Articles | Volume 18, issue 3
https://doi.org/10.5194/gmd-18-621-2025
https://doi.org/10.5194/gmd-18-621-2025
Model evaluation paper
 | 
05 Feb 2025
Model evaluation paper |  | 05 Feb 2025

Accurate space-based NOx emission estimates with the flux divergence approach require fine-scale model information on local oxidation chemistry and profile shapes

Felipe Cifuentes, Henk Eskes, Enrico Dammers, Charlotte Bryan, and Folkert Boersma

Data sets

Accurate space-based NOx emission estimates with the flux divergence approach require fine-scale model information on local oxidation chemistry and profile shapes F. Cifuentes et al. https://doi.org/10.5281/zenodo.13268654

TROPOMI Level 2 Nitrogen Dioxide total column products. Version 02 Copernicus Sentinel-5P (processed by ESA) https://doi.org/10.5270/S5P-9bnp8q8

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Short summary
We tested the capability of the flux divergence approach (FDA) to reproduce known NOx emissions using synthetic NO2 satellite column retrievals from high-resolution model simulations. The FDA accurately reproduced NOx emissions when column observations were limited to the boundary layer and when the variability of the NO2 lifetime, the NO: NO2 ratio, and NO2 profile shapes were correctly modeled. This introduces strong model dependency, reducing the simplicity of the original FDA formulation.
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