Articles | Volume 17, issue 4
https://doi.org/10.5194/gmd-17-1511-2024
https://doi.org/10.5194/gmd-17-1511-2024
Development and technical paper
 | 
20 Feb 2024
Development and technical paper |  | 20 Feb 2024

Impacts of updated reaction kinetics on the global GEOS-Chem simulation of atmospheric chemistry

Kelvin H. Bates, Mathew J. Evans, Barron H. Henderson, and Daniel J. Jacob

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Cited articles

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Baeza-Romero, M. T., Glowacki, D. R., Blitz, M. A., Heard, D. E., Pilling, M. J., Rickard, A. R., and Seakins, P. W.: A combined experimental and theoretical study of the reaction between methylglyoxal and OH/OD radical: OH regeneration, Phys. Chem. Chem. Phys., 9, 4114–4128, https://doi.org/10.1039/B702916K, 2007. a
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Bates, K. H. and Jacob, D. J.: A new model mechanism for atmospheric oxidation of isoprene: global effects on oxidants, nitrogen oxides, organic products, and secondary organic aerosol, Atmos. Chem. Phys., 19, 9613–9640, https://doi.org/10.5194/acp-19-9613-2019, 2019. a, b
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Short summary
Accurate representation of rates and products of chemical reactions in atmospheric models is crucial for simulating concentrations of pollutants and climate forcers. We update the widely used GEOS-Chem atmospheric chemistry model with reaction parameters from recent compilations of experimental data and demonstrate the implications for key atmospheric chemical species. The updates decrease tropospheric CO mixing ratios and increase stratospheric nitrogen oxide mixing ratios, among other changes.
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