Articles | Volume 10, issue 3
https://doi.org/10.5194/gmd-10-1339-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/gmd-10-1339-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Model description paper
| 
29 Mar 2017
Model description paper |
| 29 Mar 2017
CLEPS 1.0: A new protocol for cloud aqueous phase oxidation of VOC mechanisms
Camille Mouchel-Vallon
CORRESPONDING AUTHOR
Université Clermont Auvergne, CNRS Laboratoire de
Météorologie Physique, 63000 Clermont-Ferrand, France
now at:
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry,
University of York, Heslington, York, YO10 5DD, UK
Laurent Deguillaume
CORRESPONDING AUTHOR
Université Clermont Auvergne, CNRS Laboratoire de
Météorologie Physique, 63000 Clermont-Ferrand, France
Anne Monod
Aix
Marseille Université, CNRS, LCE UMR 7376, 13331 Marseille, France
Hélène Perroux
Université Clermont Auvergne, CNRS Laboratoire de
Météorologie Physique, 63000 Clermont-Ferrand, France
Clémence Rose
Université Clermont Auvergne, CNRS Laboratoire de
Météorologie Physique, 63000 Clermont-Ferrand, France
Giovanni Ghigo
Dipartimento di Chimica, Universita di Torino, V. Giuria 7, 10125
Turin, Italy
Yoann Long
Université Clermont Auvergne, CNRS Laboratoire de
Météorologie Physique, 63000 Clermont-Ferrand, France
now at: Ramboll Environ, 155 rue Louis de Broglie, 13100
Aix-en-Provence, France
Maud Leriche
Université de Toulouse, UPS, CNRS, Laboratoire
d'Aérologie, 31400 Toulouse, France
Bernard Aumont
LISA UMR CNRS 7583,
Université Paris Est Créteil et Université Paris Diderot, Paris,
France
Luc Patryl
CEA, DAM, DIF, 91297 Arpajon, France
Patrick Armand
CEA, DAM, DIF, 91297 Arpajon, France
Nadine Chaumerliac
Université Clermont Auvergne, CNRS Laboratoire de
Météorologie Physique, 63000 Clermont-Ferrand, France
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Cited
33 citations as recorded by crossref.
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- Development of a protocol for the auto-generation of explicit aqueous-phase oxidation schemes of organic compounds P. Bräuer et al. 10.5194/acp-19-9209-2019
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33 citations as recorded by crossref.
- Exploration of oxidative chemistry and secondary organic aerosol formation in the Amazon during the wet season: explicit modeling of the Manaus urban plume with GECKO-A C. Mouchel-Vallon et al. 10.5194/acp-20-5995-2020
- Opinion: Challenges and needs of tropospheric chemical mechanism development B. Ervens et al. 10.5194/acp-24-13317-2024
- First evaluation of the effect of microorganisms on steady state hydroxyl radical concentrations in atmospheric waters A. Lallement et al. 10.1016/j.chemosphere.2018.08.128
- Influence of strong iron-binding ligands on cloud water oxidant capacity A. González et al. 10.1016/j.scitotenv.2022.154642
- Box Model Intercomparison of Cloud Chemistry M. Barth et al. 10.1029/2021JD035486
- Assessing the efficiency of water-soluble organic compound biodegradation in clouds under various environmental conditions L. Pailler et al. 10.1039/D2EA00153E
- Multiphase MCM–CAPRAM modeling of the formation and processing of secondary aerosol constituents observed during the Mt. Tai summer campaign in 2014 Y. Zhu et al. 10.5194/acp-20-6725-2020
- How non-equilibrium aerosol chemistry impacts particle acidity: the GMXe AERosol CHEMistry (GMXe–AERCHEM, v1.0) sub-submodel of MESSy S. Rosanka et al. 10.5194/gmd-17-2597-2024
- Insights into tropical cloud chemistry in Réunion (Indian Ocean): results from the BIO-MAÏDO campaign P. Dominutti et al. 10.5194/acp-22-505-2022
- Treatment of non-ideality in the SPACCIM multiphase model – Part 2: Impacts on the multiphase chemical processing in deliquesced aerosol particles A. Rusumdar et al. 10.5194/acp-20-10351-2020
- Overview of the Meso-NH model version 5.4 and its applications C. Lac et al. 10.5194/gmd-11-1929-2018
- Degradation of nanoplastics in the environment: Reactivity and impact on atmospheric and surface waters A. Bianco et al. 10.1016/j.scitotenv.2020.140413
- Temperature-Dependent Oxidation of Hydroxylated Aldehydes by •OH, SO4•–, and NO3• Radicals in the Atmospheric Aqueous Phase M. Mekic et al. 10.1021/acs.jpca.3c00700
- Development of a multiphase chemical mechanism to improve secondary organic aerosol formation in CAABA/MECCA (version 4.7.0) F. Wieser et al. 10.5194/gmd-17-4311-2024
- High Resolution Dynamical Analysis of Volatile Organic Compounds (VOC) Measurements During the BIO‐MAÏDO Field Campaign (Réunion Island, Indian Ocean) M. Rocco et al. 10.1029/2021JD035570
- pH Dependence of the OH Reactivity of Organic Acids in the Aqueous Phase J. Amorim et al. 10.1021/acs.est.0c03331
- Average Cloud Droplet Size and Composition: Good Assumptions for Predicting Oxidants in the Atmospheric Aqueous Phase? B. Ervens 10.1021/acs.jpca.2c05527
- Cézeaux-Aulnat-Opme-Puy De Dôme: a multi-site for the long-term survey of the tropospheric composition and climate change J. Baray et al. 10.5194/amt-13-3413-2020
- Preliminary results from the FARCE 2015 campaign: multidisciplinary study of the forest–gas–aerosol–cloud system on the tropical island of La Réunion V. Duflot et al. 10.5194/acp-19-10591-2019
- Chloride Interferences in Wet Chemical Oxidation Measurements: Plausible Mechanisms and Implications Y. Chiu et al. 10.1021/acsestwater.4c00508
- Anthropogenic and biogenic hydrophobic VOCs detected in clouds at the puy de Dôme station using Stir Bar Sorptive Extraction: Deviation from the Henry's law prediction M. Wang et al. 10.1016/j.atmosres.2020.104844
- Biodegradation by bacteria in clouds: an underestimated sink for some organics in the atmospheric multiphase system A. Khaled et al. 10.5194/acp-21-3123-2021
- Chemical Characterization of Cloudwater Collected at Puy de Dôme by FT-ICR MS Reveals the Presence of SOA Components A. Bianco et al. 10.1021/acsearthspacechem.9b00153
- Sugars in clouds: Measurements and modelling investigation of their aqueous photodegradation A. Bianco et al. 10.1016/j.atmosenv.2025.121167
- Trace Metals in Cloud Water Sampled at the Puy De Dôme Station A. Bianco et al. 10.3390/atmos8110225
- Modeling the partitioning of organic chemical species in cloud phases with CLEPS (1.1) C. Rose et al. 10.5194/acp-18-2225-2018
- Oxidation of low-molecular-weight organic compounds in cloud droplets: development of the Jülich Aqueous-phase Mechanism of Organic Chemistry (JAMOC) in CAABA/MECCA (version 4.5.0) S. Rosanka et al. 10.5194/gmd-14-4103-2021
- Measurement report: Bio-physicochemistry of tropical clouds at Maïdo (Réunion, Indian Ocean): overview of results from the BIO-MAÏDO campaign M. Leriche et al. 10.5194/acp-24-4129-2024
- Process analysis of elevated concentrations of organic acids at Whiteface Mountain, New York C. Lawrence et al. 10.5194/acp-24-13693-2024
- Oxidation of low-molecular-weight organic compounds in cloud droplets: global impact on tropospheric oxidants S. Rosanka et al. 10.5194/acp-21-9909-2021
- Development of a protocol for the auto-generation of explicit aqueous-phase oxidation schemes of organic compounds P. Bräuer et al. 10.5194/acp-19-9209-2019
- Photochemistry of the Cloud Aqueous Phase: A Review A. Bianco et al. 10.3390/molecules25020423
- Aging of α-Pinene Secondary Organic Aerosol by Hydroxyl Radicals in the Aqueous Phase: Kinetics and Products B. Witkowski et al. 10.1021/acs.est.2c07630
Saved (final revised paper)
Latest update: 30 Mar 2025
Short summary
The Cloud Explicit Physico-chemical Scheme (CLEPS 1.0) describes oxidation of water-soluble organic compounds resulting from isoprene oxidation. It is based on structure activity relationships (SARs) (global rate constants and branching ratios for HO• abstraction and addition) and GROMHE SAR (Henry's law constants for undocumented species). It is coupled to the MCM gas phase mechanism and is included in a model using the DSMACC model and KPP to analyze experimental and field data.
The Cloud Explicit Physico-chemical Scheme (CLEPS 1.0) describes oxidation of water-soluble...
