharsha Hanumanthu, Bhupendra B. Singh, Susanne Körner, Ruud Dirksen, Manish Naja, Suvarna Fadnavis, and Thomas Peter
Atmos. Meas. Tech., 14, 239–268, https://doi.org/10.5194/amt-14-239-2021, https://doi.org/10.5194/amt-14-239-2021, 2021
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Balloon-borne frost point hygrometers are crucial for the monitoring of water vapour in the upper troposphere and lower stratosphere. We found that when traversing a mixed-phase cloud with big supercooled droplets, the intake tube of the instrument collects on its inner surface a high percentage of these droplets. The newly formed ice layer will sublimate at higher levels and contaminate the measurement. The balloon is also a source of contamination, but only at higher levels during the ascent.
Jing Dou, Peter A. Alpert, Pablo Corral Arroyo, Beiping Luo, Frederic Schneider, Jacinta Xto, Thomas Huthwelker, Camelia N. Borca, Katja D. Henzler, Jörg Raabe, Benjamin Watts, Hartmut Herrmann, Thomas Peter, Markus Ammann, and Ulrich K. Krieger
Atmos. Chem. Phys., 21, 315–338, https://doi.org/10.5194/acp-21-315-2021, https://doi.org/10.5194/acp-21-315-2021, 2021
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Photochemistry of iron(III) complexes plays an important role in aerosol aging, especially in the lower troposphere. Ensuing radical chemistry leads to decarboxylation, and the production of peroxides, and oxygenated volatile compounds, resulting in particle mass loss due to release of the volatile products to the gas phase. We investigated kinetic transport limitations due to high particle viscosity under low relative humidity conditions. For quantification a numerical model was developed.
Arseniy Karagodin-Doyennel, Eugene Rozanov, Ales Kuchar, William Ball, Pavle Arsenovic, Ellis Remsberg, Patrick Jöckel, Markus Kunze, David A. Plummer, Andrea Stenke, Daniel Marsh, Doug Kinnison, and Thomas Peter
Atmos. Chem. Phys., 21, 201–216, https://doi.org/10.5194/acp-21-201-2021, https://doi.org/10.5194/acp-21-201-2021, 2021
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The solar signal in the mesospheric H2O and CO was extracted from the CCMI-1 model simulations and satellite observations using multiple linear regression (MLR) analysis. MLR analysis shows a pronounced and statistically robust solar signal in both H2O and CO. The model results show a general agreement with observations reproducing a negative/positive solar signal in H2O/CO. The pattern of the solar signal varies among the considered models, reflecting some differences in the model setup.
Cited articles
Bodeker, G. E., Shiona, H., and Eskes, H.: Indicators of Antarctic ozone depletion, Atmos. Chem. Phys., 5, 2603–2615, https://doi.org/10.5194/acp-5-2603-2005, 2005.
Butchart, N., Charlton-Perez, A. J., Cionni, I., Hardiman, S. C., Haynes, P. H., Krüger, K., Kushner, P. J., Newman, P. A., Osprey, S. M., Perlwitz, J., Sigmond, M., Wang, L., Akiyoshi, H., Austin, J., Bekki, S., Baumgaertner, A., Braesicke, P., Brühl, C., Chipperfield, M., Dameris, M., Dhomse, S., Eyring, V., Garcia, R., Garny, H., Jöckel, P., Lamarque, J.-F., Marchand, M., Michou, M., Morgenstern, O., Nakamura, T., Pawson, S., Plummer, D., Pyle, J., Rozanov, E., Scinocca, J., Shepherd, T. G., Shibata, K., Smale, D., Teyssédre, H., Tian, W., Waugh, D., and Yamashita, Y.: Multimodel climate and variability of the stratosphere, J. Geophys. Res., 116, D05102, https://doi.org/10.1029/2010JD014995, 2011.
Cagnazzo, C., Manzini, E., Giorgetta, M. A., Forster, P. M. De F., and Morcrette, J. J.: Impact of an improved shortwave radiation scheme in the MAECHAM5 General Circulation Model, Atmos. Chem. Phys., 7, 2503–2515, https://doi.org/10.5194/acp-7-2503-2007, 2007.
Carslaw, K. S., Luo, B. P., and Peter, T.: An analytic-expression for the composition of aqueous HNO3–H2SO4 stratospheric aerosols including gas-phase removal of HNO3, Geophys. Res. Lett., 22, 1877–1880, 1995.
Courant, R., Friedrichs, K., and Levy, H.: Über die partiellen Differenzengleichungen der mathematischen Physik, Math. Ann., 100, 32–74, 1928.
Dameris, M., Grewe, V., Ponater, M., Deckert, R., Eyring, V., Mager, F., Matthes, S., Schnadt, C., Stenke, A., Steil, B., Brühl, C., and Giorgetta, M. A.: Long-term changes and variability in a transient simulation with a chemistry-climate model employing realistic forcing, Atmos. Chem. Phys., 5, 2121–2145, https://doi.org/10.5194/acp-5-2121-2005, 2005.
Egorova, T., Rozanov, E., Schlesinger, M. E., Andronova, N. G., Malyshev, S. L., Zubov, V., and Karol, I. L.: Assessment of the effect of the Montreal Protocol on atmospheric ozone, Geophys. Res. Lett., 28, 2389–2392, 2001.
Egorova, T., Rozanov, E., Zubov, V., and Karol, I. L.: Model for Investigating Ozone Trends (MEZON), Izvestiya, Atmos. Oceanic Phys., 39, 277–292, 2003.
Egorova, T., Rozanov, E., Manzini, E., Haberreiter, M., Schmutz, W., Zubov, V., and Peter, T.: Chemical and dynamical response to the 11-yr variability of the solar irradiance simulated with a chemistry-climate model, Geophys. 31, L06119, https://doi.org/10.1029/2003GL019294, 2004.
Egorova, T., Rozanov, E., Zubov, V., Manzini, E., Schmutz, W., and Peter, T.: Chemistry-climate model SOCOL: a validation of the present-day climatology, Atmos. Chem. Phys., 5, 1557–1576, https://doi.org/10.5194/acp-5-1557-2005, 2005.
Eyring, V., Butchart, N., Waugh, D. W., Akiyoshi, H., Austin, J., Bekki, S., Bodeker, G. E., Boville, B. A., Brühl, C., Chipperfield, M. P., Cordero, E., Dameris, M., Deushi, M., Fioletov, V. E., Frith, S. M., Garcia, R. R., Gettelman, A., Giorgetta, M. A., Greve, V., Jourdain, L., Kinnison, D. E., Mancini, E., Manzini, E., Marchand, M., Marsh, D. R., Nagashima, T., Newman, P. A., Nielsen, J. E., Pawson, S., Pitari, G., Plummer, D. A., Rozanov, E., Schraner, M., Shepherd, T. G., Shibata, K., Stolarski, R. S., Struthers, H., Tian, W., and Yoshiki, M.: Assessment of temperature, trace species, and ozone in chemistry-climate model simulations of the recent past, J. Geophys. Res., 111, D22308, https://doi.org/10.1029/2006JD007327, 2006.
Eyring, V., Chipperfield, M., Giorgetta, M., Kinnison, D., Manzini, E., Matthes, K., Newman, P., Pawson, S., Shepherd, T., and Waugh, D.: Overview of the New CCMVal Reference and Sensitivity Simulations in Support of Upcoming Ozone and Climate Assessments and the Planned SPARC CCMVal, SPARC Newsletter No. 30, 20–26, available at: http://www.atmosp.physics.utoronto.ca/SPARC/Newsletter30Web/53294-120Newsletter-LR.pdf, 2008.
Fouquart, Y. and Bonnel, B.: Computations of solar heating of the Earth's atmosphere: A new parameterization, Beitr. Phys. Atmos., 53, 35–62, 1980.
Gelman, M. E., Miller, A. J., Johnson, K. W., and Nagatani, R.: Detection of long-term trends in global stratospheric temperature from NMC analyses derived from NOAA satellite data, Adv. Space Res., 6, 17–26, 1996.
Gettelman, A., Birner, T., Eyring, V., Akiyoshi, H., Bekki, S., Brühl, C., Dameris, M., Kinnison, D. E., Lefevre, F., Lott, F., Mancini, E., Pitari, G., Plummer, D. A., Rozanov, E., Shibata, K., Stenke, A., Struthers, H., and Tian, W.: The Tropical Tropopause Layer 1960–2100, Atmos. Chem. Phys., 9, 1621–1637, https://doi.org/10.5194/acp-9-1621-2009, 2009.
Giorgetta, M. A.: Der Einfluss der quasi-zweijährigen Oszillation: Modellrechnungen mit ECHAM4, Max-Planck-Institut für Meteorologie, Hamburg, Examensarbeit Nr. 40, MPI-Report 218, 1996.
Giorgetta, M. A., Manzini, E., Roeckner, E., Esch, M., and Bengtsson, L.: Climatology and forcing of the quasi-biennial oscillation in the MAECHAM5 model, J. Climate, 19, 3882–3901, 2006.
Grewe, V. and Sausen, R.: Comment on "Quantitative performance metrics for stratospheric-resolving chemistry-climate models" by Waugh and Eyring (2008), Atmos. Chem. Phys., 9, 9101–9110, https://doi.org/10.5194/acp-9-9101-2009, 2009.
Grooß, J.-U. and Russell III, J. M.: Technical note: A stratospheric climatology for O3, H2O, CH4, NOx, HCl and HF derived from HALOE measurements, Atmos. Chem. Phys., 5, 2797–2807, https://doi.org/10.5194/acp-5-2797-2005, 2005.
Hall, T. M. and Prather, M. J.: Simulations of the trend and annual cycle in stratospheric CO2, J. Geophys. Res., 98, 10573–10581, https://doi.org/10.1029/93JD00325, 1993.
Hanson, D. and Ravishankara, A.: Reactive Uptake of ClONO2 onto Sulfuric Acid Due to Reaction with HCl and H2O, J. Phys. Chem., 98, 5728–5735, 1994.
Hanson, D., Ravishankara, A., and Lovejoy, E. R.:, Reaction of BrONO2 with H2O on submicron sulfuric acid aerosol and the implications for the lower stratosphere, J. Geophys. Res., 101, 9063–9069, 1996.
Hauglustaine, D. A., Granier, C., Brasseur, G., and Megie G.: The importance of atmospheric chemistry in the calculation of radiative forcing on the climate system, J. Geophys. Res., 99, 1173–1186, 1994.
Hines, C. O.: Doppler spread parameterization of gravity wave momentum deposition in the middle atmosphere, 1, Basic formulation, J. Atmos. Solar Terr. Phys., 59, 371–386, 1997a.
Hines, C. O.: Doppler spread parameterization of gravity wave momentum deposition in the middle atmosphere, 2, Broad and quasi monochromatic spectra and implementation, J. Atmos. Solar Terr. Phys., 59, 387–400, 1997b.
Horowitz, L. W., Walters, S., Mauzerall, D. L., Emmons, L. K., Rasch, P. J., Granier, C., Tie, X., Lamarque, J.-F., Schultz, M. G., Tyndall, G. S., Orlando, J. J., and Brasseur, G. P.: A global simulation of tropospheric ozone and related tracers: Description and evaluation of MOZART, version 2, J. Geophys. Res., 108, 4784, https://doi.org/10.1029/2002JD002853, 2003.
Hoyle, C. R.: Three dimensional chemical transport model study of ozone and related gases 1960–2000, Eidgenössische Technische Hochschule, Zürich, Dissertation No. 16271, available at: http://e-collection.ethbib.ethz.ch/eserv/eth:28651/eth-28651-01.pdf, 2005.
Intergovernmental Panel on Climate Change (IPCC): The scientific basis, Contribution of working group I to the third assessment report of the Intergovernmental Panel on Climate Change, Cambridge University Press, Cambridge, UK and New York, NY, USA, 2001.
Jöckel, P., von Kuhlmann, R., Lawrence, M. G., Steil, B., Brenninkmeijer, C. A. M., Crutzen, P. J., Rasch, P. J., and Eaton, B.: On a fundamental problem in implementing flux-form advection schemes for tracer transport in 3-dimensional general circulation and chemistry transport models, Q. J. R. Meteorol. Soc., 127, 1035–1052, 2001.
Lean, J., Rottman, G., Harder, J., and Kopp, G.: SORCE contributions to new understanding of global change and solar variability, Sol. Phys., 230, 27–53, 2005.
Lin, S. J. and Rood, R. B.: Multidimensional flux-form semi-Lagrangian transport schemes, Mon. Weather Rev., 124, 2046–2068, 1996.
Lohmann, U., Feichter, J., Chuang, C. C., and Penner, J.: Prediction of the number of cloud droplets in the ECHAM GCM, J. Geophys. Res., 104, 9169–9198, 1999.
Manzini, E. and Bengtsson, L.: Stratospheric climate and variability from a general circulation model and observations, Clim. Dynam., 12, 615–639, 1996.
Manzini, E. and Feichter, J.: Simulation of the SF6 tracer with the middle atmosphere MAECHAM4 model: Aspects of the large-scale transport, J. Geophys. Res., 104, 31097–31108, 1999.
Manzini, E., Giorgetta, M. A., Esch, M., Kornblueh, L., and Roeckner, E.: The influence of sea surface temperatures on the Northern winter stratosphere: Ensemble simulations with the MAECHAM5 model, J. Climate, 19, 3863–3881, 2006.
Milz, M., Clarmann, T. v., Bernath, P., Boone, C., Buehler, S. A., Chauhan, S., Deuber, B., Feist, D. G., Funke, B., Glatthor, N., Grabowski, U., Griesfeller, A., Haefele, A., Höpfner, M., Kämpfer, N., Kellmann, S., Linden, A., Müller, S., Nakajima, H., Oelhaf, H., Remsberg, E., Rohs, S., Russell III, J. M., Schiller, C., Stiller, G. P., Sugita, T., Tanaka, T., Vömel, H., Walker, K., Wetzel, G., Yokota, T., Yushkov, V., and Zhang, G.: Validation of water vapour profiles (version 13) retrieved by the IMK/IAA scientific retrieval processor based on full resolution spectra measured by MIPAS on board Envisat, Atmos. Meas. Tech., 2, 379–399, https://doi.org/10.5194/amt-2-379-2009, 2009.
Mlawer, E., Taubman, S., Brown, P., Iacono, M., and Clough, S.: Radiative transfer for inhomogeneous atmospheres: RRTM, a validated correlated-k model for the longwave, J. Geophys. Res., 102, 16663–16682, 1997.
Monge-Sanz, B. M., Chipperfield, M. P., Simmons, A. J., and Uppala, S. M.: Mean age of air and transport in a CTM: Comparison of different ECMWF analyses, Geophys. Res. Lett., 34, L04801, https://doi.org/10.1029/2006GL028515, 2007.
Mote, P., Rosenlof, K., Mclntyre, M., Carr, E., Gille, J., Holton, J., Kinnersley, J., Pumphrey, H., Russell III, J., and Waters, J.: An atmospheric tape recorder: The imprint of tropical tropopause temperatures on stratospheric water vapor, J. Geophys. Res., 101, 3989–4006, 1996.
Newman, P., Nash, E., and Rosenfield, D.: What controls the temperature of the Arctic stratosphere during spring?, J. Geophys. Res., 106, 19999–20010, 2001.
Ozolin, Y.: Modelling of diurnal variations of gas species in the atmosphere and diurnal averaging in photochemical models, Izv. Akad. Nauk. Phys. Atmos. Ocean., 28, 135–143, 1992.
Pawson, S., Kodera, K., Hamilton, K., Shepherd, T. G., Beagley, S. R., Boville, B., Farrara, J. D., Fairlie, T. D. A, Kitoh, A., Lahoz, W. A., Langematz, U., Manzini, E., Rind, D. H., Scaife, A. A., Shibata, K., Simon, P., Swinbank, R., Takacs, L., Wilson, R., Al-Saadi, J. A., Amodei, M., Chiba, M., Coy, L., de Grandpre, J., Eckman, R. S., Fiorino, M., Grose, W. L., Koide, H., Koshyk, J. N., Li, D., Lerner, J., Mahlman, J. D., McFarlane, N. A., Mechoso, C. R., Molod, A., O'Neill, A., Pierce, R. B., Randel, W. J., Rood, R. B., and Wu, F.: The GCM-reality inter-comparison project of SPARC (GRIPS): scientific issues and initial results, B. Am. Meteorol. Soc., 81, 781–796, 2000.
Prather, M. J.: Numerical Advection by Conservation of Second-Order Moments, J. Geophys. Res., 91, 6671–6681, 1986.
Pruppacher, H. and Klett, J.: Microphysics of clouds and precipitation, Springer, Dordrecht, The Netherlands, 2nd Edn., 1997.
Randel, W., Udelhofen, P., Fleming, E., Geller, M., Gelman, M., Hamilton, K., Karoly, D., Ortland, D., Pawson, S., Swonbank, R., Wu, F., Baldwin, M., Chanin, M.-L., Keckhut, P., Labitzke, K., Remsberg, E., Simmons, A., and Wu, D.: The SPARC Intercomparison of Middle-Atmosphere Climatologies, J. Climate, 17, 986–1003, 2004.
Rasch, P. J. and Lawrence, M. G.: Recent developments in transport methods at NCAR. Proceedings of the MPI Workshop on Conservative Transport Methods, B. Machenhauer, Ed., Max Planck Institute for Meteorology Rep. 265, Hamburg, Germany, 65–75, 1998.
Rasch, P. J., Coleman, D. B., Mahowald, N., Williamson, D. L., Lin, S.-J., Boville, B. A., and Hess, P.: Characteristics of Atmospheric Transport Using Three Numerical Formulations for Atmospheric Dynamics in a Single GCM Framework, J. Climate, 19, 2243–2266, 2006.
Rayner, N. A., Parker, D. E., Horton, E. B., Folland, C. K., Alexander, L. V., and Rowell, D. R.: Global analyses of sea surface temperature, sea ice, and night marine air temperature since the late nineteenth century, J. Geophys. Res., 108, 4407, https://doi.org/10.1029/2002JD002670, 2003.
Ritchie, H.: Application of a semi-Lagrangian integration scheme to the moisture equation in a regional forecast model, Mon. Weather Rev., 113, 424–435, 1985.
Roche, A. E., Kumer, J. B., Mergenthaler, J. L., Ely, G. A., Uplinger, W. G., Potter, J. F., James, T. C., and Sterritt, L. W.: The Cryogenic Limb Array Etalon Spectrometer (CLAES) on UARS: Experiment Description and Performance, J. Geophys. Res., 98, 10763–10775, 1993.
Roche, A. E., Kumer, J. B., Mergenthaler, J. L., Nightingale, R. W., Uplinger, W. G., Ely, G. A., Potter, J. F., Wuebbles, D. J., Connell, P. S., and Kinnison, D. E.: Observations of Lower Stratospheric ClONO2, HNO3, and Aerosol by the UARS CLAES Experiment, between January 1992 and April 1993, J. Atmos. Sci., 51, 2877, https://doi.org/10.1175/1520-0469(1994)051<2877:OOLSCH>2.0.CO;2, 1994.
Roeckner, E., Arpe, K., Bengtsson, L., Christoph, M., Claussen, M., Dümenil, L., Esch, M., Giorgetta, M., Schlese, U., and Schulzweida, U.: The atmospheric general circulation model ECHAM-4: Model description and simulation of present day-climate, Max-Planck-Institut für Meteorologie, Hamburg, Report No. 218, 1996.
Roeckner, E., Bäuml, G., Bonaventura, L., Brokopf, R., Esch, M., Giorgetta, M., Hagemann, S., Kirchner, I., Kornblueh, L., Manzini, E., Rhodin, A., Schlese, U., Schulzweida, U., and Tompkins, A.: The atmospheric general circulation model ECHAM 5. PART I: Model description, Max-Planck-Institut für Meteorologie, Hamburg, Report No. 349, available at: http://www.mpimet.mpg.de/fileadmin/publikationen/Reports/max_scirep_349.pdf, last access: 2 September 2013, 2003.
Roeckner, E., Brokopf, R., Esch, M., Giorgetta, M., Hagemann, S., Kornblueh, L., Manzini, E., Schlese, U., and Schulzweida, U.: Sensitivity of simulated climate to horizontal and vertical resolution in the ECHAM5 atmosphere model, J. Climate, 19, 3771–3791, 2006.
Rozanov, E., Schlesinger, M. E., Zubov, V., Yang, F., and Andronova, N. G.: The UIUC three-dimensional stratospheric chemical transport model: Description and evaluation of the simulated source gases and ozone, J. Geophys. Res., 104, 11755–11781, 1999.
Rozanov, E., Schlesinger, M. E., and Zubov, V.: The University of Illinois, Urbana-Champaign three-dimensional stratosphere-troposphere general circulation model with interactive ozone photochemistry: Fifteen-year control run climatology, J. Geophys. Res., 106, 27233–27254, 2001.
Sander, S. P., Friedl, R. R., Golden, D. M., Kurylo, M. J., Moortgat, G. K., Keller-Rudek, H., Wine, P. H., Ravishankara, A. R., Kolb, C. E., Molina, M. J., Finlayson-Pitts, B. J., Huie, R. E., and Orkin, V. L.: Chemical kinetics and photochemical data for use in atmospheric studies, Evaluation Number 15, JPL Publication 06-2, Jet Propulsion Laboratory, Pasadena, 2006.
Schraner, M., Rozanov, E., Schnadt Poberaj, C., Kenzelmann, P., Fischer, A. M., Zubov, V., Luo, B. P., Hoyle, C. R., Egorova, T., Fueglistaler, S., Brönnimann, S., Schmutz, W., and Peter, T.: Technical Note: Chemistry-climate model SOCOL: version 2.0 with improved transport and chemistry/microphysics schemes, Atmos. Chem. Phys., 8, 5957–5974, https://doi.org/10.5194/acp-8-5957-2008, 2008.
Schultz, M. and Rast, S. (Eds.): Emission data sets and methodologies for estimating emissions (http://retro.enes.org/reports/D1-6_final.pdf), REanalysis of the TROpospheric chemical composition over the past 40 years, A long-term global modelling study of tropospheric chemistry funded under the 5th EU framework programme, EUContract No. EVK2-CT-2002-00170, 2007.
Simmons, A. J., Burridge, D. M., Jarraud, M., Girard, C., and Wergen, W.: The ECMWF medium-range prediction model: Development of the numerical formulations and the impact of increased resolution, Meteorol. Atmos. Phys., 40, 28–60, 1989.
Simmons, A., Uppala, S., Dee, D., and Kobayashi, S.: ERA-Interim: New ECMWF reanalysis products from 1989 onwards, ECMWF Newsletter, No. 110, Winter 2006.
SPARC: SPARC Report on the Evaluation of Chemistry-Climate Models, edited by: Eyring, V., Shepherd, T. G., and Waugh, D. W., SPARC Report No. 5, WCRP-132, WMO/TD-No. 1526, http://www.atmosp.physics.utoronto.ca/SPARC, 2010.
Stenke, A., Grewe, V., and Ponater, M.: Lagrangian transport of water vapour and cloud water in the ECHAM4 GCM and its impact on the cold bias, Clim. Dynam., 31, 491–506, https://doi.org/10.1007/s00382-007-0347-5, 2008.
Stenke, A., Dameris, M., Grewe, V., and Garny, H.: Implications of Lagrangian transport for simulations with a coupled chemistry-climate model, Atmos. Chem. Phys., 9, 5489–5504, https://doi.org/10.5194/acp-9-5489-2009, 2009.
Stott, P. A. and Harwood, R. S.: An implicit time-stepping scheme for chemical species in a global atmospheric circulation model, Ann. Geophys., 11, 377–388, 1993.
Struthers, H., Bodeker, G. E., Austin, J., Bekki, S., Cionni, I., Dameris, M., Giorgetta, M. A., Grewe, V., Lefèvre, F., Lott, F., Manzini, E., Peter, T., Rozanov, E., and Schraner, M.: The simulation of the Antarctic ozone hole by chemistry-climate models, Atmos. Chem. Phys., 9, 6363–6376, https://doi.org/10.5194/acp-9-6363-2009, 2009.
Swinbank, R. and O' Neill, A.: A stratosphere-troposphere data assimilation system, Mon. Weather Rev., 122, 686–702, 1994.
Thomason, L. and Peter, T.: Assessment of Stratospheric Aerosol Properties (ASAP), SPARC Report No. 4., WCRP-124, WMO/TD-No. 1295, 2006.
Turman, B. N. and Edgar, B. C.: Global lightning distributions at dawn and dusk, J. Geophys. Res., 87, 1191–1206, 1982.
Waugh, D. W. and Eyring, V.: Quantitative performance metrics for stratospheric-resolving chemistry-climate models, Atmos. Chem. Phys., 8, 5699–5713, https://doi.org/10.5194/acp-8-5699-2008, 2008.
Williamson, D. L. and Rasch, P. J.: Two-dimensional semi-Lagrangian transport with shape-preserving interpolation, Mon. Weather Rev., 117, 102–129, 1989.
WMO: Scientific assessment of ozone depletion: 2006, Global ozone research and monitoring project-report No. 50, World Meteo., Geneva, Switzerland, 2007.
Zubov, V., Rozanov, E., and Schlesinger, M. E.: Hybrid scheme for three-dimensional advective transport, Mon. Weather Rev., 127, 1335–1346, 1999.
