Articles | Volume 16, issue 10
https://doi.org/10.5194/gmd-16-2873-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/gmd-16-2873-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Development and technical paper
| 
26 May 2023
Development and technical paper |
| 26 May 2023
| 26 May 2023
Halogen chemistry in volcanic plumes: a 1D framework based on MOCAGE 1D (version R1.18.1) preparing 3D global chemistry modelling
Virginie Marécal
CORRESPONDING AUTHOR
Centre National de Recherches Météorologiques, Université de Toulouse, Météo-France, CNRS, Toulouse, 31000, France
Ronan Voisin-Plessis
Centre National de Recherches Météorologiques, Université de Toulouse, Météo-France, CNRS, Toulouse, 31000, France
Tjarda Jane Roberts
Laboratoire de Physique et Chimie de l'Environnement et de l'Espace, UMR7328, CNRS-Université d'Orléans,Orléans, 45000, France
LMD/IPSL, ENS, Université PSL, École Polytechnique, Institut Polytechnique de Paris, Sorbonne Université, CNRS, Paris, France
Alessandro Aiuppa
Dipartimento di Scienze della Terra e del Mare (DiSTeM), Università di Palermo, Palermo, 90123, Italy
Herizo Narivelo
Centre National de Recherches Météorologiques, Université de Toulouse, Météo-France, CNRS, Toulouse, 31000, France
Paul David Hamer
INBY, NILU – Norwegian Institute for Air Research, P.O. Box 100, Kjeller, 2027, Norway
Béatrice Josse
Centre National de Recherches Météorologiques, Université de Toulouse, Météo-France, CNRS, Toulouse, 31000, France
Jonathan Guth
Centre National de Recherches Météorologiques, Université de Toulouse, Météo-France, CNRS, Toulouse, 31000, France
Luke Surl
Laboratoire de Physique et Chimie de l'Environnement et de l'Espace, UMR7328, CNRS-Université d'Orléans,Orléans, 45000, France
LATMOS/IPSL, Sorbonne Université, UVSQ, CNRS, Paris, France
Department of Biosciences, University of Exeter, Exeter, UK
Lisa Grellier
Centre National de Recherches Météorologiques, Université de Toulouse, Météo-France, CNRS, Toulouse, 31000, France
now at: Communication, Informatique et Développement Durable, Citepa, Paris, France
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Andrea Bevilacqua, Alvaro Aravena, Augusto Neri, Eduardo Gutiérrez, Demetrio Escobar, Melida Schliz, Alessandro Aiuppa, and Raffaello Cioni
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Paul D. Hamer, Sam-Erik Walker, Gabriela Sousa-Santos, Matthias Vogt, Dam Vo-Thanh, Susana Lopez-Aparicio, Philipp Schneider, Martin O. P. Ramacher, and Matthias Karl
Geosci. Model Dev., 13, 4323–4353, https://doi.org/10.5194/gmd-13-4323-2020, https://doi.org/10.5194/gmd-13-4323-2020, 2020
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Laaziz El Amraoui, Bojan Sič, Andrea Piacentini, Virginie Marécal, Nicolas Frebourg, and Jean-Luc Attié
Atmos. Meas. Tech., 13, 4645–4667, https://doi.org/10.5194/amt-13-4645-2020, https://doi.org/10.5194/amt-13-4645-2020, 2020
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Cited articles
Aiuppa, A., Federico, C., Franco, A., Giudice, G., Gurrieri, S., Inguaggiato, S., Liuzzo, M., McGonigle, A. J. S., and Valenza, M.:
Emission of bromine and iodine from Mount Etna volcano, Geochem. Geophy. Geosy., 6, Q08008, https://doi.org/10.1029/2005GC000965, 2005.
Aiuppa, A., Franco, A., von Glasow, R., Allen, A. G., D'Alessandro, W., Mather, T. A., Pyle, D. M., and Valenza, M.:
The tropospheric processing of acidic gases and hydrogen sulphide in volcanic gas plumes as inferred from field and model investigations, Atmos. Chem. Phys., 7, 1441–1450, https://doi.org/10.5194/acp-7-1441-2007, 2007a.
Aiuppa, A., Moretti, R., Federico, C., Giudice, G., Gurrieri, S., Liuzzo, M., Papale, P., Shinohara, H., and Valenza, M.:
Forecasting Etna eruptions by real-time observation of volcanic gas composition, Geology, 35, 1115–1118, https://doi.org/10.1130/G24149A.1, 2007b.
Aiuppa, A., Giudice, G., Gurrieri, S., Liuzzo, M., Burton, M., Caltabiano, T., McGonigle, A. J. S., Salerno, G., Shinohara, H., and Valenza, M.:
Total volatile flux from Mount Etna, Geophys. Res. Lett., 35, L24302, https://doi.org/10.1029/2008GL035871, 2008.
Aiuppa, A., Cannata, A., Cannavò, F., Di Grazia, G., Ferrari, F., Giudice, G., Gurrieri, S., Liuzzo, M., Mattia, M., Montalto, P., Patanè, D., and Puglisi, G.:
Patterns in the recent 2007–2008 activity of Mount Etna volcano investigated by integrated geophysical and geochemical observations, Geochem. Geophy. Geosy., 11, Q09008, https://doi.org/10.1029/2010GC003168, 2010.
Allard, P., B. M. and Murè, F.:
Spectroscopic evidence for a lava fountain driven by previously accumulated magmatic gas, Nature, 433, 407–410, https://doi.org/10.1038/nature03246, 2005.
Bobrowski, N. and Giuffrida, G.:
Bromine monoxide / sulphur dioxide ratios in relation to volcanological observations at Mt. Etna 2006–2009, Solid Earth, 3, 433–445, https://doi.org/10.5194/se-3-433-2012, 2012.
Bobrowski, N., Hönninger, G., Galle, B., and Platt, U.:
Detection of bromine monoxide in a volcanic plume, Nature, 423, 273–276, https://doi.org/10.1038/nature01625, 2003.
Bobrowski, N., von Glasow, R., Aiuppa, A., Inguaggiato, S., Louban, I., Ibrahim, O. W., and Platt, U.:
Reactive halogen chemistry in volcanic plumes, J. Geophys. Res, 112, D06311, https://doi.org/10.1029/2006JD007206, 2007.
Boichu, M., Oppenheimer, C., Roberts, T. J., Tsanev, V., and Kyle, P. R.:
On bromine, nitrogen oxides and ozone depletion in the tropospheric plume of Erebus volcano (Antarctica), Atmos. Environ., 45, 3856–3866, https://doi.org/10.1016/j.atmosenv.2011.03.027, 2011.
Bonaccorso, A., Bonforte, A., Calvari, S., Del Negro, C., Di Grazia, G., Ganci, G., Neri, M., Vicari, A., and Boschi, E.:
The initial phases of the 2008–2009 Mount Etna eruption: A multidisciplinary approach for hazard assessment, J. Geophys. Res.-Sol. Ea., 116, https://doi.org/10.1029/2010JB007906, 2011.
Cariolle, D., Caro, D., Paoli, R., Hauglustaine, D. A., Cuénot, B., Cozic, A., and Paugam, R.:
Parameterization of plume chemistry into large-scale atmospheric models: application to aircraft NOx emissions, J. Geophys. Res., 114, D19302, https://doi.org/10.1029/2009JD011873, 2009.
Corradini, S., Guerrieri, L., Stelitano, D., Salerno, G., Scollo, S., Merucci, L., Prestifilippo, M., Musacchio, M., Silvestri, M., Lombardo, V., and Caltabiano, T.: Near Real-Time Monitoring of the Christmas 2018 Etna Eruption Using SEVIRI and Products Validation, Remote Sensing, 12, 1336, https://doi.org/10.3390/rs12081336, 2020.
Cussac, M., Marécal, V., Thouret, V., Josse, B., and Sauvage, B.:
The impact of biomass burning on upper tropospheric carbon monoxide: a study using MOCAGE global model and IAGOS airborne data, Atmos. Chem. Phys., 20, 9393–9417, https://doi.org/10.5194/acp-20-9393-2020, 2020.
Fickert, S., Adams, J. W., and Crowley, J. N.:
Activation of Br2 and BrCl via uptake of HOBr onto aqueous salt solutions, J. Geophys. Res.-Atmos.,104, 23 719–23 727, https://doi.org/10.1029/1999JD900359, 1999.
Grellier, L., Marécal, V., Josse, B., Hamer, P. D., Roberts, T. J., Aiuppa, A., and Pirre, M.:
Towards a representation of halogen chemistry within volcanic plumes in a chemistry transport model, Geosci. Model Dev. Discuss., 7, 2581–2650, https://doi.org/10.5194/gmdd-7-2581-2014, 2014.
Gerlach, T. M.:
Volcanic sources of tropospheric ozone-depleting trace gases, Geochem. Geophy. Geosy., 5, Q09007, https://doi.org/10.1029/2004GC000747, 2004.
Guth, J., Josse, B., Marécal, V., Joly, M., and Hamer, P.:
First implementation of secondary inorganic aerosols in the MOCAGE version R2.15.0 chemistry transport model, Geosci. Model Dev., 9, 137–160, https://doi.org/10.5194/gmd-9-137-2016, 2016.
Gutmann, A., Bobrowski, N., Roberts, T. J., Rüdiger, J., and Hoffmann, T.:
Advances in bromine speciation in volcanic plumes, Front. Earth Sci., 6, 213, https://doi.org/10.3389/feart.2018.00213, 2018.
Hörmann, C., Sihler, H., Bobrowski, N., Beirle, S., Penning de Vries, M., Platt, U., and Wagner, T.:
Systematic investigation of bromine monoxide in volcanic plumes from space by using the GOME-2 instrument, Atmos. Chem. Phys., 13, 4749–4781, https://doi.org/10.5194/acp-13-4749-2013, 2013.
Josse, B., Simon, P., and Peuch, V.:
Radon global simulations with the multiscale chemistry and transport model MOCAGE, Tellus B, 56, 339–356, https://doi.org/10.1111/j.1600-0889.2004.00112.x, 2004.
Jourdain, L., Roberts, T. J., Pirre, M., and Josse, B.:
Modeling the reactive halogen plume from Ambrym and its impact on the troposphere with the CCATT-BRAMS mesoscale model, Atmos. Chem. Phys., 16, 12099–12125, https://doi.org/10.5194/acp-16-12099-2016, 2016.
Karamchandani, P., Seigneur, C., Vijayaraghavan, K., and Wu, S.-Y.:
Development and application of a state-of-the-science plume-in-grid model, J. Geophys. Res., 107, 4403, https://doi.org/10.1029/2002JD002123, 2002.
Karamchandani, P., Vijayaraghavan, K., and Yarwood, G.:
Sub-Grid Scale Plume Modeling, Atmosphere, 2, 389-406, https://doi.org/10.3390/atmos2030389, 2011.
Kelly, P. J., Kern, C., Roberts, T. J., Lopez, T., Werner, C., and Aluppe, A.:
Rapid chemical evolution of tropospheric volcanic emissions from Redoubt Volcano, Alaska, based on observations of ozone and halogen-containing gases, J. Volcanol. Geoth. Res., 259, 317–333, https://doi.org/10.1016/j.jvolgeores.2012.04.023, 2013.
Kern, C. and Lyons, J. J.:
Spatial distribution of halogen oxides in the plume of Mount Pagan Volcano, Mariana Islands, Geophys. Res. Lett., 45, 9588–9596, https://doi.org/10.1029/2018GL079245, 2018.
Lacressonnière, G., Peuch, V.-H., Vautard, R., Arteta, J., Déqué, M., Joly, M., Josse, B., Marécal, V,., and Saint-Martin, D.:
European air quality in the 2030s and 2050s: impacts of global and regional emission trends and of climate change, Atmos. Environ, 92, 348–358, https://doi.org/10.1016/j.atmosenv.2014.04.033, 2014.
Lamotte, C., Guth, J., Marécal, V., Cussac, M., Hamer, P. D., Theys, N., and Schneider, P.:
Modeling study of the impact of SO2 volcanic passive emissions on the tropospheric sulfur budget, Atmos. Chem. Phys., 21, 11379–11404, https://doi.org/10.5194/acp-21-11379-2021, 2021.
Lefèvre, F., Brasseur, G. P., Folkins, I., Smith, A. K., and Simon, P.:
Chemistry of the 1991–1992 stratospheric winter: three-dimensional model simulations, J. Geophys. Res., 99, 8183–8195, https://doi.org/10.1029/93JD03476, 1994.
Longo, K. M., Freitas, S. R., Pirre, M., Marécal, V., Rodrigues, L. F., Panetta, J., Alonso, M. F., Rosário, N. E., Moreira, D. S., Gácita, M. S., Arteta, J., Fonseca, R., Stockler, R., Katsurayama, D. M., Fazenda, A., and Bela, M.:
The Chemistry CATT-BRAMS model (CCATT-BRAMS 4.5): a regional atmospheric model system for integrated air quality and weather forecasting and research, Geosci. Model Dev., 6, 1389–1405, https://doi.org/10.5194/gmd-6-1389-2013, 2013.
Marchetti, E., Ripepe, M., Ulivieri, G., Caffo, S., and Privitera, E.:
Infrasonic evidences for branched conduit dynamics at Mt. Etna volcano, Italy, Geophys. Res. Lett., 36, L19308, https://doi.org/10.1029/2009GL040070, 2009.
Marécal, V., Peuch, V.-H., Andersson, C., Andersson, S., Arteta, J., Beekmann, M., Benedictow, A., Bergström, R., Bessagnet, B., Cansado, A., Chéroux, F., Colette, A., Coman, A., Curier, R. L., Denier van der Gon, H. A. C., Drouin, A., Elbern, H., Emili, E., Engelen, R. J., Eskes, H. J., Foret, G., Friese, E., Gauss, M., Giannaros, C., Guth, J., Joly, M., Jaumouillé, E., Josse, B., Kadygrov, N., Kaiser, J. W., Krajsek, K., Kuenen, J., Kumar, U., Liora, N., Lopez, E., Malherbe, L., Martinez, I., Melas, D., Meleux, F., Menut, L., Moinat, P., Morales, T., Parmentier, J., Piacentini, A., Plu, M., Poupkou, A., Queguiner, S., Robertson, L., Rouïl, L., Schaap, M., Segers, A., Sofiev, M., Tarasson, L., Thomas, M., Timmermans, R., Valdebenito, Á., van Velthoven, P., van Versendaal, R., Vira, J., and Ung, A.:
A regional air quality forecasting system over Europe: the MACC-II daily ensemble production, Geosci. Model Dev., 8, 2777–2813, https://doi.org/10.5194/gmd-8-2777-2015, 2015.
Marécal, V., Voisin-Plessis, R., Roberts, T. J., Narivelo, H., Hamer, P. David, J., Béatrice, G., Jonathan, S., Luke, and Grellier, L.: Code of MOCAGE-1D model version R1.18.1 (R1.18.1), Zenodo [code], https://doi.org/10.5281/zenodo.7298580, 2022a.
Marécal, V., Voisin-Plessis, R., Roberts, T. J., Narivelo, H., Hamer, P. D., Josse, B., Guth, J., Surl, L., and Grellier, L.: Dataset produced by MOCAGE-1D model version R1.18.1 for volcanic halogen chemistry study, Zenodo [data set], https://doi.org/10.5281/zenodo.7299080, 2022b.
Martin, R., Roberts, T., Mather, T., and Pyle, D.:
The implications of H2S and H2 kinetic stability in high-T mixtures of magmatic and atmospheric gases for the production of oxidized trace species (e.g., BrO and NOx), Chem. Geol., 263, 143–150, https://doi.org/10.1016/j.chemgeo.2008.12.028, 2009.
Martin, R. S., Mather, T. A., and Pyle, D. M.:
High-temperature mixtures of magmatic and atmospheric gases, Geochem. Geophy. Geosy., 7, Q04006, https://doi.org/10.1029/2009GL040070, 2006.
Martin, R. S., Ilyinskaya, E., and Oppenheimer, C.:
The enigma of reactive nitrogen in volcanic emissions, Geochim. Cosmochim. Ac., 95, 93–105, https://doi.org/10.1016/j.gca.2012.07.027, 2012.
Ménégoz, M., Salas y Melia, D., Legrand, M., Teyssèdre, H., Michou, M., Peuch, V.-H., Martet, M., Josse, B., and Dombrowski-Etchevers, I.:
Equilibrium of sinks and sources of sulphate over Europe: comparison between a six-year simulation and EMEP observations, Atmos. Chem. Phys., 9, 4505–4519, https://doi.org/10.5194/acp-9-4505-2009, 2009.
Narivelo, H., Hamer, P. D., Marécal, V., Surl, L., Roberts, T., Pelletier, S., Josse, B., Guth, J., Bacles, M., Warnach, S., Wagner, T., Corradini, S., Salerno, G., and Guerrieri, L.:
A regional modelling study of halogen chemistry within a volcanic plume of Mt Etna's Christmas 2018 eruption,
EGUsphere [preprint], https://doi.org/10.5194/egusphere-2023-184, 2023.
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3.04 – Volcanic Degassing, in: Treatise on Geochemistry, edited by Holland, H. D. and Turekian, K. K., Pergamon, Oxford, 123–166, ISBN 9780080548074, 2003.
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BrO formation in volcanic plumes, Geochim. Cosmochim. Ac., 70, 2935–2941, https://doi.org/10.1016/j.gca.2006.04.001, 2006.
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Seismological constraints for the dyke emplacement of the July-August 2001 lateral eruption at Mt. Etna volcano, Italy, Ann. Geophys., 46, 599–608, https://doi.org/10.4401/ag-6302, 2003.
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The role of halogen species in the troposphere, Chemosphere, 52, 325–338, https://doi.org/10.1016/S0045-6535(03)00216-9 , 2003.
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Reaction rates control high-temperature chemistry of volcanic gases in air, Front. Earth Sci., 7, 154, https://doi.org/10.3389/feart.2019.00154, 2019.
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Ozone depletion in tropospheric volcanic plumes: from halogen-poor to halogen-rich emissions, Geosciences, 8, 68, https://doi.org/10.3390/geosciences8020068, 2018.
Roberts, T. J., Braban, C., Martin, R., Oppenheimer, C., Adams, J., Cox, R., Jones, R., and Griffiths, P.:
Modelling reactive halogen formation and ozone depletion in volcanic plumes, Chem. Geol., 263, 151–163, https://doi.org/10.1016/j.chemgeo.2008.11.012, 2009.
Roberts, T. J., Martin, R. S., and Jourdain, L.:
Reactive bromine chemistry in Mount Etna's volcanic plume: the influence of total Br, high-temperature processing, aerosol loading and plume–air mixing, Atmos. Chem. Phys., 14, 11201–11219, https://doi.org/10.5194/acp-14-11201-2014, 2014.
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First high-resolution BrO column retrievals from TROPOMI, Atmos. Meas. Tech., 12, 2913-2932, https://doi.org/10.5194/amt-12-2913-2019, 2019.
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Short summary
We implemented a halogen volcanic chemistry scheme in a one-dimensional modelling framework preparing for further use in a three-dimensional global chemistry-transport model. The results of the simulations for an eruption of Mt Etna in 2008, including various sensitivity tests, show a good consistency with previous modelling studies.
We implemented a halogen volcanic chemistry scheme in a one-dimensional modelling framework...
