the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
The Multi-Compartment Hg Modeling and Analysis Project (MCHgMAP): Mercury modeling to support international environmental policy
Abstract. The Multi-Compartment Hg (mercury) Modeling and Analysis Project (MCHgMAP) is an international multi-model research initiative intended to simulate and analyze the geospatial distributions and temporal trends of environmental Hg to inform the effectiveness evaluations of two multilateral environmental agreements (MEAs): the Minamata Convention on Mercury (MC) and Convention on Long-Range Transboundary Air Pollution (LRTAP). This MCHgMAP overview paper presents its science objectives, background and rationale, experimental design (multi-model ensemble (MME) architecture, inputs and evaluation data, simulations and reporting framework), and methodologies for the evaluation and analysis of simulated environmental Hg levels. The primary goals of the project are to facilitate detection and attribution of recent (observed) and future (projected) spatial patterns and temporal trends of global environmental Hg levels, and identification of key knowledge gaps in Hg science and modeling to improve future effectiveness evaluation cycles of the MEAs. The current advances and challenges of Hg models, emission inventories, and observational data are examined, and an optimized multi-model experimental design is introduced for addressing the key policy questions of the MEAs. A common set of emissions, environmental conditions, and observation datasets are proposed (where possible) to enhance the MME comparability. A novel harmonized simulation approach between atmospheric, land, oceanic and multi-media models is developed to account for the short- and long-term changes in secondary Hg exchanges and to achieve mechanistic consistency of Hg levels across environmental matrices. A comprehensive set of model experiments is developed and prioritized to ensure a systematic analysis and participation of a variety of models from the scientific community.
- Preprint
(2769 KB) - Metadata XML
- BibTeX
- EndNote
Status: open (until 27 Jul 2024)
-
CC1: 'Comment on gmd-2024-65', Panos Panagos, 29 May 2024
reply
This is a very interesting manuscript which address the whole Hg cycle in all media.
As expert in soils, i would recommend that the Hg content in soils is better addressed. Reading the manuscript, you tend to explain the Hg content in soils due to natural factors while there is an important contribution by anthropogenic sources. In EU, we have done a very detailed assessment of Hg content in topsoils trying to explain both the natural and the anthropogenic drivers.
This can be done taking into account 22,000 measured samples taken with LUCAS topsoil survey in Europe. More insights can be given by the recent work Ballabio et al 2019. A spatial assessment of mercury content in the European Union topsoil .
In this assessment, authors can consider the findings of the large EU study as this is the largest harmonised and recent measured Hg campaign:
- large proportion of atmospheric Hg that is bound to soil organic matter.
- In addition, the findings indicate that soil Hg is not only bound to organic matter but associated with iron oxide and clay minerals.
- Hg accumulation increases with pH, starting from a pH of 4 and reaching a maximum at a pH of 6.5..
- Parent material also increase Hg. Highest Hg content are found in mineralized regions characterized by subduction zones and volcanic deposits.
- High correlation with NDVI - dense vegetation (higher concentration in forests and grasslands compared to croplands).
- Elevated temperatures reduce activation energy required to release Hg from soil or vegetation and subsequently increase Hg volatilisation rates to the atmosphere- However, the outliers are explained by anthropogenic activities. 1% of the samples show very high Hg values due to proximity to mining sites. Particular high Hg values have been found close to Almaden (spain), Monte Amiata (Italy) and Idrija mine in Slovenia.
- Another source of Hg is represented by coal combustion in power plants in the European Union.
- Also, sampling points close to active or past Chrol-alkali plants have shown very high Hg values .Important to notice the impact of erosion and sediment removal to transfer Hg in aquatic systems (oceans, river-basins, lakes).
Future Projections for Hg in topsoils are mainly positive as the decrease of coal combustion and the better treatment in Chrol alkali plants have positive effects. In addition, specific control technologies and legal biding regulations (in the European Union, Soil Monitoring Law, Mercury Regulation) will have positive impact in reducing Hg concentrations.
Many thanks for taking those remarks into account.
Citation: https://doi.org/10.5194/gmd-2024-65-CC1 -
CEC1: 'Comment on gmd-2024-65', Juan Antonio Añel, 14 Jun 2024
reply
Dear authors,
Unfortunately, after checking your manuscript, it has come to our attention that it does not comply with our "Code and Data Policy".
https://www.geoscientific-model-development.net/policies/code_and_data_policy.htmlYou have archived your data in three repositories that does not comply with our trustable permanent archival policy. These include https://edgar.jrc.ec.europa.eu/, https://www.amap.no/mercury-emissions, and https://ftp.as.harvard.edu/. You must archive the data that you use for your manuscript in one of the repositories that we can accept according to our policy. Therefore, please publish your data in one of the appropriate repositories, and reply to this comment with the relevant information (link and DOI) as soon as possible, as we can not accept manuscripts in Discussions that do not comply with our policy. Therefore, the current situation with your manuscript is irregular.
Also, you must include in a potentially reviewed version of your manuscript the modified 'Data Availability' section, with the DOI of the data.
Juan A. Añel
Geosci. Model Dev. Executive EditorCitation: https://doi.org/10.5194/gmd-2024-65-CEC1
Viewed
HTML | XML | Total | BibTeX | EndNote | |
---|---|---|---|---|---|
309 | 97 | 14 | 420 | 10 | 9 |
- HTML: 309
- PDF: 97
- XML: 14
- Total: 420
- BibTeX: 10
- EndNote: 9
Viewed (geographical distribution)
Country | # | Views | % |
---|
Total: | 0 |
HTML: | 0 |
PDF: | 0 |
XML: | 0 |
- 1