Articles | Volume 15, issue 1
https://doi.org/10.5194/gmd-15-15-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/gmd-15-15-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
PyCO2SYS v1.8: marine carbonate system calculations in Python
Matthew P. Humphreys
CORRESPONDING AUTHOR
Department of Ocean Systems (OCS), NIOZ Royal Netherlands Institute for Sea Research, Texel, the Netherlands
Ernie R. Lewis
Environmental and Climate Sciences Department, Brookhaven National Laboratory, Upton, NY, USA
Jonathan D. Sharp
Cooperative Institute for Climate, Ocean, and Ecosystem Studies, University of Washington, Seattle, WA, USA
Pacific Marine Environmental Laboratory, National Oceanic and Atmospheric Administration, Seattle, WA, USA
Denis Pierrot
Atlantic Oceanographic and Meteorological Laboratory, National Oceanic and Atmospheric Administration, Miami, FL, USA
Related authors
Matthew P. Humphreys
EGUsphere, https://doi.org/10.5194/egusphere-2024-626, https://doi.org/10.5194/egusphere-2024-626, 2024
Short summary
Short summary
The ocean absorbs carbon dioxide (CO2) from the atmosphere, which slows down climate change. Seawater CO2 absorption is controlled by a property called ƒCO2. This ƒCO2 changes as seawater warms up or cools down, but we haven’t known for sure how much it changes, with different measurements and calculations giving inconsistent results. Here, we work out how ƒCO2 should theoretically respond to temperature change and show that this is consistent with both measurements and calculations.
Siv K. Lauvset, Nico Lange, Toste Tanhua, Henry C. Bittig, Are Olsen, Alex Kozyr, Marta Álvarez, Kumiko Azetsu-Scott, Peter J. Brown, Brendan R. Carter, Leticia Cotrim da Cunha, Mario Hoppema, Matthew P. Humphreys, Masao Ishii, Emil Jeansson, Akihiko Murata, Jens Daniel Müller, Fiz F. Perez, Carsten Schirnick, Reiner Steinfeldt, Toru Suzuki, Adam Ulfsbo, Anton Velo, Ryan J. Woosley, and Robert Key
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2023-468, https://doi.org/10.5194/essd-2023-468, 2024
Revised manuscript accepted for ESSD
Short summary
Short summary
GLODAP is a data product for ocean inorganic carbon and related biogeochemical variables measured by the chemical analysis of water bottle samples from scientific cruises. GLODAPv2.2023 is the fifth update of GLODAPv2 from 2016. The data that are included have been subjected to extensive quality controlling, including systematic evaluation of measurement biases. This version contains data from 1108 hydrographic cruises covering the world's oceans from 1972 to 2021.
Siv K. Lauvset, Nico Lange, Toste Tanhua, Henry C. Bittig, Are Olsen, Alex Kozyr, Simone Alin, Marta Álvarez, Kumiko Azetsu-Scott, Leticia Barbero, Susan Becker, Peter J. Brown, Brendan R. Carter, Leticia Cotrim da Cunha, Richard A. Feely, Mario Hoppema, Matthew P. Humphreys, Masao Ishii, Emil Jeansson, Li-Qing Jiang, Steve D. Jones, Claire Lo Monaco, Akihiko Murata, Jens Daniel Müller, Fiz F. Pérez, Benjamin Pfeil, Carsten Schirnick, Reiner Steinfeldt, Toru Suzuki, Bronte Tilbrook, Adam Ulfsbo, Anton Velo, Ryan J. Woosley, and Robert M. Key
Earth Syst. Sci. Data, 14, 5543–5572, https://doi.org/10.5194/essd-14-5543-2022, https://doi.org/10.5194/essd-14-5543-2022, 2022
Short summary
Short summary
GLODAP is a data product for ocean inorganic carbon and related biogeochemical variables measured by the chemical analysis of water bottle samples from scientific cruises. GLODAPv2.2022 is the fourth update of GLODAPv2 from 2016. The data that are included have been subjected to extensive quality controlling, including systematic evaluation of measurement biases. This version contains data from 1085 hydrographic cruises covering the world's oceans from 1972 to 2021.
Olivier Sulpis, Matthew P. Humphreys, Monica M. Wilhelmus, Dustin Carroll, William M. Berelson, Dimitris Menemenlis, Jack J. Middelburg, and Jess F. Adkins
Geosci. Model Dev., 15, 2105–2131, https://doi.org/10.5194/gmd-15-2105-2022, https://doi.org/10.5194/gmd-15-2105-2022, 2022
Short summary
Short summary
A quarter of the surface of the Earth is covered by marine sediments rich in calcium carbonates, and their dissolution acts as a giant antacid tablet protecting the ocean against human-made acidification caused by massive CO2 emissions. Here, we present a new model of sediment chemistry that incorporates the latest experimental findings on calcium carbonate dissolution kinetics. This model can be used to predict how marine sediments evolve through time in response to environmental perturbations.
Matthew P. Humphreys, Erik H. Meesters, Henk de Haas, Szabina Karancz, Louise Delaigue, Karel Bakker, Gerard Duineveld, Siham de Goeyse, Andreas F. Haas, Furu Mienis, Sharyn Ossebaar, and Fleur C. van Duyl
Biogeosciences, 19, 347–358, https://doi.org/10.5194/bg-19-347-2022, https://doi.org/10.5194/bg-19-347-2022, 2022
Short summary
Short summary
A series of submarine sinkholes were recently discovered on Luymes Bank, part of Saba Bank, a carbonate platform in the Caribbean Netherlands. Here, we investigate the waters inside these sinkholes for the first time. One of the sinkholes contained a body of dense, low-oxygen and low-pH water, which we call the
acid lake. We use measurements of seawater chemistry to work out what processes were responsible for forming the acid lake and discuss the consequences for the carbonate platform.
Luca Possenti, Ingunn Skjelvan, Dariia Atamanchuk, Anders Tengberg, Matthew P. Humphreys, Socratis Loucaides, Liam Fernand, and Jan Kaiser
Ocean Sci., 17, 593–614, https://doi.org/10.5194/os-17-593-2021, https://doi.org/10.5194/os-17-593-2021, 2021
Short summary
Short summary
A Seaglider was deployed for 8 months in the Norwegian Sea mounting an oxygen and, for the first time, a CO2 optode and a chlorophyll fluorescence sensor. The oxygen and CO2 data were used to assess the spatial and temporal variability and calculate the net community production, N(O2) and N(CT). The dataset was used to calculate net community production from inventory changes, air–sea flux, diapycnal mixing and entrainment.
Hannah K. Donald, Gavin L. Foster, Nico Fröhberg, George E. A. Swann, Alex J. Poulton, C. Mark Moore, and Matthew P. Humphreys
Biogeosciences, 17, 2825–2837, https://doi.org/10.5194/bg-17-2825-2020, https://doi.org/10.5194/bg-17-2825-2020, 2020
Short summary
Short summary
The boron isotope pH proxy is increasingly being used to reconstruct ocean pH in the past. Here we detail a novel analytical methodology for measuring the boron isotopic composition (δ11B) of diatom opal and apply this to the study of the diatom Thalassiosira weissflogii grown in culture over a range of pH. To our knowledge this is the first study of its kind and provides unique insights into the way in which diatoms incorporate boron and their potential as archives of palaeoclimate records.
Robyn E. Tuerena, Raja S. Ganeshram, Matthew P. Humphreys, Thomas J. Browning, Heather Bouman, and Alexander P. Piotrowski
Biogeosciences, 16, 3621–3635, https://doi.org/10.5194/bg-16-3621-2019, https://doi.org/10.5194/bg-16-3621-2019, 2019
Short summary
Short summary
The carbon isotopes in algae can be used to predict food sources and environmental change. We explore how dissolved carbon is taken up by algae in the South Atlantic Ocean and how this affects their carbon isotope signature. We find that cell size controls isotope fractionation. We use our results to investigate how climate change may impact the carbon isotopes in algae. We suggest a shift to smaller algae in this region would decrease the carbon isotope ratio at the base of the food web.
Yingxu Wu, Mathis P. Hain, Matthew P. Humphreys, Sue Hartman, and Toby Tyrrell
Biogeosciences, 16, 2661–2681, https://doi.org/10.5194/bg-16-2661-2019, https://doi.org/10.5194/bg-16-2661-2019, 2019
Short summary
Short summary
This study takes advantage of the GLODAPv2 database to investigate the processes driving the surface ocean dissolved inorganic carbon distribution, with the focus on its latitudinal gradient between the polar oceans and the low-latitude oceans. Based on our quantitative study, we find that temperature-driven CO2 gas exchange and high-latitude upwelling of DIC- and TA-rich deep waters are the two major drivers, with the importance of the latter not having been previously realized.
Meike Becker, Nils Andersen, Helmut Erlenkeuser, Matthew P. Humphreys, Toste Tanhua, and Arne Körtzinger
Earth Syst. Sci. Data, 8, 559–570, https://doi.org/10.5194/essd-8-559-2016, https://doi.org/10.5194/essd-8-559-2016, 2016
Short summary
Short summary
The stable carbon isotope composition of dissolved inorganic carbon (δ13C-DIC) can be used to quantify fluxes within the marine carbon system such as the exchange between ocean and atmosphere or the amount of anthropogenic carbon in the water column. In this study, an internally consistent δ13C-DIC dataset for the North Atlantic is presented. The data have undergone a secondary quality control during which systematic biases between the respective cruises have been quantified and adjusted.
Dorothee C. E. Bakker, Benjamin Pfeil, Camilla S. Landa, Nicolas Metzl, Kevin M. O'Brien, Are Olsen, Karl Smith, Cathy Cosca, Sumiko Harasawa, Stephen D. Jones, Shin-ichiro Nakaoka, Yukihiro Nojiri, Ute Schuster, Tobias Steinhoff, Colm Sweeney, Taro Takahashi, Bronte Tilbrook, Chisato Wada, Rik Wanninkhof, Simone R. Alin, Carlos F. Balestrini, Leticia Barbero, Nicholas R. Bates, Alejandro A. Bianchi, Frédéric Bonou, Jacqueline Boutin, Yann Bozec, Eugene F. Burger, Wei-Jun Cai, Robert D. Castle, Liqi Chen, Melissa Chierici, Kim Currie, Wiley Evans, Charles Featherstone, Richard A. Feely, Agneta Fransson, Catherine Goyet, Naomi Greenwood, Luke Gregor, Steven Hankin, Nick J. Hardman-Mountford, Jérôme Harlay, Judith Hauck, Mario Hoppema, Matthew P. Humphreys, Christopher W. Hunt, Betty Huss, J. Severino P. Ibánhez, Truls Johannessen, Ralph Keeling, Vassilis Kitidis, Arne Körtzinger, Alex Kozyr, Evangelia Krasakopoulou, Akira Kuwata, Peter Landschützer, Siv K. Lauvset, Nathalie Lefèvre, Claire Lo Monaco, Ansley Manke, Jeremy T. Mathis, Liliane Merlivat, Frank J. Millero, Pedro M. S. Monteiro, David R. Munro, Akihiko Murata, Timothy Newberger, Abdirahman M. Omar, Tsuneo Ono, Kristina Paterson, David Pearce, Denis Pierrot, Lisa L. Robbins, Shu Saito, Joe Salisbury, Reiner Schlitzer, Bernd Schneider, Roland Schweitzer, Rainer Sieger, Ingunn Skjelvan, Kevin F. Sullivan, Stewart C. Sutherland, Adrienne J. Sutton, Kazuaki Tadokoro, Maciej Telszewski, Matthias Tuma, Steven M. A. C. van Heuven, Doug Vandemark, Brian Ward, Andrew J. Watson, and Suqing Xu
Earth Syst. Sci. Data, 8, 383–413, https://doi.org/10.5194/essd-8-383-2016, https://doi.org/10.5194/essd-8-383-2016, 2016
Short summary
Short summary
Version 3 of the Surface Ocean CO2 Atlas (www.socat.info) has 14.5 million CO2 (carbon dioxide) values for the years 1957 to 2014 covering the global oceans and coastal seas. Version 3 is an update to version 2 with a longer record and 44 % more CO2 values. The CO2 measurements have been made on ships, fixed moorings and drifting buoys. SOCAT enables quantification of the ocean carbon sink and ocean acidification, as well as model evaluation, thus informing climate negotiations.
Matthew P. Humphreys, Florence M. Greatrix, Eithne Tynan, Eric P. Achterberg, Alex M. Griffiths, Claudia H. Fry, Rebecca Garley, Alison McDonald, and Adrian J. Boyce
Earth Syst. Sci. Data, 8, 221–233, https://doi.org/10.5194/essd-8-221-2016, https://doi.org/10.5194/essd-8-221-2016, 2016
Short summary
Short summary
This paper reports the stable isotope composition of dissolved inorganic carbon in seawater for a transect from west to east across the North Atlantic Ocean. The results can be used to study oceanic uptake of anthropogenic carbon dioxide, and also to investigate the natural biological carbon pump. We also provide stable DIC isotope results for two batches of Dickson seawater CRMs to enable intercomparisons with other studies.
M. P. Humphreys, E. P. Achterberg, A. M. Griffiths, A. McDonald, and A. J. Boyce
Earth Syst. Sci. Data, 7, 127–135, https://doi.org/10.5194/essd-7-127-2015, https://doi.org/10.5194/essd-7-127-2015, 2015
Short summary
Short summary
We present measurements of the stable carbon isotope composition of seawater dissolved inorganic carbon. The samples were collected during two research cruises in boreal summer 2012 in the northeastern Atlantic and Nordic Seas. The results can be used to investigate the marine carbon cycle, providing information about biological productivity and oceanic uptake of anthropogenic carbon dioxide.
Matthew P. Humphreys
EGUsphere, https://doi.org/10.5194/egusphere-2024-626, https://doi.org/10.5194/egusphere-2024-626, 2024
Short summary
Short summary
The ocean absorbs carbon dioxide (CO2) from the atmosphere, which slows down climate change. Seawater CO2 absorption is controlled by a property called ƒCO2. This ƒCO2 changes as seawater warms up or cools down, but we haven’t known for sure how much it changes, with different measurements and calculations giving inconsistent results. Here, we work out how ƒCO2 should theoretically respond to temperature change and show that this is consistent with both measurements and calculations.
Siv K. Lauvset, Nico Lange, Toste Tanhua, Henry C. Bittig, Are Olsen, Alex Kozyr, Marta Álvarez, Kumiko Azetsu-Scott, Peter J. Brown, Brendan R. Carter, Leticia Cotrim da Cunha, Mario Hoppema, Matthew P. Humphreys, Masao Ishii, Emil Jeansson, Akihiko Murata, Jens Daniel Müller, Fiz F. Perez, Carsten Schirnick, Reiner Steinfeldt, Toru Suzuki, Adam Ulfsbo, Anton Velo, Ryan J. Woosley, and Robert Key
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2023-468, https://doi.org/10.5194/essd-2023-468, 2024
Revised manuscript accepted for ESSD
Short summary
Short summary
GLODAP is a data product for ocean inorganic carbon and related biogeochemical variables measured by the chemical analysis of water bottle samples from scientific cruises. GLODAPv2.2023 is the fifth update of GLODAPv2 from 2016. The data that are included have been subjected to extensive quality controlling, including systematic evaluation of measurement biases. This version contains data from 1108 hydrographic cruises covering the world's oceans from 1972 to 2021.
Pierre Friedlingstein, Michael O'Sullivan, Matthew W. Jones, Robbie M. Andrew, Dorothee C. E. Bakker, Judith Hauck, Peter Landschützer, Corinne Le Quéré, Ingrid T. Luijkx, Glen P. Peters, Wouter Peters, Julia Pongratz, Clemens Schwingshackl, Stephen Sitch, Josep G. Canadell, Philippe Ciais, Robert B. Jackson, Simone R. Alin, Peter Anthoni, Leticia Barbero, Nicholas R. Bates, Meike Becker, Nicolas Bellouin, Bertrand Decharme, Laurent Bopp, Ida Bagus Mandhara Brasika, Patricia Cadule, Matthew A. Chamberlain, Naveen Chandra, Thi-Tuyet-Trang Chau, Frédéric Chevallier, Louise P. Chini, Margot Cronin, Xinyu Dou, Kazutaka Enyo, Wiley Evans, Stefanie Falk, Richard A. Feely, Liang Feng, Daniel J. Ford, Thomas Gasser, Josefine Ghattas, Thanos Gkritzalis, Giacomo Grassi, Luke Gregor, Nicolas Gruber, Özgür Gürses, Ian Harris, Matthew Hefner, Jens Heinke, Richard A. Houghton, George C. Hurtt, Yosuke Iida, Tatiana Ilyina, Andrew R. Jacobson, Atul Jain, Tereza Jarníková, Annika Jersild, Fei Jiang, Zhe Jin, Fortunat Joos, Etsushi Kato, Ralph F. Keeling, Daniel Kennedy, Kees Klein Goldewijk, Jürgen Knauer, Jan Ivar Korsbakken, Arne Körtzinger, Xin Lan, Nathalie Lefèvre, Hongmei Li, Junjie Liu, Zhiqiang Liu, Lei Ma, Greg Marland, Nicolas Mayot, Patrick C. McGuire, Galen A. McKinley, Gesa Meyer, Eric J. Morgan, David R. Munro, Shin-Ichiro Nakaoka, Yosuke Niwa, Kevin M. O'Brien, Are Olsen, Abdirahman M. Omar, Tsuneo Ono, Melf Paulsen, Denis Pierrot, Katie Pocock, Benjamin Poulter, Carter M. Powis, Gregor Rehder, Laure Resplandy, Eddy Robertson, Christian Rödenbeck, Thais M. Rosan, Jörg Schwinger, Roland Séférian, T. Luke Smallman, Stephen M. Smith, Reinel Sospedra-Alfonso, Qing Sun, Adrienne J. Sutton, Colm Sweeney, Shintaro Takao, Pieter P. Tans, Hanqin Tian, Bronte Tilbrook, Hiroyuki Tsujino, Francesco Tubiello, Guido R. van der Werf, Erik van Ooijen, Rik Wanninkhof, Michio Watanabe, Cathy Wimart-Rousseau, Dongxu Yang, Xiaojuan Yang, Wenping Yuan, Xu Yue, Sönke Zaehle, Jiye Zeng, and Bo Zheng
Earth Syst. Sci. Data, 15, 5301–5369, https://doi.org/10.5194/essd-15-5301-2023, https://doi.org/10.5194/essd-15-5301-2023, 2023
Short summary
Short summary
The Global Carbon Budget 2023 describes the methodology, main results, and data sets used to quantify the anthropogenic emissions of carbon dioxide (CO2) and their partitioning among the atmosphere, land ecosystems, and the ocean over the historical period (1750–2023). These living datasets are updated every year to provide the highest transparency and traceability in the reporting of CO2, the key driver of climate change.
Amanda R. Fay, David R. Munro, Galen A. McKinley, Denis Pierrot, Stewart C. Sutherland, Colm Sweeney, and Rik Wanninkhof
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2023-429, https://doi.org/10.5194/essd-2023-429, 2023
Revised manuscript accepted for ESSD
Short summary
Short summary
Presented here is a near-global monthly estimate of the difference between atmosphere and ocean carbon dioxide concentrations. The ocean's ability to take up carbon, both now and in the future, is defined by this difference in concentrations. With over 30 million measurements of surface ocean carbon over the last 40 years, and utilization of an extrapolation technique, a mean estimate of surface ocean delta fCO2 is presented.
Jonathan D. Sharp, Andrea J. Fassbender, Brendan R. Carter, Gregory C. Johnson, Cristina Schultz, and John P. Dunne
Earth Syst. Sci. Data, 15, 4481–4518, https://doi.org/10.5194/essd-15-4481-2023, https://doi.org/10.5194/essd-15-4481-2023, 2023
Short summary
Short summary
Dissolved oxygen content is a critical metric of ocean health. Recently, expanding fleets of autonomous platforms that measure oxygen in the ocean have produced a wealth of new data. We leverage machine learning to take advantage of this growing global dataset, producing a gridded data product of ocean interior dissolved oxygen at monthly resolution over nearly 2 decades. This work provides novel information for investigations of spatial, seasonal, and interannual variability in ocean oxygen.
Siv K. Lauvset, Nico Lange, Toste Tanhua, Henry C. Bittig, Are Olsen, Alex Kozyr, Simone Alin, Marta Álvarez, Kumiko Azetsu-Scott, Leticia Barbero, Susan Becker, Peter J. Brown, Brendan R. Carter, Leticia Cotrim da Cunha, Richard A. Feely, Mario Hoppema, Matthew P. Humphreys, Masao Ishii, Emil Jeansson, Li-Qing Jiang, Steve D. Jones, Claire Lo Monaco, Akihiko Murata, Jens Daniel Müller, Fiz F. Pérez, Benjamin Pfeil, Carsten Schirnick, Reiner Steinfeldt, Toru Suzuki, Bronte Tilbrook, Adam Ulfsbo, Anton Velo, Ryan J. Woosley, and Robert M. Key
Earth Syst. Sci. Data, 14, 5543–5572, https://doi.org/10.5194/essd-14-5543-2022, https://doi.org/10.5194/essd-14-5543-2022, 2022
Short summary
Short summary
GLODAP is a data product for ocean inorganic carbon and related biogeochemical variables measured by the chemical analysis of water bottle samples from scientific cruises. GLODAPv2.2022 is the fourth update of GLODAPv2 from 2016. The data that are included have been subjected to extensive quality controlling, including systematic evaluation of measurement biases. This version contains data from 1085 hydrographic cruises covering the world's oceans from 1972 to 2021.
Pierre Friedlingstein, Michael O'Sullivan, Matthew W. Jones, Robbie M. Andrew, Luke Gregor, Judith Hauck, Corinne Le Quéré, Ingrid T. Luijkx, Are Olsen, Glen P. Peters, Wouter Peters, Julia Pongratz, Clemens Schwingshackl, Stephen Sitch, Josep G. Canadell, Philippe Ciais, Robert B. Jackson, Simone R. Alin, Ramdane Alkama, Almut Arneth, Vivek K. Arora, Nicholas R. Bates, Meike Becker, Nicolas Bellouin, Henry C. Bittig, Laurent Bopp, Frédéric Chevallier, Louise P. Chini, Margot Cronin, Wiley Evans, Stefanie Falk, Richard A. Feely, Thomas Gasser, Marion Gehlen, Thanos Gkritzalis, Lucas Gloege, Giacomo Grassi, Nicolas Gruber, Özgür Gürses, Ian Harris, Matthew Hefner, Richard A. Houghton, George C. Hurtt, Yosuke Iida, Tatiana Ilyina, Atul K. Jain, Annika Jersild, Koji Kadono, Etsushi Kato, Daniel Kennedy, Kees Klein Goldewijk, Jürgen Knauer, Jan Ivar Korsbakken, Peter Landschützer, Nathalie Lefèvre, Keith Lindsay, Junjie Liu, Zhu Liu, Gregg Marland, Nicolas Mayot, Matthew J. McGrath, Nicolas Metzl, Natalie M. Monacci, David R. Munro, Shin-Ichiro Nakaoka, Yosuke Niwa, Kevin O'Brien, Tsuneo Ono, Paul I. Palmer, Naiqing Pan, Denis Pierrot, Katie Pocock, Benjamin Poulter, Laure Resplandy, Eddy Robertson, Christian Rödenbeck, Carmen Rodriguez, Thais M. Rosan, Jörg Schwinger, Roland Séférian, Jamie D. Shutler, Ingunn Skjelvan, Tobias Steinhoff, Qing Sun, Adrienne J. Sutton, Colm Sweeney, Shintaro Takao, Toste Tanhua, Pieter P. Tans, Xiangjun Tian, Hanqin Tian, Bronte Tilbrook, Hiroyuki Tsujino, Francesco Tubiello, Guido R. van der Werf, Anthony P. Walker, Rik Wanninkhof, Chris Whitehead, Anna Willstrand Wranne, Rebecca Wright, Wenping Yuan, Chao Yue, Xu Yue, Sönke Zaehle, Jiye Zeng, and Bo Zheng
Earth Syst. Sci. Data, 14, 4811–4900, https://doi.org/10.5194/essd-14-4811-2022, https://doi.org/10.5194/essd-14-4811-2022, 2022
Short summary
Short summary
The Global Carbon Budget 2022 describes the datasets and methodology used to quantify the anthropogenic emissions of carbon dioxide (CO2) and their partitioning among the atmosphere, the land ecosystems, and the ocean. These living datasets are updated every year to provide the highest transparency and traceability in the reporting of CO2, the key driver of climate change.
Lu Zhang, Michal Segal-Rozenhaimer, Haochi Che, Caroline Dang, Arthur J. Sedlacek III, Ernie R. Lewis, Amie Dobracki, Jenny P. S. Wong, Paola Formenti, Steven G. Howell, and Athanasios Nenes
Atmos. Chem. Phys., 22, 9199–9213, https://doi.org/10.5194/acp-22-9199-2022, https://doi.org/10.5194/acp-22-9199-2022, 2022
Short summary
Short summary
Widespread biomass burning (BB) events occur annually in Africa and contribute ~ 1 / 3 of global BB emissions, which contain a large family of light-absorbing organics, known as brown carbon (BrC), whose absorption of incident radiation is difficult to estimate, leading to large uncertainties in the global radiative forcing estimation. This study quantifies the BrC absorption of aged BB particles and highlights the potential presence of absorbing iron oxides in this climatically important region.
Jonathan D. Sharp, Andrea J. Fassbender, Brendan R. Carter, Paige D. Lavin, and Adrienne J. Sutton
Earth Syst. Sci. Data, 14, 2081–2108, https://doi.org/10.5194/essd-14-2081-2022, https://doi.org/10.5194/essd-14-2081-2022, 2022
Short summary
Short summary
Oceanographers calculate the exchange of carbon between the ocean and atmosphere by comparing partial pressures of carbon dioxide (pCO2). Because seawater pCO2 is not measured everywhere at all times, interpolation schemes are required to fill observational gaps. We describe a monthly gap-filled dataset of pCO2 in the northeast Pacific Ocean off the west coast of North America created by machine-learning interpolation. This dataset is unique in its robust representation of coastal seasonality.
Pierre Friedlingstein, Matthew W. Jones, Michael O'Sullivan, Robbie M. Andrew, Dorothee C. E. Bakker, Judith Hauck, Corinne Le Quéré, Glen P. Peters, Wouter Peters, Julia Pongratz, Stephen Sitch, Josep G. Canadell, Philippe Ciais, Rob B. Jackson, Simone R. Alin, Peter Anthoni, Nicholas R. Bates, Meike Becker, Nicolas Bellouin, Laurent Bopp, Thi Tuyet Trang Chau, Frédéric Chevallier, Louise P. Chini, Margot Cronin, Kim I. Currie, Bertrand Decharme, Laique M. Djeutchouang, Xinyu Dou, Wiley Evans, Richard A. Feely, Liang Feng, Thomas Gasser, Dennis Gilfillan, Thanos Gkritzalis, Giacomo Grassi, Luke Gregor, Nicolas Gruber, Özgür Gürses, Ian Harris, Richard A. Houghton, George C. Hurtt, Yosuke Iida, Tatiana Ilyina, Ingrid T. Luijkx, Atul Jain, Steve D. Jones, Etsushi Kato, Daniel Kennedy, Kees Klein Goldewijk, Jürgen Knauer, Jan Ivar Korsbakken, Arne Körtzinger, Peter Landschützer, Siv K. Lauvset, Nathalie Lefèvre, Sebastian Lienert, Junjie Liu, Gregg Marland, Patrick C. McGuire, Joe R. Melton, David R. Munro, Julia E. M. S. Nabel, Shin-Ichiro Nakaoka, Yosuke Niwa, Tsuneo Ono, Denis Pierrot, Benjamin Poulter, Gregor Rehder, Laure Resplandy, Eddy Robertson, Christian Rödenbeck, Thais M. Rosan, Jörg Schwinger, Clemens Schwingshackl, Roland Séférian, Adrienne J. Sutton, Colm Sweeney, Toste Tanhua, Pieter P. Tans, Hanqin Tian, Bronte Tilbrook, Francesco Tubiello, Guido R. van der Werf, Nicolas Vuichard, Chisato Wada, Rik Wanninkhof, Andrew J. Watson, David Willis, Andrew J. Wiltshire, Wenping Yuan, Chao Yue, Xu Yue, Sönke Zaehle, and Jiye Zeng
Earth Syst. Sci. Data, 14, 1917–2005, https://doi.org/10.5194/essd-14-1917-2022, https://doi.org/10.5194/essd-14-1917-2022, 2022
Short summary
Short summary
The Global Carbon Budget 2021 describes the data sets and methodology used to quantify the emissions of carbon dioxide and their partitioning among the atmosphere, land, and ocean. These living data are updated every year to provide the highest transparency and traceability in the reporting of CO2, the key driver of climate change.
Olivier Sulpis, Matthew P. Humphreys, Monica M. Wilhelmus, Dustin Carroll, William M. Berelson, Dimitris Menemenlis, Jack J. Middelburg, and Jess F. Adkins
Geosci. Model Dev., 15, 2105–2131, https://doi.org/10.5194/gmd-15-2105-2022, https://doi.org/10.5194/gmd-15-2105-2022, 2022
Short summary
Short summary
A quarter of the surface of the Earth is covered by marine sediments rich in calcium carbonates, and their dissolution acts as a giant antacid tablet protecting the ocean against human-made acidification caused by massive CO2 emissions. Here, we present a new model of sediment chemistry that incorporates the latest experimental findings on calcium carbonate dissolution kinetics. This model can be used to predict how marine sediments evolve through time in response to environmental perturbations.
Matthew P. Humphreys, Erik H. Meesters, Henk de Haas, Szabina Karancz, Louise Delaigue, Karel Bakker, Gerard Duineveld, Siham de Goeyse, Andreas F. Haas, Furu Mienis, Sharyn Ossebaar, and Fleur C. van Duyl
Biogeosciences, 19, 347–358, https://doi.org/10.5194/bg-19-347-2022, https://doi.org/10.5194/bg-19-347-2022, 2022
Short summary
Short summary
A series of submarine sinkholes were recently discovered on Luymes Bank, part of Saba Bank, a carbonate platform in the Caribbean Netherlands. Here, we investigate the waters inside these sinkholes for the first time. One of the sinkholes contained a body of dense, low-oxygen and low-pH water, which we call the
acid lake. We use measurements of seawater chemistry to work out what processes were responsible for forming the acid lake and discuss the consequences for the carbonate platform.
Li-Qing Jiang, Richard A. Feely, Rik Wanninkhof, Dana Greeley, Leticia Barbero, Simone Alin, Brendan R. Carter, Denis Pierrot, Charles Featherstone, James Hooper, Chris Melrose, Natalie Monacci, Jonathan D. Sharp, Shawn Shellito, Yuan-Yuan Xu, Alex Kozyr, Robert H. Byrne, Wei-Jun Cai, Jessica Cross, Gregory C. Johnson, Burke Hales, Chris Langdon, Jeremy Mathis, Joe Salisbury, and David W. Townsend
Earth Syst. Sci. Data, 13, 2777–2799, https://doi.org/10.5194/essd-13-2777-2021, https://doi.org/10.5194/essd-13-2777-2021, 2021
Short summary
Short summary
Coastal ecosystems account for most of the economic activities related to commercial and recreational fisheries and aquaculture industries, supporting about 90 % of the global fisheries yield and 80 % of known species of marine fish. Despite the large potential risks from ocean acidification (OA), internally consistent water column OA data products in the coastal ocean still do not exist. This paper is the first time we report a high quality OA data product in North America's coastal waters.
Luca Possenti, Ingunn Skjelvan, Dariia Atamanchuk, Anders Tengberg, Matthew P. Humphreys, Socratis Loucaides, Liam Fernand, and Jan Kaiser
Ocean Sci., 17, 593–614, https://doi.org/10.5194/os-17-593-2021, https://doi.org/10.5194/os-17-593-2021, 2021
Short summary
Short summary
A Seaglider was deployed for 8 months in the Norwegian Sea mounting an oxygen and, for the first time, a CO2 optode and a chlorophyll fluorescence sensor. The oxygen and CO2 data were used to assess the spatial and temporal variability and calculate the net community production, N(O2) and N(CT). The dataset was used to calculate net community production from inventory changes, air–sea flux, diapycnal mixing and entrainment.
Pierre Friedlingstein, Michael O'Sullivan, Matthew W. Jones, Robbie M. Andrew, Judith Hauck, Are Olsen, Glen P. Peters, Wouter Peters, Julia Pongratz, Stephen Sitch, Corinne Le Quéré, Josep G. Canadell, Philippe Ciais, Robert B. Jackson, Simone Alin, Luiz E. O. C. Aragão, Almut Arneth, Vivek Arora, Nicholas R. Bates, Meike Becker, Alice Benoit-Cattin, Henry C. Bittig, Laurent Bopp, Selma Bultan, Naveen Chandra, Frédéric Chevallier, Louise P. Chini, Wiley Evans, Liesbeth Florentie, Piers M. Forster, Thomas Gasser, Marion Gehlen, Dennis Gilfillan, Thanos Gkritzalis, Luke Gregor, Nicolas Gruber, Ian Harris, Kerstin Hartung, Vanessa Haverd, Richard A. Houghton, Tatiana Ilyina, Atul K. Jain, Emilie Joetzjer, Koji Kadono, Etsushi Kato, Vassilis Kitidis, Jan Ivar Korsbakken, Peter Landschützer, Nathalie Lefèvre, Andrew Lenton, Sebastian Lienert, Zhu Liu, Danica Lombardozzi, Gregg Marland, Nicolas Metzl, David R. Munro, Julia E. M. S. Nabel, Shin-Ichiro Nakaoka, Yosuke Niwa, Kevin O'Brien, Tsuneo Ono, Paul I. Palmer, Denis Pierrot, Benjamin Poulter, Laure Resplandy, Eddy Robertson, Christian Rödenbeck, Jörg Schwinger, Roland Séférian, Ingunn Skjelvan, Adam J. P. Smith, Adrienne J. Sutton, Toste Tanhua, Pieter P. Tans, Hanqin Tian, Bronte Tilbrook, Guido van der Werf, Nicolas Vuichard, Anthony P. Walker, Rik Wanninkhof, Andrew J. Watson, David Willis, Andrew J. Wiltshire, Wenping Yuan, Xu Yue, and Sönke Zaehle
Earth Syst. Sci. Data, 12, 3269–3340, https://doi.org/10.5194/essd-12-3269-2020, https://doi.org/10.5194/essd-12-3269-2020, 2020
Short summary
Short summary
The Global Carbon Budget 2020 describes the data sets and methodology used to quantify the emissions of carbon dioxide and their partitioning among the atmosphere, land, and ocean. These living data are updated every year to provide the highest transparency and traceability in the reporting of CO2, the key driver of climate change.
Lawrence I. Kleinman, Arthur J. Sedlacek III, Kouji Adachi, Peter R. Buseck, Sonya Collier, Manvendra K. Dubey, Anna L. Hodshire, Ernie Lewis, Timothy B. Onasch, Jeffery R. Pierce, John Shilling, Stephen R. Springston, Jian Wang, Qi Zhang, Shan Zhou, and Robert J. Yokelson
Atmos. Chem. Phys., 20, 13319–13341, https://doi.org/10.5194/acp-20-13319-2020, https://doi.org/10.5194/acp-20-13319-2020, 2020
Short summary
Short summary
Aerosols from wildfires affect the Earth's temperature by absorbing light or reflecting it back into space. This study investigates time-dependent chemical, microphysical, and optical properties of aerosols generated by wildfires in the Pacific Northwest, USA. Wildfire smoke plumes were traversed by an instrumented aircraft at locations near the fire and up to 3.5 h travel time downwind. Although there was no net aerosol production, aerosol particles grew and became more efficient scatters.
Rik Wanninkhof, Denis Pierrot, Kevin Sullivan, Leticia Barbero, and Joaquin Triñanes
Earth Syst. Sci. Data, 12, 1489–1509, https://doi.org/10.5194/essd-12-1489-2020, https://doi.org/10.5194/essd-12-1489-2020, 2020
Short summary
Short summary
This paper describes a 17-year dataset of over a million data points of automated partial pressure of CO2 (pCO2) measurements on large luxury cruise ships of Royal Caribbean Cruise Lines (RCCL). These data are used to provide trends of ocean acidification and air–sea CO2 fluxes. The effort was possible through a unique continuing industry (RCCL), academic (University of Miami) and governmental (NOAA) partnership.
Hannah K. Donald, Gavin L. Foster, Nico Fröhberg, George E. A. Swann, Alex J. Poulton, C. Mark Moore, and Matthew P. Humphreys
Biogeosciences, 17, 2825–2837, https://doi.org/10.5194/bg-17-2825-2020, https://doi.org/10.5194/bg-17-2825-2020, 2020
Short summary
Short summary
The boron isotope pH proxy is increasingly being used to reconstruct ocean pH in the past. Here we detail a novel analytical methodology for measuring the boron isotopic composition (δ11B) of diatom opal and apply this to the study of the diatom Thalassiosira weissflogii grown in culture over a range of pH. To our knowledge this is the first study of its kind and provides unique insights into the way in which diatoms incorporate boron and their potential as archives of palaeoclimate records.
Pierre Friedlingstein, Matthew W. Jones, Michael O'Sullivan, Robbie M. Andrew, Judith Hauck, Glen P. Peters, Wouter Peters, Julia Pongratz, Stephen Sitch, Corinne Le Quéré, Dorothee C. E. Bakker, Josep G. Canadell, Philippe Ciais, Robert B. Jackson, Peter Anthoni, Leticia Barbero, Ana Bastos, Vladislav Bastrikov, Meike Becker, Laurent Bopp, Erik Buitenhuis, Naveen Chandra, Frédéric Chevallier, Louise P. Chini, Kim I. Currie, Richard A. Feely, Marion Gehlen, Dennis Gilfillan, Thanos Gkritzalis, Daniel S. Goll, Nicolas Gruber, Sören Gutekunst, Ian Harris, Vanessa Haverd, Richard A. Houghton, George Hurtt, Tatiana Ilyina, Atul K. Jain, Emilie Joetzjer, Jed O. Kaplan, Etsushi Kato, Kees Klein Goldewijk, Jan Ivar Korsbakken, Peter Landschützer, Siv K. Lauvset, Nathalie Lefèvre, Andrew Lenton, Sebastian Lienert, Danica Lombardozzi, Gregg Marland, Patrick C. McGuire, Joe R. Melton, Nicolas Metzl, David R. Munro, Julia E. M. S. Nabel, Shin-Ichiro Nakaoka, Craig Neill, Abdirahman M. Omar, Tsuneo Ono, Anna Peregon, Denis Pierrot, Benjamin Poulter, Gregor Rehder, Laure Resplandy, Eddy Robertson, Christian Rödenbeck, Roland Séférian, Jörg Schwinger, Naomi Smith, Pieter P. Tans, Hanqin Tian, Bronte Tilbrook, Francesco N. Tubiello, Guido R. van der Werf, Andrew J. Wiltshire, and Sönke Zaehle
Earth Syst. Sci. Data, 11, 1783–1838, https://doi.org/10.5194/essd-11-1783-2019, https://doi.org/10.5194/essd-11-1783-2019, 2019
Short summary
Short summary
The Global Carbon Budget 2019 describes the data sets and methodology used to quantify the emissions of carbon dioxide and their partitioning among the atmosphere, land, and ocean. These living data are updated every year to provide the highest transparency and traceability in the reporting of CO2, the key driver of climate change.
Robyn E. Tuerena, Raja S. Ganeshram, Matthew P. Humphreys, Thomas J. Browning, Heather Bouman, and Alexander P. Piotrowski
Biogeosciences, 16, 3621–3635, https://doi.org/10.5194/bg-16-3621-2019, https://doi.org/10.5194/bg-16-3621-2019, 2019
Short summary
Short summary
The carbon isotopes in algae can be used to predict food sources and environmental change. We explore how dissolved carbon is taken up by algae in the South Atlantic Ocean and how this affects their carbon isotope signature. We find that cell size controls isotope fractionation. We use our results to investigate how climate change may impact the carbon isotopes in algae. We suggest a shift to smaller algae in this region would decrease the carbon isotope ratio at the base of the food web.
Yingxu Wu, Mathis P. Hain, Matthew P. Humphreys, Sue Hartman, and Toby Tyrrell
Biogeosciences, 16, 2661–2681, https://doi.org/10.5194/bg-16-2661-2019, https://doi.org/10.5194/bg-16-2661-2019, 2019
Short summary
Short summary
This study takes advantage of the GLODAPv2 database to investigate the processes driving the surface ocean dissolved inorganic carbon distribution, with the focus on its latitudinal gradient between the polar oceans and the low-latitude oceans. Based on our quantitative study, we find that temperature-driven CO2 gas exchange and high-latitude upwelling of DIC- and TA-rich deep waters are the two major drivers, with the importance of the latter not having been previously realized.
Corinne Le Quéré, Robbie M. Andrew, Pierre Friedlingstein, Stephen Sitch, Judith Hauck, Julia Pongratz, Penelope A. Pickers, Jan Ivar Korsbakken, Glen P. Peters, Josep G. Canadell, Almut Arneth, Vivek K. Arora, Leticia Barbero, Ana Bastos, Laurent Bopp, Frédéric Chevallier, Louise P. Chini, Philippe Ciais, Scott C. Doney, Thanos Gkritzalis, Daniel S. Goll, Ian Harris, Vanessa Haverd, Forrest M. Hoffman, Mario Hoppema, Richard A. Houghton, George Hurtt, Tatiana Ilyina, Atul K. Jain, Truls Johannessen, Chris D. Jones, Etsushi Kato, Ralph F. Keeling, Kees Klein Goldewijk, Peter Landschützer, Nathalie Lefèvre, Sebastian Lienert, Zhu Liu, Danica Lombardozzi, Nicolas Metzl, David R. Munro, Julia E. M. S. Nabel, Shin-ichiro Nakaoka, Craig Neill, Are Olsen, Tsueno Ono, Prabir Patra, Anna Peregon, Wouter Peters, Philippe Peylin, Benjamin Pfeil, Denis Pierrot, Benjamin Poulter, Gregor Rehder, Laure Resplandy, Eddy Robertson, Matthias Rocher, Christian Rödenbeck, Ute Schuster, Jörg Schwinger, Roland Séférian, Ingunn Skjelvan, Tobias Steinhoff, Adrienne Sutton, Pieter P. Tans, Hanqin Tian, Bronte Tilbrook, Francesco N. Tubiello, Ingrid T. van der Laan-Luijkx, Guido R. van der Werf, Nicolas Viovy, Anthony P. Walker, Andrew J. Wiltshire, Rebecca Wright, Sönke Zaehle, and Bo Zheng
Earth Syst. Sci. Data, 10, 2141–2194, https://doi.org/10.5194/essd-10-2141-2018, https://doi.org/10.5194/essd-10-2141-2018, 2018
Short summary
Short summary
The Global Carbon Budget 2018 describes the data sets and methodology used to quantify the emissions of carbon dioxide and their partitioning among the atmosphere, land, and ocean. These living data are updated every year to provide the highest transparency and traceability in the reporting of CO2, the key driver of climate change.
Gilles Reverdin, Nicolas Metzl, Solveig Olafsdottir, Virginie Racapé, Taro Takahashi, Marion Benetti, Hedinn Valdimarsson, Alice Benoit-Cattin, Magnus Danielsen, Jonathan Fin, Aicha Naamar, Denis Pierrot, Kevin Sullivan, Francis Bringas, and Gustavo Goni
Earth Syst. Sci. Data, 10, 1901–1924, https://doi.org/10.5194/essd-10-1901-2018, https://doi.org/10.5194/essd-10-1901-2018, 2018
Short summary
Short summary
This paper presents the SURATLANT data set (SURveillance ATLANTique), consisting of individual data of temperature, salinity, parameters of the carbonate system, nutrients, and water stable isotopes (δ18O and δD) collected mostly from ships of opportunity since 1993 along transects between Iceland and Newfoundland. These data are used to quantify the seasonal cycle and can be used to investigate long-term tendencies in the surface ocean, including of pCO2 and pH.
Corinne Le Quéré, Robbie M. Andrew, Pierre Friedlingstein, Stephen Sitch, Julia Pongratz, Andrew C. Manning, Jan Ivar Korsbakken, Glen P. Peters, Josep G. Canadell, Robert B. Jackson, Thomas A. Boden, Pieter P. Tans, Oliver D. Andrews, Vivek K. Arora, Dorothee C. E. Bakker, Leticia Barbero, Meike Becker, Richard A. Betts, Laurent Bopp, Frédéric Chevallier, Louise P. Chini, Philippe Ciais, Catherine E. Cosca, Jessica Cross, Kim Currie, Thomas Gasser, Ian Harris, Judith Hauck, Vanessa Haverd, Richard A. Houghton, Christopher W. Hunt, George Hurtt, Tatiana Ilyina, Atul K. Jain, Etsushi Kato, Markus Kautz, Ralph F. Keeling, Kees Klein Goldewijk, Arne Körtzinger, Peter Landschützer, Nathalie Lefèvre, Andrew Lenton, Sebastian Lienert, Ivan Lima, Danica Lombardozzi, Nicolas Metzl, Frank Millero, Pedro M. S. Monteiro, David R. Munro, Julia E. M. S. Nabel, Shin-ichiro Nakaoka, Yukihiro Nojiri, X. Antonio Padin, Anna Peregon, Benjamin Pfeil, Denis Pierrot, Benjamin Poulter, Gregor Rehder, Janet Reimer, Christian Rödenbeck, Jörg Schwinger, Roland Séférian, Ingunn Skjelvan, Benjamin D. Stocker, Hanqin Tian, Bronte Tilbrook, Francesco N. Tubiello, Ingrid T. van der Laan-Luijkx, Guido R. van der Werf, Steven van Heuven, Nicolas Viovy, Nicolas Vuichard, Anthony P. Walker, Andrew J. Watson, Andrew J. Wiltshire, Sönke Zaehle, and Dan Zhu
Earth Syst. Sci. Data, 10, 405–448, https://doi.org/10.5194/essd-10-405-2018, https://doi.org/10.5194/essd-10-405-2018, 2018
Short summary
Short summary
The Global Carbon Budget 2017 describes data sets and methodology to quantify the five major components of the global carbon budget and their uncertainties. It is the 12th annual update and the 6th published in this journal.
Corinne Le Quéré, Robbie M. Andrew, Josep G. Canadell, Stephen Sitch, Jan Ivar Korsbakken, Glen P. Peters, Andrew C. Manning, Thomas A. Boden, Pieter P. Tans, Richard A. Houghton, Ralph F. Keeling, Simone Alin, Oliver D. Andrews, Peter Anthoni, Leticia Barbero, Laurent Bopp, Frédéric Chevallier, Louise P. Chini, Philippe Ciais, Kim Currie, Christine Delire, Scott C. Doney, Pierre Friedlingstein, Thanos Gkritzalis, Ian Harris, Judith Hauck, Vanessa Haverd, Mario Hoppema, Kees Klein Goldewijk, Atul K. Jain, Etsushi Kato, Arne Körtzinger, Peter Landschützer, Nathalie Lefèvre, Andrew Lenton, Sebastian Lienert, Danica Lombardozzi, Joe R. Melton, Nicolas Metzl, Frank Millero, Pedro M. S. Monteiro, David R. Munro, Julia E. M. S. Nabel, Shin-ichiro Nakaoka, Kevin O'Brien, Are Olsen, Abdirahman M. Omar, Tsuneo Ono, Denis Pierrot, Benjamin Poulter, Christian Rödenbeck, Joe Salisbury, Ute Schuster, Jörg Schwinger, Roland Séférian, Ingunn Skjelvan, Benjamin D. Stocker, Adrienne J. Sutton, Taro Takahashi, Hanqin Tian, Bronte Tilbrook, Ingrid T. van der Laan-Luijkx, Guido R. van der Werf, Nicolas Viovy, Anthony P. Walker, Andrew J. Wiltshire, and Sönke Zaehle
Earth Syst. Sci. Data, 8, 605–649, https://doi.org/10.5194/essd-8-605-2016, https://doi.org/10.5194/essd-8-605-2016, 2016
Short summary
Short summary
The Global Carbon Budget 2016 is the 11th annual update of emissions of carbon dioxide (CO2) and their partitioning among the atmosphere, land, and ocean. This data synthesis brings together measurements, statistical information, and analyses of model results in order to provide an assessment of the global carbon budget and their uncertainties for years 1959 to 2015, with a projection for year 2016.
Meike Becker, Nils Andersen, Helmut Erlenkeuser, Matthew P. Humphreys, Toste Tanhua, and Arne Körtzinger
Earth Syst. Sci. Data, 8, 559–570, https://doi.org/10.5194/essd-8-559-2016, https://doi.org/10.5194/essd-8-559-2016, 2016
Short summary
Short summary
The stable carbon isotope composition of dissolved inorganic carbon (δ13C-DIC) can be used to quantify fluxes within the marine carbon system such as the exchange between ocean and atmosphere or the amount of anthropogenic carbon in the water column. In this study, an internally consistent δ13C-DIC dataset for the North Atlantic is presented. The data have undergone a secondary quality control during which systematic biases between the respective cruises have been quantified and adjusted.
Dorothee C. E. Bakker, Benjamin Pfeil, Camilla S. Landa, Nicolas Metzl, Kevin M. O'Brien, Are Olsen, Karl Smith, Cathy Cosca, Sumiko Harasawa, Stephen D. Jones, Shin-ichiro Nakaoka, Yukihiro Nojiri, Ute Schuster, Tobias Steinhoff, Colm Sweeney, Taro Takahashi, Bronte Tilbrook, Chisato Wada, Rik Wanninkhof, Simone R. Alin, Carlos F. Balestrini, Leticia Barbero, Nicholas R. Bates, Alejandro A. Bianchi, Frédéric Bonou, Jacqueline Boutin, Yann Bozec, Eugene F. Burger, Wei-Jun Cai, Robert D. Castle, Liqi Chen, Melissa Chierici, Kim Currie, Wiley Evans, Charles Featherstone, Richard A. Feely, Agneta Fransson, Catherine Goyet, Naomi Greenwood, Luke Gregor, Steven Hankin, Nick J. Hardman-Mountford, Jérôme Harlay, Judith Hauck, Mario Hoppema, Matthew P. Humphreys, Christopher W. Hunt, Betty Huss, J. Severino P. Ibánhez, Truls Johannessen, Ralph Keeling, Vassilis Kitidis, Arne Körtzinger, Alex Kozyr, Evangelia Krasakopoulou, Akira Kuwata, Peter Landschützer, Siv K. Lauvset, Nathalie Lefèvre, Claire Lo Monaco, Ansley Manke, Jeremy T. Mathis, Liliane Merlivat, Frank J. Millero, Pedro M. S. Monteiro, David R. Munro, Akihiko Murata, Timothy Newberger, Abdirahman M. Omar, Tsuneo Ono, Kristina Paterson, David Pearce, Denis Pierrot, Lisa L. Robbins, Shu Saito, Joe Salisbury, Reiner Schlitzer, Bernd Schneider, Roland Schweitzer, Rainer Sieger, Ingunn Skjelvan, Kevin F. Sullivan, Stewart C. Sutherland, Adrienne J. Sutton, Kazuaki Tadokoro, Maciej Telszewski, Matthias Tuma, Steven M. A. C. van Heuven, Doug Vandemark, Brian Ward, Andrew J. Watson, and Suqing Xu
Earth Syst. Sci. Data, 8, 383–413, https://doi.org/10.5194/essd-8-383-2016, https://doi.org/10.5194/essd-8-383-2016, 2016
Short summary
Short summary
Version 3 of the Surface Ocean CO2 Atlas (www.socat.info) has 14.5 million CO2 (carbon dioxide) values for the years 1957 to 2014 covering the global oceans and coastal seas. Version 3 is an update to version 2 with a longer record and 44 % more CO2 values. The CO2 measurements have been made on ships, fixed moorings and drifting buoys. SOCAT enables quantification of the ocean carbon sink and ocean acidification, as well as model evaluation, thus informing climate negotiations.
Matthew P. Humphreys, Florence M. Greatrix, Eithne Tynan, Eric P. Achterberg, Alex M. Griffiths, Claudia H. Fry, Rebecca Garley, Alison McDonald, and Adrian J. Boyce
Earth Syst. Sci. Data, 8, 221–233, https://doi.org/10.5194/essd-8-221-2016, https://doi.org/10.5194/essd-8-221-2016, 2016
Short summary
Short summary
This paper reports the stable isotope composition of dissolved inorganic carbon in seawater for a transect from west to east across the North Atlantic Ocean. The results can be used to study oceanic uptake of anthropogenic carbon dioxide, and also to investigate the natural biological carbon pump. We also provide stable DIC isotope results for two batches of Dickson seawater CRMs to enable intercomparisons with other studies.
M. P. Humphreys, E. P. Achterberg, A. M. Griffiths, A. McDonald, and A. J. Boyce
Earth Syst. Sci. Data, 7, 127–135, https://doi.org/10.5194/essd-7-127-2015, https://doi.org/10.5194/essd-7-127-2015, 2015
Short summary
Short summary
We present measurements of the stable carbon isotope composition of seawater dissolved inorganic carbon. The samples were collected during two research cruises in boreal summer 2012 in the northeastern Atlantic and Nordic Seas. The results can be used to investigate the marine carbon cycle, providing information about biological productivity and oceanic uptake of anthropogenic carbon dioxide.
Related subject area
Oceanography
LOCATE v1.0: numerical modelling of floating marine debris dispersion in coastal regions using Parcels v2.4.2
New insights into the South China Sea throughflow and water budget seasonal cycle: evaluation and analysis of a high-resolution configuration of the ocean model SYMPHONIE version 2.4
MQGeometry-1.0: a multi-layer quasi-geostrophic solver on non-rectangular geometries
Parameter estimation for ocean background vertical diffusivity coefficients in the Community Earth System Model (v1.2.1) and its impact on El Niño–Southern Oscillation forecasts
Great Lakes wave forecast system on high-resolution unstructured meshes
Impact of increased resolution on Arctic Ocean simulations in Ocean Model Intercomparison Project phase 2 (OMIP-2)
A high-resolution physical–biogeochemical model for marine resource applications in the northwest Atlantic (MOM6-COBALT-NWA12 v1.0)
A flexible z-layers approach for the accurate representation of free surface flows in a coastal ocean model (SHYFEM v. 7_5_71)
Implementation and assessment of a model including mixotrophs and the carbonate cycle (Eco3M_MIX-CarbOx v1.0) in a highly dynamic Mediterranean coastal environment (Bay of Marseille, France) – Part 1: Evolution of ecosystem composition under limited light and nutrient conditions
Ocean wave tracing v.1: a numerical solver of the wave ray equations for ocean waves on variable currents at arbitrary depths
Design and evaluation of an efficient high-precision ocean surface wave model with a multiscale grid system (MSG_Wav1.0)
Evaluation of the CMCC global eddying ocean model for the Ocean Model Intercomparison Project (OMIP2)
Comparison of 4-Dimensional Variational and Ensemble Optimal Interpolation data assimilation systems using a Regional Ocean Modelling System (v3.4) configuration of the eddy-dominated East Australian Current System
CAR36, a regional high-resolution ocean forecasting system for improving drift and beaching of Sargassum in the Caribbean Archipelago
Barents-2.5km v2.0: an operational data-assimilative coupled ocean and sea ice ensemble prediction model for the Barents Sea and Svalbard
Open-ocean tides simulated by ICON-O, version icon-2.6.6
Using Probability Density Functions to Evaluate Models (PDFEM, v1.0) to compare a biogeochemical model with satellite-derived chlorophyll
Data assimilation sensitivity experiments in the East Auckland Current system using 4D-Var
Using the COAsT Python package to develop a standardised validation workflow for ocean physics models
Improving Antarctic Bottom Water precursors in NEMO for climate applications
Formulation, optimization, and sensitivity of NitrOMZv1.0, a biogeochemical model of the nitrogen cycle in oceanic oxygen minimum zones
Implementation of additional spectral wave field exchanges in a 3D wave-current coupled WAVEWATCH-III (version 6.07) – CROCO (version 1.2) configuration and assessment of their implications for macro-tidal coastal hydrodynamics
Waves in SKRIPS: WAVEWATCH III coupling implementation and a case study of Tropical Cyclone Mekunu
Adding sea ice effects to a global operational model (NEMO v3.6) for forecasting total water level: approach and impact
Enhanced ocean wave modeling by including effect of breaking under both deep- and shallow-water conditions
An internal solitary wave forecasting model in the northern South China Sea (ISWFM-NSCS)
Intercomparisons of five ocean particle tracking software packages
The 3D biogeochemical marine mercury cycling model MERCY v2.0 – linking atmospheric Hg to methylmercury in fish
Global seamless tidal simulation using a 3D unstructured-grid model (SCHISM v5.10.0)
Arctic Ocean simulations in the CMIP6 Ocean Model Intercomparison Project (OMIP)
ChemicalDrift 1.0: an open-source Lagrangian chemical-fate and transport model for organic aquatic pollutants
The Met Office operational wave forecasting system: the evolution of the regional and global models
4DVarNet-SSH: end-to-end learning of variational interpolation schemes for nadir and wide-swath satellite altimetry
Development and validation of a global 1∕32° surface-wave–tide–circulation coupled ocean model: FIO-COM32
Reproducible and relocatable regional ocean modelling: fundamentals and practices
Barotropic tides in MPAS-Ocean (E3SM V2): impact of ice shelf cavities
Using the two-way nesting technique AGRIF with MARS3D V11.2 to improve hydrodynamics and estimate environmental indicators
Multidecadal and climatological surface current simulations for the southwestern Indian Ocean at 1∕50° resolution
The tidal effects in the Finite-volumE Sea ice–Ocean Model (FESOM2.1): a comparison between parameterised tidal mixing and explicit tidal forcing
HIDRA2: deep-learning ensemble sea level and storm tide forecasting in the presence of seiches – the case of the northern Adriatic
Moana Ocean Hindcast – a > 25-year simulation for New Zealand waters using the Regional Ocean Modeling System (ROMS) v3.9 model
A nonhydrostatic oceanic regional model, ORCTM v1, for internal solitary wave simulation
How does 4DVar data assimilation affect the vertical representation of mesoscale eddies? A case study with observing system simulation experiments (OSSEs) using ROMS v3.9
An ensemble Kalman filter-based ocean data assimilation system improved by adaptive observation error inflation (AOEI)
GULF18, a high-resolution NEMO-based tidal ocean model of the Arabian/Persian Gulf
The Baltic Sea Model Intercomparison Project (BMIP) – a platform for model development, evaluation, and uncertainty assessment
An ensemble Kalman filter system with the Stony Brook Parallel Ocean Model v1.0
Wind work at the air-sea interface: a modeling study in anticipation of future space missions
Improved upper-ocean thermodynamical structure modeling with combined effects of surface waves and M2 internal tides on vertical mixing: a case study for the Indian Ocean
The bulk parameterizations of turbulent air–sea fluxes in NEMO4: the origin of sea surface temperature differences in a global model study
Ivan Hernandez, Leidy M. Castro-Rosero, Manuel Espino, and Jose M. Alsina Torrent
Geosci. Model Dev., 17, 2221–2245, https://doi.org/10.5194/gmd-17-2221-2024, https://doi.org/10.5194/gmd-17-2221-2024, 2024
Short summary
Short summary
The LOCATE numerical model was developed to conduct Lagrangian simulations of the transport and dispersion of marine debris at coastal scales. High-resolution hydrodynamic data and a beaching module that used particle distance to the shore for land–water boundary detection were used on a realistic debris discharge scenario comparing hydrodynamic data at various resolutions. Coastal processes and complex geometric structures were resolved when using nested grids and distance-to-shore beaching.
Ngoc B. Trinh, Marine Herrmann, Caroline Ulses, Patrick Marsaleix, Thomas Duhaut, Thai To Duy, Claude Estournel, and R. Kipp Shearman
Geosci. Model Dev., 17, 1831–1867, https://doi.org/10.5194/gmd-17-1831-2024, https://doi.org/10.5194/gmd-17-1831-2024, 2024
Short summary
Short summary
A high-resolution model was built to study the South China Sea (SCS) water, heat, and salt budgets. Model performance is demonstrated by comparison with observations and simulations. Important discards are observed if calculating offline, instead of online, lateral inflows and outflows of water, heat, and salt. The SCS mainly receives water from the Luzon Strait and releases it through the Mindoro, Taiwan, and Karimata straits. SCS surface interocean water exchanges are driven by monsoon winds.
Louis Thiry, Long Li, Guillaume Roullet, and Etienne Mémin
Geosci. Model Dev., 17, 1749–1764, https://doi.org/10.5194/gmd-17-1749-2024, https://doi.org/10.5194/gmd-17-1749-2024, 2024
Short summary
Short summary
We present a new way of solving the quasi-geostrophic (QG) equations, a simple set of equations describing ocean dynamics. Our method is solely based on the numerical methods used to solve the equations and requires no parameter tuning. Moreover, it can handle non-rectangular geometries, opening the way to study QG equations on realistic domains. We release a PyTorch implementation to ease future machine-learning developments on top of the presented method.
Zheqi Shen, Yihao Chen, Xiaojing Li, and Xunshu Song
Geosci. Model Dev., 17, 1651–1665, https://doi.org/10.5194/gmd-17-1651-2024, https://doi.org/10.5194/gmd-17-1651-2024, 2024
Short summary
Short summary
Parameter estimation is the process that optimizes model parameters using observations, which could reduce model errors and improve forecasting. In this study, we conducted parameter estimation experiments using the CESM and the ensemble adjustment Kalman filter. The obtained initial conditions and parameters are used to perform ensemble forecast experiments for ENSO forecasting. The results revealed that parameter estimation could reduce analysis errors and improve ENSO forecast skills.
Ali Abdolali, Saeideh Banihashemi, Jose Henrique Alves, Aron Roland, Tyler J. Hesser, Mary Anderson Bryant, and Jane McKee Smith
Geosci. Model Dev., 17, 1023–1039, https://doi.org/10.5194/gmd-17-1023-2024, https://doi.org/10.5194/gmd-17-1023-2024, 2024
Short summary
Short summary
This article presents an overview of the development and implementation of Great Lake Wave Unstructured (GLWUv2.0), including the core model and workflow design and development. The validation was conducted against in situ data for the re-forecasted duration for summer and wintertime (ice season). The article describes the limitations and challenges encountered in the operational environment and the path forward for the next generation of wave forecast systems in enclosed basins like the GL.
Qiang Wang, Qi Shu, Alexandra Bozec, Eric P. Chassignet, Pier Giuseppe Fogli, Baylor Fox-Kemper, Andy McC. Hogg, Doroteaciro Iovino, Andrew E. Kiss, Nikolay Koldunov, Julien Le Sommer, Yiwen Li, Pengfei Lin, Hailong Liu, Igor Polyakov, Patrick Scholz, Dmitry Sidorenko, Shizhu Wang, and Xiaobiao Xu
Geosci. Model Dev., 17, 347–379, https://doi.org/10.5194/gmd-17-347-2024, https://doi.org/10.5194/gmd-17-347-2024, 2024
Short summary
Short summary
Increasing resolution improves model skills in simulating the Arctic Ocean, but other factors such as parameterizations and numerics are at least of the same importance for obtaining reliable simulations.
Andrew C. Ross, Charles A. Stock, Alistair Adcroft, Enrique Curchitser, Robert Hallberg, Matthew J. Harrison, Katherine Hedstrom, Niki Zadeh, Michael Alexander, Wenhao Chen, Elizabeth J. Drenkard, Hubert du Pontavice, Raphael Dussin, Fabian Gomez, Jasmin G. John, Dujuan Kang, Diane Lavoie, Laure Resplandy, Alizée Roobaert, Vincent Saba, Sang-Ik Shin, Samantha Siedlecki, and James Simkins
Geosci. Model Dev., 16, 6943–6985, https://doi.org/10.5194/gmd-16-6943-2023, https://doi.org/10.5194/gmd-16-6943-2023, 2023
Short summary
Short summary
We evaluate a model for northwest Atlantic Ocean dynamics and biogeochemistry that balances high resolution with computational economy by building on the new regional features in the MOM6 ocean model and COBALT biogeochemical model. We test the model's ability to simulate impactful historical variability and find that the model simulates the mean state and variability of most features well, which suggests the model can provide information to inform living-marine-resource applications.
Luca Arpaia, Christian Ferrarin, Marco Bajo, and Georg Umgiesser
Geosci. Model Dev., 16, 6899–6919, https://doi.org/10.5194/gmd-16-6899-2023, https://doi.org/10.5194/gmd-16-6899-2023, 2023
Short summary
Short summary
We propose a discrete multilayer shallow water model based on z-layers which, thanks to the insertion and removal of surface layers, can deal with an arbitrarily large tidal oscillation independently of the vertical resolution. The algorithm is based on a two-step procedure used in numerical simulations with moving boundaries (grid movement followed by a grid topology change, that is, the insertion/removal of surface layers), which avoids the appearance of very thin surface layers.
Lucille Barré, Frédéric Diaz, Thibaut Wagener, France Van Wambeke, Camille Mazoyer, Christophe Yohia, and Christel Pinazo
Geosci. Model Dev., 16, 6701–6739, https://doi.org/10.5194/gmd-16-6701-2023, https://doi.org/10.5194/gmd-16-6701-2023, 2023
Short summary
Short summary
While several studies have shown that mixotrophs play a crucial role in the carbon cycle, the impact of environmental forcings on their dynamics remains poorly investigated. Using a biogeochemical model that considers mixotrophs, we study the impact of light and nutrient concentration on the ecosystem composition in a highly dynamic Mediterranean coastal area: the Bay of Marseille. We show that mixotrophs cope better with oligotrophic conditions compared to strict auto- and heterotrophs.
Trygve Halsne, Kai Håkon Christensen, Gaute Hope, and Øyvind Breivik
Geosci. Model Dev., 16, 6515–6530, https://doi.org/10.5194/gmd-16-6515-2023, https://doi.org/10.5194/gmd-16-6515-2023, 2023
Short summary
Short summary
Surface waves that propagate in oceanic or coastal environments get influenced by their surroundings. Changes in the ambient current or the depth profile affect the wave propagation path, and the change in wave direction is called refraction. Some analytical solutions to the governing equations exist under ideal conditions, but for realistic situations, the equations must be solved numerically. Here we present such a numerical solver under an open-source license.
Jiangyu Li, Shaoqing Zhang, Qingxiang Liu, Xiaolin Yu, and Zhiwei Zhang
Geosci. Model Dev., 16, 6393–6412, https://doi.org/10.5194/gmd-16-6393-2023, https://doi.org/10.5194/gmd-16-6393-2023, 2023
Short summary
Short summary
Ocean surface waves play an important role in the air–sea interface but are rarely activated in high-resolution Earth system simulations due to their expensive computational costs. To alleviate this situation, this paper designs a new wave modeling framework with a multiscale grid system. Evaluations of a series of numerical experiments show that it has good feasibility and applicability in the WAVEWATCH III model, WW3, and can achieve the goals of efficient and high-precision wave simulation.
Doroteaciro Iovino, Pier Giuseppe Fogli, and Simona Masina
Geosci. Model Dev., 16, 6127–6159, https://doi.org/10.5194/gmd-16-6127-2023, https://doi.org/10.5194/gmd-16-6127-2023, 2023
Short summary
Short summary
This paper describes the model performance of three global ocean–sea ice configurations, from non-eddying (1°) to eddy-rich (1/16°) resolutions. Model simulations are obtained following the Ocean Model Intercomparison Project phase 2 (OMIP2) protocol. We compare key global climate variables across the three models and against observations, emphasizing the relative advantages and disadvantages of running forced ocean–sea ice models at higher resolution.
Colette Gabrielle Kerry, Moninya Roughan, Shane Keating, David Gwyther, Gary Brassington, Adil Siripitana, and Joao Marcos A. C. Souza
EGUsphere, https://doi.org/10.5194/egusphere-2023-2355, https://doi.org/10.5194/egusphere-2023-2355, 2023
Short summary
Short summary
Ocean forecasting relies on the combination of numerical models and ocean observations through data assimilation (DA). Here we assess the performance of two DA systems in a dynamic Western Boundary Current, the East Australian Current, across a common modelling and observational framework. We show that the more advanced, time-dependent method outperforms the time-independent method for forecast horizons of 5 days. This advocates the use of advanced methods for highly variable oceanic regions.
Sylvain Cailleau, Laurent Bessières, Léonel Chiendje, Flavie Dubost, Guillaume Reffray, Jean-Michel Lellouche, Simon van Gennip, Charly Régnier, Marie Drevillon, Marc Tressol, Matthieu Clavier, Julien Temple-Boyer, and Léo Berline
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2023-183, https://doi.org/10.5194/gmd-2023-183, 2023
Revised manuscript accepted for GMD
Short summary
Short summary
In order to improve the Sargassum drift forecasting in the Caribbean area, drift models can be forced by higher resolution ocean currents. To this goal a 3-km resolution regional ocean model has been developed. its assessment is presented with a particular focus on the reproduction of fine structures representing key features of the Caribbean region dynamics and Sargassum transport. The simulated propagation of a North Brazil Current eddy and its dissipation were found to be quite realistic.
Johannes Röhrs, Yvonne Gusdal, Edel S. U. Rikardsen, Marina Durán Moro, Jostein Brændshøi, Nils Melsom Kristensen, Sindre Fritzner, Keguang Wang, Ann Kristin Sperrevik, Martina Idžanović, Thomas Lavergne, Jens Boldingh Debernard, and Kai H. Christensen
Geosci. Model Dev., 16, 5401–5426, https://doi.org/10.5194/gmd-16-5401-2023, https://doi.org/10.5194/gmd-16-5401-2023, 2023
Short summary
Short summary
A model to predict ocean currents, temperature, and sea ice is presented, covering the Barents Sea and northern Norway. To quantify forecast uncertainties, the model calculates ensemble forecasts with 24 realizations of ocean and ice conditions. Observations from satellites, buoys, and ships are ingested by the model. The model forecasts are compared with observations, and we show that the ocean model has skill in predicting sea surface temperatures.
Jin-Song von Storch, Eileen Hertwig, Veit Lüschow, Nils Brüggemann, Helmuth Haak, Peter Korn, and Vikram Singh
Geosci. Model Dev., 16, 5179–5196, https://doi.org/10.5194/gmd-16-5179-2023, https://doi.org/10.5194/gmd-16-5179-2023, 2023
Short summary
Short summary
The new ocean general circulation model ICON-O is developed for running experiments at kilometer scales and beyond. One targeted application is to simulate internal tides crucial for ocean mixing. To ensure their realism, which is difficult to assess, we evaluate the barotropic tides that generate internal tides. We show that ICON-O is able to realistically simulate the major aspects of the observed barotropic tides and discuss the aspects that impact the quality of the simulated tides.
Bror F. Jönsson, Christopher L. Follett, Jacob Bien, Stephanie Dutkiewicz, Sangwon Hyun, Gemma Kulk, Gael L. Forget, Christian Müller, Marie-Fanny Racault, Christopher N. Hill, Thomas Jackson, and Shubha Sathyendranath
Geosci. Model Dev., 16, 4639–4657, https://doi.org/10.5194/gmd-16-4639-2023, https://doi.org/10.5194/gmd-16-4639-2023, 2023
Short summary
Short summary
While biogeochemical models and satellite-derived ocean color data provide unprecedented information, it is problematic to compare them. Here, we present a new approach based on comparing probability density distributions of model and satellite properties to assess model skills. We also introduce Earth mover's distances as a novel and powerful metric to quantify the misfit between models and observations. We find that how 3D chlorophyll fields are aggregated can be a significant source of error.
Rafael Santana, Helen Macdonald, Joanne O'Callaghan, Brian Powell, Sarah Wakes, and Sutara H. Suanda
Geosci. Model Dev., 16, 3675–3698, https://doi.org/10.5194/gmd-16-3675-2023, https://doi.org/10.5194/gmd-16-3675-2023, 2023
Short summary
Short summary
We show the importance of assimilating subsurface temperature and velocity data in a model of the East Auckland Current. Assimilation of velocity increased the representation of large oceanic vortexes. Assimilation of temperature is needed to correctly simulate temperatures around 100 m depth, which is the most difficult region to simulate in ocean models. Our simulations showed improved results in comparison to the US Navy global model and highlight the importance of regional models.
David Byrne, Jeff Polton, Enda O'Dea, and Joanne Williams
Geosci. Model Dev., 16, 3749–3764, https://doi.org/10.5194/gmd-16-3749-2023, https://doi.org/10.5194/gmd-16-3749-2023, 2023
Short summary
Short summary
Validation is a crucial step during the development of models for ocean simulation. The purpose of validation is to assess how accurate a model is. It is most commonly done by comparing output from a model to actual observations. In this paper, we introduce and demonstrate usage of the COAsT Python package to standardise the validation process for physical ocean models. We also discuss our five guiding principles for standardised validation.
Katherine Hutchinson, Julie Deshayes, Christian Éthé, Clément Rousset, Casimir de Lavergne, Martin Vancoppenolle, Nicolas C. Jourdain, and Pierre Mathiot
Geosci. Model Dev., 16, 3629–3650, https://doi.org/10.5194/gmd-16-3629-2023, https://doi.org/10.5194/gmd-16-3629-2023, 2023
Short summary
Short summary
Bottom Water constitutes the lower half of the ocean’s overturning system and is primarily formed in the Weddell and Ross Sea in the Antarctic due to interactions between the atmosphere, ocean, sea ice and ice shelves. Here we use a global ocean 1° resolution model with explicit representation of the three large ice shelves important for the formation of the parent waters of Bottom Water. We find doing so reduces salt biases, improves water mass realism and gives realistic ice shelf melt rates.
Daniele Bianchi, Daniel McCoy, and Simon Yang
Geosci. Model Dev., 16, 3581–3609, https://doi.org/10.5194/gmd-16-3581-2023, https://doi.org/10.5194/gmd-16-3581-2023, 2023
Short summary
Short summary
We present NitrOMZ, a new model of the oceanic nitrogen cycle that simulates chemical transformations within oxygen minimum zones (OMZs). We describe the model formulation and its implementation in a one-dimensional representation of the water column before evaluating its ability to reproduce observations in the eastern tropical South Pacific. We conclude by describing the model sensitivity to parameter choices and environmental factors and its application to nitrogen cycling in the ocean.
Gaetano Porcile, Anne-Claire Bennis, Martial Boutet, Sophie Le Bot, Franck Dumas, and Swen Jullien
EGUsphere, https://doi.org/10.5194/egusphere-2023-715, https://doi.org/10.5194/egusphere-2023-715, 2023
Short summary
Short summary
Here a new method of modeling the interaction between ocean currents and waves is presented. We developed an advanced coupling of two models, one for ocean circulation and one for waves. In previous couplings, some wave-related calculations were based on simplified assumptions. Our method uses more complex calculations to better represent wave-current interactions. We tested it in a macro-tidal coastal area and found that it significantly improves the model accuracy, especially during storms.
Rui Sun, Alison Cobb, Ana B. Villas Bôas, Sabique Langodan, Aneesh C. Subramanian, Matthew R. Mazloff, Bruce D. Cornuelle, Arthur J. Miller, Raju Pathak, and Ibrahim Hoteit
Geosci. Model Dev., 16, 3435–3458, https://doi.org/10.5194/gmd-16-3435-2023, https://doi.org/10.5194/gmd-16-3435-2023, 2023
Short summary
Short summary
In this work, we integrated the WAVEWATCH III model into the regional coupled model SKRIPS. We then performed a case study using the newly implemented model to study Tropical Cyclone Mekunu, which occurred in the Arabian Sea. We found that the coupled model better simulates the cyclone than the uncoupled model, but the impact of waves on the cyclone is not significant. However, the waves change the sea surface temperature and mixed layer, especially in the cold waves produced due to the cyclone.
Pengcheng Wang and Natacha B. Bernier
Geosci. Model Dev., 16, 3335–3354, https://doi.org/10.5194/gmd-16-3335-2023, https://doi.org/10.5194/gmd-16-3335-2023, 2023
Short summary
Short summary
Effects of sea ice are typically neglected in operational flood forecast systems. In this work, we capture these effects via the addition of a parameterized ice–ocean stress. The parameterization takes advantage of forecast fields from an advanced ice–ocean model and features a novel, consistent representation of the tidal relative ice–ocean velocity. The new parameterization leads to improved forecasts of tides and storm surges in polar regions. Associated physical processes are discussed.
Yue Xu and Xiping Yu
Geosci. Model Dev., 16, 2811–2831, https://doi.org/10.5194/gmd-16-2811-2023, https://doi.org/10.5194/gmd-16-2811-2023, 2023
Short summary
Short summary
An accurate description of the wind energy input into ocean waves is crucial to ocean wave modeling, and a physics-based consideration of the effect of wave breaking is absolutely necessary to obtain such an accurate description, particularly under extreme conditions. This study evaluates the performance of a recently improved formula, taking into account not only the effect of breaking but also the effect of airflow separation on the leeside of steep wave crests in a reasonably consistent way.
Yankun Gong, Xueen Chen, Jiexin Xu, Jieshuo Xie, Zhiwu Chen, Yinghui He, and Shuqun Cai
Geosci. Model Dev., 16, 2851–2871, https://doi.org/10.5194/gmd-16-2851-2023, https://doi.org/10.5194/gmd-16-2851-2023, 2023
Short summary
Short summary
Internal solitary waves (ISWs) play crucial roles in mass transport and ocean mixing in the northern South China Sea. Massive numerical investigations have been conducted in this region, but there was no systematic evaluation of a three-dimensional model about precisely simulating ISWs. Here, an ISW forecasting model is employed to evaluate the roles of resolution, tidal forcing and stratification in accurately reproducing wave properties via comparison to field and remote-sensing observations.
Jilian Xiong and Parker MacCready
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2023-45, https://doi.org/10.5194/gmd-2023-45, 2023
Revised manuscript accepted for GMD
Short summary
Short summary
A new offline particle tracking model, Tracker, was introduced to work with the Regional Ocean Modeling System (ROMS). Its performance was compared with four other particle tracking models and passive dye, which span a representative range of tracking algorithms. All tracking models perform similarly, especially for the first day. The comparison of multiple tracking codes in the same circulation model establishes confidence in all, and allows comparison of performance and ease of use.
Johannes Bieser, David J. Amptmeijer, Ute Daewel, Joachim Kuss, Anne L. Soerensen, and Corinna Schrum
Geosci. Model Dev., 16, 2649–2688, https://doi.org/10.5194/gmd-16-2649-2023, https://doi.org/10.5194/gmd-16-2649-2023, 2023
Short summary
Short summary
MERCY is a 3D model to study mercury (Hg) cycling in the ocean. Hg is a highly harmful pollutant regulated by the UN Minamata Convention on Mercury due to widespread human emissions. These emissions eventually reach the oceans, where Hg transforms into the even more toxic and bioaccumulative pollutant methylmercury. MERCY predicts the fate of Hg in the ocean and its buildup in the food chain. It is the first model to consider Hg accumulation in fish, a major source of Hg exposure for humans.
Y. Joseph Zhang, Tomas Fernandez-Montblanc, William Pringle, Hao-Cheng Yu, Linlin Cui, and Saeed Moghimi
Geosci. Model Dev., 16, 2565–2581, https://doi.org/10.5194/gmd-16-2565-2023, https://doi.org/10.5194/gmd-16-2565-2023, 2023
Short summary
Short summary
Simulating global ocean from deep basins to coastal areas is a daunting task but is important for disaster mitigation efforts. We present a new 3D global ocean model on flexible mesh to study both tidal and nontidal processes and total water prediction. We demonstrate the potential for
seamlesssimulation, on a single mesh, from the global ocean to a few estuaries along the US West Coast. The model can serve as the backbone of a global tide surge and compound flooding forecasting framework.
Qi Shu, Qiang Wang, Chuncheng Guo, Zhenya Song, Shizhu Wang, Yan He, and Fangli Qiao
Geosci. Model Dev., 16, 2539–2563, https://doi.org/10.5194/gmd-16-2539-2023, https://doi.org/10.5194/gmd-16-2539-2023, 2023
Short summary
Short summary
Ocean models are often used for scientific studies on the Arctic Ocean. Here the Arctic Ocean simulations by state-of-the-art global ocean–sea-ice models participating in the Ocean Model Intercomparison Project (OMIP) were evaluated. The simulations on Arctic Ocean hydrography, freshwater content, stratification, sea surface height, and gateway transports were assessed and the common biases were detected. The simulations forced by different atmospheric forcing were also evaluated.
Manuel Aghito, Loris Calgaro, Knut-Frode Dagestad, Christian Ferrarin, Antonio Marcomini, Øyvind Breivik, and Lars Robert Hole
Geosci. Model Dev., 16, 2477–2494, https://doi.org/10.5194/gmd-16-2477-2023, https://doi.org/10.5194/gmd-16-2477-2023, 2023
Short summary
Short summary
The newly developed ChemicalDrift model can simulate the transport and fate of chemicals in the ocean and in coastal regions. The model combines ocean physics, including transport due to currents, turbulence due to surface winds and the sinking of particles to the sea floor, with ocean chemistry, such as the partitioning, the degradation and the evaporation of chemicals. The model will be utilized for risk assessment of ocean and sea-floor contamination from pollutants emitted from shipping.
Nieves G. Valiente, Andrew Saulter, Breogan Gomez, Christopher Bunney, Jian-Guo Li, Tamzin Palmer, and Christine Pequignet
Geosci. Model Dev., 16, 2515–2538, https://doi.org/10.5194/gmd-16-2515-2023, https://doi.org/10.5194/gmd-16-2515-2023, 2023
Short summary
Short summary
We document the Met Office operational global and regional wave models which provide wave forecasts up to 7 d ahead. Our models present coarser resolution offshore to higher resolution near the coastline. The increased resolution led to replication of the extremes but to some overestimation during modal conditions. If currents are included, wave directions and long period swells near the coast are significantly improved. New developments focus on the optimisation of the models with resolution.
Maxime Beauchamp, Quentin Febvre, Hugo Georgenthum, and Ronan Fablet
Geosci. Model Dev., 16, 2119–2147, https://doi.org/10.5194/gmd-16-2119-2023, https://doi.org/10.5194/gmd-16-2119-2023, 2023
Short summary
Short summary
4DVarNet is a learning-based method based on traditional data assimilation (DA). This new class of algorithms can be used to provide efficient reconstructions of a dynamical system based on single observations. We provide a 4DVarNet application to sea surface height reconstructions based on nadir and future Surface Water and Ocean and Topography data. It outperforms other methods, from optimal interpolation to sophisticated DA algorithms. This work is part of on-going AI Chair Oceanix projects.
Bin Xiao, Fangli Qiao, Qi Shu, Xunqiang Yin, Guansuo Wang, and Shihong Wang
Geosci. Model Dev., 16, 1755–1777, https://doi.org/10.5194/gmd-16-1755-2023, https://doi.org/10.5194/gmd-16-1755-2023, 2023
Short summary
Short summary
A new global surface-wave–tide–circulation coupled ocean model (FIO-COM32) with a resolution of 1/32° × 1/32° is developed and validated. Both the promotion of the horizontal resolution and included physical processes are shown to be important contributors to the significant improvements in FIO-COM32 simulations. It is time to merge these separated model components (surface waves, tidal currents and ocean circulation) and start a new generation of ocean model development.
Jeff Polton, James Harle, Jason Holt, Anna Katavouta, Dale Partridge, Jenny Jardine, Sarah Wakelin, Julia Rulent, Anthony Wise, Katherine Hutchinson, David Byrne, Diego Bruciaferri, Enda O'Dea, Michela De Dominicis, Pierre Mathiot, Andrew Coward, Andrew Yool, Julien Palmiéri, Gennadi Lessin, Claudia Gabriela Mayorga-Adame, Valérie Le Guennec, Alex Arnold, and Clément Rousset
Geosci. Model Dev., 16, 1481–1510, https://doi.org/10.5194/gmd-16-1481-2023, https://doi.org/10.5194/gmd-16-1481-2023, 2023
Short summary
Short summary
The aim is to increase the capacity of the modelling community to respond to societally important questions that require ocean modelling. The concept of reproducibility for regional ocean modelling is developed: advocating methods for reproducible workflows and standardised methods of assessment. Then, targeting the NEMO framework, we give practical advice and worked examples, highlighting key considerations that will the expedite development cycle and upskill the user community.
Nairita Pal, Kristin N. Barton, Mark R. Petersen, Steven R. Brus, Darren Engwirda, Brian K. Arbic, Andrew F. Roberts, Joannes J. Westerink, and Damrongsak Wirasaet
Geosci. Model Dev., 16, 1297–1314, https://doi.org/10.5194/gmd-16-1297-2023, https://doi.org/10.5194/gmd-16-1297-2023, 2023
Short summary
Short summary
Understanding tides is essential to accurately predict ocean currents. Over the next several decades coastal processes such as flooding and erosion will be severely impacted due to climate change. Tides affect currents along the coastal regions the most. In this paper we show the results of implementing tides in a global ocean model known as MPAS–Ocean. We also show how Antarctic ice shelf cavities affect global tides. Our work points towards future research with tide–ice interactions.
Sébastien Petton, Valérie Garnier, Matthieu Caillaud, Laurent Debreu, and Franck Dumas
Geosci. Model Dev., 16, 1191–1211, https://doi.org/10.5194/gmd-16-1191-2023, https://doi.org/10.5194/gmd-16-1191-2023, 2023
Short summary
Short summary
The nesting AGRIF library is implemented in the MARS3D hydrodynamic model, a semi-implicit, free-surface numerical model which uses a time scheme as an alternating-direction implicit (ADI) algorithm. Two applications at the regional and coastal scale are introduced. We compare the two-nesting approach to the classic offline one-way approach, based on an in situ dataset. This method is an efficient means to significantly improve the physical hydrodynamics and unravel ecological challenges.
Noam S. Vogt-Vincent and Helen L. Johnson
Geosci. Model Dev., 16, 1163–1178, https://doi.org/10.5194/gmd-16-1163-2023, https://doi.org/10.5194/gmd-16-1163-2023, 2023
Short summary
Short summary
Ocean currents transport things over large distances across the ocean surface. Predicting this transport is key for tackling many environmental problems, such as marine plastic pollution and coral reef resilience. However, doing this requires a good understanding ocean currents, which is currently lacking. Here, we present and validate state-of-the-art simulations for surface currents in the southwestern Indian Ocean, which will support future marine dispersal studies across this region.
Pengyang Song, Dmitry Sidorenko, Patrick Scholz, Maik Thomas, and Gerrit Lohmann
Geosci. Model Dev., 16, 383–405, https://doi.org/10.5194/gmd-16-383-2023, https://doi.org/10.5194/gmd-16-383-2023, 2023
Short summary
Short summary
Tides have essential effects on the ocean and climate. Most previous research applies parameterised tidal mixing to discuss their effects in models. By comparing the effect of a tidal mixing parameterisation and tidal forcing on the ocean state, we assess the advantages and disadvantages of the two methods. Our results show that tidal mixing in the North Pacific Ocean strongly affects the global thermohaline circulation. We also list some effects that are not considered in the parameterisation.
Marko Rus, Anja Fettich, Matej Kristan, and Matjaž Ličer
Geosci. Model Dev., 16, 271–288, https://doi.org/10.5194/gmd-16-271-2023, https://doi.org/10.5194/gmd-16-271-2023, 2023
Short summary
Short summary
We propose a new fast and reliable deep-learning architecture HIDRA2 for sea level and storm surge modeling. HIDRA2 features new feature encoders and a fusion-regression block. We test HIDRA2 on Adriatic storm surges, which depend on an interaction between tides and seiches. We demonstrate that HIDRA2 learns to effectively mimic the timing and amplitude of Adriatic seiches. This is essential for reliable HIDRA2 predictions of total storm surge sea levels.
Joao Marcos Azevedo Correia de Souza, Sutara H. Suanda, Phellipe P. Couto, Robert O. Smith, Colette Kerry, and Moninya Roughan
Geosci. Model Dev., 16, 211–231, https://doi.org/10.5194/gmd-16-211-2023, https://doi.org/10.5194/gmd-16-211-2023, 2023
Short summary
Short summary
The current paper describes the configuration and evaluation of the Moana Ocean Hindcast, a > 25-year simulation of the ocean state around New Zealand using the Regional Ocean Modeling System v3.9. This is the first open-access, long-term, continuous, realistic ocean simulation for this region and provides information for improving the understanding of the ocean processes that affect the New Zealand exclusive economic zone.
Hao Huang, Pengyang Song, Shi Qiu, Jiaqi Guo, and Xueen Chen
Geosci. Model Dev., 16, 109–133, https://doi.org/10.5194/gmd-16-109-2023, https://doi.org/10.5194/gmd-16-109-2023, 2023
Short summary
Short summary
The Oceanic Regional Circulation and Tide Model (ORCTM) is developed to reproduce internal solitary wave dynamics. The three-dimensional nonlinear momentum equations are involved with the nonhydrostatic pressure obtained via solving the Poisson equation. The validation experimental results agree with the internal wave theories and observations, demonstrating that the ORCTM can successfully describe the life cycle of nonlinear internal solitary waves under different oceanic environments.
David E. Gwyther, Shane R. Keating, Colette Kerry, and Moninya Roughan
Geosci. Model Dev., 16, 157–178, https://doi.org/10.5194/gmd-16-157-2023, https://doi.org/10.5194/gmd-16-157-2023, 2023
Short summary
Short summary
Ocean eddies are important for weather, climate, biology, navigation, and search and rescue. Since eddies change rapidly, models that incorporate or assimilate observations are required to produce accurate eddy timings and locations, yet the model accuracy is rarely assessed below the surface. We use a unique type of ocean model experiment to assess three-dimensional eddy structure in the East Australian Current and explore two pathways in which this subsurface structure is being degraded.
Shun Ohishi, Takemasa Miyoshi, and Misako Kachi
Geosci. Model Dev., 15, 9057–9073, https://doi.org/10.5194/gmd-15-9057-2022, https://doi.org/10.5194/gmd-15-9057-2022, 2022
Short summary
Short summary
An adaptive observation error inflation (AOEI) method was proposed for atmospheric data assimilation to mitigate erroneous analysis updates caused by large observation-minus-forecast differences for satellite brightness temperature around clear- and cloudy-sky boundaries. This study implemented the AOEI with an ocean data assimilation system, leading to an improvement of analysis accuracy and dynamical balance around the frontal regions with large meridional temperature differences.
Diego Bruciaferri, Marina Tonani, Isabella Ascione, Fahad Al Senafi, Enda O'Dea, Helene T. Hewitt, and Andrew Saulter
Geosci. Model Dev., 15, 8705–8730, https://doi.org/10.5194/gmd-15-8705-2022, https://doi.org/10.5194/gmd-15-8705-2022, 2022
Short summary
Short summary
More accurate predictions of the Gulf's ocean dynamics are needed. We investigate the impact on the predictive skills of a numerical shelf sea model of the Gulf after changing a few key aspects. Increasing the lateral and vertical resolution and optimising the vertical coordinate system to best represent the leading physical processes at stake significantly improve the accuracy of the simulated dynamics. Additional work may be needed to get real benefit from using a more realistic bathymetry.
Matthias Gröger, Manja Placke, H. E. Markus Meier, Florian Börgel, Sandra-Esther Brunnabend, Cyril Dutheil, Ulf Gräwe, Magnus Hieronymus, Thomas Neumann, Hagen Radtke, Semjon Schimanke, Jian Su, and Germo Väli
Geosci. Model Dev., 15, 8613–8638, https://doi.org/10.5194/gmd-15-8613-2022, https://doi.org/10.5194/gmd-15-8613-2022, 2022
Short summary
Short summary
Comparisons of oceanographic climate data from different models often suffer from different model setups, forcing fields, and output of variables. This paper provides a protocol to harmonize these elements to set up multidecadal simulations for the Baltic Sea, a marginal sea in Europe. First results are shown from six different model simulations from four different model platforms. Topical studies for upwelling, marine heat waves, and stratification are also assessed.
Shun Ohishi, Tsutomu Hihara, Hidenori Aiki, Joji Ishizaka, Yasumasa Miyazawa, Misako Kachi, and Takemasa Miyoshi
Geosci. Model Dev., 15, 8395–8410, https://doi.org/10.5194/gmd-15-8395-2022, https://doi.org/10.5194/gmd-15-8395-2022, 2022
Short summary
Short summary
We develop an ensemble-Kalman-filter-based regional ocean data assimilation system in which satellite and in situ observations are assimilated at a daily frequency. We find the best setting for dynamical balance and accuracy based on sensitivity experiments focused on how to inflate the ensemble spread and how to apply the analysis update to the model evolution. This study has a broader impact on more general data assimilation systems in which the initial shocks are a significant issue.
Hector S. Torres, Patrice Klein, Jinbo Wang, Alexander Wineteer, Bo Qiu, Andrew F. Thompson, Lionel Renault, Ernesto Rodriguez, Dimitris Menemenlis, Andrea Molod, Christopher N. Hill, Ehud Strobach, Hong Zhang, Mar Flexas, and Dragana Perkovic-Martin
Geosci. Model Dev., 15, 8041–8058, https://doi.org/10.5194/gmd-15-8041-2022, https://doi.org/10.5194/gmd-15-8041-2022, 2022
Short summary
Short summary
Wind work at the air-sea interface is the scalar product of winds and currents and is the transfer of kinetic energy between the ocean and the atmosphere. Using a new global coupled ocean-atmosphere simulation performed at kilometer resolution, we show that all scales of winds and currents impact the ocean dynamics at spatial and temporal scales. The consequential interplay of surface winds and currents in the numerical simulation motivates the need for a winds and currents satellite mission.
Zhanpeng Zhuang, Quanan Zheng, Yongzeng Yang, Zhenya Song, Yeli Yuan, Chaojie Zhou, Xinhua Zhao, Ting Zhang, and Jing Xie
Geosci. Model Dev., 15, 7221–7241, https://doi.org/10.5194/gmd-15-7221-2022, https://doi.org/10.5194/gmd-15-7221-2022, 2022
Short summary
Short summary
We evaluate the impacts of surface waves and internal tides on the upper-ocean mixing in the Indian Ocean. The surface-wave-generated turbulent mixing is dominant if depth is < 30 m, while the internal-tide-induced mixing is larger than surface waves in the ocean interior from 40
to 130 m. The simulated thermal structure, mixed layer depth and surface current are all improved when the mixing schemes are jointly incorporated into the ocean model because of the strengthened vertical mixing.
Giulia Bonino, Doroteaciro Iovino, Laurent Brodeau, and Simona Masina
Geosci. Model Dev., 15, 6873–6889, https://doi.org/10.5194/gmd-15-6873-2022, https://doi.org/10.5194/gmd-15-6873-2022, 2022
Short summary
Short summary
The sea surface temperature (SST) is highly influenced by the transfer of energy driven by turbulent air–sea fluxes (TASFs). In the NEMO ocean general circulation model, TASFs are computed by means of bulk formulas. Bulk formulas require the choice of a given bulk parameterization, which influences the magnitudes of the TASFs. Our results show that parameterization-related SST differences are primarily sensitive to the wind stress differences across parameterizations.
Cited articles
Abril, G., Bouillon, S., Darchambeau, F., Teodoru, C. R., Marwick, T. R., Tamooh, F., Ochieng Omengo, F., Geeraert, N., Deirmendjian, L., Polsenaere, P., and Borges, A. V.: Technical Note: Large overestimation of pCO2 calculated from pH and alkalinity in acidic, organic-rich freshwaters, Biogeosciences, 12, 67–78, https://doi.org/10.5194/bg-12-67-2015, 2015. a
Álvarez, M., Sanleón-Bartolomé, H., Tanhua, T., Mintrop, L., Luchetta, A., Cantoni, C., Schroeder, K., and Civitarese, G.: The CO2 system in the Mediterranean Sea: a basin wide perspective, Ocean Sci., 10, 69–92, https://doi.org/10.5194/os-10-69-2014, 2014. a
Bach, L. T.: Reconsidering the role of carbonate ion concentration in calcification by marine organisms, Biogeosciences, 12, 4939–4951, https://doi.org/10.5194/bg-12-4939-2015, 2015. a, b
Bakker, D. C. E., Pfeil, B., Landa, C. S., Metzl, N., O'Brien, K. M., Olsen, A., Smith, K., Cosca, C., Harasawa, S., Jones, S. D., Nakaoka, S., Nojiri, Y., Schuster, U., Steinhoff, T., Sweeney, C., Takahashi, T., Tilbrook, B., Wada, C., Wanninkhof, R., Alin, S. R., Balestrini, C. F., Barbero, L., Bates, N. R., Bianchi, A. A., Bonou, F., Boutin, J., Bozec, Y., Burger, E. F., Cai, W.-J., Castle, R. D., Chen, L., Chierici, M., Currie, K., Evans, W., Featherstone, C., Feely, R. A., Fransson, A., Goyet, C., Greenwood, N., Gregor, L., Hankin, S., Hardman-Mountford, N. J., Harlay, J., Hauck, J., Hoppema, M., Humphreys, M. P., Hunt, C. W., Huss, B., Ibánhez, J. S. P., Johannessen, T., Keeling, R., Kitidis, V., Körtzinger, A., Kozyr, A., Krasakopoulou, E., Kuwata, A., Landschützer, P., Lauvset, S. K., Lefèvre, N., Lo Monaco, C., Manke, A., Mathis, J. T., Merlivat, L., Millero, F. J., Monteiro, P. M. S., Munro, D. R., Murata, A., Newberger, T., Omar, A. M., Ono, T., Paterson, K., Pearce, D., Pierrot, D., Robbins, L. L., Saito, S., Salisbury, J., Schlitzer, R., Schneider, B., Schweitzer, R., Sieger, R., Skjelvan, I., Sullivan, K. F., Sutherland, S. C., Sutton, A. J., Tadokoro, K., Telszewski, M., Tuma, M., van Heuven, S. M. A. C., Vandemark, D., Ward, B., Watson, A. J., and Xu, S.: A multi-decade record of high-quality fCO2 data in version 3 of the Surface Ocean CO2 Atlas (SOCAT), Earth Syst. Sci. Data, 8, 383–413, https://doi.org/10.5194/essd-8-383-2016, 2016. a
Bradbury, J., Frostig, R., Hawkins, P., Johnson, M. J., Leary, C., Maclaurin,
D., and Wanderman-Milne, S.: JAX: composable transformations of
Python+NumPy programs, GitHub, available at: http://github.com/google/jax (last access: 23 December 2021), 2018. a
Branson, O.: oscarbranson/cbsyst: beta, Zenodo [code], https://doi.org/10.5281/zenodo.1402261, 2018. a
Broecker, W. S., Takahashi, T., Simpson, H. J., and Peng, T.-H.: Fate of
Fossil Fuel Carbon Dioxide and the Global Carbon Budget,
Science, 206, 409–418, https://doi.org/10.1126/science.206.4417.409, 1979. a
Cai, W.-J. and Wang, Y.: The chemistry, fluxes, and sources of carbon dioxide
in the estuarine waters of the Satilla and Altamaha Rivers, Georgia,
Limnol. Oceanogr., 43, 657–668, https://doi.org/10.4319/lo.1998.43.4.0657, 1998. a
Cai, W.-J., Huang, W.-J., Luther, G. W., Pierrot, D., Li, M., Testa, J., Xue,
M., Joesoef, A., Mann, R., Brodeur, J., Xu, Y.-Y., Chen, B., Hussain, N.,
Waldbusser, G. G., Cornwell, J., and Kemp, W. M.: Redox reactions and weak
buffering capacity lead to acidification in the Chesapeake Bay, Nat.
Commun., 8, 369, https://doi.org/10.1038/s41467-017-00417-7, 2017. a
Cantrell, K. J., Serkiz, S. M., and Perdue, E. M.: Evaluation of acid
neutralizing capacity data for solutions containing natural organic acids,
Geochim. Cosmochim. Acta, 54, 1247–1254,
https://doi.org/10.1016/0016-7037(90)90150-J, 1990. a
Clarke, J. S., Achterberg, E. P., Connelly, D. P., Schuster, U., and Mowlem,
M.: Developments in marine pCO2 measurement
technology; towards sustained in situ observations, Trends Anal.
Chem., 88, 53–61, https://doi.org/10.1016/j.trac.2016.12.008, 2017. a
Clegg, S. L. and Whitfield, M.: A chemical model of seawater including
dissolved ammonia and the stoichiometric dissociation constant of ammonia in
estuarine water and seawater from −2 to 40 ∘C, Geochim. Cosmochim. Acta, 59, 2403–2421, https://doi.org/10.1016/0016-7037(95)00135-2, 1995. a
Deffeyes, K. S.: Carbonate Equilibria: A Graphic and Algebraic
Approach, Limnol. Oceanogr., 10, 412–426,
https://doi.org/10.4319/lo.1965.10.3.0412, 1965. a
Dickson, A. and Millero, F.: A comparison of the equilibrium constants for the dissociation of carbonic acid in seawater media, Deep-Sea Res. Pt. A, 34,
1733–1743, https://doi.org/10.1016/0198-0149(87)90021-5, 1987. a, b, c
Dickson, A. G.: Standard potential of the reaction: , and the standard acidity constant of the ion HSO in synthetic sea water from 273.15 to 318.15 K, J. Chem. Thermodyn., 22, 113–127, https://doi.org/10.1016/0021-9614(90)90074-Z,
1990a. a
Dickson, A. G.: Thermodynamics of the dissociation of boric acid in synthetic
seawater from 273.15 to 318.15 K, Deep-Sea Res. Pt. A, 37, 755–766,
https://doi.org/10.1016/0198-0149(90)90004-F, 1990b. a
Dickson, A. G. and Riley, J. P.: The estimation of acid dissociation constants in sea-water media from potentiometric titrations with strong base. II. The dissociation of phosphoric acid, Mar. Chem., 7, 101–109,
https://doi.org/10.1016/0304-4203(79)90002-1, 1979. a
Dickson, A. G., Sabine, C. L., and Christian, J. R. (Eds.): Guide to Best
Practices for Ocean CO2 Measurements, PICES Special
Publication 3, North Pacific Marine Science Organization, Sidney, BC, Canada, 2007. a
Dickson, A. G., Camões, M. F., Spitzer, P., Fisicaro, P., Stoica, D.,
Pawlowicz, R., and Feistel, R.: Metrological challenges for measurements of
key climatological observables. Part 3: seawater pH, Metrologia, 53,
R26–R39, https://doi.org/10.1088/0026-1394/53/1/R26, 2015. a
Doney, S. C., Fabry, V. J., Feely, R. A., and Kleypas, J. A.: Ocean
Acidification: The Other CO2 Problem, Annu. Rev.
Marine Sci., 1, 169–192, https://doi.org/10.1146/annurev.marine.010908.163834, 2009. a
Edmond, J. M. and Gieskes, J. M. T. M.: On the calculation of the degree of
saturation of sea water with respect to calcium carbonate under in situ
conditions, Geochim. Cosmochim. Acta, 34, 1261–1291,
https://doi.org/10.1016/0016-7037(70)90041-4, 1970. a
Frankignoulle, M.: A complete set of buffer factors for acid/base
CO2 system in seawater, J. Mar. Syst., 5, 111–118,
https://doi.org/10.1016/0924-7963(94)90026-4, 1994. a
Frankignoulle, M., Canon, C., and Gattuso, J.-P.: Marine calcification as a
source of carbon dioxide: Positive feedback of increasing atmospheric
CO2, Limnol. Oceanogr., 39, 458–462,
https://doi.org/10.4319/lo.1994.39.2.0458, 1994. a, b, c
Friedlingstein, P., O'Sullivan, M., Jones, M. W., Andrew, R. M., Hauck, J., Olsen, A., Peters, G. P., Peters, W., Pongratz, J., Sitch, S., Le Quéré, C., Canadell, J. G., Ciais, P., Jackson, R. B., Alin, S., Aragão, L. E. O. C., Arneth, A., Arora, V., Bates, N. R., Becker, M., Benoit-Cattin, A., Bittig, H. C., Bopp, L., Bultan, S., Chandra, N., Chevallier, F., Chini, L. P., Evans, W., Florentie, L., Forster, P. M., Gasser, T., Gehlen, M., Gilfillan, D., Gkritzalis, T., Gregor, L., Gruber, N., Harris, I., Hartung, K., Haverd, V., Houghton, R. A., Ilyina, T., Jain, A. K., Joetzjer, E., Kadono, K., Kato, E., Kitidis, V., Korsbakken, J. I., Landschützer, P., Lefèvre, N., Lenton, A., Lienert, S., Liu, Z., Lombardozzi, D., Marland, G., Metzl, N., Munro, D. R., Nabel, J. E. M. S., Nakaoka, S.-I., Niwa, Y., O'Brien, K., Ono, T., Palmer, P. I., Pierrot, D., Poulter, B., Resplandy, L., Robertson, E., Rödenbeck, C., Schwinger, J., Séférian, R., Skjelvan, I., Smith, A. J. P., Sutton, A. J., Tanhua, T., Tans, P. P., Tian, H., Tilbrook, B., van der Werf, G., Vuichard, N., Walker, A. P., Wanninkhof, R., Watson, A. J., Willis, D., Wiltshire, A. J., Yuan, W., Yue, X., and Zaehle, S.: Global Carbon Budget 2020, Earth Syst. Sci. Data, 12, 3269–3340, https://doi.org/10.5194/essd-12-3269-2020, 2020. a
Gattuso, J.-P., Epitalon, J.-M., Lavigne, H., Orr, J., Gentili, B., Hagens, M., Hofmann, A., Mueller, J.-D., Proye, A., Rae, J., and Soetaert, K.: seacarb: Seawater Carbonate Chemistry, available at: https://CRAN.R-project.org/package=seacarb, last access: 23 December 2021. a
Goyet, C. and Poisson, A.: New determination of carbonic acid dissociation
constants in seawater as a function of temperature and salinity, Deep-Sea
Res. Pt. A, 36, 1635–1654, https://doi.org/10.1016/0198-0149(89)90064-2, 1989. a
Hagens, M. and Middelburg, J. J.: Generalised expressions for the response of
pH to changes in ocean chemistry, Geochim. Cosmochim. Acta, 187,
334–349, https://doi.org/10.1016/j.gca.2016.04.012, 2016. a
Hansson, I.: The Determination of Dissociation Constants of Carbonic
Acid in Synthetic Sea Water in the Salinity Range of 20–40 ‰ and Temperature Range of 5–30 ∘C, Acta Chem. Scand., 27, 931–944, https://doi.org/10.3891/acta.chem.scand.27-0931, 1973a. a, b
Hansson, I.: A new set of acidity constants for carbonic acid and boric acid in sea water, Deep-Sea Res., 20, 461–478, https://doi.org/10.1016/0011-7471(73)90100-9, 1973b. a, b
Harris, C. R., Millman, K. J., van der Walt, S. J., Gommers, R., Virtanen, P., Cournapeau, D., Wieser, E., Taylor, J., Berg, S., Smith, N. J., Kern, R.,
Picus, M., Hoyer, S., van Kerkwijk, M. H., Brett, M., Haldane, A., del Río,
J. F., Wiebe, M., Peterson, P., Gérard-Marchant, P., Sheppard, K., Reddy,
T., Weckesser, W., Abbasi, H., Gohlke, C., and Oliphant, T. E.: Array
programming with NumPy, Nature, 585, 357–362,
https://doi.org/10.1038/s41586-020-2649-2, 2020. a
Humphreys, M. P., Gregor, L., Pierrot, D., van Heuven, S. M. A. C., Lewis, E. R., and Wallace, D. W. R.: PyCO2SYS: marine carbonate system calculations in Python (v1.3.0), Zenodo [code], https://doi.org/10.5281/zenodo.3780139, 2020. a
Humphreys, M. P., Schiller, A. J., Sandborn, D., Gregor, L., Pierrot, D., van Heuven, S. M. A. C., Lewis, E. R., and Wallace, D. W. R.: PyCO2SYS: marine carbonate system calculations in Python (v1.8.0), Zenodo [code], https://doi.org/10.5281/zenodo.5602840, 2021. a, b, c, d
Ingle, S. E.: Solubility of calcite in the ocean, Mar. Chem., 3, 301–319,
https://doi.org/10.1016/0304-4203(75)90010-9, 1975. a, b, c
Ingle, S. E., Culberson, C. H., Hawley, J. E., and Pytkowicz, R. M.: The
solubility of calcite in seawater at atmospheric pressure and 35 ‰ salinity, Mar. Chem., 1, 295–307, https://doi.org/10.1016/0304-4203(73)90019-4, 1973. a
IUPAC: Compendium of Chemical Terminology, 2nd edn. (the “Gold Book”), Blackwell Scientific Publications, Oxford, UK,
https://doi.org/10.1351/goldbook, 1997. a
JCGM: JCGM 100:2008 Evaluation of measurement data – Guide to the
expression of uncertainty in measurement, Bureau International des Poids et
Mesures, Sèvres, France, available at: https://www.bipm.org/utils/common/documents/jcgm/JCGM_100_2008_E.pdf (last access: 23 December 2021), 2008. a
Kester, D. R. and Pytkowicz, R. M.: Determination of the Apparent
Dissociation Constants of Phosphoric Acid in Seawater, Limnol.
Oceanogr., 12, 243–252, https://doi.org/10.4319/lo.1967.12.2.0243, 1967. a
Khoo, K. H., Ramette, R. W., Culberson, C. H., and Bates, R. G.: Determination of hydrogen ion concentrations in seawater from 5 to 40C: standard potentials at salinities from 20 to 45 per mille, Anal. Chem., 49, 29–34, https://doi.org/10.1021/ac50009a016, 1977. a
Kuliński, K., Schneider, B., Hammer, K., Machulik, U., and Schulz-Bull, D.:
The influence of dissolved organic matter on the acid–base system of the
Baltic Sea, J. Mar. Syst., 132, 106–115,
https://doi.org/10.1016/j.jmarsys.2014.01.011, 2014. a
Lauvset, S. K., Lange, N., Tanhua, T., Bittig, H. C., Olsen, A., Kozyr, A., Álvarez, M., Becker, S., Brown, P. J., Carter, B. R., Cotrim da Cunha, L., Feely, R. A., van Heuven, S., Hoppema, M., Ishii, M., Jeansson, E., Jutterström, S., Jones, S. D., Karlsen, M. K., Lo Monaco, C., Michaelis, P., Murata, A., Pérez, F. F., Pfeil, B., Schirnick, C., Steinfeldt, R., Suzuki, T., Tilbrook, B., Velo, A., Wanninkhof, R., Woosley, R. J., and Key, R. M.: An updated version of the global interior ocean biogeochemical data product, GLODAPv2.2021, Earth Syst. Sci. Data, 13, 5565–5589, https://doi.org/10.5194/essd-13-5565-2021, 2021. a
Lee, K., Kim, T.-W., Byrne, R. H., Millero, F. J., Feely, R. A., and Liu,
Y.-M.: The universal ratio of boron to chlorinity for the North Pacific
and North Atlantic oceans, Geochim. Cosmochim. Acta, 74, 1801–1811,
https://doi.org/10.1016/j.gca.2009.12.027, 2010. a
Li, Y.-H., Takahashi, T., and Broecker, W. S.: Degree of saturation of
CaCO3 in the oceans, J. Geophys. Res., 74, 5507–5525,
https://doi.org/10.1029/JC074i023p05507, 1969. a
Lueker, T. J., Dickson, A. G., and Keeling, C. D.: Ocean pCO2 calculated from dissolved inorganic carbon, alkalinity, and equations for K1 and K2: validation based on laboratory measurements of CO2 in gas and seawater at equilibrium, Mar. Chem., 70, 105–119,
https://doi.org/10.1016/S0304-4203(00)00022-0, 2000. a
Maclaurin, D.: Autograd: Automatic Differentiation for Python, in:
Modeling, Inference and Optimization with Composable Differentiable
Procedures, PhD thesis, Harvard University, Cambridge, MA, USA, 41–57, available at: https://dougalmaclaurin.com/phd-thesis.pdf (last access: 23 December 2021), 2016. a
Mehrbach, C., Culberson, C. H., Hawley, J. E., and Pytkowicz, R. M.:
Measurement of the Apparent Dissociation Constants of Carbonic Acid
in Seawater at Atmospheric Pressure, Limnol. Oceanogr., 18, 897–907,
https://doi.org/10.4319/lo.1973.18.6.0897, 1973. a, b, c, d
Millero, F. J.: The thermodynamics of the carbonate system in seawater,
Geochim. Cosmochim. Acta, 43, 1651–1661, https://doi.org/10.1016/0016-7037(79)90184-4,
1979. a, b, c, d
Millero, F. J.: The Carbonate System in Marine Environments, in:
Chemical Processes in Marine Environments, edited by: Gianguzza, A.,
Pelizetti, E., and Sammartano, S., Environmental Science,
Springer, Berlin, Heidelberg, 9–41, https://doi.org/10.1007/978-3-662-04207-6_2, 2000. a
Millero, F. J.: Carbonate constants for estuarine waters, Mar. Freshw. Res., 61, 139–142, https://doi.org/10.1071/MF09254, 2010. a
Millero, F. J., Pierrot, D., Lee, K., Wanninkhof, R., Feely, R., Sabine, C. L., Key, R. M., and Takahashi, T.: Dissociation constants for carbonic acid determined from field measurements, Deep-Sea Res. Pt. I, 49, 1705–1723,
https://doi.org/10.1016/S0967-0637(02)00093-6, 2002. a
Millero, F. J., Graham, T. B., Huang, F., Bustos-Serrano, H., and Pierrot, D.: Dissociation constants of carbonic acid in seawater as a function of salinity and temperature, Mar. Chem., 100, 80–94,
https://doi.org/10.1016/j.marchem.2005.12.001, 2006. a
Millero, F. J., Feistel, R., Wright, D. G., and McDougall, T. J.: The
composition of Standard Seawater and the definition of the
Reference-Composition Salinity Scale, Deep-Sea Res. Pt. I, 55, 50–72, https://doi.org/10.1016/j.dsr.2007.10.001, 2008. a
Mojica Prieto, F. J. and Millero, F. J.: The values of pK1 + pK2 for the dissociation of carbonic acid in seawater, Geochim. Cosmochim. Acta, 66, 2529–2540,
https://doi.org/10.1016/S0016-7037(02)00855-4, 2002. a
Morris, A. W. and Riley, J. P.: The bromide/chlorinity and sulphate/chlorinity ratio in sea water, Deep-Sea Res., 13, 699–705,
https://doi.org/10.1016/0011-7471(66)90601-2, 1966. a, b
Muller, F. L. L. and Bleie, B.: Estimating the organic acid contribution to
coastal seawater alkalinity by potentiometric titrations in a closed cell,
Anal. Chim. Acta, 619, 183–191, https://doi.org/10.1016/j.aca.2008.05.018, 2008. a
Munhoven, G.: SolveSAPHE-r2 (v2.0.1): revisiting and extending the Solver Suite for Alkalinity-PH Equations for usage with CO2, HCO or CO input data, Geosci. Model Dev., 14, 4225–4240, https://doi.org/10.5194/gmd-14-4225-2021, 2021. a, b, c
Orr, J. C.: Recent and future changes in ocean carbonate chemistry, in: Ocean
Acidification, edited by: Gattuso, J. P. and Hansson, L., Oxford
University Press, 41–66, https://doi.org/10.1093/oso/9780199591091.003.0008, 2011. a
Orr, J. C., Najjar, R. G., Aumont, O., Bopp, L., Bullister, J. L., Danabasoglu, G., Doney, S. C., Dunne, J. P., Dutay, J.-C., Graven, H., Griffies, S. M., John, J. G., Joos, F., Levin, I., Lindsay, K., Matear, R. J., McKinley, G. A., Mouchet, A., Oschlies, A., Romanou, A., Schlitzer, R., Tagliabue, A., Tanhua, T., and Yool, A.: Biogeochemical protocols and diagnostics for the CMIP6 Ocean Model Intercomparison Project (OMIP), Geosci. Model Dev., 10, 2169–2199, https://doi.org/10.5194/gmd-10-2169-2017, 2017. a
Park, P. K.: Oceanic CO2 system: an evaluation of ten methods
of investigation, Limnol. Oceanogr., 14, 179–186,
https://doi.org/10.4319/lo.1969.14.2.0179, 1969. a
Peng, T.-H., Takahashi, T., Broecker, W. S., and Olafsson, J.: Seasonal
variability of carbon dioxide, nutrients and oxygen in the northern North
Atlantic surface water: observations and a model, Tellus B, 39, 439–458,
https://doi.org/10.3402/tellusb.v39i5.15361, 1987. a, b
Perez, F. F. and Fraga, F.: Association constant of fluoride and hydrogen ions in seawater, Mar. Chem., 21, 161–168, https://doi.org/10.1016/0304-4203(87)90036-3, 1987. a
Pierrot, D., Lewis, E., and Wallace, D. W. R.: MS Excel Program
Developed for CO2 System Calculations, available at: https://cdiac.ess-dive.lbl.gov/ftp/co2sys/CO2SYS_calc_XLS_v2.1/ (last access: 23 December 2021),
2006. a
Raimondi, L., Matthews, J. B. R., Atamanchuk, D., Azetsu-Scott, K., and
Wallace, D. W. R.: The internal consistency of the marine carbon dioxide
system for high latitude shipboard and in situ monitoring, Mar.
Chem., 213, 49–70, https://doi.org/10.1016/j.marchem.2019.03.001, 2019. a
Revelle, R. and Suess, H. E.: Carbon Dioxide Exchange Between
Atmosphere and Ocean and the Question of an Increase of Atmospheric
CO2 during the Past Decades, Tellus, 9, 18–27,
https://doi.org/10.3402/tellusa.v9i1.9075, 1957. a
Richier, S., Achterberg, E. P., Humphreys, M. P., Poulton, A. J., Suggett,
D. J., Tyrrell, T., and Moore, C. M.: Geographical CO2
sensitivity of phytoplankton correlates with ocean buffer capacity, Glob.
Change Biol., 24, 4438–4452, https://doi.org/10.1111/gcb.14324, 2018. a
Riley, J. P.: The occurrence of anomalously high fluoride concentrations in the North Atlantic, Deep-Sea Res., 12, 219–220,
https://doi.org/10.1016/0011-7471(65)90027-6, 1965. a, b
Riley, J. P. and Tongudai, M.: The major cation/chlorinity ratios in sea water, Chem. Geol., 2, 263–269, https://doi.org/10.1016/0009-2541(67)90026-5, 1967. a
Roy, R. N., Roy, L. N., Vogel, K. M., Porter-Moore, C., Pearson, T., Good,
C. E., Millero, F. J., and Campbell, D. M.: The dissociation constants of
carbonic acid in seawater at salinities 5 to 45 and temperatures 0 to
45 ∘C, Mar. Chem., 44, 249–267, https://doi.org/10.1016/0304-4203(93)90207-5, 1993. a
Schockman, K. M. and Byrne, R. H.: Spectrophotometric Determination of the
Bicarbonate Dissociation Constant in Seawater, Geochim. Cosmochim.
Acta, 300, 231–245, https://doi.org/10.1016/j.gca.2021.02.008, 2021. a, b, c
Schoonen, M. A. A. and Barnes, H. L.: An approximation of the second
dissociation constant for H2S, Geochim. Cosmochim. Acta,
52, 649–654, https://doi.org/10.1016/0016-7037(88)90326-2, 1988. a
Sharp, J. D. and Byrne, R. H.: Carbonate ion concentrations in seawater:
Spectrophotometric determination at ambient temperatures and evaluation of
propagated calculation uncertainties, Mar. Chem., 209, 70–80,
https://doi.org/10.1016/j.marchem.2018.12.001, 2019. a
Sharp, J. D. and Byrne, R. H.: Interpreting measurements of total alkalinity in marine and estuarine waters in the presence of proton-binding organic matter, Deep-Sea Res. Pt. I, 165, 103 338, https://doi.org/10.1016/j.dsr.2020.103338, 2020. a, b
Sillén, L. G., Martell, A. E., and Bjerrum, J.: Stability constants of
metal-ion complexes, special publication, 17th edn., Chemical Society, London, UK, 1964. a
Sulpis, O., Lauvset, S. K., and Hagens, M.: Current estimates of K1* and K2* appear inconsistent with measured CO2 system parameters in cold oceanic regions, Ocean Sci., 16, 847–862, https://doi.org/10.5194/os-16-847-2020, 2020. a, b, c
Takahashi, T., Sutherland, S. C., Wanninkhof, R., Sweeney, C., Feely, R. A.,
Chipman, D. W., Hales, B., Friederich, G., Chavez, F., Sabine, C., Watson,
A., Bakker, D. C., Schuster, U., Metzl, N., Yoshikawa-Inoue, H., Ishii, M.,
Midorikawa, T., Nojiri, Y., Körtzinger, A., Steinhoff, T., Hoppema, M.,
Olafsson, J., Arnarson, T. S., Tilbrook, B., Johannessen, T., Olsen, A.,
Bellerby, R., Wong, C., Delille, B., Bates, N., and de Baar, H. J.:
Climatological mean and decadal change in surface ocean
pCO2, and net sea–air CO2 flux
over the global oceans, Deep-Sea Res. Pt. II, 56, 554–577,
https://doi.org/10.1016/j.dsr2.2008.12.009, 2009.
a
Turner, D. R., Achterberg, E. P., Chen, C.-T. A., Clegg, S. L., Hatje, V.,
Maldonado, M. T., Sander, S. G., Berg, V. D., G, C. M., and Wells, M.: Toward
a Quality-Controlled and Accessible Pitzer Model for Seawater and
Related Systems, Front. Mar. Sci., 3, 139, https://doi.org/10.3389/fmars.2016.00139, 2016. a
Ulfsbo, A., Kuliński, K., Anderson, L. G., and Turner, D. R.: Modelling
organic alkalinity in the Baltic Sea using a Humic-Pitzer approach,
Mar. Chem., 168, 18–26, https://doi.org/10.1016/j.marchem.2014.10.013, 2015. a
Uppström, L. R.: The boron/chlorinity ratio of deep-sea water from the
Pacific Ocean, Deep-Sea Res., 21, 161–162,
https://doi.org/10.1016/0011-7471(74)90074-6, 1974. a
van Heuven, S., Pierrot, D., Rae, J. W. B., Lewis, E., and Wallace, D. W. R.:
CO2SYS v 1.1, MATLAB program developed for CO2 system calculations, ORNL/CDIAC-105b, Carbon Dioxide Information Analysis Center, Oak Ridge National Laboratory, U.S. Department of Energy, Oak Ridge, TN, USA,
available at: https://cdiac.ess-dive.lbl.gov/ftp/co2sys/CO2SYS_calc_MATLAB_v1.1/ (last access: 23 December 2021), 2011. a, b, c
Velo, A., Pérez, F. F., Lin, X., Key, R. M., Tanhua, T., de la Paz, M., Olsen, A., van Heuven, S., Jutterström, S., and Ríos, A. F.: CARINA data synthesis project: pH data scale unification and cruise adjustments, Earth Syst. Sci. Data, 2, 133–155, https://doi.org/10.5194/essd-2-133-2010, 2010. a, b
Waters, J., Millero, F. J., and Woosley, R. J.: Corrigendum to “The free
proton concentration scale for seawater pH”, [MARCHE: 149 (2013)
8–22], Mar. Chem., 165, 66–67, https://doi.org/10.1016/j.marchem.2014.07.004, 2014. a, b
Waters, J. F. and Millero, F. J.: The free proton concentration scale for
seawater pH, Mar. Chem., 149, 8–22, https://doi.org/10.1016/j.marchem.2012.11.003,
2013. a, b, c
Weiss, R. F. and Price, B. A.: Nitrous oxide solubility in water and seawater, Mar. Chem., 8, 347–359, https://doi.org/10.1016/0304-4203(80)90024-9, 1980. a, b
Wolf-Gladrow, D. A., Zeebe, R. E., Klaas, C., Körtzinger, A., and Dickson,
A. G.: Total alkalinity: The explicit conservative expression and its
application to biogeochemical processes, Mar. Chem., 106, 287–300,
https://doi.org/10.1016/j.marchem.2007.01.006, 2007. a, b
Xu, Y.-Y., Pierrot, D., and Cai, W.-J.: Ocean carbonate system computation for anoxic waters using an updated CO2SYS program, Mar. Chem., 195, 90–93,
https://doi.org/10.1016/j.marchem.2017.07.002, 2017. a, b
Yao, W. and Millero, F. J.: The chemistry of the anoxic waters in the
Framvaren Fjord, Norway, Aquat. Geochem., 1, 53–88,
https://doi.org/10.1007/BF01025231, 1995. a, b, c
Short summary
The ocean helps to mitigate our impact on Earth's climate by absorbing about a quarter of the carbon dioxide (CO2) released by human activities each year. However, once absorbed, chemical reactions between CO2 and water reduce seawater pH (
ocean acidification), which may have adverse effects on marine ecosystems. Our Python package, PyCO2SYS, models the chemical reactions of CO2 in seawater, allowing us to quantify the corresponding changes in pH and related chemical properties.
The ocean helps to mitigate our impact on Earth's climate by absorbing about a quarter of the...