Articles | Volume 9, issue 2
https://doi.org/10.5194/gmd-9-799-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/gmd-9-799-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
The description and validation of the computationally Efficient CH4–CO–OH (ECCOHv1.01) chemistry module for 3-D model applications
Yasin F. Elshorbany
CORRESPONDING AUTHOR
NASA Goddard Space Flight Center, Greenbelt, Maryland, USA
Earth System Science Interdisciplinary Center, University of Maryland,
College Park, Maryland, USA
Bryan N. Duncan
NASA Goddard Space Flight Center, Greenbelt, Maryland, USA
Sarah A. Strode
NASA Goddard Space Flight Center, Greenbelt, Maryland, USA
Universities Space Research Association, Columbia, Maryland, USA
James S. Wang
NASA Goddard Space Flight Center, Greenbelt, Maryland, USA
Universities Space Research Association, Columbia, Maryland, USA
Jules Kouatchou
NASA Goddard Space Flight Center, Greenbelt, Maryland, USA
Science Systems and Applications Inc., Lanham, Maryland, USA
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We describe a methodology that combines machine learning, satellite observations, and 3D chemical model output to infer the abundance of the hydroxyl radical (OH), a chemical that removes many trace gases from the atmosphere. The methodology successfully captures the variability of observed OH, although further observations are needed to evaluate absolute accuracy. Current satellite observations are of sufficient quality to infer OH, but retrieval validation in the remote tropics is needed.
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The hydroxyl radical (OH) is the most important chemical in the atmosphere for removing certain pollutants, including methane, the second-most-important greenhouse gas. We present a methodology to create an easily modifiable parameterization that can calculate OH concentrations in a computationally efficient way. The parameterization, which predicts OH within 5 %, can be integrated into larger climate models to allow for calculation of the interactions between OH, methane, and other chemicals.
Cited articles
Amnuaylojaroen, T., Barth, M. C., Emmons, L. K., Carmichael, G. R., Kreasuwun, J., Prasitwattanaseree, S., and Chantara, S.: Effect of different emission inventories on modeled
ozone and carbon monoxide in Southeast Asia, Atmos. Chem. Phys., 14, 12983–13012, https://doi.org/10.5194/acp-14-12983-2014, 2014.
Bousquet, P., Ciais, P., Miller, J. B., Dlugokencky, E. J., Hauglustaine,
D. A., Prigent, C., Van der Werf, G. R., Peylin, P., Brunke, E. G., Carouge,
C., Langenfelds, R. L., Lathiere, J., Papa, F., Ramonet, M., Schmidt, M.,
Steele, L. P., Tyler, S. C., and White, J.: Contribution of anthropogenic and
natural sources to atmospheric methane variability, Nature, 443, 439–443,
2006.
Bovensmann, H., Burrows, J. P., Buchwitz, M., Frerick, J., Noël, S., Rozanov, V. V., Chance, K. V., and Goede, A.: SCIAMACHY – Mission Objectives and measurement Modes, J. Atmos. Sci., 56,
127–150, 1999.
Chameides, W., Liu, S. C., and Cicerone, R. J.: Possible variations in
atmospheric methane, J. Geophys. Res., 81, 4997–5001, 1976.
Chen, Y.-H. and Prinn, R. G.: Estimation of atmospheric methane emissions between 1996 and 2001 using a three-dimensional global chemical transport model, J. Geophys. Res., 111, D10307, https://doi.org/10.1029/2005JD006058, 2006.
Deeter, M. N.: MOPITT (Measurement of Pollution in the Troposphere) Version6
Product User's Guide, available at:
http://www2.acd.ucar.edu/sites/default/files/mopitt/v6_users_guide_201309.pdf
(last access: 28 May 2015), 2013.
Deeter, M. N., Worden, H. M., Edwards, D. P., Gille, J. C., and Andrews, A.
E.: Evaluation of MOPITT retrievals of lower tropospheric carbon monoxide
over the United States, J. Geophys. Res., 117, D13306,
https://doi.org/10.1029/2012JD017553, 2012.
Dlugokencky, E. J., Lang, P. M., and Masarie, K. A.: Atmospheric Methane Dry
Air Mole Fractions from the NOAA ESRL Carbon Cycle Cooperative Global Air
Sampling Network, 1983–2014, Version: 2015-08-03, available at: ftp://aftp.cmdl.noaa.gov/data/trace_gases/ch4/flask/surface, last access: 22 February 2016.
Dlugokencky, E. J., Lang, P. M., Crotwell, A. M., Masarie, K. A., and Crotwell,
M. J.: Atmospheric Methane Dry Air Mole Fractions from the NOAA ESRL Carbon
Cycle, Cooperative Global Air Sampling Network, 1983–2013, Version:
2014-06-24, 2014.
Duncan, B. N. and Logan, J. A.: Model analysis of the factors regulating the
trends and variability of carbon monoxide between 1988 and 1997, Atmos. Chem.
Phys., 8, 7389–7403, https://doi.org/10.5194/acp-8-7389-2008, 2008.
Duncan, B. N., Portman, D., Bey, I., and Spivakovsky, C. M.:
Parameterization of OH for efficient computation in chemical tracer models,
J. Geophys. Res., 105, 12259–12262, 2000.
Duncan, B. N., Martin, R. V., Staudt, A. C., Yevich, R. M., and Logan, J.
A.: Interannual and Seasonal Variability of Biomass Burning Emissions
Constrained by Satellite Observations, J. Geophys. Res., 108, 4040,
https://doi.org/10.1029/2002JD002378, 2003a.
Duncan, B. N., Bey, I., Chin, M., Mickley, L. J., Fairlie, T. D., Martin, R. V., and
Matsueda, H.: Indonesian Wildfires of 1997: Impact on Tropospheric Chemistry,
J. Geophys. Res., 108, 4458, https://doi.org/10.1029/2002JD003195, 2003b.
Duncan, B. N., Logan, J. A., Bey, I., Megretskaia, I. A., Yantosca, R. M.,
Novelli, P. C., Jones, N. B., and Rinsland, C. P.: Global budget of CO,
1988–1997: Source estimates and validation with a global model, J. Geophys.
Res., 112, D22301, https://doi.org/10.1029/2007JD008459, 2007a.
Duncan, B. N., Strahan, S. E., Yoshida, Y., Steenrod, S. D., and Livesey, N.:
Model study of the cross-tropopause transport of biomass burning pollution,
Atmos. Chem. Phys., 7, 3713–3736, https://doi.org/10.5194/acp-7-3713-2007, 2007b.
Elshorbany, Y. F., Barnes, I., Becker, K. H., Kleffmann, J., and Wiesen, P.:
Sources and Cycling of Tropospheric Hydroxyl Radicals – An Overview, Z.
Phys. Chem., 224, 967–987, https://doi.org/10.1524/zpch.2010.6136, 2010.
Elshorbany, Y. F., Kleffmann, J., Hofzumahaus, A., Kurtenbach, R., Wiesen,
P., Dorn,H.-P., Schlosser, E., Brauers, T., Fuchs, H., Rohrer, F., Wahner,
A., Kanaya, Y., Yoshino, A., Nishida, S., Kajii, Y., Martinez, M., Rudolf,
M., Harder, H., Lelieveld, J., Elste, T., Plass-Dülmer, C., Stange, G.,
and Berresheim, H.: HOx Budgets during HOxComp: a Case Study of HOx
Chemistry under NOx limited Conditions, J. Geoophys. Res., 117, D03307,
https://doi.org/10.1029/2011JD017008, 2012a.
Elshorbany, Y. F., Steil, B., Brühl, C., and Lelieveld, J.: Impact of HONO
on global atmospheric chemistry calculated with an empirical parameterization
in the EMAC model, Atmos. Chem. Phys., 12, 9977–10000,
https://doi.org/10.5194/acp-12-9977-2012, 2012b.
Elshorbany, Y. F., Crutzen, P. J., Steil, B., Pozzer, A., Tost, H., and
Lelieveld, J.: Global and regional impacts of HONO on the chemical
composition of clouds and aerosols, Atmos. Chem. Phys., 14, 1167–1184,
https://doi.org/10.5194/acp-14-1167-2014, 2014.
Fiore, A. M., Jacob, D. J., Field, B. D., Streets, D. G., Fernandes, S. D.,
and Jang, C.: Linking air pollution and climate change: The case for
controlling methane, Geophys. Res. Lett., 29, 1919, https://doi.org/10.1029/2002GL015601,
2002.
Fiore, A. M., Horowitz, L. W., Dlugokencky, E. J., and West, J. J.: Impact of
meteorology and emissions on methane trends, 1990–2004, Geophys. Res. Lett.,
33, L12809, https://doi.org/10.1029/2006GL026199, 2006.
Fiore, A. M., Dentener, F. J., Wild, O., Cuvelier, C., Schultz, M. G., Hess,
P., Textor, C., Schulz, M., Doherty, R. M., Horowitz, L. W., MacKenzie, I.
A., Sanderson, M. G., Shindell, D. T., Stevenson, D. S., Szopa, S., Van
Dingenen, R., Zeng, G., Atherton, C., Bergmann, D., Bey, I., Carmichael, G.,
Collins, W. J., Duncan, B. N., Faluvegi, G., Folberth, G., Gauss, M., Gong,
S., Hauglustaine, D., Holloway, T., Isaksen, I. S. A., Jacob, D. J., Jonson,
J. E., Kaminski, J. W., Keating, T. J., Lupu, A., Marmer, E., Montanaro, V.,
Park, R. J., Pitari, G., Pringle, K. J., Pyle, J. A., Schroeder, S., Vivanco,
M. G., Wind, P., Wojcik, G., Wu, S., and Zuber, A.: Multimodel estimates of
intercontinental source-receptor relationships for ozone pollution, J.
Geophys. Res., 114, D04301, https://doi.org/10.1029/2008JD010816, 2009.
Frankenberg, C., Aben, I., Bergamaschi, P., Dlugokencky, E. J., van Hees,
R., Houweling, S., van der Meer, P., Snel, R., and Tol, P.: Global
column-averaged methane mixing ratios from 2003 to 2009 as derived from
SCIAMACHY: Trends and variability, J. of Geophys. Res., 116, D04302,
https://doi.org/10.1029/2010JD014849, 2011.
Fuchs, H., Hofzumahaus, A., Rohrer, F., Bohn, B., Brauers, T., Dorn, H.-P.,
Hasseler, R., Holland, F., Kaminski, M., Li, X., Lu, K., Nehr, S.,
Tillmann, R., Wegener, R., and Wahner, A.: Experimental evidence for
efficient hydroxyl radical regeneration in isoprene oxidation, Nat. Geosci.
6, 1023–1026, https://doi.org/10.1038/ngeo1964, 2013.
Fujino, J., Nair, R., Kainuma, M., Masui, T., and Matsuoka, Y.: Multigas mitigation
analysis on stabilization scenarios using aim global model, Energy J.,
Special issue, 3, 343–354, 2006.
Giglio, L., Randerson, J. T., van der Werf, G. R., Kasibhatla, P. S.,
Collatz, G. J., Morton, D. C., and DeFries, R. S.: Assessing variability and
long-term trends in burned area by merging multiple satellite fire products,
Biogeosciences, 7, 1171–1186, https://doi.org/10.5194/bg-7-1171-2010, 2010.
Gloudemans, A. M. S., Schrijver, H., Hasekamp, O. P., and Aben, I.: Error
analysis for CO and CH4 total column retrievals from SCIAMACHY
2.3 µm spectra, Atmos. Chem. Phys., 8, 3999–4017,
https://doi.org/10.5194/acp-8-3999-2008, 2008.
Hijioka, Y., Matsuoka, Y., Nishimoto, H., Masui, T., and Kainuma, M.: Global GHG emission
scenarios under GHG concentration stabilization targets, J. Glob. Environ.
Eng., 13, 97–108, 2008.
Ho, S.-P., Edwards, D. P., Gille, J. C., Luo, M., Osterman, G. B., Kulawik,
S. S., and Worden, H.: A global comparison of carbon monoxide profiles and
column amounts from Tropospheric Emission Spectrometer (TES) and Measurements
of Pollution in the Troposphere (MOPITT), J. Geophys. Res., 114, D21307,
https://doi.org/10.1029/2009JD012242, 2009.
Holmes, C. D., Prather, M. J., Søvde, O. A., and Myhre, G.: Future methane,
hydroxyl, and their uncertainties: key climate and emission parameters for
future predictions, Atmos. Chem. Phys., 13, 285–302,
https://doi.org/10.5194/acp-13-285-2013, 2013.
Houweling, S., Krol, M., Bergamaschi, P., Frankenberg, C., Dlugokencky, E.
J., Morino, I., Notholt, J., Sherlock, V., Wunch, D., Beck, V., Gerbig, C.,
Chen, H., Kort, E. A., Röckmann, T., and Aben, I.: A multi-year methane
inversion using SCIAMACHY, accounting for systematic errors using TCCON
measurements, Atmos. Chem. Phys., 14, 3991–4012,
https://doi.org/10.5194/acp-14-3991-2014, 2014.
Kirschke, S., Bousquet, P., Ciais, P., Saunois, M., Canadell, J. G., Dlugokencky, E. J., Bergamaschi,
P., Bergmann, D., Blake, D. R., Bruhwiler, L., Cameron-Smith, P., Castaldi, S., Chevallier,
F., Feng, L., Fraser, A., Heimann, M., Hodson, E. L., Houweling, S., Josse, B., Fraser, P.
J., Krummel, P. B., Lamarque, J.-F., Langenfelds, R. L., Le Quéré, C., Naik, V., O'Doherty, S.,
15 Palmer, P. I., Pison, I., Plummer, D., Poulter, B., Prinn, R. G., Rigby, M., Ringeval, B., Santini,
M., Schmidt, M., Shindell, D. T., Simpson, I. J., Spahni, R., Steele, L. P., Strode, S. A., Sudo,
K., Szopa, S., van der Werf, G. R., Voulgarakis, A., van Weele, M., Weiss, R. F., Williams,
J. E., and Zeng, G.: Three decades of global methane sources and sinks, Nat. Geosci., 6,
813–823, https://doi.org/10.1038/ngeo1955, 2013.
Lamarque, J.-F., Shindell, D. T., Josse, B., Young, P. J., Cionni, I.,
Eyring, V., Bergmann, D., Cameron-Smith, P., Collins, W. J., Doherty, R.,
Dalsoren, S., Faluvegi, G., Folberth, G., Ghan, S. J., Horowitz, L. W., Lee,
Y. H., MacKenzie, I. A., Nagashima, T., Naik, V., Plummer, D., Righi, M.,
Rumbold, S. T., Schulz, M., Skeie, R. B., Stevenson, D. S., Strode, S., Sudo,
K., Szopa, S., Voulgarakis, A., and Zeng, G.: The Atmospheric Chemistry and
Climate Model Intercomparison Project (ACCMIP): overview and description of
models, simulations and climate diagnostics, Geosci. Model Dev., 6, 179–206,
https://doi.org/10.5194/gmd-6-179-2013, 2013.
Lawrence, M. G., Jöckel, P., and von Kuhlmann, R.: What does the global
mean OH concentration tell us?, Atmos. Chem. Phys., 1, 37–49,
https://doi.org/10.5194/acp-1-37-2001, 2001.
Lelieveld, J., Peters, W., Dentener, F. J., and Krol, M. C.: Stability of
tropospheric hydroxyl chemistry, J. Geophys. Res., 107, 4715,
https://doi.org/10.1029/2002JD002272, 2002.
Lin, S.-J.: A “vertically Lagrangian” finite-volume dynamical core for
global models, Mon. Weather Rev., 132, 2293–2307, 2004.
Luo, M., Read, W., Kulawik, S., Worden, J., Livesey, N., Bowman, K., and
Herman, R.: Carbon monoxide (CO) vertical profiles derived from joined TES
and MLS measurements, J. Geophys. Res. Atmos., 118, 10601–10613,
https://doi.org/10.1002/jgrd.50800, 2013.
Molod, A., Takacs, L., Suarez, M., Bacmeister, J., Song, I.-S., and
Eichmann, A.: The GEOS-5 Atmospheric General Circulation Model: Mean Climate
and Development from MERRA to Fortuna, NASA/TM–2012-104606, Technical Report
Series on Global Modeling and Data Assimilation, edited by: Suarez, M., Vol.
28, available at: http://gmao.gsfc.nasa.gov/pubs/docs/tm28.pdf (last
access: 27 October 2015), 2012.
Monks, S. A., Arnold, S. R., Emmons, L. K., Law, K. S., Turquety, S., Duncan,
B. N., Flemming, J., Huijnen, V., Tilmes, S., Langner, J., Mao, J., Long, Y.,
Thomas, J. L., Steenrod, S. D., Raut, J. C., Wilson, C., Chipperfield, M. P.,
Diskin, G. S., Weinheimer, A., Schlager, H., and Ancellet, G.: Multi-model
study of chemical and physical controls on transport of anthropogenic and
biomass burning pollution to the Arctic, Atmos. Chem. Phys., 15, 3575–3603,
https://doi.org/10.5194/acp-15-3575-2015, 2015.
Montzka, S. A., Krol, M., Dlugokencky, E., Hall, B., Joeckel, P., and
Lelieveld, J.: Small interannual variability of global atmospheric hydroxyl,
Science, 331, 67–69, https://doi.org/10.1126/science.1197640, 2011.
Murray, L. T., Logan, J. A., and Jacob, D. J.: Interannual variability in
tropical tropospheric ozone and OH: The role of lightning, J. Geophys. Res.
Atmos., 118, 11468–11480, https://doi.org/10.1002/jgrd.50857, 2013.
Myhre, G., Shindell, D., Breìon, F.-M., Collins, W., Fuglestvedt, J.,
Huang, J., Koch, D., Lamarque, J.-F., Lee, D.,
Mendoza, B., Nakajima, T., Robock, A., Stephens, G., Takemura, T., and Zhang,
H.: Anthropogenic and natural radiative forcing, in: Climate Change 2013: The
Physical Science Basis. Contribution of Working Group I to the Fifth
Assessment Report of the Intergovernmental Panel on Climate Change, edited
by: Stocker, T. F., Qin, D., Plattner, G.-K., Tignor, M., Allen, S. K.,
Boschung, J., Nauels, A., Xia, Y., Bex, V., and Midgley, P. M., availa1able
at: http://www.climatechange2013.org/images/report/WG1AR5_ALL_FINAL.pdf
(last access: 27 October 2015), 2013.
Naik, V., Voulgarakis, A., Fiore, A. M., Horowitz, L. W., Lamarque, J.-F.,
Lin, M., Prather, M. J., Young, P. J., Bergmann, D., Cameron-Smith, P. J.,
Cionni, I., Collins, W. J., Dalsøren, S. B., Doherty, R., Eyring, V.,
Faluvegi, G., Folberth, G. A., Josse, B., Lee, Y. H., MacKenzie, I. A.,
Nagashima, T., van Noije, T. P. C., Plummer, D. A., Righi, M., Rumbold, S.
T., Skeie, R., Shindell, D. T., Stevenson, D. S., Strode, S., Sudo, K.,
Szopa, S., and Zeng, G.: Preindustrial to present-day changes in tropospheric
hydroxyl radical and methane lifetime from the Atmospheric Chemistry and
Climate Model Intercomparison Project (ACCMIP), Atmos. Chem. Phys., 13,
5277–5298, https://doi.org/10.5194/acp-13-5277-2013, 2013.
Novelli, P., Steele, P., and Tans, P. P.: Mixing ratios of carbon monoxide in
the troposphere, J. Geophys. Res., 102, 12855–12861, https://doi.org/10.1029/92JD02010,
1992.
Novelli, P., Masarie, K. A., and Lang, P. M.: Distributions and recent changes
in carbon monoxide in the lower troposphere, J. Geosphys. Res., 103,
19015–19033, 1998.
Oman, L. D., Ziemke, J. R., Douglass, A. R., Waugh, D. W., Lang, C.,
Rodriguez, J. M., and Nielsen, J. E.: The response of tropical tropospheric
ozone to ENSO, Geophys. Res. Lett., 38, L13706, https://doi.org/10.1029/2011GL047865,
2011.
Ott, L., Duncan, B., Pawson, S., Colarco, P., Chin, M., Randles, C., Diehl,
T., and Nielsen, E.: Influence of the 2006 Indonesian biomass burning
aerosols on tropical dynamics studied with the GEOS5 AGCM, J. Geophys. Res.,
115, D14121, https://doi.org/10.1029/2009JD013181, 2010.
Patra, P. K., Houweling, S., Krol, M., Bousquet, P., Belikov, D., Bergmann,
D., Bian, H., Cameron-Smith, P., Chipperfield, M. P., Corbin, K.,
Fortems-Cheiney, A., Fraser, A., Gloor, E., Hess, P., Ito, A., Kawa, S. R.,
Law, R. M., Loh, Z., Maksyutov, S., Meng, L., Palmer, P. I., Prinn, R. G.,
Rigby, M., Saito, R., and Wilson, C.: TransCom model simulations of CH4 and
related species: linking transport, surface flux and chemical loss with
CH4
variability in the troposphere and lower stratosphere, Atmos. Chem. Phys.,
11, 12813–12837, https://doi.org/10.5194/acp-11-12813-2011, 2011.
Patra, P. K., Krol, M. C., Montzka, S. A., Arnold, T., Atlas, E. L.,
Lintner, B. R., Xiang, B., Elkins, J. W., Fraser, P. J., Ghosh, A., Hintsa,
E. J., Hurst, D. F., Ishijima, K., Krummel, P. B., Miller, B. R., Miyazaki,
K., Moore, F. L., Mühle, J., O'Doherty, S., Prinn, R. G., Steele, L. P.,
Takigawa, M., Wang, H. J., Weiss, R. F., Wofsy, S. C., and Young, D.:
Observational evidence for interhemispheric hydroxyl-radical parity, Nature,
513, 219–223, https://doi.org/10.1038/nature13721, 2014.
Pawson, S. R., Stolarski, S., Douglass, A. R., Newman, P. A., Nielsen, J.
E., Frith, S. M., and Gupta, M. L.: Goddard Earth Observing System
chemistry-climate model simulations of stratospheric ozone-temperature
coupling between 1950 and 2005, J. Geophys. Res., 113, D12103,
https://doi.org/10.1029/2007JD009511, 2008.
Prather, M.: Lifetimes and Eigen states in atmospheric chemistry, Geophys.
Res. Lett., 21, 801–804, 1994.
Prather, M.: Time scales in atmospheric chemistry: Theory, GWPs for CH4
and CO, and runaway growth, Geophys. Res. Lett., 23, 2597–2600,
https://doi.org/10.1029/96GL02371, 1996.
Prather, M. and Spivakovsky, C. M.: Tropospheric OH and the lifetimes of
hydrochlorofluorocarbons, J. Geophys. Res., 95, 18723–18729,
https://doi.org/10.1029/JD095iD11p18723, 1990.
Prather, M. J., Holmes, C. D., and Hsu, J.: Reactive greenhouse gas
scenarios: Systematic exploration of uncertainties and the role of
atmospheric chemistry, Geophys. Res. Lett., 39, L09803,
https://doi.org/10.1029/2012GL051440, 2012.
Prinn, R. G., Huang, J., Weiss, R. F., Cunnold, D. M., Fraser, P. J.,
Simmonds, P. G., McCulloch, A., Harth, C., Reimann, S., Salameh, P.,
O'Doherty, S., Wang, R. H. J., Porter, L. W., Miller, B. R., and Krummel, P.
B.: Evidence for variability of atmospheric hydroxyl radicals over the past
quarter century, Geophys. Res. Lett., 32, L07809, https://doi.org/10.1029/2004GL022228,
2005.
Randerson, J. T., van der Werf, G. R., Giglio, L., Collatz, G. J., and
Kasibhatl, P. S.: Global Fire Emissions Database, Version 3 (GFEDv3.1), Data
set, Oak Ridge National Laboratory Distributed Active Archive Center, Oak
Ridge, Tennessee, USA, available at: http://daac.ornl.gov (last access:
27 October 2015), https://doi.org/10.3334/ORNLDAAC/1191, 2013.
Rienecker, M. M., Suarez, M. J., Todling, R., Bacmeister, J., Takacs, L.,
Liu, H.-C., Gu, W., Sienkiewicz, M., Koster, R. D., Gelaro, R., Stajner, I.,
and Nielsen, J. E.: The GEOS-5 data assimilation system – Documentation of
Versions 5.0.1, 5.1.0, and 5.2.0, Technical Report Series on Global Modeling
and Data Assimilation, Vol. 27, available at:
http://gmao.gsfc.nasa.gov/pubs/docs/GEOS5_104606-Vol27.pdf (last
access: 27 October 2015), 2008.
Rohrer, F. and Berresheim, H.: Strong correlations between levels of
tropospheric hydroxyl radicals and solar ultraviolet radiation, Nature, 442,
184–187, https://doi.org/10.1038/nature04924, 2006.
Rohrer, F., Lu, K., Hofzumahaus, A., Bohn, B., Brauers, T., Chang, C.-C.,
Fuchs, H., Häseler, R., Holland, F., Hu, M., Kita, K., Kondo, Y., Li, X.,
Lou, S., Oebel, A., Shao, M., Zeng, L., Zhu, T., Zhang, Y., and Wahner, A.:
Maximum efficiency in the hydroxyl-radical-based self-cleansing of the
troposphere, Nat. Geosci. 7, 559–563, https://doi.org/10.1038/ngeo2199, 2014.
Sander, S. P., Abbatt, J., Barker, J. R., Burkholder, J. B., Friedl, R. R.,
Golden, D. M., Huie, R. E., Kolb, C. E., Kurylo, M. J., Moortgat, G. K.,
Orkin, V. L., and Wine, P. H.: Chemical Kinetics and Photochemical Data for
Use in Atmospheric Studies, Evaluation No. 17, JPL Publication 10-6, Jet
Propulsion Laboratory, Pasadena, available at:
http://jpldataeval.jpl.nasa.gov (last access: 27 October 2015), 2011.
Schneising, O., Buchwitz, M., Burrows, J. P., Bovensmann, H., Bergamaschi,
P., and Peters, W.: Three years of greenhouse gas column-averaged dry air
mole fractions retrieved from satellite – Part 2: Methane, Atmos. Chem.
Phys., 9, 443–465, https://doi.org/10.5194/acp-9-443-2009, 2009.
Schneising, O., Buchwitz, M., Reuter, M., Heymann, J., Bovensmann, H., and
Burrows, J. P.: Long-term analysis of carbon dioxide and methane
column-averaged mole fractions retrieved from SCIAMACHY, Atmos. Chem. Phys.,
11, 2863–2880, https://doi.org/10.5194/acp-11-2863-2011, 2011.
Schultz, M., Rast, S., van het Bolscher, M., Pulles, T., Brand, R.,
Pereira, J., Mota, B., Spessa, A., Dalsøren, S., van Nojie, T., and Szopa,
S.: Emission data sets and methodologies for estimating emissions, RETRO
project report D1-6, Hamburg, 26 February 2007, available at:
http://gcmd.gsfc.nasa.gov/records/GCMD_GEIA_RETRO.html (last access:
27 October 2015), 2007.
Shindell, D. T., Faluvegi, G., Stevenson, D. S., Krol, M. C., Emmons, L. K.,
Lamarque, J.-F., Petron, G., Dentener, F. J., Ellingsne, K., Schultz, M. G.,
Wild, O., Amann, M., Atherton, C. S., Bergmann, D. J., Bey, I., Butler, T.,
Cofala, J., Collins, W. J., Derwent, R. G., Doherty, R. M., Drevet, J.,
Eskes, H. J., Fiore, A. M., Gauss, M., Hauglustaine, D. A., Horowitz, L. W.,
Isaksen, I. S. A., Lawrence, M. G., Montanaro, V., Müller, J.-F., Pitari,
G., Prather, M. J., Pyle, J. A., Rast, S., Rodriguez, J. M., Sanderson, M.
G., Savage, N. H., Strahan, S. E., Sudo, K., Szopa, S., Unger, N., van Noije,
T. P. C., and Zeng, G.: Multimodel simulations of carbon monoxide: Comparison
with observations and projected near-future changes, J. Geophys. Res., 111,
D19306, https://doi.org/10.1029/2006JD007100, 2006.
Spivakovsky, C., Wofsy, S., and Prather, M.: A numerical method for the
parameterization of atmospheric chemistry: Computation of tropospheric OH, J.
Geophys. Res., 95, 18433–18439, 1990a.
Spivakovsky, C. M., Yevich, R., Logan, J. A., Wofsy, S. C., McElroy, M. B., and
Prather, M. J.: Tropospheric OH in a three-dimensional chemical tracer model:
An assessment based on observations of CH3CC13, J. Geophys. Res.,
95, 18441–18471, https://doi.org/10.1029/JD095iD11p18441, 1990b.
Spivakovsky, C. M., Logan, J. A., Montzka, S. A., Balkanski, Y.
J., Foreman-Fowler, M., Jones, D. B. A., Horowitz, L. W., Fusco, A. C.,
Brenninkmeijer, C. A. M., Prather, M. J., Wofsy, S. C., and McElroy, M. B.:
Three-dimensional climatological distribution of tropospheric OH: Update and
evaluation, J. Geophys. Res., 105, 8931–8980, https://doi.org/10.1029/1999JD901006,
2000.
Stone, D., Whalley, L. K., and Heard, D. E.: Tropospheric OH and HO2 radicals:
field measurements and model comparisons, Chem. Soc. Rev., 41, 6348,
https://doi.org/10.1039/c2cs35140d, 2012.
Strahan, S. E., Duncan, B. N., and Hoor, P.: Observationally derived
transport diagnostics for the lowermost stratosphere and their application to
the GMI chemistry and transport model, Atmos. Chem. Phys., 7, 2435–2445,
https://doi.org/10.5194/acp-7-2435-2007, 2007.
Strode, S. A., Duncan, B. N., Yegorova, E. A., Kouatchou, J., Ziemke, J. R.,
and Douglass, A. R.: Implications of carbon monoxide bias for methane
lifetime and atmospheric composition in chemistry climate models, Atmos.
Chem. Phys., 15, 11789–11805, https://doi.org/10.5194/acp-15-11789-2015,
2015.
Voulgarakis, A., Naik, V., Lamarque, J.-F., Shindell, D. T., Young, P. J.,
Prather, M. J., Wild, O., Field, R. D., Bergmann, D., Cameron-Smith, P.,
Cionni, I., Collins, W. J., Dalsøren, S. B., Doherty, R. M., Eyring, V.,
Faluvegi, G., Folberth, G. A., Horowitz, L. W., Josse, B., MacKenzie, I. A.,
Nagashima, T., Plummer, D. A., Righi, M., Rumbold, S. T., Stevenson, D. S.,
Strode, S. A., Sudo, K., Szopa, S., and Zeng, G.: Analysis of present day and
future OH and methane lifetime in the ACCMIP simulations, Atmos. Chem. Phys.,
13, 2563–2587, https://doi.org/10.5194/acp-13-2563-2013, 2013.
Voulgarakis, A., Marlier, M. E., Faluvegi, G., Shindell, D. T.,
Tsigaridis, K., and Mangeon, S.: Interannual variability of tropospheric
trace gases and aerosols: The role of biomass burning emissions, J. Geophys.
Res. Atmos., 120, 7157–7173, https://doi.org/10.1002/2014JD022926, 2015.
Wang, J. S., Logan, J. A., McElroy, M. B., Duncan, B. N., Megretskaia, I.
A., and Yantosca, R. M.: A 3-D model analysis of the slowdown and interannual
variability in the methane growth rate from 1988 to 1997, Global Biogeochem.
Cy., 18, GB3011, https://doi.org/10.1029/2003GB002180, 2004.
Wang, J. S., McElroy, M. B., Logan, J. A., Palmer, P. I., Chameides, W. L.,
Wang, Y., and Megretskaia, I. A.: A quantitative assessment of uncertainties
affecting estimates of global mean OH derived from methyl chloroform
observations, J. Geophys. Res., 113, D12302, https://doi.org/10.1029/2007JD008496, 2008.
Wild, O. and Palmer, P. I.: How sensitive is tropospheric oxidation to
anthropogenic emissions?, Geophys. Res. Lett., 35, L22802,
https://doi.org/10.1029/2008GL035718, 2008.
Wolter, K. and Timlin, M. S.: El Niño/Southern Oscillation behaviour
since 1871 as diagnosed in an extended multivariate ENSO index (MEI.ext),
Int. J. Climatol., 31, 1074–1087, https://doi.org/10.1002/joc.2336, 2011.
Worden, H. M., Deeter, M. N., Edwards, D. P., Gille, J. C., Drummond, J. R.,
and Nédélec, P.: Observations of near-surface carbon monoxide from
space using MOPITT multispectral retrievals, J. Geophys., Res., 115, D18314,
https://doi.org/10.1029/2010JD014242, 2010.
Short summary
The ECCOH (pronounced "echo") chemistry module interactively simulates the photochemistry of the CH4–CO–OH system within a chemistry climate model, carbon cycle model, or Earth system model. The computational efficiency of the module allows many multi-decadal sensitivity simulations of the CH4–CO–OH system. This capability is important for capturing nonlinear feedbacks of the CH4–CO–OH system and understanding the perturbations to methane, CO, and OH and the concomitant climate impacts.
The ECCOH (pronounced "echo") chemistry module interactively simulates the photochemistry of the...