Articles | Volume 16, issue 17
https://doi.org/10.5194/gmd-16-5251-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/gmd-16-5251-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Simulation model of Reactive Nitrogen Species in an Urban Atmosphere using a Deep Neural Network: RNDv1.0
Junsu Gil
Department of Earth and Environmental Sciences, Korea University,
Seoul, South Korea
Department of Earth and Environmental Sciences, Korea University,
Seoul, South Korea
Jeonghwan Kim
Department of Environmental Science, Hankuk University of Foreign
Studies, Yongin, South Korea
Gangwoong Lee
Department of Environmental Science, Hankuk University of Foreign
Studies, Yongin, South Korea
Joonyoung Ahn
Climate and Air Quality Research
Department, Air Quality Forecasting Center, National Institute of Environmental Research (NIER), Incheon,
South Korea
Cheol-Hee Kim
Department of Atmospheric Sciences, Pusan National University, Busan, South Korea
Related authors
Ke Li, Rong Tan, Wenhao Qiao, Taegyung Lee, Yufen Wang, Danyuting Zhang, Minglong Tang, Wenqing Zhao, Yixuan Gu, Shaojia Fan, Jinqiang Zhang, Xiaopu Lyu, Likun Xue, Jianming Xu, Zhiqiang Ma, Mohd Talib Latif, Teerachai Amnuaylojaroen, Junsu Gil, Mee-Hye Lee, Juseon Bak, Joowan Kim, Hong Liao, Yugo Kanaya, Xiao Lu, Tatsuya Nagashima, and Ja-Ho Koo
EGUsphere, https://doi.org/10.5194/egusphere-2024-3756, https://doi.org/10.5194/egusphere-2024-3756, 2025
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
Short summary
Short summary
East Asia and Southeast Asia has been identified as a global hot spot with the fastest ozone increase. This paper presents the most comprehensive observational view of ozone distributions and evolution over East Asia and Southeast Asia across different spatiotemporal scales in the past two decades, which will have important implications for assessing ozone impacts on public health and crop yields, and for developing future ozone control strategies.
Saehee Lim, Meehye Lee, Paolo Laj, Sang-Woo Kim, Kang-Ho Ahn, Junsoo Gil, Xiaona Shang, Marco Zanatta, and Kyeong-Sik Kang
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2020-1247, https://doi.org/10.5194/acp-2020-1247, 2021
Preprint withdrawn
Short summary
Short summary
This study identifies the main drivers of the formation and transformation processes of submicron particles and highlights that the thick coating of rBC was a result of active conversion of hygroscopic inorganic salts leading to fine aerosol pollution. Consequently, we suggest BC particles as a key contributor to PM2.5 mass increase, which implies that BC reduction is an effective mitigation against haze pollution as well as climate change in Northeast Asia.
Junsu Gil, Jeonghwan Kim, Meehye Lee, Gangwoong Lee, Dongsoo Lee, Jinsang Jung, Joonyeong An, Jinkyu Hong, Seogju Cho, Jeonghoon Lee, and Russell Long
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2019-1012, https://doi.org/10.5194/acp-2019-1012, 2019
Preprint withdrawn
Short summary
Short summary
During the KORUS-AQ campaign, nitrous acid (HONO) concentrations in Seoul were higher in high-O3 episodes than non-episodes. The photochemical model simulation demonstrates the role of HONO in promoting O3 formation through OH production and subsequent VOCs oxidation. The ambient HONO concentrations were reasonably represented by an Artificial Neural Network model, highlighting NOx, surface area, and relative humidity as crucial parameters for HONO formation in Seoul under high NOx conditions.
Ke Li, Rong Tan, Wenhao Qiao, Taegyung Lee, Yufen Wang, Danyuting Zhang, Minglong Tang, Wenqing Zhao, Yixuan Gu, Shaojia Fan, Jinqiang Zhang, Xiaopu Lyu, Likun Xue, Jianming Xu, Zhiqiang Ma, Mohd Talib Latif, Teerachai Amnuaylojaroen, Junsu Gil, Mee-Hye Lee, Juseon Bak, Joowan Kim, Hong Liao, Yugo Kanaya, Xiao Lu, Tatsuya Nagashima, and Ja-Ho Koo
EGUsphere, https://doi.org/10.5194/egusphere-2024-3756, https://doi.org/10.5194/egusphere-2024-3756, 2025
This preprint is open for discussion and under review for Atmospheric Chemistry and Physics (ACP).
Short summary
Short summary
East Asia and Southeast Asia has been identified as a global hot spot with the fastest ozone increase. This paper presents the most comprehensive observational view of ozone distributions and evolution over East Asia and Southeast Asia across different spatiotemporal scales in the past two decades, which will have important implications for assessing ozone impacts on public health and crop yields, and for developing future ozone control strategies.
Juseon Bak, Xiong Liu, Kai Yang, Gonzalo Gonzalez Abad, Ewan O'Sullivan, Kelly Chance, and Cheol-Hee Kim
Atmos. Meas. Tech., 17, 1891–1911, https://doi.org/10.5194/amt-17-1891-2024, https://doi.org/10.5194/amt-17-1891-2024, 2024
Short summary
Short summary
The new version (V2) of the OMI ozone profile product is introduced to improve retrieval quality and long-term consistency of tropospheric ozone by incorporating the recent collection 4 OMI L1b spectral products and refining radiometric correction, forward model calculation, and a priori ozone data.
Juseon Bak, Eun-Ji Song, Hyo-Jung Lee, Xiong Liu, Ja-Ho Koo, Joowan Kim, Wonbae Jeon, Jae-Hwan Kim, and Cheol-Hee Kim
Atmos. Chem. Phys., 22, 14177–14187, https://doi.org/10.5194/acp-22-14177-2022, https://doi.org/10.5194/acp-22-14177-2022, 2022
Short summary
Short summary
Our study investigates the temporal variations of ozone profiles at Pohang in the Korean Peninsula from multiple ozone products. We discuss the quantitative relationships between daily surface measurements and key meteorological variables, different seasonality of ozone between the troposphere and stratosphere, and interannual changes in the lower tropospheric ozone, linked by the weather pattern driven by the East Asian summer monsoon.
Lim-Seok Chang, Donghee Kim, Hyunkee Hong, Deok-Rae Kim, Jeong-Ah Yu, Kwangyul Lee, Hanlim Lee, Daewon Kim, Jinkyu Hong, Hyun-Young Jo, and Cheol-Hee Kim
Atmos. Chem. Phys., 22, 10703–10720, https://doi.org/10.5194/acp-22-10703-2022, https://doi.org/10.5194/acp-22-10703-2022, 2022
Short summary
Short summary
Our study explored the synergy of combined column and surface measurements during GMAP (GEMS Map of Air Pollution) campaign. It has several points to note for vertical distribution analysis. Particularly under prevailing local wind meteorological conditions, Pandora-based vertical structures sometimes showed negative correlations between column and surface measurements. Vertical analysis should be done carefully in some local meteorological conditions when employing either surface or columns.
Saehee Lim, Meehye Lee, Joel Savarino, and Paolo Laj
Atmos. Chem. Phys., 22, 5099–5115, https://doi.org/10.5194/acp-22-5099-2022, https://doi.org/10.5194/acp-22-5099-2022, 2022
Short summary
Short summary
We determined δ15N(NO3−) and Δ17O(NO3−) of PM2.5 in Seoul during 2018–2019 and estimated quantitatively the contribution of oxidation pathways to NO3− formation and NOx emission sources. The nighttime pathway played a significant role in NO3− formation during the winter, and its contribution further increased up to 70 % on haze days when PM2.5 was greater than 75 µg m−3. Vehicle emissions were confirmed as a main NO3− source with an increasing contribution from coal combustion in winter.
Md. Mozammel Haque, Yanlin Zhang, Srinivas Bikkina, Meehye Lee, and Kimitaka Kawamura
Atmos. Chem. Phys., 22, 1373–1393, https://doi.org/10.5194/acp-22-1373-2022, https://doi.org/10.5194/acp-22-1373-2022, 2022
Short summary
Short summary
We attempt to understand the current state of East Asian organic aerosols with both the molecular marker approach and 14° C data of carbonaceous components. A significant positive correlation of nonfossil- and fossil-derived organic carbon with levoglucosan suggests the importance of biomass burning (BB) and coal combustion sources in the East Asian outflow. Thus, attribution of ambient levoglucosan levels over the western North Pacific to the impact of BB emission may cause large uncertainty.
Chinmoy Sarkar, Gracie Wong, Anne Mielnik, Sanjeevi Nagalingam, Nicole Jenna Gross, Alex B. Guenther, Taehyoung Lee, Taehyun Park, Jihee Ban, Seokwon Kang, Jin-Soo Park, Joonyoung Ahn, Danbi Kim, Hyunjae Kim, Jinsoo Choi, Beom-Keun Seo, Jong-Ho Kim, Jeong-Ho Kim, Soo Bog Park, and Saewung Kim
Atmos. Chem. Phys., 21, 11505–11518, https://doi.org/10.5194/acp-21-11505-2021, https://doi.org/10.5194/acp-21-11505-2021, 2021
Short summary
Short summary
We present experimental proofs illustrating the emission of an unexplored volatile organic compound, tentatively assigned as ketene, in an industrial facility in South Korea. The emission of such a compound has rarely been reported, but our experimental data show that the emission rate is substantial. It potentially has tremendous implications for regional air quality and public health, as it is highly reactive and toxic at the same time.
Dianne Sanchez, Roger Seco, Dasa Gu, Alex Guenther, John Mak, Youngjae Lee, Danbi Kim, Joonyoung Ahn, Don Blake, Scott Herndon, Daun Jeong, John T. Sullivan, Thomas Mcgee, Rokjin Park, and Saewung Kim
Atmos. Chem. Phys., 21, 6331–6345, https://doi.org/10.5194/acp-21-6331-2021, https://doi.org/10.5194/acp-21-6331-2021, 2021
Short summary
Short summary
We present observations of total reactive gases in a suburban forest observatory in the Seoul metropolitan area. The quantitative comparison with speciated trace gas observations illustrated significant underestimation in atmospheric reactivity from the speciated trace gas observational dataset. We present scientific discussion about potential causes.
Saehee Lim, Meehye Lee, Paolo Laj, Sang-Woo Kim, Kang-Ho Ahn, Junsoo Gil, Xiaona Shang, Marco Zanatta, and Kyeong-Sik Kang
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2020-1247, https://doi.org/10.5194/acp-2020-1247, 2021
Preprint withdrawn
Short summary
Short summary
This study identifies the main drivers of the formation and transformation processes of submicron particles and highlights that the thick coating of rBC was a result of active conversion of hygroscopic inorganic salts leading to fine aerosol pollution. Consequently, we suggest BC particles as a key contributor to PM2.5 mass increase, which implies that BC reduction is an effective mitigation against haze pollution as well as climate change in Northeast Asia.
Haeyoung Lee, Edward J. Dlugokencky, Jocelyn C. Turnbull, Sepyo Lee, Scott J. Lehman, John B. Miller, Gabrielle Pétron, Jeong-Sik Lim, Gang-Woong Lee, Sang-Sam Lee, and Young-San Park
Atmos. Chem. Phys., 20, 12033–12045, https://doi.org/10.5194/acp-20-12033-2020, https://doi.org/10.5194/acp-20-12033-2020, 2020
Short summary
Short summary
To understand South Korea's CO2 emissions and sinks as well as those of the surrounding region, we used flask-air samples collected for 2 years at Anmyeondo (36.53° N, 126.32° E; 46 m a.s.l.), South Korea, for analysis of observed 14C in atmospheric CO2 as a tracer of fossil fuel CO2 contribution (Cff). Here, we showed our observation result of 14C and Cff. SF6 and CO can be good proxies of Cff in this study, and the ratio of CO to Cff was compared to a bottom-up inventory.
Najin Kim, Seong Soo Yum, Minsu Park, Jong Sung Park, Hye Jung Shin, and Joon Young Ahn
Atmos. Chem. Phys., 20, 11245–11262, https://doi.org/10.5194/acp-20-11245-2020, https://doi.org/10.5194/acp-20-11245-2020, 2020
Short summary
Short summary
Chemical effects on the size-resolved hygroscopicity of urban aerosols were examined based on the KORUS-AQ field campaign data (HTDMA and HR-ToF-AMS). The size-resolved chemical composition data were found to be critical in explaining the size-dependent hygroscopicity, as well as the diurnal variation of κ for small particles. Aerosol mixing state information was associated with the size-resolved chemical composition data to reveal chemical information of different hygroscopicity modes.
Meng Gao, Zhiwei Han, Zhining Tao, Jiawei Li, Jeong-Eon Kang, Kan Huang, Xinyi Dong, Bingliang Zhuang, Shu Li, Baozhu Ge, Qizhong Wu, Hyo-Jung Lee, Cheol-Hee Kim, Joshua S. Fu, Tijian Wang, Mian Chin, Meng Li, Jung-Hun Woo, Qiang Zhang, Yafang Cheng, Zifa Wang, and Gregory R. Carmichael
Atmos. Chem. Phys., 20, 1147–1161, https://doi.org/10.5194/acp-20-1147-2020, https://doi.org/10.5194/acp-20-1147-2020, 2020
Short summary
Short summary
Topic 3 of the Model Inter-Comparison Study for Asia (MICS-Asia) Phase III examines how online coupled air quality models perform in simulating high aerosol pollution in the North China Plain region during wintertime haze events and evaluates the importance of aerosol radiative feedbacks. This paper discusses the estimates of aerosol radiative forcing, aerosol feedbacks, and possible causes for the differences among the models.
Lei Kong, Xiao Tang, Jiang Zhu, Zifa Wang, Joshua S. Fu, Xuemei Wang, Syuichi Itahashi, Kazuyo Yamaji, Tatsuya Nagashima, Hyo-Jung Lee, Cheol-Hee Kim, Chuan-Yao Lin, Lei Chen, Meigen Zhang, Zhining Tao, Jie Li, Mizuo Kajino, Hong Liao, Zhe Wang, Kengo Sudo, Yuesi Wang, Yuepeng Pan, Guiqian Tang, Meng Li, Qizhong Wu, Baozhu Ge, and Gregory R. Carmichael
Atmos. Chem. Phys., 20, 181–202, https://doi.org/10.5194/acp-20-181-2020, https://doi.org/10.5194/acp-20-181-2020, 2020
Short summary
Short summary
Evaluation and uncertainty investigation of NO2, CO and NH3 modeling over China were conducted in this study using 14 chemical transport model results from MICS-Asia III. All models largely underestimated CO concentrations and showed very poor performance in reproducing the observed monthly variations of NH3 concentrations. Potential factors related to such deficiencies are investigated and discussed in this paper.
Yongjoo Choi, Yugo Kanaya, Seung-Myung Park, Atsushi Matsuki, Yasuhiro Sadanaga, Sang-Woo Kim, Itsushi Uno, Xiaole Pan, Meehye Lee, Hyunjae Kim, and Dong Hee Jung
Atmos. Chem. Phys., 20, 83–98, https://doi.org/10.5194/acp-20-83-2020, https://doi.org/10.5194/acp-20-83-2020, 2020
Short summary
Short summary
The relationship between black carbon (BC) and carbon monoxide (CO) can differ by the different structure of fuel consumption. By investigating the representativeness of the BC and CO emission inventory for real-world comparison with reliable observations, this study suggested that accurate CO emissions should be preferentially investigated to enhance the accuracy of the BC emission rate over East Asia.
Junsu Gil, Jeonghwan Kim, Meehye Lee, Gangwoong Lee, Dongsoo Lee, Jinsang Jung, Joonyeong An, Jinkyu Hong, Seogju Cho, Jeonghoon Lee, and Russell Long
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2019-1012, https://doi.org/10.5194/acp-2019-1012, 2019
Preprint withdrawn
Short summary
Short summary
During the KORUS-AQ campaign, nitrous acid (HONO) concentrations in Seoul were higher in high-O3 episodes than non-episodes. The photochemical model simulation demonstrates the role of HONO in promoting O3 formation through OH production and subsequent VOCs oxidation. The ambient HONO concentrations were reasonably represented by an Artificial Neural Network model, highlighting NOx, surface area, and relative humidity as crucial parameters for HONO formation in Seoul under high NOx conditions.
Jie Li, Tatsuya Nagashima, Lei Kong, Baozhu Ge, Kazuyo Yamaji, Joshua S. Fu, Xuemei Wang, Qi Fan, Syuichi Itahashi, Hyo-Jung Lee, Cheol-Hee Kim, Chuan-Yao Lin, Meigen Zhang, Zhining Tao, Mizuo Kajino, Hong Liao, Meng Li, Jung-Hun Woo, Jun-ichi Kurokawa, Zhe Wang, Qizhong Wu, Hajime Akimoto, Gregory R. Carmichael, and Zifa Wang
Atmos. Chem. Phys., 19, 12993–13015, https://doi.org/10.5194/acp-19-12993-2019, https://doi.org/10.5194/acp-19-12993-2019, 2019
Short summary
Short summary
This study evaluated and intercompared 14 CTMs with ozone observations in East Asia, within the framework of the Model Inter-Comparison Study for ASIA Phase III (MICS-Asia III). Potential causes of the discrepancies between model results and observation were investigated by assessing the planetary boundary layer heights, emission fluxes, dry deposition, chemistry and vertical transport among models. Finally, a multi-model estimate of pollution distributions was provided.
Daun Jeong, Roger Seco, Dasa Gu, Youngro Lee, Benjamin A. Nault, Christoph J. Knote, Tom Mcgee, John T. Sullivan, Jose L. Jimenez, Pedro Campuzano-Jost, Donald R. Blake, Dianne Sanchez, Alex B. Guenther, David Tanner, L. Gregory Huey, Russell Long, Bruce E. Anderson, Samuel R. Hall, Kirk Ullmann, Hye-jung Shin, Scott C. Herndon, Youngjae Lee, Danbi Kim, Joonyoung Ahn, and Saewung Kim
Atmos. Chem. Phys., 19, 12779–12795, https://doi.org/10.5194/acp-19-12779-2019, https://doi.org/10.5194/acp-19-12779-2019, 2019
Haeyoung Lee, Sang-Ok Han, Sang-Boom Ryoo, Jeong-Soon Lee, and Gang-Woong Lee
Atmos. Chem. Phys., 19, 2149–2163, https://doi.org/10.5194/acp-19-2149-2019, https://doi.org/10.5194/acp-19-2149-2019, 2019
Short summary
Short summary
We introduced our identical systems, which were installed at three S. Korea stations, using CRDS and a drying system. The measurement uncertainty was ~ 0.11 ppm across the stations. CO2 observed in the west of S. Korea was very sensitive to East Asia (e.g., China), indicating that data include CO2 flux information from East Asia. Through long-term comparison to other East Asian stations, it was suggested that they could be affected not only by local vegetation but also by measurement quality.
Xiaona Shang, Meehye Lee, Saehee Lim, Örjan Gustafsson, Gangwoong Lee, and Limseok Chang
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2018-721, https://doi.org/10.5194/acp-2018-721, 2018
Preprint withdrawn
Short summary
Short summary
At Gosan Climate Observatory, the three main sources including anthropogenic pollution, soil dust, and agricultural fertilizer were distinguished for PM10, PM2.5, and PM1, which accounted for 71 % of the total variances for their mass and composition. The mass of mean + σ were comparable to the 90th percentile and the top 10 % implies the substantial impact of soil dust and haze pollution. In PM2.5, the contribution from non-combustion source such as soil dust should not be ignored.
Eunha Kang, Meehye Lee, William H. Brune, Taehyoung Lee, Taehyun Park, Joonyoung Ahn, and Xiaona Shang
Atmos. Chem. Phys., 18, 6661–6677, https://doi.org/10.5194/acp-18-6661-2018, https://doi.org/10.5194/acp-18-6661-2018, 2018
Short summary
Short summary
A potential aerosol mass (PAM) reactor expedites slow atmospheric oxidation reactions and enables the observation of chemical aging processes and the determination of the aerosol-forming power of an air mass. A PAM reactor was deployed at Baengnyeong Island in the Yellow Sea. Experimental results confirm the key role of SO2 in generating secondary aerosols in northeast Asia, and the contribution of organics to secondary aerosols is more variable during transport in the atmosphere.
Meng Gao, Zhiwei Han, Zirui Liu, Meng Li, Jinyuan Xin, Zhining Tao, Jiawei Li, Jeong-Eon Kang, Kan Huang, Xinyi Dong, Bingliang Zhuang, Shu Li, Baozhu Ge, Qizhong Wu, Yafang Cheng, Yuesi Wang, Hyo-Jung Lee, Cheol-Hee Kim, Joshua S. Fu, Tijian Wang, Mian Chin, Jung-Hun Woo, Qiang Zhang, Zifa Wang, and Gregory R. Carmichael
Atmos. Chem. Phys., 18, 4859–4884, https://doi.org/10.5194/acp-18-4859-2018, https://doi.org/10.5194/acp-18-4859-2018, 2018
Short summary
Short summary
Topic 3 of the Model Inter-Comparison Study for Asia (MICS-Asia) Phase III examines how online coupled air quality models perform in simulating high aerosol pollution in the North China Plain region during wintertime haze events and evaluates the importance of aerosol radiative and microphysical feedbacks. A comprehensive overview of the MICS-ASIA III Topic 3 study design is presented.
Xiaona Shang, Kai Zhang, Fan Meng, Shihao Wang, Meehye Lee, Inseon Suh, Daigon Kim, Kwonho Jeon, Hyunju Park, Xuezhong Wang, and Yuxi Zhao
Atmos. Chem. Phys., 18, 2573–2584, https://doi.org/10.5194/acp-18-2573-2018, https://doi.org/10.5194/acp-18-2573-2018, 2018
Short summary
Short summary
The main sources of PM2.5 during the 2013–2014 winter period in Beijing were identified as soil dust, traffic emission, biomass combustion, industrial emission, and coal combustion. A red-alert haze was almost equally contributed by local traffic and transported coal combustion emissions from Beijing vicinities. This study emphasizes the role of weather condition in haze formation by building up stagnant condition that facilitates the transport of emissions from Beijing's neighboring cities.
Jihyun Han, Meehye Lee, Xiaona Shang, Gangwoong Lee, and Louisa K. Emmons
Atmos. Chem. Phys., 17, 10619–10631, https://doi.org/10.5194/acp-17-10619-2017, https://doi.org/10.5194/acp-17-10619-2017, 2017
Short summary
Short summary
Peroxyacetyl nitrate (PAN) was first measured at Gosan Climate Observatory during the fall of 2010, when PAN was better correlated with PM10 than with O3. In particular, PAN and O3 concentrations were greatly elevated in haze and the Beijing plume and much higher than those from model simulation. This study highlights the decoupling of PAN from O3 in Chinese outflows and suggests PAN as a potential indicator of overall aerosol formation in aged air masses impacted by biomass burning.
Holger Baars, Thomas Kanitz, Ronny Engelmann, Dietrich Althausen, Birgit Heese, Mika Komppula, Jana Preißler, Matthias Tesche, Albert Ansmann, Ulla Wandinger, Jae-Hyun Lim, Joon Young Ahn, Iwona S. Stachlewska, Vassilis Amiridis, Eleni Marinou, Patric Seifert, Julian Hofer, Annett Skupin, Florian Schneider, Stephanie Bohlmann, Andreas Foth, Sebastian Bley, Anne Pfüller, Eleni Giannakaki, Heikki Lihavainen, Yrjö Viisanen, Rakesh Kumar Hooda, Sérgio Nepomuceno Pereira, Daniele Bortoli, Frank Wagner, Ina Mattis, Lucja Janicka, Krzysztof M. Markowicz, Peggy Achtert, Paulo Artaxo, Theotonio Pauliquevis, Rodrigo A. F. Souza, Ved Prakesh Sharma, Pieter Gideon van Zyl, Johan Paul Beukes, Junying Sun, Erich G. Rohwer, Ruru Deng, Rodanthi-Elisavet Mamouri, and Felix Zamorano
Atmos. Chem. Phys., 16, 5111–5137, https://doi.org/10.5194/acp-16-5111-2016, https://doi.org/10.5194/acp-16-5111-2016, 2016
Short summary
Short summary
The findings from more than 10 years of global aerosol lidar measurements with Polly systems are summarized, and a data set of optical properties for specific aerosol types is given. An automated data retrieval algorithm for continuous Polly lidar observations is presented and discussed by means of a Saharan dust advection event in Leipzig, Germany. Finally, a statistic on the vertical aerosol distribution including the seasonal variability at PollyNET locations around the globe is presented.
S. Kundu, K. Kawamura, M. Kobayashi, E. Tachibana, M. Lee, P. Q. Fu, and J. Jung
Atmos. Chem. Phys., 16, 585–596, https://doi.org/10.5194/acp-16-585-2016, https://doi.org/10.5194/acp-16-585-2016, 2016
Short summary
Short summary
Chemistry-transport models have predicted a change in secondary organic aerosols (SOA) in the future atmosphere with a large uncertainty. This study measures diacids, major water-soluble surrogates of SOA, on a sub-decadal scale in atmospheric aerosols in eastern Asia. Diacids are observed to increase by 3.9–47.4 % per year. The increases in the water-soluble organic acid fraction could modify the aerosol organic composition and its sensitivity to climate-relevant physical properties.
J. Han, B. Shin, M. Lee, G. Hwang, J. Kim, J. Shim, G. Lee, and C. Shim
Atmos. Chem. Phys., 15, 12611–12621, https://doi.org/10.5194/acp-15-12611-2015, https://doi.org/10.5194/acp-15-12611-2015, 2015
Short summary
Short summary
In east Asia, emissions of O3 precursors have gradually increased and O3 concentrations are expected to increase in the near future. Ieodo Ocean Research Station (IORS), located in the East China Sea, is a unique research tower suitable for observing continental outflows from east Asia. In this study, we present long-term measurements of O3 at IORS, describe their characteristic variations, and evaluate their continental influence on the regional background concentrations of O3.
S. Kim, S.-Y. Kim, M. Lee, H. Shim, G. M. Wolfe, A. B. Guenther, A. He, Y. Hong, and J. Han
Atmos. Chem. Phys., 15, 4357–4371, https://doi.org/10.5194/acp-15-4357-2015, https://doi.org/10.5194/acp-15-4357-2015, 2015
S. Lim, M. Lee, S.-W. Kim, S.-C. Yoon, G. Lee, and Y. J. Lee
Atmos. Chem. Phys., 14, 7781–7793, https://doi.org/10.5194/acp-14-7781-2014, https://doi.org/10.5194/acp-14-7781-2014, 2014
E. N. Kirillova, A. Andersson, J. Han, M. Lee, and Ö. Gustafsson
Atmos. Chem. Phys., 14, 1413–1422, https://doi.org/10.5194/acp-14-1413-2014, https://doi.org/10.5194/acp-14-1413-2014, 2014
Related subject area
Atmospheric sciences
Forecasting contrail climate forcing for flight planning and air traffic management applications: the CocipGrid model in pycontrails 0.51.0
Simulation of the heat mitigation potential of unsealing measures in cities by parameterizing grass grid pavers for urban microclimate modelling with ENVI-met (V5)
AI-NAOS: an AI-based nonspherical aerosol optical scheme for the chemical weather model GRAPES_Meso5.1/CUACE
Orbital-Radar v1.0.0: a tool to transform suborbital radar observations to synthetic EarthCARE cloud radar data
The Modular and Integrated Data Assimilation System at Environment and Climate Change Canada (MIDAS v3.9.1)
Modeling of polycyclic aromatic hydrocarbons (PAHs) from global to regional scales: model development (IAP-AACM_PAH v1.0) and investigation of health risks in 2013 and 2018 in China
LIMA (v2.0): A full two-moment cloud microphysical scheme for the mesoscale non-hydrostatic model Meso-NH v5-6
SLUCM+BEM (v1.0): a simple parameterisation for dynamic anthropogenic heat and electricity consumption in WRF-Urban (v4.3.2)
NAQPMS-PDAF v2.0: a novel hybrid nonlinear data assimilation system for improved simulation of PM2.5 chemical components
Source-specific bias correction of US background and anthropogenic ozone modeled in CMAQ
Observational operator for fair model evaluation with ground NO2 measurements
Valid time shifting ensemble Kalman filter (VTS-EnKF) for dust storm forecasting
An updated parameterization of the unstable atmospheric surface layer in the Weather Research and Forecasting (WRF) modeling system
The impact of cloud microphysics and ice nucleation on Southern Ocean clouds assessed with single-column modeling and instrument simulators
An updated aerosol simulation in the Community Earth System Model (v2.1.3): dust and marine aerosol emissions and secondary organic aerosol formation
Exploring ship track spreading rates with a physics-informed Langevin particle parameterization
Do data-driven models beat numerical models in forecasting weather extremes? A comparison of IFS HRES, Pangu-Weather, and GraphCast
Development of the MPAS-CMAQ coupled system (V1.0) for multiscale global air quality modeling
Assessment of object-based indices to identify convective organization
The Global Forest Fire Emissions Prediction System version 1.0
NEIVAv1.0: Next-generation Emissions InVentory expansion of Akagi et al. (2011) version 1.0
FLEXPART version 11: improved accuracy, efficiency, and flexibility
Challenges of high-fidelity air quality modeling in urban environments – PALM sensitivity study during stable conditions
Air quality modeling intercomparison and multiscale ensemble chain for Latin America
Recommended coupling to global meteorological fields for long-term tracer simulations with WRF-GHG
Selecting CMIP6 global climate models (GCMs) for Coordinated Regional Climate Downscaling Experiment (CORDEX) dynamical downscaling over Southeast Asia using a standardised benchmarking framework
Improved definition of prior uncertainties in CO2 and CO fossil fuel fluxes and its impact on multi-species inversion with GEOS-Chem (v12.5)
RASCAL v1.0: an open-source tool for climatological time series reconstruction and extension
Introducing graupel density prediction in Weather Research and Forecasting (WRF) double-moment 6-class (WDM6) microphysics and evaluation of the modified scheme during the ICE-POP field campaign
Enabling high-performance cloud computing for the Community Multiscale Air Quality Model (CMAQ) version 5.3.3: performance evaluation and benefits for the user community
Atmospheric-river-induced precipitation in California as simulated by the regionally refined Simple Convective Resolving E3SM Atmosphere Model (SCREAM) Version 0
Sensitivity of predicted ultrafine particle size distributions in Europe to different nucleation rate parameterizations using PMCAMx-UF v2.2
Recent improvements and maximum covariance analysis of aerosol and cloud properties in the EC-Earth3-AerChem model
GPU-HADVPPM4HIP V1.0: using the heterogeneous-compute interface for portability (HIP) to speed up the piecewise parabolic method in the CAMx (v6.10) air quality model on China's domestic GPU-like accelerator
Preliminary evaluation of the effect of electro-coalescence with conducting sphere approximation on the formation of warm cumulus clouds using SCALE-SDM version 0.2.5–2.3.0
Similarity-Based Analysis of Atmospheric Organic Compounds for Machine Learning Applications
Cell tracking -based framework for assessing nowcasting model skill in reproducing growth and decay of convective rainfall
Exploring the footprint representation of microwave radiance observations in an Arctic limited-area data assimilation system
Analysis of model error in forecast errors of extended atmospheric Lorenz 05 systems and the ECMWF system
Description and validation of Vehicular Emissions from Road Traffic (VERT) 1.0, an R-based framework for estimating road transport emissions from traffic flows
Improving the EnSRF in the Community Inversion Framework: a case study with ICON-ART 2024.01
AeroMix v1.0.1: a Python package for modeling aerosol optical properties and mixing states
Impact of ITCZ width on global climate: ITCZ-MIP
Deep-learning-driven simulations of boundary layer clouds over the Southern Great Plains
Mixed-precision computing in the GRIST dynamical core for weather and climate modelling
A conservative immersed boundary method for the multi-physics urban large-eddy simulation model uDALES v2.0
Accurate space-based NOx emission estimates with the flux divergence approach require fine-scale model information on local oxidation chemistry and profile shapes
RCEMIP-II: mock-Walker simulations as phase II of the radiative–convective equilibrium model intercomparison project
The MESSy DWARF (based on MESSy v2.55.2)
Objective identification of meteorological fronts and climatologies from ERA-Interim and ERA5
Zebediah Engberg, Roger Teoh, Tristan Abbott, Thomas Dean, Marc E. J. Stettler, and Marc L. Shapiro
Geosci. Model Dev., 18, 253–286, https://doi.org/10.5194/gmd-18-253-2025, https://doi.org/10.5194/gmd-18-253-2025, 2025
Short summary
Short summary
Contrails forming in some atmospheric conditions may persist and become strongly warming cirrus, while in other conditions may be neutral or cooling. We develop a contrail forecast model to predict contrail climate forcing for any arbitrary point in space and time and explore integration into flight planning and air traffic management. This approach enables contrail interventions to target high-probability high-climate-impact regions and reduce unintended consequences of contrail management.
Nils Eingrüber, Alina Domm, Wolfgang Korres, and Karl Schneider
Geosci. Model Dev., 18, 141–160, https://doi.org/10.5194/gmd-18-141-2025, https://doi.org/10.5194/gmd-18-141-2025, 2025
Short summary
Short summary
Climate change adaptation measures like unsealings can reduce urban heat stress. As grass grid pavers have never been parameterized for microclimate model simulations with ENVI-met, a new parameterization was developed based on field measurements. To analyse the cooling potential, scenario analyses were performed for a densely developed area in Cologne. Statistically significant average cooling effects of up to −11.1 K were found for surface temperature and up to −2.9 K for 1 m air temperature.
Xuan Wang, Lei Bi, Hong Wang, Yaqiang Wang, Wei Han, Xueshun Shen, and Xiaoye Zhang
Geosci. Model Dev., 18, 117–139, https://doi.org/10.5194/gmd-18-117-2025, https://doi.org/10.5194/gmd-18-117-2025, 2025
Short summary
Short summary
The Artificial-Intelligence-based Nonspherical Aerosol Optical Scheme (AI-NAOS) was developed to improve the estimation of the aerosol direct radiation effect and was coupled online with a chemical weather model. The AI-NAOS scheme considers black carbon as fractal aggregates and soil dust as super-spheroids, encapsulated with hygroscopic aerosols. Real-case simulations emphasize the necessity of accurately representing nonspherical and inhomogeneous aerosols in chemical weather models.
Lukas Pfitzenmaier, Pavlos Kollias, Nils Risse, Imke Schirmacher, Bernat Puigdomenech Treserras, and Katia Lamer
Geosci. Model Dev., 18, 101–115, https://doi.org/10.5194/gmd-18-101-2025, https://doi.org/10.5194/gmd-18-101-2025, 2025
Short summary
Short summary
The Python tool Orbital-Radar transfers suborbital radar data (ground-based, airborne, and forward-simulated numerical weather prediction model) into synthetic spaceborne cloud profiling radar data, mimicking platform-specific instrument characteristics, e.g. EarthCARE or CloudSat. The tool's novelty lies in simulating characteristic errors and instrument noise. Thus, existing data sets are transferred into synthetic observations and can be used for satellite calibration–validation studies.
Mark Buehner, Jean-Francois Caron, Ervig Lapalme, Alain Caya, Ping Du, Yves Rochon, Sergey Skachko, Maziar Bani Shahabadi, Sylvain Heilliette, Martin Deshaies-Jacques, Weiguang Chang, and Michael Sitwell
Geosci. Model Dev., 18, 1–18, https://doi.org/10.5194/gmd-18-1-2025, https://doi.org/10.5194/gmd-18-1-2025, 2025
Short summary
Short summary
The Modular and Integrated Data Assimilation System (MIDAS) software is described. The flexible design of MIDAS enables both deterministic and ensemble prediction applications for the atmosphere and several other Earth system components. It is currently used for all main operational weather prediction systems in Canada and also for sea ice and sea surface temperature analysis. The use of MIDAS for multiple Earth system components will facilitate future research on coupled data assimilation.
Zichen Wu, Xueshun Chen, Zifa Wang, Huansheng Chen, Zhe Wang, Qing Mu, Lin Wu, Wending Wang, Xiao Tang, Jie Li, Ying Li, Qizhong Wu, Yang Wang, Zhiyin Zou, and Zijian Jiang
Geosci. Model Dev., 17, 8885–8907, https://doi.org/10.5194/gmd-17-8885-2024, https://doi.org/10.5194/gmd-17-8885-2024, 2024
Short summary
Short summary
We developed a model to simulate polycyclic aromatic hydrocarbons (PAHs) from global to regional scales. The model can reproduce PAH distribution well. The concentration of BaP (indicator species for PAHs) could exceed the target values of 1 ng m-3 over some areas (e.g., in central Europe, India, and eastern China). The change in BaP is lower than that in PM2.5 from 2013 to 2018. China still faces significant potential health risks posed by BaP although the Action Plan has been implemented.
Marie Taufour, Jean-Pierre Pinty, Christelle Barthe, Benoît Vié, and Chien Wang
Geosci. Model Dev., 17, 8773–8798, https://doi.org/10.5194/gmd-17-8773-2024, https://doi.org/10.5194/gmd-17-8773-2024, 2024
Short summary
Short summary
We have developed a complete two-moment version of the LIMA (Liquid Ice Multiple Aerosols) microphysics scheme. We have focused on collection processes, where the hydrometeor number transfer is often estimated in proportion to the mass transfer. The impact of these parameterizations on a convective system and the prospects for more realistic estimates of secondary parameters (reflectivity, hydrometeor size) are shown in a first test on an idealized case.
Yuya Takane, Yukihiro Kikegawa, Ko Nakajima, and Hiroyuki Kusaka
Geosci. Model Dev., 17, 8639–8664, https://doi.org/10.5194/gmd-17-8639-2024, https://doi.org/10.5194/gmd-17-8639-2024, 2024
Short summary
Short summary
A new parameterisation for dynamic anthropogenic heat and electricity consumption is described. The model reproduced the temporal variation in and spatial distributions of electricity consumption and temperature well in summer and winter. The partial air conditioning was the most critical factor, significantly affecting the value of anthropogenic heat emission.
Hongyi Li, Ting Yang, Lars Nerger, Dawei Zhang, Di Zhang, Guigang Tang, Haibo Wang, Yele Sun, Pingqing Fu, Hang Su, and Zifa Wang
Geosci. Model Dev., 17, 8495–8519, https://doi.org/10.5194/gmd-17-8495-2024, https://doi.org/10.5194/gmd-17-8495-2024, 2024
Short summary
Short summary
To accurately characterize the spatiotemporal distribution of particulate matter <2.5 µm chemical components, we developed the Nested Air Quality Prediction Model System with the Parallel Data Assimilation Framework (NAQPMS-PDAF) v2.0 for chemical components with non-Gaussian and nonlinear properties. NAQPMS-PDAF v2.0 has better computing efficiency, excels when used with a small ensemble size, and can significantly improve the simulation performance of chemical components.
T. Nash Skipper, Christian Hogrefe, Barron H. Henderson, Rohit Mathur, Kristen M. Foley, and Armistead G. Russell
Geosci. Model Dev., 17, 8373–8397, https://doi.org/10.5194/gmd-17-8373-2024, https://doi.org/10.5194/gmd-17-8373-2024, 2024
Short summary
Short summary
Chemical transport model simulations are combined with ozone observations to estimate the bias in ozone attributable to US anthropogenic sources and individual sources of US background ozone: natural sources, non-US anthropogenic sources, and stratospheric ozone. Results indicate a positive bias correlated with US anthropogenic emissions during summer in the eastern US and a negative bias correlated with stratospheric ozone during spring.
Li Fang, Jianbing Jin, Arjo Segers, Ke Li, Ji Xia, Wei Han, Baojie Li, Hai Xiang Lin, Lei Zhu, Song Liu, and Hong Liao
Geosci. Model Dev., 17, 8267–8282, https://doi.org/10.5194/gmd-17-8267-2024, https://doi.org/10.5194/gmd-17-8267-2024, 2024
Short summary
Short summary
Model evaluations against ground observations are usually unfair. The former simulates mean status over coarse grids and the latter the surrounding atmosphere. To solve this, we proposed the new land-use-based representative (LUBR) operator that considers intra-grid variance. The LUBR operator is validated to provide insights that align with satellite measurements. The results highlight the importance of considering fine-scale urban–rural differences when comparing models and observation.
Mijie Pang, Jianbing Jin, Arjo Segers, Huiya Jiang, Wei Han, Batjargal Buyantogtokh, Ji Xia, Li Fang, Jiandong Li, Hai Xiang Lin, and Hong Liao
Geosci. Model Dev., 17, 8223–8242, https://doi.org/10.5194/gmd-17-8223-2024, https://doi.org/10.5194/gmd-17-8223-2024, 2024
Short summary
Short summary
The ensemble Kalman filter (EnKF) improves dust storm forecasts but faces challenges with position errors. The valid time shifting EnKF (VTS-EnKF) addresses this by adjusting for position errors, enhancing accuracy in forecasting dust storms, as proven in tests on 2021 events, even with smaller ensembles and time intervals.
Prabhakar Namdev, Maithili Sharan, Piyush Srivastava, and Saroj Kanta Mishra
Geosci. Model Dev., 17, 8093–8114, https://doi.org/10.5194/gmd-17-8093-2024, https://doi.org/10.5194/gmd-17-8093-2024, 2024
Short summary
Short summary
Inadequate representation of surface–atmosphere interaction processes is a major source of uncertainty in numerical weather prediction models. Here, an effort has been made to improve the Weather Research and Forecasting (WRF) model version 4.2.2 by introducing a unique theoretical framework under convective conditions. In addition, to enhance the potential applicability of the WRF modeling system, various commonly used similarity functions under convective conditions have also been installed.
Andrew Gettelman, Richard Forbes, Roger Marchand, Chih-Chieh Chen, and Mark Fielding
Geosci. Model Dev., 17, 8069–8092, https://doi.org/10.5194/gmd-17-8069-2024, https://doi.org/10.5194/gmd-17-8069-2024, 2024
Short summary
Short summary
Supercooled liquid clouds (liquid clouds colder than 0°C) are common at higher latitudes (especially over the Southern Ocean) and are critical for constraining climate projections. We compare a single-column version of a weather model to observations with two different cloud schemes and find that both the dynamical environment and atmospheric aerosols are important for reproducing observations.
Yujuan Wang, Peng Zhang, Jie Li, Yaman Liu, Yanxu Zhang, Jiawei Li, and Zhiwei Han
Geosci. Model Dev., 17, 7995–8021, https://doi.org/10.5194/gmd-17-7995-2024, https://doi.org/10.5194/gmd-17-7995-2024, 2024
Short summary
Short summary
This study updates the CESM's aerosol schemes, focusing on dust, marine aerosol emissions, and secondary organic aerosol (SOA) . Dust emission modifications make deflation areas more continuous, improving results in North America and the sub-Arctic. Humidity correction to sea-salt emissions has a minor effect. Introducing marine organic aerosol emissions, coupled with ocean biogeochemical processes, and adding aqueous reactions for SOA formation advance the CESM's aerosol modelling results.
Lucas A. McMichael, Michael J. Schmidt, Robert Wood, Peter N. Blossey, and Lekha Patel
Geosci. Model Dev., 17, 7867–7888, https://doi.org/10.5194/gmd-17-7867-2024, https://doi.org/10.5194/gmd-17-7867-2024, 2024
Short summary
Short summary
Marine cloud brightening (MCB) is a climate intervention technique to potentially cool the climate. Climate models used to gauge regional climate impacts associated with MCB often assume large areas of the ocean are uniformly perturbed. However, a more realistic representation of MCB application would require information about how an injected particle plume spreads. This work aims to develop such a plume-spreading model.
Leonardo Olivetti and Gabriele Messori
Geosci. Model Dev., 17, 7915–7962, https://doi.org/10.5194/gmd-17-7915-2024, https://doi.org/10.5194/gmd-17-7915-2024, 2024
Short summary
Short summary
Data-driven models are becoming a viable alternative to physics-based models for weather forecasting up to 15 d into the future. However, it is unclear whether they are as reliable as physics-based models when forecasting weather extremes. We evaluate their performance in forecasting near-surface cold, hot, and windy extremes globally. We find that data-driven models can compete with physics-based models and that the choice of the best model mainly depends on the region and type of extreme.
David C. Wong, Jeff Willison, Jonathan E. Pleim, Golam Sarwar, James Beidler, Russ Bullock, Jerold A. Herwehe, Rob Gilliam, Daiwen Kang, Christian Hogrefe, George Pouliot, and Hosein Foroutan
Geosci. Model Dev., 17, 7855–7866, https://doi.org/10.5194/gmd-17-7855-2024, https://doi.org/10.5194/gmd-17-7855-2024, 2024
Short summary
Short summary
This work describe how we linked the meteorological Model for Prediction Across Scales – Atmosphere (MPAS-A) with the Community Multiscale Air Quality (CMAQ) air quality model to form a coupled modelling system. This could be used to study air quality or climate and air quality interaction at a global scale. This new model scales well in high-performance computing environments and performs well with respect to ground surface networks in terms of ozone and PM2.5.
Giulio Mandorli and Claudia J. Stubenrauch
Geosci. Model Dev., 17, 7795–7813, https://doi.org/10.5194/gmd-17-7795-2024, https://doi.org/10.5194/gmd-17-7795-2024, 2024
Short summary
Short summary
In recent years, several studies focused their attention on the disposition of convection. Lots of methods, called indices, have been developed to quantify the amount of convection clustering. These indices are evaluated in this study by defining criteria that must be satisfied and then evaluating the indices against these standards. None of the indices meet all criteria, with some only partially meeting them.
Kerry Anderson, Jack Chen, Peter Englefield, Debora Griffin, Paul A. Makar, and Dan Thompson
Geosci. Model Dev., 17, 7713–7749, https://doi.org/10.5194/gmd-17-7713-2024, https://doi.org/10.5194/gmd-17-7713-2024, 2024
Short summary
Short summary
The Global Forest Fire Emissions Prediction System (GFFEPS) is a model that predicts smoke and carbon emissions from wildland fires. The model calculates emissions from the ground up based on satellite-detected fires, modelled weather and fire characteristics. Unlike other global models, GFFEPS uses daily weather conditions to capture changing burning conditions on a day-to-day basis. GFFEPS produced lower carbon emissions due to the changing weather not captured by the other models.
Samiha Binte Shahid, Forrest G. Lacey, Christine Wiedinmyer, Robert J. Yokelson, and Kelley C. Barsanti
Geosci. Model Dev., 17, 7679–7711, https://doi.org/10.5194/gmd-17-7679-2024, https://doi.org/10.5194/gmd-17-7679-2024, 2024
Short summary
Short summary
The Next-generation Emissions InVentory expansion of Akagi (NEIVA) v.1.0 is a comprehensive biomass burning emissions database that allows integration of new data and flexible querying. Data are stored in connected datasets, including recommended averages of ~1500 constituents for 14 globally relevant fire types. Individual compounds were mapped to common model species to allow better attribution of emissions in modeling studies that predict the effects of fires on air quality and climate.
Lucie Bakels, Daria Tatsii, Anne Tipka, Rona Thompson, Marina Dütsch, Michael Blaschek, Petra Seibert, Katharina Baier, Silvia Bucci, Massimo Cassiani, Sabine Eckhardt, Christine Groot Zwaaftink, Stephan Henne, Pirmin Kaufmann, Vincent Lechner, Christian Maurer, Marie D. Mulder, Ignacio Pisso, Andreas Plach, Rakesh Subramanian, Martin Vojta, and Andreas Stohl
Geosci. Model Dev., 17, 7595–7627, https://doi.org/10.5194/gmd-17-7595-2024, https://doi.org/10.5194/gmd-17-7595-2024, 2024
Short summary
Short summary
Computer models are essential for improving our understanding of how gases and particles move in the atmosphere. We present an update of the atmospheric transport model FLEXPART. FLEXPART 11 is more accurate due to a reduced number of interpolations and a new scheme for wet deposition. It can simulate non-spherical aerosols and includes linear chemical reactions. It is parallelised using OpenMP and includes new user options. A new user manual details how to use FLEXPART 11.
Jaroslav Resler, Petra Bauerová, Michal Belda, Martin Bureš, Kryštof Eben, Vladimír Fuka, Jan Geletič, Radek Jareš, Jan Karel, Josef Keder, Pavel Krč, William Patiño, Jelena Radović, Hynek Řezníček, Matthias Sühring, Adriana Šindelářová, and Ondřej Vlček
Geosci. Model Dev., 17, 7513–7537, https://doi.org/10.5194/gmd-17-7513-2024, https://doi.org/10.5194/gmd-17-7513-2024, 2024
Short summary
Short summary
Detailed modeling of urban air quality in stable conditions is a challenge. We show the unprecedented sensitivity of a large eddy simulation (LES) model to meteorological boundary conditions and model parameters in an urban environment under stable conditions. We demonstrate the crucial role of boundary conditions for the comparability of results with observations. The study reveals a strong sensitivity of the results to model parameters and model numerical instabilities during such conditions.
Jorge E. Pachón, Mariel A. Opazo, Pablo Lichtig, Nicolas Huneeus, Idir Bouarar, Guy Brasseur, Cathy W. Y. Li, Johannes Flemming, Laurent Menut, Camilo Menares, Laura Gallardo, Michael Gauss, Mikhail Sofiev, Rostislav Kouznetsov, Julia Palamarchuk, Andreas Uppstu, Laura Dawidowski, Nestor Y. Rojas, María de Fátima Andrade, Mario E. Gavidia-Calderón, Alejandro H. Delgado Peralta, and Daniel Schuch
Geosci. Model Dev., 17, 7467–7512, https://doi.org/10.5194/gmd-17-7467-2024, https://doi.org/10.5194/gmd-17-7467-2024, 2024
Short summary
Short summary
Latin America (LAC) has some of the most populated urban areas in the world, with high levels of air pollution. Air quality management in LAC has been traditionally focused on surveillance and building emission inventories. This study performed the first intercomparison and model evaluation in LAC, with interesting and insightful findings for the region. A multiscale modeling ensemble chain was assembled as a first step towards an air quality forecasting system.
David Ho, Michał Gałkowski, Friedemann Reum, Santiago Botía, Julia Marshall, Kai Uwe Totsche, and Christoph Gerbig
Geosci. Model Dev., 17, 7401–7422, https://doi.org/10.5194/gmd-17-7401-2024, https://doi.org/10.5194/gmd-17-7401-2024, 2024
Short summary
Short summary
Atmospheric model users often overlook the impact of the land–atmosphere interaction. This study accessed various setups of WRF-GHG simulations that ensure consistency between the model and driving reanalysis fields. We found that a combination of nudging and frequent re-initialization allows certain improvement by constraining the soil moisture fields and, through its impact on atmospheric mixing, improves atmospheric transport.
Phuong Loan Nguyen, Lisa V. Alexander, Marcus J. Thatcher, Son C. H. Truong, Rachael N. Isphording, and John L. McGregor
Geosci. Model Dev., 17, 7285–7315, https://doi.org/10.5194/gmd-17-7285-2024, https://doi.org/10.5194/gmd-17-7285-2024, 2024
Short summary
Short summary
We use a comprehensive approach to select a subset of CMIP6 models for dynamical downscaling over Southeast Asia, taking into account model performance, model independence, data availability and the range of future climate projections. The standardised benchmarking framework is applied to assess model performance through both statistical and process-based metrics. Ultimately, we identify two independent model groups that are suitable for dynamical downscaling in the Southeast Asian region.
Ingrid Super, Tia Scarpelli, Arjan Droste, and Paul I. Palmer
Geosci. Model Dev., 17, 7263–7284, https://doi.org/10.5194/gmd-17-7263-2024, https://doi.org/10.5194/gmd-17-7263-2024, 2024
Short summary
Short summary
Monitoring greenhouse gas emission reductions requires a combination of models and observations, as well as an initial emission estimate. Each component provides information with a certain level of certainty and is weighted to yield the most reliable estimate of actual emissions. We describe efforts for estimating the uncertainty in the initial emission estimate, which significantly impacts the outcome. Hence, a good uncertainty estimate is key for obtaining reliable information on emissions.
Álvaro González-Cervera and Luis Durán
Geosci. Model Dev., 17, 7245–7261, https://doi.org/10.5194/gmd-17-7245-2024, https://doi.org/10.5194/gmd-17-7245-2024, 2024
Short summary
Short summary
RASCAL is an open-source Python tool designed for reconstructing daily climate observations, especially in regions with complex local phenomena. It merges large-scale weather patterns with local weather using the analog method. Evaluations in central Spain show that RASCAL outperforms ERA20C reanalysis in reconstructing precipitation and temperature. RASCAL offers opportunities for broad scientific applications, from short-term forecasts to local-scale climate change scenarios.
Sun-Young Park, Kyo-Sun Sunny Lim, Kwonil Kim, Gyuwon Lee, and Jason A. Milbrandt
Geosci. Model Dev., 17, 7199–7218, https://doi.org/10.5194/gmd-17-7199-2024, https://doi.org/10.5194/gmd-17-7199-2024, 2024
Short summary
Short summary
We enhance the WDM6 scheme by incorporating predicted graupel density. The modification affects graupel characteristics, including fall velocity–diameter and mass–diameter relationships. Simulations highlight changes in graupel distribution and precipitation patterns, potentially influencing surface snow amounts. The study underscores the significance of integrating predicted graupel density for a more realistic portrayal of microphysical properties in weather models.
Christos I. Efstathiou, Elizabeth Adams, Carlie J. Coats, Robert Zelt, Mark Reed, John McGee, Kristen M. Foley, Fahim I. Sidi, David C. Wong, Steven Fine, and Saravanan Arunachalam
Geosci. Model Dev., 17, 7001–7027, https://doi.org/10.5194/gmd-17-7001-2024, https://doi.org/10.5194/gmd-17-7001-2024, 2024
Short summary
Short summary
We present a summary of enabling high-performance computing of the Community Multiscale Air Quality Model (CMAQ) – a state-of-the-science community multiscale air quality model – on two cloud computing platforms through documenting the technologies, model performance, scaling and relative merits. This may be a new paradigm for computationally intense future model applications. We initiated this work due to a need to leverage cloud computing advances and to ease the learning curve for new users.
Peter A. Bogenschutz, Jishi Zhang, Qi Tang, and Philip Cameron-Smith
Geosci. Model Dev., 17, 7029–7050, https://doi.org/10.5194/gmd-17-7029-2024, https://doi.org/10.5194/gmd-17-7029-2024, 2024
Short summary
Short summary
Using high-resolution and state-of-the-art modeling techniques we simulate five atmospheric river events for California to test the capability to represent precipitation for these events. We find that our model is able to capture the distribution of precipitation very well but suffers from overestimating the precipitation amounts over high elevation. Increasing the resolution further has no impact on reducing this bias, while increasing the domain size does have modest impacts.
David Patoulias, Kalliopi Florou, and Spyros N. Pandis
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2024-145, https://doi.org/10.5194/gmd-2024-145, 2024
Revised manuscript accepted for GMD
Short summary
Short summary
The effect of the assumed atmospheric nucleation mechanism on particle number concentrations and size distribution was investigated. Two quite different mechanisms involving sulfuric acid and ammonia or a biogenic organic vapor gave quite similar results which were consistent with measurements in 26 measurement stations across Europe. The number of larger particles that serve as cloud condensation nuclei showed little sensitivity to the assumed nucleation mechanism.
Manu Anna Thomas, Klaus Wyser, Shiyu Wang, Marios Chatziparaschos, Paraskevi Georgakaki, Montserrat Costa-Surós, Maria Gonçalves Ageitos, Maria Kanakidou, Carlos Pérez García-Pando, Athanasios Nenes, Twan van Noije, Philippe Le Sager, and Abhay Devasthale
Geosci. Model Dev., 17, 6903–6927, https://doi.org/10.5194/gmd-17-6903-2024, https://doi.org/10.5194/gmd-17-6903-2024, 2024
Short summary
Short summary
Aerosol–cloud interactions occur at a range of spatio-temporal scales. While evaluating recent developments in EC-Earth3-AerChem, this study aims to understand the extent to which the Twomey effect manifests itself at larger scales. We find a reduction in the warm bias over the Southern Ocean due to model improvements. While we see footprints of the Twomey effect at larger scales, the negative relationship between cloud droplet number and liquid water drives the shortwave radiative effect.
Kai Cao, Qizhong Wu, Lingling Wang, Hengliang Guo, Nan Wang, Huaqiong Cheng, Xiao Tang, Dongxing Li, Lina Liu, Dongqing Li, Hao Wu, and Lanning Wang
Geosci. Model Dev., 17, 6887–6901, https://doi.org/10.5194/gmd-17-6887-2024, https://doi.org/10.5194/gmd-17-6887-2024, 2024
Short summary
Short summary
AMD’s heterogeneous-compute interface for portability was implemented to port the piecewise parabolic method solver from NVIDIA GPUs to China's GPU-like accelerators. The results show that the larger the model scale, the more acceleration effect on the GPU-like accelerator, up to 28.9 times. The multi-level parallelism achieves a speedup of 32.7 times on the heterogeneous cluster. By comparing the results, the GPU-like accelerators have more accuracy for the geoscience numerical models.
Ruyi Zhang, Limin Zhou, Shin-ichiro Shima, and Huawei Yang
Geosci. Model Dev., 17, 6761–6774, https://doi.org/10.5194/gmd-17-6761-2024, https://doi.org/10.5194/gmd-17-6761-2024, 2024
Short summary
Short summary
Solar activity weakly ionises Earth's atmosphere, charging cloud droplets. Electro-coalescence is when oppositely charged droplets stick together. We introduce an analytical expression of electro-coalescence probability and use it in a warm-cumulus-cloud simulation. Results show that charge cases increase rain and droplet size, with the new method outperforming older ones. The new method requires longer computation time, but its impact on rain justifies inclusion in meteorology models.
Hilda Sandström and Patrick Rinke
EGUsphere, https://doi.org/10.48550/arXiv.2406.18171, https://doi.org/10.48550/arXiv.2406.18171, 2024
Short summary
Short summary
Machine learning has the potential to aid the identification organic molecules involved in aerosol formation. Yet, progress is stalled by a lack of curated atmospheric molecular datasets. Here, we compared atmospheric compounds with large molecular datasets used in machine learning and found minimal overlap with similarity algorithms. Our result underlines the need for collaborative efforts to curate atmospheric molecular data to facilitate machine learning model in atmospheric sciences.
Jenna Ritvanen, Seppo Pulkkinen, Dmitri Moisseev, and Daniele Nerini
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2024-99, https://doi.org/10.5194/gmd-2024-99, 2024
Revised manuscript accepted for GMD
Short summary
Short summary
Nowcasting models struggle with the rapid evolution of heavy rain, and common verification methods are unable to describe how accurately the models predict the growth and decay of heavy rainfall. We propose a framework to assess model performance. In the framework, convective cells are identified and tracked in the forecasts and observations, and then the model skill is evaluated by comparing differences between forecast and observed cells. We demonstrate the framework with 4 open-source models.
Máté Mile, Stephanie Guedj, and Roger Randriamampianina
Geosci. Model Dev., 17, 6571–6587, https://doi.org/10.5194/gmd-17-6571-2024, https://doi.org/10.5194/gmd-17-6571-2024, 2024
Short summary
Short summary
Satellite observations provide crucial information about atmospheric constituents in a global distribution that helps to better predict the weather over sparsely observed regions like the Arctic. However, the use of satellite data is usually conservative and imperfect. In this study, a better spatial representation of satellite observations is discussed and explored by a so-called footprint function or operator, highlighting its added value through a case study and diagnostics.
Hynek Bednář and Holger Kantz
Geosci. Model Dev., 17, 6489–6511, https://doi.org/10.5194/gmd-17-6489-2024, https://doi.org/10.5194/gmd-17-6489-2024, 2024
Short summary
Short summary
The forecast error growth of atmospheric phenomena is caused by initial and model errors. When studying the initial error growth, it may turn out that small-scale phenomena, which contribute little to the forecast product, significantly affect the ability to predict this product. With a negative result, we investigate in the extended Lorenz (2005) system whether omitting these phenomena will improve predictability. A theory explaining and describing this behavior is developed.
Giorgio Veratti, Alessandro Bigi, Sergio Teggi, and Grazia Ghermandi
Geosci. Model Dev., 17, 6465–6487, https://doi.org/10.5194/gmd-17-6465-2024, https://doi.org/10.5194/gmd-17-6465-2024, 2024
Short summary
Short summary
In this study, we present VERT (Vehicular Emissions from Road Traffic), an R package designed to estimate transport emissions using traffic estimates and vehicle fleet composition data. Compared to other tools available in the literature, VERT stands out for its user-friendly configuration and flexibility of user input. Case studies demonstrate its accuracy in both urban and regional contexts, making it a valuable tool for air quality management and transport scenario planning.
Joël Thanwerdas, Antoine Berchet, Lionel Constantin, Aki Tsuruta, Michael Steiner, Friedemann Reum, Stephan Henne, and Dominik Brunner
EGUsphere, https://doi.org/10.5194/egusphere-2024-2197, https://doi.org/10.5194/egusphere-2024-2197, 2024
Short summary
Short summary
The Community Inversion Framework (CIF) brings together methods for estimating greenhouse gas fluxes from atmospheric observations. The initial ensemble method implemented in CIF was found to be incomplete and could hardly be compared to other ensemble methods employed in the inversion community. In this paper, we present and evaluate a more efficient implementation of the serial and batch versions of the Ensemble Square Root Filter (EnSRF) algorithm in CIF.
Sam P. Raj, Puna Ram Sinha, Rohit Srivastava, Srinivas Bikkina, and Damu Bala Subrahamanyam
Geosci. Model Dev., 17, 6379–6399, https://doi.org/10.5194/gmd-17-6379-2024, https://doi.org/10.5194/gmd-17-6379-2024, 2024
Short summary
Short summary
A Python successor to the aerosol module of the OPAC model, named AeroMix, has been developed, with enhanced capabilities to better represent real atmospheric aerosol mixing scenarios. AeroMix’s performance in modeling aerosol mixing states has been evaluated against field measurements, substantiating its potential as a versatile aerosol optical model framework for next-generation algorithms to infer aerosol mixing states and chemical composition.
Angeline G. Pendergrass, Michael P. Byrne, Oliver Watt-Meyer, Penelope Maher, and Mark J. Webb
Geosci. Model Dev., 17, 6365–6378, https://doi.org/10.5194/gmd-17-6365-2024, https://doi.org/10.5194/gmd-17-6365-2024, 2024
Short summary
Short summary
The width of the tropical rain belt affects many aspects of our climate, yet we do not understand what controls it. To better understand it, we present a method to change it in numerical model experiments. We show that the method works well in four different models. The behavior of the width is unexpectedly simple in some ways, such as how strong the winds are as it changes, but in other ways, it is more complicated, especially how temperature increases with carbon dioxide.
Tianning Su and Yunyan Zhang
Geosci. Model Dev., 17, 6319–6336, https://doi.org/10.5194/gmd-17-6319-2024, https://doi.org/10.5194/gmd-17-6319-2024, 2024
Short summary
Short summary
Using 2 decades of field observations over the Southern Great Plains, this study developed a deep-learning model to simulate the complex dynamics of boundary layer clouds. The deep-learning model can serve as the cloud parameterization within reanalysis frameworks, offering insights into improving the simulation of low clouds. By quantifying biases due to various meteorological factors and parameterizations, this deep-learning-driven approach helps bridge the observation–modeling divide.
Siyuan Chen, Yi Zhang, Yiming Wang, Zhuang Liu, Xiaohan Li, and Wei Xue
Geosci. Model Dev., 17, 6301–6318, https://doi.org/10.5194/gmd-17-6301-2024, https://doi.org/10.5194/gmd-17-6301-2024, 2024
Short summary
Short summary
This study explores strategies and techniques for implementing mixed-precision code optimization within an atmosphere model dynamical core. The coded equation terms in the governing equations that are sensitive (or insensitive) to the precision level have been identified. The performance of mixed-precision computing in weather and climate simulations was analyzed.
Sam O. Owens, Dipanjan Majumdar, Chris E. Wilson, Paul Bartholomew, and Maarten van Reeuwijk
Geosci. Model Dev., 17, 6277–6300, https://doi.org/10.5194/gmd-17-6277-2024, https://doi.org/10.5194/gmd-17-6277-2024, 2024
Short summary
Short summary
Designing cities that are resilient, sustainable, and beneficial to health requires an understanding of urban climate and air quality. This article presents an upgrade to the multi-physics numerical model uDALES, which can simulate microscale airflow, heat transfer, and pollutant dispersion in urban environments. This upgrade enables it to resolve realistic urban geometries more accurately and to take advantage of the resources available on current and future high-performance computing systems.
Felipe Cifuentes, Henk Eskes, Folkert Boersma, Enrico Dammers, and Charlotte Bryan
EGUsphere, https://doi.org/10.5194/egusphere-2024-2225, https://doi.org/10.5194/egusphere-2024-2225, 2024
Short summary
Short summary
We tested the capability of the flux divergence approach (FDA) to reproduce known NOX emissions using synthetic NO2 satellite column retrievals derived from high-resolution model simulations. The FDA accurately reproduced NOX emissions when column observations were limited to the boundary layer and when the variability of NO2 lifetime, NOX:NO2 ratio, and NO2 profile shapes were correctly modeled. This introduces a strong model dependency, reducing the simplicity of the original FDA formulation.
Allison A. Wing, Levi G. Silvers, and Kevin A. Reed
Geosci. Model Dev., 17, 6195–6225, https://doi.org/10.5194/gmd-17-6195-2024, https://doi.org/10.5194/gmd-17-6195-2024, 2024
Short summary
Short summary
This paper presents the experimental design for a model intercomparison project to study tropical clouds and climate. It is a follow-up from a prior project that used a simplified framework for tropical climate. The new project adds one new component – a specified pattern of sea surface temperatures as the lower boundary condition. We provide example results from one cloud-resolving model and one global climate model and test the sensitivity to the experimental parameters.
Astrid Kerkweg, Timo Kirfel, Doung H. Do, Sabine Griessbach, Patrick Jöckel, and Domenico Taraborrelli
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2024-117, https://doi.org/10.5194/gmd-2024-117, 2024
Revised manuscript accepted for GMD
Short summary
Short summary
This article introduces the MESSy DWARF. Usually, the Modular Earth Submodel System (MESSy) is linked to full dynamical models to build chemistry climate models. However, due to the modular concept of MESSy, and the newly developed DWARF component, it is now possible to create simplified models containing just one or some process descriptions. This renders very useful for technical optimisation (e.g., GPU porting) and can be used to create less complex models, e.g., a chemical box model.
Philip G. Sansom and Jennifer L. Catto
Geosci. Model Dev., 17, 6137–6151, https://doi.org/10.5194/gmd-17-6137-2024, https://doi.org/10.5194/gmd-17-6137-2024, 2024
Short summary
Short summary
Weather fronts bring a lot of rain and strong winds to many regions of the mid-latitudes. We have developed an updated method of identifying these fronts in gridded data that can be used on new datasets with small grid spacing. The method can be easily applied to different datasets due to the use of open-source software for its development and shows improvements over similar previous methods. We present an updated estimate of the average frequency of fronts over the past 40 years.
Cited articles
Akimoto, H. and Tanimoto, H.: Review of Comprehensive Measurements of
Speciated NOy and its Chemistry: Need for Quantifying the Role of
Heterogeneous Processes of HNO3 and HONO, Aerosol Air Qual. Res., 21, 200395, https://doi.org/10.4209/aaqr.2020.07.0395,
2021.
Akimoto, H., Nagashima, T., Li, J., Fu, J. S., Ji, D., Tan, J., and Wang, Z.: Comparison of surface ozone simulation among selected regional models in MICS-Asia III – effects of chemistry and vertical transport for the causes of difference, Atmos. Chem. Phys., 19, 603–615, https://doi.org/10.5194/acp-19-603-2019, 2019.
Anderson, D. C., Loughner, C. P., Diskin, G., Weinheimer, A., Canty, T. P.,
Salawitch, R. J., Worden, H. M., Fried, A., Mikoviny, T., and Wisthaler, A.:
Measured and modeled CO and NOy in DISCOVER-AQ: An evaluation of emissions
and chemistry over the eastern US, Atmos. Environ., 96, 78–87, 2014.
Appel, K. W., Bash, J. O., Fahey, K. M., Foley, K. M., Gilliam, R. C., Hogrefe, C., Hutzell, W. T., Kang, D., Mathur, R., Murphy, B. N., Napelenok, S. L., Nolte, C. G., Pleim, J. E., Pouliot, G. A., Pye, H. O. T., Ran, L., Roselle, S. J., Sarwar, G., Schwede, D. B., Sidi, F. I., Spero, T. L., and Wong, D. C.: The Community Multiscale Air Quality (CMAQ) model versions 5.3 and 5.3.1: system updates and evaluation, Geosci. Model Dev., 14, 2867–2897, https://doi.org/10.5194/gmd-14-2867-2021, 2021.
Arcomano, T., Szunyogh, I., Wikner, A., Pathak, J., Hunt, B. R., and Ott,
E.: A Hybrid Approach to Atmospheric Modeling that Combines Machine Learning
with a Physics-Based Numerical Model, J. Adv. Model. Earth Sy., 14, e2021MS002712, https://doi.org/10.1029/2021MS002712,
2021.
Armante, R., Perrin, A., Kwabia Tchana, F., and Manceron, L.: The ν4 bands at 11 µm: linelists for the Trans- and Cis- conformer forms of nitrous acid (HONO) in the 2019 version of the GEISA database, Mol. Phys., 120,
e1951860, https://doi.org/10.1080/00268976.2021.1951860, 2021.
Arnell, N. W., Lowe, J. A., Challinor, A. J., and Osborn, T. J.: Global and
regional impacts of climate change at different levels of global temperature
increase, Climatic Change, 155, 377–391, 2019.
Baek, W.-K. and Jung, H.-S.: Performance Comparison of Oil Spill and Ship
Classification from X-Band Dual-and Single-Polarized SAR Image Using Support
Vector Machine, Random Forest, and Deep Neural Network, Remote Sens.-Basel,
13, 3203, https://doi.org/10.3390/rs13163203, 2021.
Bao, F., Cheng, Y., Kuhn, U., Li, G., Wang, W., Kratz, A. M., Weber, J.,
Weber, B., Pöschl, U., and Su, H.: Key Role of
Equilibrium HONO Concentration over Soil in Quantifying Soil–Atmosphere
HONO Fluxes, Environ. Sci. Technol., 56, 2204–2212, 2022.
Bengio, Y. and Grandvalet, Y.: No unbiased estimator of the variance of
K-fold cross-validation, in: Advances in Neural Information Processing Systems, vol. 16, edited by: Thrun, S., Saul, L., and Schölkopf, B., MIT Press, https://proceedings.neurips.cc/paper/2003/hash/e82c4b19b8151ddc25d4d93baf7b908f-Abstract.html, last access: 11 September 2003.
Bloss, W. J., Kramer, L., Crilley, L. R., Vu, T., Harrison, R. M., Shi, Z.,
Lee, J. D., Squires, F. A., Whalley, L. K., and Slater, E.: Insights into
air pollution chemistry and sulphate formation from nitrous acid (HONO)
measurements during haze events in Beijing, Faraday Discuss., 226, 223–238,
2021.
Brown, S. S., An, H., Lee, M., Park, J.-H., Lee, S.-D., Fibiger, D. L.,
McDuffie, E. E., Dubé, W. P., Wagner, N. L., and Min, K.-E.: Cavity
enhanced spectroscopy for measurement of nitrogen oxides in the
Anthropocene: results from the Seoul tower during MAPS 2015, Faraday Discuss., 200, 529–557, 2017.
Canty, T. P., Hembeck, L., Vinciguerra, T. P., Anderson, D. C., Goldberg, D. L., Carpenter, S. F., Allen, D. J., Loughner, C. P., Salawitch, R. J., and Dickerson, R. R.: Ozone and NOx chemistry in the eastern US: evaluation of CMAQ/CB05 with satellite (OMI) data, Atmos. Chem. Phys., 15, 10965–10982, https://doi.org/10.5194/acp-15-10965-2015, 2015.
Chen, G., Li, S., Knibbs, L. D., Hamm, N. A., Cao, W., Li, T., Guo, J., Ren,
H., Abramson, M. J., and Guo, Y.: A machine learning method to estimate PM2.
5 concentrations across China with remote sensing, meteorological and land
use information, Sci. Total Environ., 636, 52–60, 2018.
Chen, Y., Wolke, R., Ran, L., Birmili, W., Spindler, G., Schröder, W., Su, H., Cheng, Y., Tegen, I., and Wiedensohler, A.: A parameterization of the heterogeneous hydrolysis of N2O5 for mass-based aerosol models: improvement of particulate nitrate prediction, Atmos. Chem. Phys., 18, 673–689, https://doi.org/10.5194/acp-18-673-2018, 2018.
Cheng, P., Pour-Biazar, A., White, A. T., and McNider, R. T.: Improvement of
summertime surface ozone prediction by assimilating Geostationary
Operational Environmental Satellite cloud observations, Atmos. Environ., 268,
118751, https://doi.org/10.1016/j.atmosenv.2021.118751, 2022.
Clarisse, L., R'Honi, Y., Coheur, P. F., Hurtmans, D., and Clerbaux, C.:
Thermal infrared nadir observations of 24 atmospheric gases, Geophys. Res.
Lett., 38, L10802, https://doi.org/10.1029/2011GL047271, 2011.
Cui, L. and Wang, S.: Mapping the daily nitrous acid (HONO) concentrations
across China during 2006–2017 through ensemble machine-learning algorithm,
Sci. Total Environ., 785, 147325, https://doi.org/10.1016/j.scitotenv.2021.147325, 2021.
Dang, C., Liu, Y., Yue, H., Qian, J., and Zhu, R.: Autumn crop yield
prediction using data-driven approaches:-support vector machines, random
forest, and deep neural network methods, Can. J. Remote Sens., 47, 162–181,
2021.
Ding, B., Qian, H., and Zhou J.: Activation functions and their characteristics in deep neural networks, in: 2018 Chinese Control And Decision Conference (CCDC), Shenyang, China, 9 July 2018, 1836–1841, https://doi.org/10.1109/CCDC.2018.8407425, 2018.
Ge, B., Xu, X., Ma, Z., Pan, X., Wang, Z., Lin, W., Ouyang, B., Xu, D., Lee,
J., and Zheng, M.: Role of Ammonia on the Feedback Between AWC and Inorganic
Aerosol Formation During Heavy Pollution in the North China Plain, Astr. Soc.
P., 6, 1675–1693, 2019.
Gen, M., Liang, Z., Zhang, R., Mabato, B. R. G., and Chan, C. K.:
Particulate nitrate photolysis in the atmosphere, Environmental Science:
Atmospheres, 2022, 111–127, https://doi.org/10.1039/D1EA00087J, 2022.
Gil, J.: RNDv1.0 and example, Zenodo [code and data set], https://doi.org/10.5281/zenodo.5540180, 2021.
Gil, J., Son, J., Kang, S., Park, J., Lee, M., Jeon, E., and Shim, M.: HONO
measurement in Seoul during Summer 2018 and its Impact on Photochemistry,
Journal of Korean Society for Atmospheric Environment, 36, 579–588,
https://doi.org/10.5572/KOSAE.2020.36.5.579, 2020.
Gil, J., Kim, J., Lee, M., Lee, G., Ahn, J., Lee, D. S., Jung, J., Cho, S.,
Whitehill, A., Szykman, J., and Lee, J.: Characteristics of HONO and its
impact on O3 formation in the Seoul Metropolitan Area during the Korea-US
Air Quality study, Atmos. Environ., 247, 118182,
https://doi.org/10.1016/j.atmosenv.2020.118182, 2021.
Gil, J., Lee, M., Lee, H., and Jang, J.: Seasonal Characteristics of HONO
Variations in Seoul during 2021–2022, Journal of Korean
Society for Atmospheric Environment, 39, 308–319, 2023.
Gu, R., Wang, W., Peng, X., Xia, M., Zhao, M., Zhang, Y., Liu, Y., Shen, H.,
Xue, L., and Wang, T.: Nitrous acid in the polluted coastal atmosphere of
the South China Sea: Ship emissions, budgets, and impacts, Sci. Total Environ., 826, 153692, https://doi.org/10.1016/j.scitotenv.2022.153692, 2022.
IPCC: Summary for policymakers, in: Climate Change 2014: Impacts, Adaption,
and Vulnerability. Part A: Global and Sectoral Aspects. Contribution of
Working Group II to the Fifth Assessment Report of the Intergovernmental
Panel on Climate Change, edited by: Field, C. B., Barros, V. R., Dokken, D. J., Mach, K. J., Mastrandrea, M. D., Bilir, T. E., Chatterjee, M., Ebi, K. L., Estrada, Y. O., Genova, R. C., Girma, B., Kissel, E. S., Levy, A. N., MacCracken, S., Mastrandrea, P. R.,
and White, L. L., Cambridge, United Kingdom and New York, NY, USA,
1–32, https://doi.org/10.1017/CBO9781107415379.003, 2014.
IPCC: Sections, in: Climate Change 2023: Synthesis Report. Contribution of
Working Groups I, II and III to the Sixth Assessment Report of the
Intergovernmental Panel on Climate Change, 35–115, https://www.ipcc.ch/report/sixth-assessment-report-cycle/, last access: 11 September 2023.
Jia, C., Tong, S., Zhang, W., Zhang, X., Li, W., Wang, Z., Wang, L., Liu,
Z., Hu, B., and Zhao, P.: Pollution characteristics and potential sources of
nitrous acid (HONO) in early autumn 2018 of Beijing, Sci. Total Environ., 735,
139317, https://doi.org/10.1016/j.scitotenv.2020.139317, 2020.
Joutsensaari, J., Ozon, M., Nieminen, T., Mikkonen, S., Lähivaara, T., Decesari, S., Facchini, M. C., Laaksonen, A., and Lehtinen, K. E. J.: Identification of new particle formation events with deep learning, Atmos. Chem. Phys., 18, 9597–9615, https://doi.org/10.5194/acp-18-9597-2018, 2018.
Kang, Y., Choi, H., Im, J., Park, S., Shin, M., Song, C.-K., and Kim, S.:
Estimation of surface-level NO2 and O3 concentrations using TROPOMI data and
machine learning over East Asia, Environ. Pollut., 288, 117711, https://doi.org/10.1016/j.envpol.2021.117711, 2021.
Kim, H., Gil, J., Lee, M., Jung, J., Whitehill, A., Szykman, J., Lee, G.,
Kim, D.-S., Cho, S., and Ahn, J.-Y.: Factors controlling surface ozone in
the Seoul Metropolitan Area during the KORUS-AQ campaign, Elementa: Science
of the Anthropocene, 8, 46, https://doi.org/10.1525/elementa.444, 2020.
Kleffmann, J., Lörzer, J., Wiesen, P., Kern, C., Trick, S., Volkamer,
R., Rodenas, M., and Wirtz, K.: Intercomparison of the DOAS and LOPAP
techniques for the detection of nitrous acid (HONO), Atmos. Environ., 40,
3640–3652, 2006.
Kleinert, F., Leufen, L. H., and Schultz, M. G.: IntelliO3-ts v1.0: a neural network approach to predict near-surface ozone concentrations in Germany, Geosci. Model Dev., 14, 1–25, https://doi.org/10.5194/gmd-14-1-2021, 2021.
Krishnamurthy, R., Newsom, R. K., Berg, L. K., Xiao, H., Ma, P.-L., and Turner, D. D.: On the estimation of boundary layer heights: a machine learning approach, Atmos. Meas. Tech., 14, 4403–4424, https://doi.org/10.5194/amt-14-4403-2021, 2021.
Lee, B. H., Wood, E. C., Zahniser, M. S., McManus, J. B., Nelson, D. D.,
Herndon, S. C., Santoni, G., Wofsy, S. C., and Munger, J. W.: Simultaneous
measurements of atmospheric HONO and NO2 via absorption spectroscopy using
tunable mid-infrared continuous-wave quantum cascade lasers, Appl. Phys. B,
102, 417–423, 2011.
Levy, M., Zhang, R., Zheng, J., Zhang, A. L., Xu, W., Gomez-Hernandez, M.,
Wang, Y., and Olaguer, E.: Measurements of nitrous acid (HONO) using ion
drift-chemical ionization mass spectrometry during the 2009 SHARP field
campaign, Atmos. Environ., 94, 231–240, 2014.
Li, S., Song, W., Zhan, H., Zhang, Y., Zhang, X., Li, W., Tong, S., Pei, C.,
Wang, Y., and Chen, Y.: Contribution of Vehicle Emission and NO2 Surface
Conversion to Nitrous Acid (HONO) in Urban Environments: Implications from
Tests in a Tunnel, Environ. Sci. Technol., 55, 15616–15624, 2021.
Li, Y., Wang, X., Wu, Z., Li, L., Wang, C., Li, H., Zhang, X., Zhang, Y.,
Li, J., and Gao, R.: Atmospheric nitrous acid (HONO) in an alternate process
of haze pollution and ozone pollution in urban Beijing in summertime:
Variations, sources and contribution to atmospheric photochemistry, Atmos.
Res., 260, 105689, https://doi.org/10.1016/j.atmosres.2021.105689, 2021.
Li, Z., Xie, P., Hu, R., Wang, D., Jin, H., Chen, H., Lin, C., and Liu, W.:
Observations of N2O5 and NO3 at a suburban environment in Yangtze river
delta in China: Estimating heterogeneous N2O5 uptake coefficients, J. Environ.
Sci., 95, 248–255, https://doi.org/10.1016/j.jes.2020.04.041, 2020.
Liebmann, J., Karu, E., Sobanski, N., Schuladen, J., Ehn, M., Schallhart, S., Quéléver, L., Hellen, H., Hakola, H., Hoffmann, T., Williams, J., Fischer, H., Lelieveld, J., and Crowley, J. N.: Direct measurement of NO3 radical reactivity in a boreal forest, Atmos. Chem. Phys., 18, 3799–3815, https://doi.org/10.5194/acp-18-3799-2018, 2018.
Liu, Y., Lu, K., Li, X., Dong, H., Tan, Z., Wang, H., Zou, Q., Wu, Y., Zeng,
L., and Hu, M.: A comprehensive model test of the HONO sources constrained
to field measurements at rural North China Plain, Environ. Sci. Technol., 53,
3517–3525, 2019.
Mallet, V. and Sportisse, B.: Uncertainty in a chemistry-transport model due
to physical parameterizations and numerical approximations: An ensemble
approach applied to ozone modeling, J. Geophys. Res.-Atmos., 111, D01302, https://doi.org/10.1029/2005JD006149, 2006.
Meng, F., Qin, M., Fang, W., Duan, J., Tang, K., Zhang, H., Shao, D., Liao,
Z., Feng, Y., and Huang, Y.: Measurement of HONO flux using the aerodynamic
gradient method over an agricultural field in the Huaihe River Basin, China,
J. Environ. Sci., 114, 297–307, https://doi.org/10.1016/j.jes.2021.09.005, 2022.
Monks, P. S., Archibald, A. T., Colette, A., Cooper, O., Coyle, M., Derwent, R., Fowler, D., Granier, C., Law, K. S., Mills, G. E., Stevenson, D. S., Tarasova, O., Thouret, V., von Schneidemesser, E., Sommariva, R., Wild, O., and Williams, M. L.: Tropospheric ozone and its precursors from the urban to the global scale from air quality to short-lived climate forcer, Atmos. Chem. Phys., 15, 8889–8973, https://doi.org/10.5194/acp-15-8889-2015, 2015.
Myhre, G., Aas, W., Cherian, R., Collins, W., Faluvegi, G., Flanner, M., Forster, P., Hodnebrog, Ø., Klimont, Z., Lund, M. T., Mülmenstädt, J., Lund Myhre, C., Olivié, D., Prather, M., Quaas, J., Samset, B. H., Schnell, J. L., Schulz, M., Shindell, D., Skeie, R. B., Takemura, T., and Tsyro, S.: Multi-model simulations of aerosol and ozone radiative forcing due to anthropogenic emission changes during the period 1990–2015, Atmos. Chem. Phys., 17, 2709–2720, https://doi.org/10.5194/acp-17-2709-2017, 2017.
NIER: Improvement of Air Quality Forecast based on the Measurement –Focused on Spring Episodes of PM2.5, 1–220, https://ecolibrary.me.go.kr/nier/#/search/detail/5711273?offset=1 (last access: 11 September 2023), 2020.
Pinto, J., Dibb, J., Lee, B., Rappenglück, B., Wood, E., Levy, M.,
Zhang, R. Y., Lefer, B., Ren, X. R., and Stutz, J.: Intercomparison of field
measurements of nitrous acid (HONO) during the SHARP campaign, J. Geophys.
Res.-Atmos., 119, 5583–5601, 2014.
Reichstein, M., Camps-Valls, G., Stevens, B., Jung, M., Denzler, J., and
Carvalhais, N.: Deep learning and process understanding for data-driven
Earth system science, Nature, 566, 195–204, 2019.
Roberts, J. M., Veres, P., Warneke, C., Neuman, J. A., Washenfelder, R. A., Brown, S. S., Baasandorj, M., Burkholder, J. B., Burling, I. R., Johnson, T. J., Yokelson, R. J., and de Gouw, J.: Measurement of HONO, HNCO, and other inorganic acids by negative-ion proton-transfer chemical-ionization mass spectrometry (NI-PT-CIMS): application to biomass burning emissions, Atmos. Meas. Tech., 3, 981–990, https://doi.org/10.5194/amt-3-981-2010, 2010.
Schultz, M., Betancourt, C., Gong, B., Kleinert, F., Langguth, M., Leufen,
L., Mozaffari, A., and Stadtler, S.: Can deep learning beat numerical
weather prediction?, Philos. T. R. Soc. A, 379, 20200097, https://doi.org/10.1098/rsta.2020.0097, 2021.
Shahriar, S. A., Kayes, I., Hasan, K., Salam, M. A., and Chowdhury, S.:
Applicability of machine learning in modeling of atmospheric particle
pollution in Bangladesh, Air Qual. Atmos. Hlth., 13, 1247–1256, 2020.
Shareef, M. M., Husain, T., and Alharbi, B.: Studying the Effect of
Different Gas-Phase Chemical Kinetic Mechanisms on the Formation of
Oxidants, Nitrogen Compounds and Ozone in Arid Regions, Journal of
Environmental Protection, 10, 1006–1031, 2019.
Shindell, D. T., Lamarque, J.-F., Schulz, M., Flanner, M., Jiao, C., Chin, M., Young, P. J., Lee, Y. H., Rotstayn, L., Mahowald, N., Milly, G., Faluvegi, G., Balkanski, Y., Collins, W. J., Conley, A. J., Dalsoren, S., Easter, R., Ghan, S., Horowitz, L., Liu, X., Myhre, G., Nagashima, T., Naik, V., Rumbold, S. T., Skeie, R., Sudo, K., Szopa, S., Takemura, T., Voulgarakis, A., Yoon, J.-H., and Lo, F.: Radiative forcing in the ACCMIP historical and future climate simulations, Atmos. Chem. Phys., 13, 2939–2974, https://doi.org/10.5194/acp-13-2939-2013, 2013.
Stadtler, S., Simpson, D., Schröder, S., Taraborrelli, D., Bott, A., and Schultz, M.: Ozone impacts of gas–aerosol uptake in global chemistry transport models, Atmos. Chem. Phys., 18, 3147–3171, https://doi.org/10.5194/acp-18-3147-2018, 2018.
Stevenson, D. S., Young, P. J., Naik, V., Lamarque, J.-F., Shindell, D. T., Voulgarakis, A., Skeie, R. B., Dalsoren, S. B., Myhre, G., Berntsen, T. K., Folberth, G. A., Rumbold, S. T., Collins, W. J., MacKenzie, I. A., Doherty, R. M., Zeng, G., van Noije, T. P. C., Strunk, A., Bergmann, D., Cameron-Smith, P., Plummer, D. A., Strode, S. A., Horowitz, L., Lee, Y. H., Szopa, S., Sudo, K., Nagashima, T., Josse, B., Cionni, I., Righi, M., Eyring, V., Conley, A., Bowman, K. W., Wild, O., and Archibald, A.: Tropospheric ozone changes, radiative forcing and attribution to emissions in the Atmospheric Chemistry and Climate Model Intercomparison Project (ACCMIP), Atmos. Chem. Phys., 13, 3063–3085, https://doi.org/10.5194/acp-13-3063-2013, 2013.
Sumathi, S. and Pugalendhi, G. K.: Cognition based spam mail text analysis
using combined approach of deep neural network classifier and random forest,
J. Amb. Intel. Hum. Comp., 12, 5721–5731, 2021.
Sun, Y., Wang, L., Wang, Y., Quan, L., and Zirui, L.: In situ measurements
of SO2, NOx, NOy, and O3 in Beijing, China during August 2008, Sci. Total Environ., 409, 933–940, 2011.
Theys, N., Volkamer, R., Müller, J.-F., Zarzana, K. J., Kille, N.,
Clarisse, L., De Smedt, I., Lerot, C., Finkenzeller, H., and Hendrick, F.:
Global nitrous acid emissions and levels of regional oxidants enhanced by
wildfires, Nat. Geosci., 13, 681–686, 2020.
Tie, X., Geng, F., Guenther, A., Cao, J., Greenberg, J., Zhang, R., Apel, E., Li, G., Weinheimer, A., Chen, J., and Cai, C.: Megacity impacts on regional ozone formation: observations and WRF-Chem modeling for the MIRAGE-Shanghai field campaign, Atmos. Chem. Phys., 13, 5655–5669, https://doi.org/10.5194/acp-13-5655-2013, 2013.
VandenBoer, T., Markovic, M., Sanders, J., Ren, X., Pusede, S., Browne, E.,
Cohen, R., Zhang, L., Thomas, J., and Brune, W. H.: Evidence for a nitrous
acid (HONO) reservoir at the ground surface in Bakersfield, CA, during
CalNex 2010, J. Geophys. Res.-Atmos., 119, 9093–9106, 2014.
Varotsos, K., Giannakopoulos, C., and Tombrou, M.: Assessment of the Impacts
of climate change on european ozone levels, Water Air Soil Poll., 224, 1596, https://doi.org/10.1007/s11270-013-1596-z,
2013.
Wang, T., Qin, Z., Zhu, M.: An ELU Network with Total Variation for Image Denoising, in: Neural Information Processing, edited by: Liu, D., Xie, S., Li, Y., Zhao, D., and El-Alfy, E., ICONIP 2017, Lecture Notes in Computer Science, vol. 10636, Springer, Cham, https://doi.org/10.1007/978-3-319-70090-8_24, 2017.
Wang, X., Wang, H., Xue, L., Wang, T., Wang, L., Gu, R., Wang, W., Tham, Y.
J., Wang, Z., and Yang, L.: Observations of N2O5 and ClNO2 at a polluted urban surface site in North China: High N2O5 uptake coefficients and low ClNO2 product yields, Atmos. Environ., 156, 125–134, 2017.
Wang, X., Dalton, E. Z., Payne, Z. C., Perrier, S., Riva, M., Raff, J. D.,
and George, C.: Superoxide and nitrous acid production from nitrate
photolysis is enhanced by dissolved aliphatic organic matter, Environ. Sci.
Tech. Let., 8, 53–58, 2020.
Wolfe, G. M., Marvin, M. R., Roberts, S. J., Travis, K. R., and Liao, J.: The Framework for 0-D Atmospheric Modeling (F0AM) v3.1, Geosci. Model Dev., 9, 3309–3319, https://doi.org/10.5194/gmd-9-3309-2016, 2016.
Xu, Z., Liu, Y., Nie, W., Sun, P., Chi, X., and Ding, A.: Evaluating the measurement interference of wet rotating-denuder–ion chromatography in measuring atmospheric HONO in a highly polluted area, Atmos. Meas. Tech., 12, 6737–6748, https://doi.org/10.5194/amt-12-6737-2019, 2019.
Xue, C., Ye, C., Ma, Z., Liu, P., Zhang, Y., Zhang, C., Tang, K., Zhang, W.,
Zhao, X., and Wang, Y.: Development of stripping coil-ion chromatograph
method and intercomparison with CEAS and LOPAP to measure atmospheric HONO,
Sci. Total Environ., 646, 187–195, 2019.
Ye, C., Zhou, X., Pu, D., Stutz, J., Festa, J., Spolaor, M., Tsai, C.,
Cantrell, C., Mauldin, R. L., and Campos, T.: Rapid cycling of reactive
nitrogen in the marine boundary layer, Nature, 532, 489–491, 2016.
Short summary
In this study, the framework for calculating reactive nitrogen species using a deep neural network (RND) was developed. It works through simple Python codes and provides high-accuracy reactive nitrogen oxide data. In the first version (RNDv1.0), the model calculates the nitrous acid (HONO) in urban areas, which has an important role in producing O3 and fine aerosol.
In this study, the framework for calculating reactive nitrogen species using a deep neural...