<?xml version="1.0" encoding="UTF-8"?>
<!DOCTYPE article PUBLIC "-//NLM//DTD Journal Publishing with OASIS Tables v3.0 20080202//EN" "https://jats.nlm.nih.gov/nlm-dtd/publishing/3.0/journalpub-oasis3.dtd">
<article xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:oasis="http://docs.oasis-open.org/ns/oasis-exchange/table" xml:lang="en" dtd-version="3.0" article-type="research-article">
  <front>
    <journal-meta><journal-id journal-id-type="publisher">GMD</journal-id><journal-title-group>
    <journal-title>Geoscientific Model Development</journal-title>
    <abbrev-journal-title abbrev-type="publisher">GMD</abbrev-journal-title><abbrev-journal-title abbrev-type="nlm-ta">Geosci. Model Dev.</abbrev-journal-title>
  </journal-title-group><issn pub-type="epub">1991-9603</issn><publisher>
    <publisher-name>Copernicus Publications</publisher-name>
    <publisher-loc>Göttingen, Germany</publisher-loc>
  </publisher></journal-meta>
    <article-meta>
      <article-id pub-id-type="doi">10.5194/gmd-19-4775-2026</article-id><title-group><article-title>A unified Hapke-HSR <inline-formula><mml:math id="M1" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> MARMIT-2 soil radiative transfer model for reflectance simulation under varying moisture conditions</article-title><alt-title>A unified Hapke-HSR <inline-formula><mml:math id="M2" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> MARMIT-2 soil radiative transfer model</alt-title>
      </title-group>
      <contrib-group>
        <contrib contrib-type="author" corresp="no" rid="aff1 aff2">
          <name><surname>Ding</surname><given-names>Anxin</given-names></name>
          
        <ext-link>https://orcid.org/0000-0001-6591-328X</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff3">
          <name><surname>Ma</surname><given-names>Han</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-1123-7447</ext-link></contrib>
        <contrib contrib-type="author" corresp="yes" rid="aff3">
          <name><surname>Liang</surname><given-names>Shunlin</given-names></name>
          <email>shunlin@hku.hk</email>
        <ext-link>https://orcid.org/0000-0003-2708-9183</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff4 aff5">
          <name><surname>Jiao</surname><given-names>Ziti</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff6">
          <name><surname>Kokhanovsky</surname><given-names>Alexander A.</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff7">
          <name><surname>Shi</surname><given-names>Hanyu</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff8">
          <name><surname>Xie</surname><given-names>Rui</given-names></name>
          
        </contrib>
        <aff id="aff1"><label>1</label><institution>Key Laboratory of Humid Subtropical Eco-Geographical Process (Ministry of Education),  Fujian Normal University, Fuzhou 350000, China</institution>
        </aff>
        <aff id="aff2"><label>2</label><institution>School of Geographical Sciences, School of Carbon Neutrality Future Technology,   Fujian Normal University, Fuzhou 350000, China</institution>
        </aff>
        <aff id="aff3"><label>3</label><institution>Jockey Club STEM Laboratory of Quantitative Remote Sensing, Department of Geography,  University of Hong Kong, Hong Kong 999077, China</institution>
        </aff>
        <aff id="aff4"><label>4</label><institution>State Key Laboratory of Remote Sensing and Digital Earth, Faculty of Geographical Science,  Beijing Normal University, Beijing 100875, China</institution>
        </aff>
        <aff id="aff5"><label>5</label><institution>Faculty of Geographical Science, Institute of Remote Sensing Science and Engineering,  Beijing Normal University, Beijing 100875, China</institution>
        </aff>
        <aff id="aff6"><label>6</label><institution>Philipps-Universität Marburg Department of Geography Laboratory for Climatology and Remote Sensing F|14, Deutschhausstr. 12, 35032 Marburg, Germany</institution>
        </aff>
        <aff id="aff7"><label>7</label><institution>School of Geospatial Artificial Intelligence, East China Normal University, Shanghai 200241, China</institution>
        </aff>
        <aff id="aff8"><label>8</label><institution>International Institute for Earth System Sciences, and School of Geography and Ocean Science,  Nanjing University, Nanjing 210023, China</institution>
        </aff>
      </contrib-group>
      <author-notes><corresp id="corr1">Shunlin Liang (shunlin@hku.hk)</corresp></author-notes><pub-date><day>3</day><month>June</month><year>2026</year></pub-date>
      
      <volume>19</volume>
      <issue>11</issue>
      <fpage>4775</fpage><lpage>4795</lpage>
      <history>
        <date date-type="received"><day>21</day><month>January</month><year>2026</year></date>
           <date date-type="rev-request"><day>3</day><month>March</month><year>2026</year></date>
           <date date-type="rev-recd"><day>30</day><month>April</month><year>2026</year></date>
           <date date-type="accepted"><day>24</day><month>May</month><year>2026</year></date>
      </history>
      <permissions>
        <copyright-statement>Copyright: © 2026 Anxin Ding et al.</copyright-statement>
        <copyright-year>2026</copyright-year>
      <license license-type="open-access"><license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri" xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p></license></permissions><self-uri xlink:href="https://gmd.copernicus.org/articles/19/4775/2026/gmd-19-4775-2026.html">This article is available from https://gmd.copernicus.org/articles/19/4775/2026/gmd-19-4775-2026.html</self-uri><self-uri xlink:href="https://gmd.copernicus.org/articles/19/4775/2026/gmd-19-4775-2026.pdf">The full text article is available as a PDF file from https://gmd.copernicus.org/articles/19/4775/2026/gmd-19-4775-2026.pdf</self-uri>
      <abstract><title>Abstract</title>

      <p id="d2e211">Soil radiative transfer models (RTMs) provide a physical basis for interpreting surface reflectance and retrieving land-surface parameters. However, most existing soil RTMs represent either the spectral-directional scattering behavior of dry soils or the moisture-induced absorption effects of wet soils, and a physically consistent formulation capable of jointly describing both processes remains limited. In this study, we develop a unified soil RTM by refining the Hapke-based hyperspectral reflectance model (Hapke-HSR) using dry soil reflectance and dynamically coupling it with the improved multilayer RTM of soil reflectance (MARMIT-2). The proposed Hapke-HSR <inline-formula><mml:math id="M3" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> MARMIT-2 model explicitly represents the interaction between particle scattering and moisture-dependent absorption and refraction processes, enabling joint spectral-directional simulation of soil reflectance under varying soil moisture conditions. The model is systematically evaluated using eight independent soil spectral databases spanning a wide range of textures and moisture levels. Results show that the Hapke-HSR <inline-formula><mml:math id="M4" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> MARMIT-2 model consistently improves simulation accuracy and stability relative to the individual Hapke-HSR and MARMIT-2 models, with particularly pronounced gains at high soil moisture regimes (SMC <inline-formula><mml:math id="M5" display="inline"><mml:mo>≥</mml:mo></mml:math></inline-formula> 30 %). Across all datasets, the proposed model achieves higher performance (<inline-formula><mml:math id="M6" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.993</mml:mn></mml:mrow></mml:math></inline-formula>, RMSE <inline-formula><mml:math id="M7" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.007) than MARMIT-2 (<inline-formula><mml:math id="M8" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.983</mml:mn></mml:mrow></mml:math></inline-formula>, RMSE <inline-formula><mml:math id="M9" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.012) and Hapke-HSR (<inline-formula><mml:math id="M10" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.909</mml:mn></mml:mrow></mml:math></inline-formula>, RMSE <inline-formula><mml:math id="M11" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.028). The proposed framework provides a physically interpretable and extensible basis for soil reflectance modeling and offers a robust foundation for future developments in multi-angular hyperspectral remote sensing and land-surface parameter inversion.</p>
  </abstract>
    
<funding-group>
<award-group id="gs1">
<funding-source>National Natural Science Foundation of China</funding-source>
<award-id>42301363</award-id>
</award-group>
<award-group id="gs2">
<funding-source>State Key Laboratory of Remote Sensing Science</funding-source>
<award-id>OFSLRSS202412</award-id>
</award-group>
</funding-group>
</article-meta>
  </front>
<body>
      

<sec id="Ch1.S1" sec-type="intro">
  <label>1</label><title>Introduction</title>
      <p id="d2e311">Soils are fundamental components of the Earth's surface system and play a critical role in agricultural productivity, ecosystem functioning, and hydrological processes (Fan et al., 2025; Rizzo et al., 2023; Shoshany et al., 2022). Soil reflectance is governed by a range of physical properties, including soil moisture content (SMC), particle size, and surface roughness, which jointly regulate the scattering and absorption of solar radiation (Gholami and Mobasheri, 2018; Labarre et al., 2019; Nolin and Liang, 2000; Sheng et al., 2024). Among these factors, SMC is one of the most influential and dynamic variables, exerting a dominant control on soil spectral behavior, particularly in the shortwave infrared region where water absorption features are pronounced (Bablet et al., 2018; Jiang and Fang, 2019; Xu et al., 2025). Because soil reflectance constitutes a fundamental component of optical remote sensing signals, a physically consistent soil radiative transfer model is essential for reliably linking observed reflectance to soil and vegetation parameters and for supporting the inversion of land-surface biophysical variables (Gao et al., 2024; Lei  and Bailey, 2025; Yang et al., 2025).</p>
      <p id="d2e314">Soil radiative transfer models (RTMs) describe the absorption, scattering, and transmission of solar radiation within soil media and provide a physically based framework for linking surface reflectance to soil properties (Bach and Mauser, 1994; Jacquemoud, 1992; Liang and Townshend, 1996a, b; Sadeghi et al., 2017). Owing to their explicit physical formulation, RTMs have become a fundamental tool for the inversion of soil-related parameters from optical remote sensing observations. Moreover, soil reflectance constitutes a key background component of vegetation canopies and directly affects the accuracy of vegetation radiative transfer models and the retrieval of biophysical vegetation variables (Ni and Li, 2000; Ma et al., 2017a, b; Yang, 2022; Zeng et al., 2021). Despite substantial progress, important limitations remain in current soil RTMs. Many widely used models, including the multilayer radiative transfer model of soil reflectance (MARMIT) (Bablet et al., 2018) and the brightness-shape-moisture (BSM) model (Verhoef et al., 2018), rely on simplified assumptions of soil reflectance behavior and do not fully capture the combined spectral variability and moisture-dependent effects of natural soils (Jiang and Fang, 2019; Yang, 2022). Consequently, the development of physically consistent soil RTMs that can jointly represent spectral behavior and moisture-driven processes remains a critical requirement for reliable surface radiative transfer modeling and parameter inversion (Cheng et al., 2022; Jiang et al., 2023; Li et al., 2021; Verhoef  and Bach, 2007). To address this requirement, appropriate model selection is essential for constructing a physically consistent framework. Among the soil models listed in Table 1, the Hapke-HSR and MARMIT-2 models were selected due to their complementary physical characteristics. The Hapke-HSR model explicitly represents directional scattering and provides a physically based description of dry soil reflectance, whereas the MARMIT-2 model focuses on moisture-related absorption processes but does not account for angular effects and depends on externally prescribed dry soil reflectance. Their combination therefore enables a physically consistent integration of directional and moisture-dependent processes, which is not achievable with semi-empirical models such as the BSM model.</p>

<table-wrap id="T1" specific-use="star"><label>Table 1</label><caption><p id="d2e320">Summary of the strengths and limitations of existing soil radiative transfer models.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="5">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="right"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:colspec colnum="4" colname="col4" align="right"/>
     <oasis:colspec colnum="5" colname="col5" align="right"/>
     <oasis:thead>
       <oasis:row>
         <oasis:entry colname="col1">Models/References</oasis:entry>
         <oasis:entry colname="col2">Modelling</oasis:entry>
         <oasis:entry colname="col3">Absorption of</oasis:entry>
         <oasis:entry colname="col4">Irregular water</oasis:entry>
         <oasis:entry colname="col5">BRDF</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">dry soil</oasis:entry>
         <oasis:entry colname="col3">water film</oasis:entry>
         <oasis:entry colname="col4">film thickness</oasis:entry>
         <oasis:entry colname="col5">signatures</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
         <oasis:entry colname="col1">Ångström (Ångström, 1925)</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M12" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M13" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M14" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M15" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Lekner and Dorf (1988)</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M16" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M17" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M18" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M19" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Bach and Mauser (1994)</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M20" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M21" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M22" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M23" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SPLITS (Kimmel and Baranoski, 2007)</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M24" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M25" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M26" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M27" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Hapke (2012)</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M28" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M29" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M30" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M31" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Sadeghi et al. (2017)</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M32" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M33" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M34" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M35" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">BSM (Verhoef et al., 2018)</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M36" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M37" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M38" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M39" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">MARMIT (Bablet et al., 2018)</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M40" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M41" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M42" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M43" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Hapke-HSR (Ding et al., 2022)</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M44" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M45" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M46" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M47" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">MARMIT-2 (Dupiau et al., 2022)</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M48" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M49" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M50" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M51" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula></oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

      <p id="d2e762">The Hapke model has been widely applied in remote sensing for the retrieval of soil physical and biochemical properties (Hapke, 2012; Zhao et al., 2023). Building on this framework, we previously developed a hyperspectral Hapke model (i.e, the Hapke-HSR model) by establishing a wavelength-dependent representation of the single scattering albedo (SSA) (Ding et al., 2022), which enables improved simulation of dry soil spectral reflectance (SSR). Nevertheless, important limitations remain in the representation of moisture-dependent soil reflectance. First, the Hapke-HSR model is primarily parameterized for dry soil conditions, and its extension to wet soils relies on simplified assumptions. Second, the influence of soil moisture is represented through an idealized surface water layer, which restricts the model's ability to accurately characterize reflectance variations across a broad range of soil moisture content (SMC) and leads to systematic biases in major water absorption regions. Recently, the MARMIT-2 model has demonstrated strong performance in simulating SSR under varying moisture conditions by incorporating reflectance properties from diverse soil types (Dupiau et al., 2022). However, the MARMIT-2 model does not explicitly represent angular effects and requires prior knowledge of dry soil reflectance, which is often difficult to obtain from field or satellite observations. These limitations indicate that neither Hapke-HSR nor MARMIT-2 model alone provides a fully consistent framework for modeling soil reflectance under varying moisture conditions, thereby motivating the development of a unified soil modeling framework.</p>
      <p id="d2e765">To address these limitations, this study develops a unified soil radiative transfer framework by coupling the improved Hapke-HSR model with the MARMIT-2 model. The main contributions can be summarized as follows. First, the proposed framework integrates directional scattering and moisture-related absorption processes within a physically consistent formulation, which is not achieved by existing models. Second, the improved Hapke-HSR model dynamically provides dry soil reflectance, thereby removing the dependency of MARMIT-2 model on externally prescribed dry reflectance. Third, the coupled model enhances simulation robustness under high soil moisture conditions, particularly in strong water absorption regions. Overall, this study presents a unified and physically interpretable framework for simulating soil reflectance under varying moisture conditions, improving both consistency and applicability for remote sensing inversion.</p>
</sec>
<sec id="Ch1.S2">
  <label>2</label><title>Soil radiative transfer models</title>
<sec id="Ch1.S2.SS1">
  <label>2.1</label><title>Hapke-HSR model</title>
      <p id="d2e783">In the Hapke-HSR model, dry soil is treated as a semi-infinite horizontal surface containing irregularly and randomly distributed absorbing particles (Ding et al., 2022), and the formulas of this model are defined as follows:

                <disp-formula specific-use="gather" content-type="numbered"><mml:math id="M52" display="block"><mml:mtable displaystyle="true"><mml:mlabeledtr id="Ch1.E1"><mml:mtd><mml:mtext>1</mml:mtext></mml:mtd><mml:mtd><mml:mrow><mml:mstyle displaystyle="true" class="stylechange"/><mml:mtable class="split" rowspacing="0.2ex" displaystyle="true" columnalign="right left"><mml:mtr><mml:mtd><mml:mrow><mml:msub><mml:mi>R</mml:mi><mml:mi mathvariant="normal">d</mml:mi></mml:msub></mml:mrow></mml:mtd><mml:mtd><mml:mrow><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>,</mml:mo><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">v</mml:mi></mml:msub><mml:mo>,</mml:mo><mml:mi mathvariant="italic">φ</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mi mathvariant="italic">ω</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:mfrac></mml:mstyle><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mn mathvariant="normal">1</mml:mn><mml:mrow><mml:mi>cos⁡</mml:mi><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>+</mml:mo><mml:mi>cos⁡</mml:mi><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">v</mml:mi></mml:msub></mml:mrow></mml:mfrac></mml:mstyle></mml:mrow></mml:mtd></mml:mtr><mml:mtr><mml:mtd/><mml:mtd><mml:mrow><mml:mo mathvariant="italic">{</mml:mo><mml:mo>[</mml:mo><mml:mi>P</mml:mi><mml:mo>(</mml:mo><mml:mi>g</mml:mi><mml:mo>,</mml:mo><mml:msup><mml:mi>g</mml:mi><mml:mo>′</mml:mo></mml:msup><mml:mo>)</mml:mo><mml:mo>(</mml:mo><mml:mn mathvariant="normal">1</mml:mn><mml:mo>+</mml:mo><mml:mi>B</mml:mi><mml:mo>(</mml:mo><mml:mi>g</mml:mi><mml:mo>)</mml:mo><mml:mo>)</mml:mo><mml:mo>]</mml:mo><mml:mo>+</mml:mo><mml:mi>H</mml:mi><mml:mo>(</mml:mo><mml:mi>cos⁡</mml:mi><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:mi>H</mml:mi><mml:mo>(</mml:mo><mml:mi>cos⁡</mml:mi><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">v</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn><mml:mo mathvariant="italic">}</mml:mo></mml:mrow></mml:mtd></mml:mtr></mml:mtable></mml:mrow></mml:mtd></mml:mlabeledtr><mml:mlabeledtr id="Ch1.E2"><mml:mtd><mml:mtext>2</mml:mtext></mml:mtd><mml:mtd><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:mtable rowspacing="0.2ex" class="split" displaystyle="true" columnalign="right left"><mml:mtr><mml:mtd><mml:mrow><mml:mi>P</mml:mi><mml:mo>(</mml:mo><mml:mi>g</mml:mi><mml:mo>,</mml:mo><mml:msup><mml:mi>g</mml:mi><mml:mo>′</mml:mo></mml:msup><mml:mo>)</mml:mo></mml:mrow></mml:mtd><mml:mtd><mml:mrow><mml:mo>=</mml:mo><mml:mn mathvariant="normal">1</mml:mn><mml:mo>+</mml:mo><mml:mi>b</mml:mi><mml:mi>cos⁡</mml:mi><mml:mi>g</mml:mi><mml:mo>+</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mi>c</mml:mi><mml:mo>(</mml:mo><mml:mn mathvariant="normal">3</mml:mn><mml:msup><mml:mi>cos⁡</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mi>g</mml:mi><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn><mml:mo>)</mml:mo></mml:mrow><mml:mn mathvariant="normal">2</mml:mn></mml:mfrac></mml:mstyle><mml:mo>+</mml:mo><mml:msup><mml:mi>b</mml:mi><mml:mo>′</mml:mo></mml:msup><mml:mi>cos⁡</mml:mi><mml:msup><mml:mi>g</mml:mi><mml:mo>′</mml:mo></mml:msup></mml:mrow></mml:mtd></mml:mtr><mml:mtr><mml:mtd/><mml:mtd><mml:mrow><mml:mo>+</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:msup><mml:mi>c</mml:mi><mml:mo>′</mml:mo></mml:msup><mml:mo>(</mml:mo><mml:mn mathvariant="normal">3</mml:mn><mml:msup><mml:mi>cos⁡</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:msup><mml:mi>g</mml:mi><mml:mo>′</mml:mo></mml:msup><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn><mml:mo>)</mml:mo></mml:mrow><mml:mn mathvariant="normal">2</mml:mn></mml:mfrac></mml:mstyle></mml:mrow></mml:mtd></mml:mtr></mml:mtable></mml:mrow></mml:mtd></mml:mlabeledtr><mml:mlabeledtr id="Ch1.E3"><mml:mtd><mml:mtext>3</mml:mtext></mml:mtd><mml:mtd><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:mi>cos⁡</mml:mi><mml:mi>g</mml:mi><mml:mo>=</mml:mo><mml:mi>cos⁡</mml:mi><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mi>cos⁡</mml:mi><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">v</mml:mi></mml:msub><mml:mo>+</mml:mo><mml:mi>sin⁡</mml:mi><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mi>sin⁡</mml:mi><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">v</mml:mi></mml:msub><mml:mi>cos⁡</mml:mi><mml:mi mathvariant="italic">φ</mml:mi></mml:mrow></mml:mtd></mml:mlabeledtr><mml:mlabeledtr id="Ch1.E4"><mml:mtd><mml:mtext>4</mml:mtext></mml:mtd><mml:mtd><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:mi>cos⁡</mml:mi><mml:msup><mml:mi>g</mml:mi><mml:mo>′</mml:mo></mml:msup><mml:mo>=</mml:mo><mml:mi>cos⁡</mml:mi><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mi>cos⁡</mml:mi><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">v</mml:mi></mml:msub><mml:mo>-</mml:mo><mml:mi>sin⁡</mml:mi><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mi>sin⁡</mml:mi><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">v</mml:mi></mml:msub><mml:mi>cos⁡</mml:mi><mml:mi mathvariant="italic">φ</mml:mi></mml:mrow></mml:mtd></mml:mlabeledtr><mml:mlabeledtr id="Ch1.E5"><mml:mtd><mml:mtext>5</mml:mtext></mml:mtd><mml:mtd><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:mi>B</mml:mi><mml:mo>(</mml:mo><mml:mrow class="chem"><mml:mi mathvariant="normal">g</mml:mi></mml:mrow><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:msub><mml:mi>B</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>+</mml:mo><mml:mstyle displaystyle="false"><mml:mfrac style="text"><mml:mn mathvariant="normal">1</mml:mn><mml:mi>h</mml:mi></mml:mfrac></mml:mstyle><mml:mi>tan⁡</mml:mi><mml:mo>(</mml:mo><mml:mstyle displaystyle="false"><mml:mfrac style="text"><mml:mi>g</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:mfrac></mml:mstyle><mml:mo>)</mml:mo></mml:mrow></mml:mfrac></mml:mstyle></mml:mrow></mml:mtd></mml:mlabeledtr><mml:mlabeledtr id="Ch1.E6"><mml:mtd><mml:mtext>6</mml:mtext></mml:mtd><mml:mtd><mml:mrow><mml:mstyle displaystyle="true" class="stylechange"/><mml:mi>H</mml:mi><mml:mo>(</mml:mo><mml:mi>x</mml:mi><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>+</mml:mo><mml:mn mathvariant="normal">2</mml:mn><mml:mi>x</mml:mi></mml:mrow><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>+</mml:mo><mml:mn mathvariant="normal">2</mml:mn><mml:mi>x</mml:mi><mml:msqrt><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>-</mml:mo><mml:mi mathvariant="italic">ω</mml:mi></mml:mrow></mml:msqrt></mml:mrow></mml:mfrac></mml:mstyle></mml:mrow></mml:mtd></mml:mlabeledtr></mml:mtable></mml:math></disp-formula>

          where <inline-formula><mml:math id="M53" display="inline"><mml:mrow><mml:msub><mml:mi>R</mml:mi><mml:mi mathvariant="normal">d</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M54" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">v</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M55" display="inline"><mml:mi mathvariant="italic">φ</mml:mi></mml:math></inline-formula>, <inline-formula><mml:math id="M56" display="inline"><mml:mrow><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> represents dry soil reflectance, and <inline-formula><mml:math id="M57" display="inline"><mml:mi mathvariant="italic">ω</mml:mi></mml:math></inline-formula> denotes the average SSA. <inline-formula><mml:math id="M58" display="inline"><mml:mrow><mml:mi>B</mml:mi><mml:mo>(</mml:mo><mml:mi>g</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> is the hotspot function, with <inline-formula><mml:math id="M59" display="inline"><mml:mrow><mml:msub><mml:mi>B</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.4</mml:mn></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M60" display="inline"><mml:mrow><mml:mi>h</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.1</mml:mn></mml:mrow></mml:math></inline-formula> adopted as optimal values. The scattering phase function is represented by <inline-formula><mml:math id="M61" display="inline"><mml:mrow><mml:mi>P</mml:mi><mml:mo>(</mml:mo><mml:mi>g</mml:mi><mml:mo>,</mml:mo><mml:msup><mml:mi>g</mml:mi><mml:mo>′</mml:mo></mml:msup><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>, for which the parameters are set as <inline-formula><mml:math id="M62" display="inline"><mml:mrow><mml:msup><mml:mi>b</mml:mi><mml:mo>′</mml:mo></mml:msup><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.4</mml:mn></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M63" display="inline"><mml:mrow><mml:mi>c</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.4</mml:mn></mml:mrow></mml:math></inline-formula>, and <inline-formula><mml:math id="M64" display="inline"><mml:mrow><mml:msup><mml:mi>c</mml:mi><mml:mo>′</mml:mo></mml:msup><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0</mml:mn></mml:mrow></mml:math></inline-formula>. These parameter values are adopted from previous studies (e.g., Hapke, 2012; Ding et al., 2022) and represent commonly used or empirically optimized values for soil surfaces, providing stable and physically reasonable simulations across a wide range of conditions. The <inline-formula><mml:math id="M65" display="inline"><mml:mrow><mml:mi>P</mml:mi><mml:mo>(</mml:mo><mml:mi>g</mml:mi><mml:mo>,</mml:mo><mml:msup><mml:mi>g</mml:mi><mml:mo>′</mml:mo></mml:msup><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> function is employed in this study because it provides an improved representation of soil anisotropic scattering characteristics. Here, <inline-formula><mml:math id="M66" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M67" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">v</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, and <inline-formula><mml:math id="M68" display="inline"><mml:mi mathvariant="italic">φ</mml:mi></mml:math></inline-formula> denote the solar zenith angle (SZA), view zenith angle (VZA), and relative azimuth angle (RAA), respectively.</p>
      <p id="d2e1460">The relationship between the soil SSA and wavelength was established via radiative transfer theory. The association formulas of the SSA and wavelength are as follows:

            <disp-formula id="Ch1.E7" content-type="numbered"><label>7</label><mml:math id="M69" display="block"><mml:mrow><mml:mi mathvariant="italic">ω</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">1</mml:mn><mml:mo>-</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mn mathvariant="normal">4</mml:mn><mml:mi mathvariant="italic">π</mml:mi><mml:mi>M</mml:mi><mml:msub><mml:mi mathvariant="italic">χ</mml:mi><mml:mi mathvariant="normal">soil</mml:mi></mml:msub></mml:mrow><mml:mi mathvariant="italic">λ</mml:mi></mml:mfrac></mml:mstyle></mml:mrow></mml:math></disp-formula>

          where <inline-formula><mml:math id="M70" display="inline"><mml:mi>M</mml:mi></mml:math></inline-formula> represents the soil particle size and shape-dependent parameter and <inline-formula><mml:math id="M71" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">χ</mml:mi><mml:mi mathvariant="normal">soil</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is the soil refractive index, which is important for simulating soil optical properties.</p>
      <p id="d2e1511">In the Hapke-HSR model, the relationship between SSA (<inline-formula><mml:math id="M72" display="inline"><mml:mi mathvariant="italic">ω</mml:mi></mml:math></inline-formula>) and wavelength is further simplified as follows:

                <disp-formula specific-use="gather" content-type="numbered"><mml:math id="M73" display="block"><mml:mtable displaystyle="true"><mml:mlabeledtr id="Ch1.E8"><mml:mtd><mml:mtext>8</mml:mtext></mml:mtd><mml:mtd><mml:mrow><mml:mstyle displaystyle="true" class="stylechange"/><mml:msub><mml:mi mathvariant="italic">ω</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub><mml:mo>=</mml:mo><mml:mn mathvariant="normal">1</mml:mn><mml:mo>-</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mn mathvariant="normal">1</mml:mn><mml:mrow><mml:msub><mml:mi>A</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>+</mml:mo><mml:msub><mml:mi>A</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub></mml:mrow></mml:mfrac></mml:mstyle></mml:mrow></mml:mtd></mml:mlabeledtr><mml:mlabeledtr id="Ch1.E9"><mml:mtd><mml:mtext>9</mml:mtext></mml:mtd><mml:mtd><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:msub><mml:mi mathvariant="italic">ω</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mo>=</mml:mo><mml:mn mathvariant="normal">1</mml:mn><mml:mo>-</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mn mathvariant="normal">1</mml:mn><mml:mrow><mml:msub><mml:mi>A</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>+</mml:mo><mml:msub><mml:mi>A</mml:mi><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>+</mml:mo><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>d</mml:mi></mml:mrow></mml:mtd></mml:mlabeledtr></mml:mtable></mml:math></disp-formula>

          where <inline-formula><mml:math id="M74" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>d</mml:mi></mml:mrow></mml:math></inline-formula> refers to the offset of two soil spectra and where <inline-formula><mml:math id="M75" display="inline"><mml:mrow><mml:msub><mml:mi>A</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M76" display="inline"><mml:mrow><mml:msub><mml:mi>A</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M77" display="inline"><mml:mrow><mml:msub><mml:mi>A</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M78" display="inline"><mml:mrow><mml:msub><mml:mi>A</mml:mi><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> represent the soil spectral parameters.</p>
      <p id="d2e1662">Considering the influence of SMC, we assume that the equivalent water thickness represents the transition from dry soil to wet soil (Yang et al., 2011). The formulas are defined as follows:

                <disp-formula specific-use="gather" content-type="numbered"><mml:math id="M79" display="block"><mml:mtable displaystyle="true"><mml:mlabeledtr id="Ch1.E10"><mml:mtd><mml:mtext>10</mml:mtext></mml:mtd><mml:mtd><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:msub><mml:mi>R</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>,</mml:mo><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mrow class="chem"><mml:mi mathvariant="normal">v</mml:mi></mml:mrow></mml:msub><mml:mo>,</mml:mo><mml:mi mathvariant="italic">ϕ</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:msub><mml:mi>R</mml:mi><mml:mi mathvariant="normal">d</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>,</mml:mo><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mrow class="chem"><mml:mi mathvariant="normal">v</mml:mi></mml:mrow></mml:msub><mml:mo>,</mml:mo><mml:mi mathvariant="italic">φ</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>)</mml:mo><mml:mo>×</mml:mo><mml:msup><mml:mi>e</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:msub><mml:mi mathvariant="italic">α</mml:mi><mml:mi mathvariant="normal">water</mml:mi></mml:msub><mml:mi>f</mml:mi></mml:mrow></mml:msup></mml:mrow></mml:mtd></mml:mlabeledtr><mml:mlabeledtr id="Ch1.E11"><mml:mtd><mml:mtext>11</mml:mtext></mml:mtd><mml:mtd><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:msub><mml:mi mathvariant="italic">α</mml:mi><mml:mi mathvariant="normal">water</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mn mathvariant="normal">4</mml:mn><mml:mi mathvariant="italic">π</mml:mi><mml:msub><mml:mi mathvariant="italic">χ</mml:mi><mml:mi mathvariant="normal">water</mml:mi></mml:msub></mml:mrow><mml:mi mathvariant="italic">λ</mml:mi></mml:mfrac></mml:mstyle></mml:mrow></mml:mtd></mml:mlabeledtr></mml:mtable></mml:math></disp-formula>

          where <inline-formula><mml:math id="M80" display="inline"><mml:mrow><mml:msub><mml:mi>R</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M81" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">v</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M82" display="inline"><mml:mi mathvariant="italic">φ</mml:mi></mml:math></inline-formula>, <inline-formula><mml:math id="M83" display="inline"><mml:mrow><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> represents wet soil reflectance, <inline-formula><mml:math id="M84" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">χ</mml:mi><mml:mi mathvariant="normal">water</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is the water refractive index for water, and <inline-formula><mml:math id="M85" display="inline"><mml:mi>f</mml:mi></mml:math></inline-formula> is the equivalent water thickness.</p>
</sec>
<sec id="Ch1.S2.SS2">
  <label>2.2</label><title>Improvement of the Hapke-HSR model</title>
      <p id="d2e1858">The primary challenge in addressing the statistical relationship between the SSA and wavelength of the Hapke-HSR model is to provide a stable parameter <inline-formula><mml:math id="M86" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">χ</mml:mi><mml:mi mathvariant="normal">soil</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>. In this study, we assume that the shape of the dry SSR is consistent with the variation in the SSA with wavelength (Ding et al., 2022). A method is proposed to calculate the parameter <inline-formula><mml:math id="M87" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">χ</mml:mi><mml:mi mathvariant="normal">soil</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> via the dry SSR and improve the Hapke-HSR model. The SSA typically has a significant influence on the SSR, with multiple scattering events often disregarded in the theoretical derivation (Yang, 2022). The relationships between dry SSR and SSA are as follows:

                <disp-formula specific-use="gather" content-type="numbered"><mml:math id="M88" display="block"><mml:mtable displaystyle="true"><mml:mlabeledtr id="Ch1.E12"><mml:mtd><mml:mtext>12</mml:mtext></mml:mtd><mml:mtd><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:msub><mml:mi>R</mml:mi><mml:mi mathvariant="normal">d</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>,</mml:mo><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">v</mml:mi></mml:msub><mml:mo>,</mml:mo><mml:mi mathvariant="italic">φ</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:msub><mml:mi>C</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub><mml:mo>×</mml:mo><mml:mi mathvariant="italic">ω</mml:mi></mml:mrow></mml:mtd></mml:mlabeledtr><mml:mlabeledtr id="Ch1.E13"><mml:mtd><mml:mtext>13</mml:mtext></mml:mtd><mml:mtd><mml:mrow><mml:mstyle displaystyle="true" class="stylechange"/><mml:msub><mml:mi>C</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mn mathvariant="normal">1</mml:mn><mml:mrow><mml:mn mathvariant="normal">4</mml:mn><mml:mo>(</mml:mo><mml:mi>cos⁡</mml:mi><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>+</mml:mo><mml:mi>cos⁡</mml:mi><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">v</mml:mi></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:mfrac></mml:mstyle><mml:mo mathvariant="italic">{</mml:mo><mml:mo>[</mml:mo><mml:mi>P</mml:mi><mml:mo>(</mml:mo><mml:mi>g</mml:mi><mml:mo>,</mml:mo><mml:msup><mml:mi>g</mml:mi><mml:mo>′</mml:mo></mml:msup><mml:mo>)</mml:mo><mml:mo>(</mml:mo><mml:mn mathvariant="normal">1</mml:mn><mml:mo>+</mml:mo><mml:mi>B</mml:mi><mml:mo>(</mml:mo><mml:mi>g</mml:mi><mml:mo>)</mml:mo><mml:mo>)</mml:mo><mml:mo>]</mml:mo><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn><mml:mo mathvariant="italic">}</mml:mo></mml:mrow></mml:mtd></mml:mlabeledtr><mml:mlabeledtr id="Ch1.E14"><mml:mtd><mml:mtext>14</mml:mtext></mml:mtd><mml:mtd><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:mi mathvariant="italic">ω</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">1</mml:mn><mml:mo>-</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:msub><mml:mi>C</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mo>×</mml:mo><mml:msub><mml:mi mathvariant="italic">χ</mml:mi><mml:mi mathvariant="normal">soil</mml:mi></mml:msub></mml:mrow><mml:mi mathvariant="italic">λ</mml:mi></mml:mfrac></mml:mstyle></mml:mrow></mml:mtd></mml:mlabeledtr><mml:mlabeledtr id="Ch1.E15"><mml:mtd><mml:mtext>15</mml:mtext></mml:mtd><mml:mtd><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:msub><mml:mi>C</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mo>=</mml:mo><mml:mn mathvariant="normal">4</mml:mn><mml:mi mathvariant="italic">π</mml:mi><mml:mi>M</mml:mi></mml:mrow></mml:mtd></mml:mlabeledtr><mml:mlabeledtr id="Ch1.E16"><mml:mtd><mml:mtext>16</mml:mtext></mml:mtd><mml:mtd><mml:mrow><mml:mstyle displaystyle="true" class="stylechange"/><mml:msub><mml:mi mathvariant="italic">χ</mml:mi><mml:mi mathvariant="normal">soil</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mi mathvariant="italic">λ</mml:mi><mml:mrow><mml:msub><mml:mi>C</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>×</mml:mo><mml:mo>(</mml:mo><mml:mn mathvariant="normal">1</mml:mn><mml:mo>-</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:msub><mml:mi>R</mml:mi><mml:mi mathvariant="normal">d</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>,</mml:mo><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">v</mml:mi></mml:msub><mml:mo>,</mml:mo><mml:mi mathvariant="italic">φ</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>)</mml:mo></mml:mrow><mml:mrow><mml:msub><mml:mi>C</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>)</mml:mo></mml:mrow></mml:mtd></mml:mlabeledtr></mml:mtable></mml:math></disp-formula>

          where <inline-formula><mml:math id="M89" display="inline"><mml:mrow><mml:msub><mml:mi>C</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M90" display="inline"><mml:mrow><mml:msub><mml:mi>C</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> are the shape adjustment parameters of the dry SSR. We use <inline-formula><mml:math id="M91" display="inline"><mml:mrow><mml:msub><mml:mi>C</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub><mml:mo>=</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M92" display="inline"><mml:mrow><mml:msub><mml:mi>C</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mo>=</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:math></inline-formula> as the initial values to simplify the calculation, and we then further calculate the shape adjustment parameters.</p>
      <p id="d2e2200">To incorporate the impact of multiple scattering within the soil, we first calculate the <inline-formula><mml:math id="M93" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">χ</mml:mi><mml:mi mathvariant="normal">soil</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> parameter via Eq. (16). This parameter is then utilized in the improved Hapke-HSR model to determine the dry SSR. We adjust the dry SSR estimated with the improved Hapke-HSR model via the measured SSR and then calculate the adjusted dry SSR. The relationship between the dry SSR simulated via the improved Hapke-HSR model and the measured dry SSR can be expressed via the following formula:

            <disp-formula id="Ch1.E17" content-type="numbered"><label>17</label><mml:math id="M94" display="block"><mml:mrow><mml:msubsup><mml:mi>R</mml:mi><mml:mi mathvariant="normal">d</mml:mi><mml:mo>′</mml:mo></mml:msubsup><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>,</mml:mo><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">v</mml:mi></mml:msub><mml:mo>,</mml:mo><mml:mi mathvariant="italic">φ</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:msub><mml:mi>C</mml:mi><mml:mn mathvariant="normal">3</mml:mn></mml:msub><mml:mo>×</mml:mo><mml:msub><mml:mi>R</mml:mi><mml:mi mathvariant="normal">d</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>,</mml:mo><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">v</mml:mi></mml:msub><mml:mo>,</mml:mo><mml:mi mathvariant="italic">φ</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>)</mml:mo><mml:mo>+</mml:mo><mml:msub><mml:mi>C</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:msub></mml:mrow></mml:math></disp-formula>

          where <inline-formula><mml:math id="M95" display="inline"><mml:mrow><mml:msub><mml:mi>C</mml:mi><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M96" display="inline"><mml:mrow><mml:msub><mml:mi>C</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> are spectral shape adjustment parameters for dry soil reflectance, obtained through linear regression between simulated and measured reflectance, and used as empirical correction terms to compensate for discrepancies arising from the simplified treatment of multiple scattering in the Hapke-HSR model. Here, <inline-formula><mml:math id="M97" display="inline"><mml:mrow><mml:msub><mml:mi>R</mml:mi><mml:mi mathvariant="normal">d</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M98" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">v</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M99" display="inline"><mml:mi mathvariant="italic">φ</mml:mi></mml:math></inline-formula>, <inline-formula><mml:math id="M100" display="inline"><mml:mrow><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> denotes the reflectance simulated by the improved Hapke-HSR model, and <inline-formula><mml:math id="M101" display="inline"><mml:mrow><mml:msubsup><mml:mi>R</mml:mi><mml:mi mathvariant="normal">d</mml:mi><mml:mo>′</mml:mo></mml:msubsup><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M102" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">v</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M103" display="inline"><mml:mi mathvariant="italic">φ</mml:mi></mml:math></inline-formula>, <inline-formula><mml:math id="M104" display="inline"><mml:mrow><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> represents the measured dry soil reflectance.</p>

      <fig id="F1" specific-use="star"><label>Figure 1</label><caption><p id="d2e2418">The variation in the soil refractive index (parameter <inline-formula><mml:math id="M105" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">χ</mml:mi><mml:mi mathvariant="normal">soil</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>) and SSA of dry soil with wavelength <bold>(a)</bold>. The measured dry soil reflectance (i.e., dup20_009) and soil reflectance calculated with the improved Hapke-HSR model <bold>(b)</bold>.</p></caption>
          <graphic xlink:href="https://gmd.copernicus.org/articles/19/4775/2026/gmd-19-4775-2026-f01.png"/>

        </fig>

      <p id="d2e2445">Figure 1a shows the variation in the parameter <inline-formula><mml:math id="M106" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">χ</mml:mi><mml:mi mathvariant="normal">soil</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> and soil SSA calculated with the dry SSR (i.e., dup20_009) considering the wavelength. The parameter <inline-formula><mml:math id="M107" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">χ</mml:mi><mml:mi mathvariant="normal">soil</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> increases with wavelength, the slope clearly increases at wavelengths of 2.0–2.5 <inline-formula><mml:math id="M108" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula>, and there are obvious peak values in the absorption band of water (centred at 1.47, 1.90 and 2.21 <inline-formula><mml:math id="M109" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula>). The soil SSA is highly similar to the dry SSR. With increasing wavelength, the SSA increases significantly in the spectral range of 0.4–1.36 <inline-formula><mml:math id="M110" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula>. In the spectral range of 1.36–2.5 <inline-formula><mml:math id="M111" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula>, obvious valleys occur in the absorption band of water, which is similar to that of dry SSR. In general, the SSA and dry SSR curves display very high similarity in terms of shape, but the SSA curve is flatter. Figure 1b shows the measured dry SSR and the SSR estimated with the improved Hapke-HSR model. Clearly, the SSR modelled by the improved Hapke-HSR model matches well with the measured dry SSR and can characterize the dry SSR characteristics well. The accuracy of this improved model in fitting these typical data is shown in Table 4 (<inline-formula><mml:math id="M112" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mo>=</mml:mo><mml:mn mathvariant="normal">1.00</mml:mn></mml:mrow></mml:math></inline-formula>, RMSE <inline-formula><mml:math id="M113" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.001). These analyses suggest that calculating the parameter <inline-formula><mml:math id="M114" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">χ</mml:mi><mml:mi mathvariant="normal">soil</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> via dry SSR data is feasible and can solve the problems associated with the statistical relationship between the SSA and wavelength of the Hapke-HSR model.</p>
</sec>
<sec id="Ch1.S2.SS3">
  <label>2.3</label><title>Coupling strategy between the improved Hapke-HSR and MARMIT-2 models</title>
<sec id="Ch1.S2.SS3.SSS1">
  <label>2.3.1</label><title>Physical coupling mechanism between the improved Hapke-HSR model and MARMIT-2 model</title>
      <p id="d2e2559">The improved Hapke-HSR model provides an effective description of multi-angular dry soil spectral reflectance, whereas the MARMIT-2 model explicitly accounts for the influence of SMC on soil reflectance but assumes that dry reflectance is known and does not incorporate directional information. By coupling these two models, their complementary strengths can be integrated to achieve a more physically consistent representation of both the spectral and moisture-dependent behavior of soils. In the proposed framework, dry soil reflectance under different viewing geometries is first simulated using the improved Hapke-HSR model and subsequently used as input to the MARMIT-2 model. As a result, the MARMIT-2 model no longer requires externally prescribed dry reflectance. Moreover, because the simulations of the Hapke-HSR model retain angular information, the coupled Hapke-HSR <inline-formula><mml:math id="M115" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> MARMIT-2 model is able to account for the influence of observation geometry on soil reflectance. Through this coupling strategy, the reflectance properties of both dry and wet soils can be simulated under varying angular and moisture conditions within a unified framework (Ding et al., 2025).</p>
</sec>
<sec id="Ch1.S2.SS3.SSS2">
  <label>2.3.2</label><title>Radiative transfer formulation of the coupled Hapke-HSR <inline-formula><mml:math id="M116" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> MARMIT-2 model</title>
      <p id="d2e2585">In the MARMIT-2 model, wet soil is described as dry soil overlaid with a thin layer of water (Dupiau et al., 2022). Therefore, the wet SSR is described as follows:

              <disp-formula id="Ch1.E18" content-type="numbered"><label>18</label><mml:math id="M117" display="block"><mml:mtable rowspacing="0.2ex" class="split" displaystyle="true" columnalign="right left"><mml:mtr><mml:mtd><mml:mrow><mml:msub><mml:mi>R</mml:mi><mml:mi mathvariant="normal">mod</mml:mi></mml:msub></mml:mrow></mml:mtd><mml:mtd><mml:mrow><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>,</mml:mo><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">v</mml:mi></mml:msub><mml:mo>,</mml:mo><mml:mi mathvariant="italic">φ</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:mo mathvariant="italic">{</mml:mo><mml:mi mathvariant="italic">ε</mml:mi><mml:msub><mml:mi>R</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>,</mml:mo><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">v</mml:mi></mml:msub><mml:mo>,</mml:mo><mml:mi mathvariant="italic">φ</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="italic">λ</mml:mi><mml:msup><mml:mo>)</mml:mo><mml:mstyle scriptlevel="+1"><mml:mfrac><mml:mn mathvariant="normal">1</mml:mn><mml:mn mathvariant="normal">2.27</mml:mn></mml:mfrac></mml:mstyle></mml:msup></mml:mrow></mml:mtd></mml:mtr><mml:mtr><mml:mtd/><mml:mtd><mml:mrow><mml:mo>+</mml:mo><mml:mo>(</mml:mo><mml:mn mathvariant="normal">1</mml:mn><mml:mo>-</mml:mo><mml:mi mathvariant="italic">ε</mml:mi><mml:mo>)</mml:mo><mml:msub><mml:mi>R</mml:mi><mml:mi mathvariant="normal">d</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>,</mml:mo><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">v</mml:mi></mml:msub><mml:mo>,</mml:mo><mml:mi mathvariant="italic">φ</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="italic">λ</mml:mi><mml:msup><mml:mo>)</mml:mo><mml:mstyle scriptlevel="+1"><mml:mfrac><mml:mn mathvariant="normal">1</mml:mn><mml:mn mathvariant="normal">2.27</mml:mn></mml:mfrac></mml:mstyle></mml:msup><mml:msup><mml:mo mathvariant="italic">}</mml:mo><mml:mn mathvariant="normal">2.27</mml:mn></mml:msup></mml:mrow></mml:mtd></mml:mtr></mml:mtable></mml:math></disp-formula>

            where <inline-formula><mml:math id="M118" display="inline"><mml:mrow><mml:msub><mml:mi>R</mml:mi><mml:mi mathvariant="normal">mod</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M119" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">v</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M120" display="inline"><mml:mi mathvariant="italic">φ</mml:mi></mml:math></inline-formula>, <inline-formula><mml:math id="M121" display="inline"><mml:mrow><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> is the wet SSR, <inline-formula><mml:math id="M122" display="inline"><mml:mrow><mml:msub><mml:mi>R</mml:mi><mml:mi mathvariant="normal">d</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M123" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">v</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M124" display="inline"><mml:mi mathvariant="italic">φ</mml:mi></mml:math></inline-formula>, <inline-formula><mml:math id="M125" display="inline"><mml:mrow><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> is the dry SSR calculated via the improved Hapke-HSR model, <inline-formula><mml:math id="M126" display="inline"><mml:mrow><mml:msub><mml:mi>R</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M127" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">v</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M128" display="inline"><mml:mi mathvariant="italic">φ</mml:mi></mml:math></inline-formula>, <inline-formula><mml:math id="M129" display="inline"><mml:mrow><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> refers to the fully wet SSR, <inline-formula><mml:math id="M130" display="inline"><mml:mi mathvariant="italic">ε</mml:mi></mml:math></inline-formula> is the wet soil fraction, and <inline-formula><mml:math id="M131" display="inline"><mml:mrow><mml:msub><mml:mi>R</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M132" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">v</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M133" display="inline"><mml:mi mathvariant="italic">φ</mml:mi></mml:math></inline-formula>, <inline-formula><mml:math id="M134" display="inline"><mml:mrow><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> is described as:

              <disp-formula id="Ch1.E19" content-type="numbered"><label>19</label><mml:math id="M135" display="block"><mml:mrow><mml:msub><mml:mi>R</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>,</mml:mo><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mrow class="chem"><mml:mi mathvariant="normal">v</mml:mi></mml:mrow></mml:msub><mml:mo>,</mml:mo><mml:mi mathvariant="italic">φ</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:msub><mml:mi>t</mml:mi><mml:mn mathvariant="normal">12</mml:mn></mml:msub><mml:msub><mml:mi>t</mml:mi><mml:mn mathvariant="normal">21</mml:mn></mml:msub><mml:msub><mml:mi>R</mml:mi><mml:mi mathvariant="normal">d</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>,</mml:mo><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mrow class="chem"><mml:mi mathvariant="normal">v</mml:mi></mml:mrow></mml:msub><mml:mo>,</mml:mo><mml:mi mathvariant="italic">φ</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>)</mml:mo><mml:msubsup><mml:mi>T</mml:mi><mml:mi mathvariant="normal">w</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msubsup></mml:mrow><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>-</mml:mo><mml:msub><mml:mi>r</mml:mi><mml:mn mathvariant="normal">21</mml:mn></mml:msub><mml:msub><mml:mi>R</mml:mi><mml:mi mathvariant="normal">d</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>,</mml:mo><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mrow class="chem"><mml:mi mathvariant="normal">v</mml:mi></mml:mrow></mml:msub><mml:mo>,</mml:mo><mml:mi mathvariant="italic">φ</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>)</mml:mo><mml:msubsup><mml:mi>T</mml:mi><mml:mi mathvariant="normal">w</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msubsup></mml:mrow></mml:mfrac></mml:mstyle></mml:mrow></mml:math></disp-formula>

            where <inline-formula><mml:math id="M136" display="inline"><mml:mrow><mml:msub><mml:mi>t</mml:mi><mml:mn mathvariant="normal">12</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M137" display="inline"><mml:mrow><mml:msub><mml:mi>t</mml:mi><mml:mn mathvariant="normal">21</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> are the interface transmittance of light passing into and out of the water layer, respectively.</p>
      <p id="d2e3083">To address the presence of multiple scattering events within the water layer, transmittance (<inline-formula><mml:math id="M138" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>) is considered.

              <disp-formula id="Ch1.E20" content-type="numbered"><label>20</label><mml:math id="M139" display="block"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mo>(</mml:mo><mml:mn mathvariant="normal">1</mml:mn><mml:mo>-</mml:mo><mml:msub><mml:mi mathvariant="italic">α</mml:mi><mml:mi mathvariant="normal">water</mml:mi></mml:msub><mml:mi>L</mml:mi><mml:mo>)</mml:mo><mml:msup><mml:mi>e</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:msub><mml:mi mathvariant="italic">α</mml:mi><mml:mi mathvariant="normal">water</mml:mi></mml:msub><mml:mi>L</mml:mi></mml:mrow></mml:msup><mml:mo>+</mml:mo><mml:msub><mml:mi mathvariant="italic">α</mml:mi><mml:mi mathvariant="normal">water</mml:mi></mml:msub><mml:mi>L</mml:mi><mml:munderover><mml:mo movablelimits="false">∫</mml:mo><mml:mrow><mml:msub><mml:mi mathvariant="italic">α</mml:mi><mml:mi mathvariant="normal">water</mml:mi></mml:msub><mml:mi>L</mml:mi></mml:mrow><mml:mi mathvariant="normal">∞</mml:mi></mml:munderover><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:msup><mml:mi>e</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mi>x</mml:mi></mml:mrow></mml:msup></mml:mrow><mml:mi>x</mml:mi></mml:mfrac></mml:mstyle><mml:mi mathvariant="normal">d</mml:mi><mml:mi>x</mml:mi></mml:mrow></mml:math></disp-formula>

            where <inline-formula><mml:math id="M140" display="inline"><mml:mi>L</mml:mi></mml:math></inline-formula> refers to the water layer thickness.

              <disp-formula id="Ch1.E21" content-type="numbered"><label>21</label><mml:math id="M141" display="block"><mml:mrow><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">mix</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mi mathvariant="italic">δ</mml:mi><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">soil</mml:mi></mml:msub><mml:mo>+</mml:mo><mml:mo>(</mml:mo><mml:mn mathvariant="normal">1</mml:mn><mml:mo>-</mml:mo><mml:mi mathvariant="italic">δ</mml:mi><mml:mo>)</mml:mo><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">water</mml:mi></mml:msub></mml:mrow></mml:math></disp-formula>

            where <inline-formula><mml:math id="M142" display="inline"><mml:mrow><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">mix</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> represents the result of the linear weighting of the complex refractive index of water and soil, <inline-formula><mml:math id="M143" display="inline"><mml:mrow><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">soil</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M144" display="inline"><mml:mrow><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">water</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> represents the complex refractive index of water and soil particles respectively, and <inline-formula><mml:math id="M145" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula> represents the volume fraction of soil particles.</p>
</sec>
<sec id="Ch1.S2.SS3.SSS3">
  <label>2.3.3</label><title>Computational procedure and evaluation scheme</title>
      <p id="d2e3271">Figure 2 illustrates the workflow of the improved Hapke-HSR model and its coupling with the MARMIT-2 model. First, the soil parameter <inline-formula><mml:math id="M146" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">χ</mml:mi><mml:mi mathvariant="normal">soil</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is estimated from measured dry SSR by assuming similarity between the spectral shapes of the single-scattering albedo and dry SSR. The derived <inline-formula><mml:math id="M147" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">χ</mml:mi><mml:mi mathvariant="normal">soil</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is then incorporated into the Hapke-HSR model, which alleviates the limitations associated with piecewise fitting of the single scattering albedo and improves the numerical stability of the formulation. The refined Hapke-HSR model is subsequently used to simulate dry SSR under different viewing geometries, and these simulations are provided as input to the MARMIT-2 model, thereby enabling the dynamic coupling of the two formulations. For parameter estimation, the coupled model allows flexible inversion strategies. In this study, the parameters can be estimated either simultaneously by jointly optimizing all model parameters, or sequentially by first determining the dry-soil scattering parameters (e.g., <inline-formula><mml:math id="M148" display="inline"><mml:mi>b</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math id="M149" display="inline"><mml:mi>M</mml:mi></mml:math></inline-formula>) using the Hapke-HSR model, followed by the estimation of moisture-related parameters (e.g., <inline-formula><mml:math id="M150" display="inline"><mml:mi mathvariant="italic">ε</mml:mi></mml:math></inline-formula>, <inline-formula><mml:math id="M151" display="inline"><mml:mi>L</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math id="M152" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula>) using the MARMIT-2 model. Finally, the performance of the coupled Hapke-HSR <inline-formula><mml:math id="M153" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> MARMIT-2 model is evaluated using eight independent soil spectral databases spanning a range of soil moisture conditions. Model performance is assessed using multiple statistical metrics, including the coefficient of determination (<inline-formula><mml:math id="M154" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>), root mean square error (RMSE), normalized RMSE (NRMSE), mean relative error (MRE), and bias.</p>

      <fig id="F2"><label>Figure 2</label><caption><p id="d2e3352">The workflow of the improved Hapke-HSR model and the coupled MARMIT-2 model.</p></caption>
            <graphic xlink:href="https://gmd.copernicus.org/articles/19/4775/2026/gmd-19-4775-2026-f02.png"/>

          </fig>

</sec>
</sec>
</sec>
<sec id="Ch1.S3">
  <label>3</label><title>Databases and methods</title>
<sec id="Ch1.S3.SS1">
  <label>3.1</label><title>Databases of soil spectral reflectance</title>
      <p id="d2e3378">In this section, eight different databases provided by Dupiau et al. (2022) are used to verify the Hapke-HSR <inline-formula><mml:math id="M155" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> MARMIT-2 model (Table 2). These eight datasets were acquired primarily via the Analytical Spectra Devices (ASD) FieldSpec spectroradiometer. The soil types in the datasets are diverse, consisting primarily of clay, silt, and sand as the main components. The Bab16, Dup20, and Liu02 databases provide the soil components of each sample, such as organic matter, iron, nitrogen and organic carbon. These eight databases provide dry and wet SSR data for 219 soil samples, spanning 1984 spectra in the 0.4–2.5 <inline-formula><mml:math id="M156" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula> range. The data quality of these databases is high, but there are some uncertainties in the 2.4–2.5 <inline-formula><mml:math id="M157" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula> range. Therefore, these databases offer crucial data for validating the ability of the Hapke-HSR <inline-formula><mml:math id="M158" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> MARMIT-2 model to describe SSR features.</p>

<table-wrap id="T2" specific-use="star"><label>Table 2</label><caption><p id="d2e3418">The main information on the eight soil databases. </p></caption><oasis:table frame="topbot"><oasis:tgroup cols="6">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="left"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:colspec colnum="4" colname="col4" align="right"/>
     <oasis:colspec colnum="5" colname="col5" align="right"/>
     <oasis:colspec colnum="6" colname="col6" align="right"/>
     <oasis:thead>
       <oasis:row>
         <oasis:entry colname="col1">Databases</oasis:entry>
         <oasis:entry colname="col2">Locations</oasis:entry>
         <oasis:entry colname="col3">Number of</oasis:entry>
         <oasis:entry colname="col4">Spectral range</oasis:entry>
         <oasis:entry colname="col5">Spectral resolution</oasis:entry>
         <oasis:entry colname="col6">SMCg</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2"/>
         <oasis:entry colname="col3">soil spectrum</oasis:entry>
         <oasis:entry colname="col4">(<inline-formula><mml:math id="M159" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col5">(<inline-formula><mml:math id="M160" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col6">(%)</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
         <oasis:entry colname="col1">Bab16</oasis:entry>
         <oasis:entry colname="col2">ONERA, Toulouse (France)</oasis:entry>
         <oasis:entry colname="col3">106</oasis:entry>
         <oasis:entry colname="col4">0.4–2.4</oasis:entry>
         <oasis:entry colname="col5">0.001</oasis:entry>
         <oasis:entry colname="col6">0–79.2</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Dup20</oasis:entry>
         <oasis:entry colname="col2">ONERA, Toulouse (France)</oasis:entry>
         <oasis:entry colname="col3">72</oasis:entry>
         <oasis:entry colname="col4">0.4–2.5</oasis:entry>
         <oasis:entry colname="col5">0.001</oasis:entry>
         <oasis:entry colname="col6">0–68.91</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Hum15</oasis:entry>
         <oasis:entry colname="col2">ONERA, Toulouse (France)</oasis:entry>
         <oasis:entry colname="col3">455</oasis:entry>
         <oasis:entry colname="col4">0.4–2.298</oasis:entry>
         <oasis:entry colname="col5">0.001</oasis:entry>
         <oasis:entry colname="col6">0–67</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Les08</oasis:entry>
         <oasis:entry colname="col2">ONERA, Toulouse (France)</oasis:entry>
         <oasis:entry colname="col3">190</oasis:entry>
         <oasis:entry colname="col4">0.4–2.4</oasis:entry>
         <oasis:entry colname="col5">0.001</oasis:entry>
         <oasis:entry colname="col6">0–87</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Liu02</oasis:entry>
         <oasis:entry colname="col2">INRAE, Avignon (France)</oasis:entry>
         <oasis:entry colname="col3">367</oasis:entry>
         <oasis:entry colname="col4">0.4–2.4</oasis:entry>
         <oasis:entry colname="col5">0.001</oasis:entry>
         <oasis:entry colname="col6">0–81.1</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Lob02</oasis:entry>
         <oasis:entry colname="col2">Standford University, Standford (CA, USA)</oasis:entry>
         <oasis:entry colname="col3">41</oasis:entry>
         <oasis:entry colname="col4">0.4–2.49</oasis:entry>
         <oasis:entry colname="col5">0.001</oasis:entry>
         <oasis:entry colname="col6">0–109.4</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Mar12</oasis:entry>
         <oasis:entry colname="col2">CEA, Bruyères le Chatel (France)</oasis:entry>
         <oasis:entry colname="col3">258</oasis:entry>
         <oasis:entry colname="col4">0.4–2.4</oasis:entry>
         <oasis:entry colname="col5">0.001</oasis:entry>
         <oasis:entry colname="col6">0–52.9</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Phil14</oasis:entry>
         <oasis:entry colname="col2">Cornell University, Ithaca (NY, USA)</oasis:entry>
         <oasis:entry colname="col3">405</oasis:entry>
         <oasis:entry colname="col4">0.4–2.5</oasis:entry>
         <oasis:entry colname="col5">0.001</oasis:entry>
         <oasis:entry colname="col6">0–50.71</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table><table-wrap-foot><p id="d2e3421">Note: SMCg is the soil moisture content (SMC) as a weight percent.</p></table-wrap-foot></table-wrap>

</sec>
</sec>
<sec id="Ch1.S4">
  <label>4</label><title>Results and analysis</title>
<sec id="Ch1.S4.SS1">
  <label>4.1</label><title>Parameters analysis of the Hapke-HSR <inline-formula><mml:math id="M161" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> MARMIT-2 model</title>
      <p id="d2e3711">In this section, we first analyse the effects of the main input parameters of the Hapke-HSR <inline-formula><mml:math id="M162" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> MARMIT-2 (HM) model on the soil reflectance properties. Table 3 shows the main input variables of the HM model. The Hapke-HSR model has many input variables, and the variables of this model were optimized in previous studies (Ding et al., 2022; Dupiau et al., 2022; Hapke, 2012; Verhoef et al., 2018); five main variables were used to describe the soil spectral and angular features. The MARMIT-2 model includes three main parameters that describe the influence of the SMC on SSR. We analyse the effects of different parameters in the HM model on the simulated SSR.</p>

<table-wrap id="T3" specific-use="star"><label>Table 3</label><caption><p id="d2e3724">The main input variables of the Hapke-HSR <inline-formula><mml:math id="M163" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> MARMIT-2 (HM) model.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="4">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="left"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:colspec colnum="4" colname="col4" align="left"/>
     <oasis:thead>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">Databases</oasis:entry>
         <oasis:entry colname="col2">Parameters</oasis:entry>
         <oasis:entry colname="col3">Range of values</oasis:entry>
         <oasis:entry colname="col4">Units</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
         <oasis:entry colname="col1">Hapke-HSR</oasis:entry>
         <oasis:entry colname="col2">Solar zenith angle (SZA)</oasis:entry>
         <oasis:entry colname="col3">0–90</oasis:entry>
         <oasis:entry colname="col4">degrees (°)</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">View zenith angle (VZA)</oasis:entry>
         <oasis:entry colname="col3">0–90</oasis:entry>
         <oasis:entry colname="col4">degrees (°)</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">Relative azimuth angle (RAA)</oasis:entry>
         <oasis:entry colname="col3">0–180</oasis:entry>
         <oasis:entry colname="col4">degrees (°)</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">The coefficient of the scattering phase function (<inline-formula><mml:math id="M164" display="inline"><mml:mi>b</mml:mi></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col3">0–6</oasis:entry>
         <oasis:entry colname="col4">–</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">Soil particle size and shape-dependent parameter (<inline-formula><mml:math id="M165" display="inline"><mml:mi>M</mml:mi></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col3">0–1</oasis:entry>
         <oasis:entry colname="col4">mm</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">MARMIT-2</oasis:entry>
         <oasis:entry colname="col2">Volume fraction of soil particles (<inline-formula><mml:math id="M166" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col3">0–0.25</oasis:entry>
         <oasis:entry colname="col4">–</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">Thickness of water layer (<inline-formula><mml:math id="M167" display="inline"><mml:mi>L</mml:mi></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col3">0–0.15</oasis:entry>
         <oasis:entry colname="col4">cm</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">Surface coverage fraction of water (<inline-formula><mml:math id="M168" display="inline"><mml:mi mathvariant="italic">ε</mml:mi></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col3">0–1</oasis:entry>
         <oasis:entry colname="col4">–</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

      <p id="d2e3919">Figure 3 illustrates the impact of the main variables of the Hapke-HSR <inline-formula><mml:math id="M169" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> MARMIT-2 (HM) model on the SSR. For the influence of angle variation, the SSR calculated via the HM model increases with increasing SZA parameters. The increase in SSR is obvious in the range of 0.4–1.36 <inline-formula><mml:math id="M170" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula>; however, the rate of increase in SSR subsequently decreases. The impact of VZA parameters on SSR is consistent with the influence of the SZA parameters since the Hapke-HSR model is reciprocal. Furthermore, the influence of the RAA parameters on SSR is basically the same as that of the SZA parameters with increasing RAA parameters; however, the changes in soil reflectance are slightly different. With increasing parameter <inline-formula><mml:math id="M171" display="inline"><mml:mi>b</mml:mi></mml:math></inline-formula>, the SSR simulated by the HM model decreases, with a more pronounced reduction in the range of 0.4–1.36 <inline-formula><mml:math id="M172" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula> than in 1.36–2.5 <inline-formula><mml:math id="M173" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula>. Both parameters <inline-formula><mml:math id="M174" display="inline"><mml:mi>b</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math id="M175" display="inline"><mml:mi>c</mml:mi></mml:math></inline-formula> influence the BRDF shape through the phase function. However, <inline-formula><mml:math id="M176" display="inline"><mml:mi>b</mml:mi></mml:math></inline-formula> primarily controls the overall anisotropy of scattering, whereas <inline-formula><mml:math id="M177" display="inline"><mml:mi>c</mml:mi></mml:math></inline-formula> governs the forward–backward asymmetry. Under the observational configurations considered in this study, <inline-formula><mml:math id="M178" display="inline"><mml:mi>b</mml:mi></mml:math></inline-formula> shows a stronger and more stable influence on reflectance, while the sensitivity of <inline-formula><mml:math id="M179" display="inline"><mml:mi>c</mml:mi></mml:math></inline-formula> is relatively weaker. Therefore, the discussion focuses on parameter <inline-formula><mml:math id="M180" display="inline"><mml:mi>b</mml:mi></mml:math></inline-formula> (Ding et al., 2022). The SSR simulated with the HM model also decreases with increasing <inline-formula><mml:math id="M181" display="inline"><mml:mi>M</mml:mi></mml:math></inline-formula>; this finding corroborates the experimental observations regarding spectral variations due to soil particle size reported by Sun et al. (2023). However, the variation in the parameter <inline-formula><mml:math id="M182" display="inline"><mml:mi>M</mml:mi></mml:math></inline-formula> of the SSR is basically the same at different wavelengths. A possible reason is that the influence of the parameter <inline-formula><mml:math id="M183" display="inline"><mml:mi>M</mml:mi></mml:math></inline-formula> in the range of 0.4–2.5 <inline-formula><mml:math id="M184" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula> on the SSR is consistent, which may be related to the structure of Eq. (7). For the variables related to the SMC, with increasing parameter <inline-formula><mml:math id="M185" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula>, the SSR decreases, whereas in the strong absorption band of water, this effect is smaller. A possible reason for this result is that the absorption of water weakens the impact of the parameter  <inline-formula><mml:math id="M186" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula> on the SSR. As the parameter <inline-formula><mml:math id="M187" display="inline"><mml:mi>L</mml:mi></mml:math></inline-formula> increases, the SSR decreases in the range of 1.0–2.5 <inline-formula><mml:math id="M188" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula>, whereas the variation in the parameter <inline-formula><mml:math id="M189" display="inline"><mml:mi>L</mml:mi></mml:math></inline-formula> has no effect on the soil reflectance in the range of 0.4–1.0 <inline-formula><mml:math id="M190" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula>. With increasing parameter <inline-formula><mml:math id="M191" display="inline"><mml:mi mathvariant="italic">ε</mml:mi></mml:math></inline-formula>, the SSR decreases. In the strong absorption band of water, the simulated SSR quickly decreases. In summary, the main parameters of the Hapke-HSR model are related to the influence of dry SSR and angular variation characteristics, and the variables of the MARMIT-2 model mainly account for the influence of SMC on the SSR. Therefore, the HM model can characterize the spectral and angular reflectance attributes of dry and wet soils by coupling the Hapke-HSR and MARMIT-2 models.</p>

      <fig id="F3" specific-use="star"><label>Figure 3</label><caption><p id="d2e4107">Influence of the SZA <bold>(a)</bold>, VZA <bold>(b)</bold>, RAA <bold>(c)</bold>, <inline-formula><mml:math id="M192" display="inline"><mml:mi>b</mml:mi></mml:math></inline-formula> <bold>(d)</bold>, <inline-formula><mml:math id="M193" display="inline"><mml:mi>M</mml:mi></mml:math></inline-formula> <bold>(e)</bold>, <inline-formula><mml:math id="M194" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula> <bold>(f)</bold>, and <inline-formula><mml:math id="M195" display="inline"><mml:mi mathvariant="italic">ε</mml:mi></mml:math></inline-formula> <bold>(h)</bold> in the Hapke-HSR <inline-formula><mml:math id="M196" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> MARMIT-2 (HM) model on soil reflectance.</p></caption>
          <graphic xlink:href="https://gmd.copernicus.org/articles/19/4775/2026/gmd-19-4775-2026-f03.png"/>

        </fig>

</sec>
<sec id="Ch1.S4.SS2">
  <label>4.2</label><title>Validating the Hapke-HSR <inline-formula><mml:math id="M197" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> MARMIT-2 model to describe soil reflectance properties</title>
      <p id="d2e4190">In previous studies, we assessed the Hapke-HSR model to describe soil BRDF features (Ding et al., 2022). Therefore, we focus mainly on evaluating the soil spectral characteristics in this paper. In addition, these eight soil databases do not provide angle-related information. Therefore, we use SZA <inline-formula><mml:math id="M198" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 45°, VZA <inline-formula><mml:math id="M199" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0° and RAA <inline-formula><mml:math id="M200" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0° as fixed values because SSR is usually measured in the nadir direction. Figure 4 shows that the Hapke-HSR, MARMIT-2 and Hapke-HSR <inline-formula><mml:math id="M201" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> MARMIT-2 (HM) models effectively fit the influence of the typical fitted SSR (dup20_009-001) at SMCs <inline-formula><mml:math id="M202" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0 %, 14.45 %, 27.34 %, 31.6 %, 36.2 %, 40.34 %, 45.07 %, 49.25 %, and 57.06 %, respectively. The SSR decreases significantly with increasing SMC, and the main absorption bands (centred at 1.47 and 1.90 <inline-formula><mml:math id="M203" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula>) of water become wider. The outcomes simulated using the Hapke-HSR, MARMIT-2 and HM models can be used to determine the change in SSR with increasing SMC and are highly in line with the measured SSR values. On the basis of a comparison of the results, the HM model fits the measured SSR better than the Hapke-HSR and MARMIT-2 models do, especially at SMC <inline-formula><mml:math id="M204" display="inline"><mml:mo>≥</mml:mo></mml:math></inline-formula> 30 %. Compared with the MARMIT-2 model, the HM model yields slightly better results. The main reason is that the MARMIT-2 model yields very high accuracy in characterizing SSR characteristics. The ability of the Hapke-HSR model to accurately fit the measured SSR decreases with increasing SMC. The correlation analysis results indicate that the fitting ability of these two models meets the relevant requirements. However, at SMC <inline-formula><mml:math id="M205" display="inline"><mml:mo>≥</mml:mo></mml:math></inline-formula> 30 %, the fitting capability of the MARMIT-2 model is relatively low due to slight underestimations in the range of 0.4–1.36 <inline-formula><mml:math id="M206" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula>, and there is an overestimation in the strong water absorption band; moreover, the Hapke-HSR model has difficulty capturing the SSR characteristics in the absorption band of water, which leads to significant underestimation of the fitted SSR at a wavelength of approximately 1.90 <inline-formula><mml:math id="M207" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula>. However, the HM model effectively considers the influence of these factors, resulting in high accuracy for characterizing SSR attributes. To show the differences between the SSR values simulated with these three models and the measured spectral reflectance values, we calculate the bias between them, as shown in Appendix Fig. A1. In addition, the Hapke-HSR and HM models are applied to simulate the dry SSR, and the SSR simulated via the HM model is more consistent with the measured results than the SSR obtained with the Hapke-HSR model is.</p>
      <p id="d2e4273">Table 4 shows that the Hapke-HSR, MARMIT-2 and HM models fit the parameters and statistical results of the SSR. With increasing SMC, the parameters <inline-formula><mml:math id="M208" display="inline"><mml:mi>L</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math id="M209" display="inline"><mml:mi mathvariant="italic">ε</mml:mi></mml:math></inline-formula> in the MARMIT-2 model increase significantly, whereas the parameter <inline-formula><mml:math id="M210" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula>shows little variation. The parameter f increases significantly. Moreover, the SSR fitting accuracy of the Hapke-HSR and MARMIT-2 models decreases with increasing SMC, especially at SMC <inline-formula><mml:math id="M211" display="inline"><mml:mo>≥</mml:mo></mml:math></inline-formula> 30 %. This finding may be because the MARMIT-2 model ignores the variations in soil scattering characteristics, particle size and shape with increasing SMC. In the Hapke-HSR model, a dry soil surface is overlaid with a water layer to reflect the influence of the SMC on the SSR. This simple assumption limits the ability of the Hapke-HSR model to fit the variable characteristics of the SMC. The overall <inline-formula><mml:math id="M212" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula> values for the Hapke-HSR model in SSR fitting vary from 0.952 to 0.971, with RMSE values varying from 0.016 to 0.019, and the MARMIT-2 model achieves <inline-formula><mml:math id="M213" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula> values between 0.957 and 0.995 in SSR fitting, with RMSE values ranging from 0.007 to 0.021 and negligible bias. These results indicate that these two models can effectively characterize the variation in SSR with SMC and yield high fitting accuracy. However, the HM model is accurate (RMSE <inline-formula><mml:math id="M214" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.008), presenting a high <inline-formula><mml:math id="M215" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula> (<inline-formula><mml:math id="M216" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.991</mml:mn></mml:mrow></mml:math></inline-formula>) and a small bias in relation to the measured SSR. This is because the HM model considers the variations in the soil scattering characteristics, particle size and particle shape with increasing SMC. Therefore, the HM model can effectively characterize the attributes of SSR and exhibits greater accuracy than the Hapke-HSR and MARMIT-2 models do, especially at SMC <inline-formula><mml:math id="M217" display="inline"><mml:mo>≥</mml:mo></mml:math></inline-formula> 30 %.</p>

      <fig id="F4" specific-use="star"><label>Figure 4</label><caption><p id="d2e4369">The Hapke-HSR (red), MARMIT-2 (blue) and Hapke-HSR <inline-formula><mml:math id="M218" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> MARMIT-2 (HM) (lime) models fit the measured soil reflectance (black) at SMC <inline-formula><mml:math id="M219" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0 % <bold>(a)</bold>, 14.45 % <bold>(b)</bold>, 27.34 % <bold>(c)</bold>, 31.6 % <bold>(d)</bold>, 36.2 % <bold>(e)</bold>, 40.34 % <bold>(f)</bold>, 45.07 % <bold>(g)</bold>, 49.25 % <bold>(h)</bold>, and 57.06 % <bold>(i)</bold>, respectively.</p></caption>
          <graphic xlink:href="https://gmd.copernicus.org/articles/19/4775/2026/gmd-19-4775-2026-f04.png"/>

        </fig>

<table-wrap id="T4" specific-use="star"><label>Table 4</label><caption><p id="d2e4424">The Hapke-HSR, MARMIT-2 and Hapke-HSR <inline-formula><mml:math id="M220" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> MARMIT-2 (HM) models fit the soil reflectance variables and statistical outcomes.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="11">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="left"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:colspec colnum="4" colname="col4" align="right"/>
     <oasis:colspec colnum="5" colname="col5" align="right"/>
     <oasis:colspec colnum="6" colname="col6" align="right"/>
     <oasis:colspec colnum="7" colname="col7" align="right"/>
     <oasis:colspec colnum="8" colname="col8" align="right"/>
     <oasis:colspec colnum="9" colname="col9" align="right"/>
     <oasis:colspec colnum="10" colname="col10" align="right"/>
     <oasis:colspec colnum="11" colname="col11" align="right"/>
     <oasis:thead>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">Models</oasis:entry>
         <oasis:entry colname="col2">SMC (%)</oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M221" display="inline"><mml:mi>b</mml:mi></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M222" display="inline"><mml:mrow><mml:mi>f</mml:mi><mml:mo>/</mml:mo><mml:mi>M</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M223" display="inline"><mml:mrow><mml:msub><mml:mi>A</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub><mml:mo>/</mml:mo><mml:mi mathvariant="italic">δ</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M224" display="inline"><mml:mrow><mml:msub><mml:mi>A</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub><mml:mo>/</mml:mo><mml:mi>L</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M225" display="inline"><mml:mrow><mml:msub><mml:mi>A</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mo>/</mml:mo><mml:mi mathvariant="italic">ε</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col8"><inline-formula><mml:math id="M226" display="inline"><mml:mrow><mml:msub><mml:mi>A</mml:mi><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col9"><inline-formula><mml:math id="M227" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col10">RMSE</oasis:entry>
         <oasis:entry colname="col11">bias</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
         <oasis:entry colname="col1">Hapke-HSR</oasis:entry>
         <oasis:entry colname="col2">0.0</oasis:entry>
         <oasis:entry colname="col3">4.4</oasis:entry>
         <oasis:entry colname="col4">0.4</oasis:entry>
         <oasis:entry colname="col5">0.782</oasis:entry>
         <oasis:entry colname="col6">0.723</oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M228" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>1.141</oasis:entry>
         <oasis:entry colname="col8">4.178</oasis:entry>
         <oasis:entry colname="col9">0.972</oasis:entry>
         <oasis:entry colname="col10">0.016</oasis:entry>
         <oasis:entry colname="col11">0.001</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">14.45</oasis:entry>
         <oasis:entry colname="col3">4.8</oasis:entry>
         <oasis:entry colname="col4">1.0</oasis:entry>
         <oasis:entry colname="col5">0.545</oasis:entry>
         <oasis:entry colname="col6">0.796</oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M229" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.708</oasis:entry>
         <oasis:entry colname="col8">3.054</oasis:entry>
         <oasis:entry colname="col9">0.976</oasis:entry>
         <oasis:entry colname="col10">0.013</oasis:entry>
         <oasis:entry colname="col11">0.001</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">27.34</oasis:entry>
         <oasis:entry colname="col3">3.0</oasis:entry>
         <oasis:entry colname="col4">1.6</oasis:entry>
         <oasis:entry colname="col5">0.861</oasis:entry>
         <oasis:entry colname="col6">0.677</oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M230" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>1.151</oasis:entry>
         <oasis:entry colname="col8">4.336</oasis:entry>
         <oasis:entry colname="col9">0.968</oasis:entry>
         <oasis:entry colname="col10">0.016</oasis:entry>
         <oasis:entry colname="col11">0.000</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">31.6</oasis:entry>
         <oasis:entry colname="col3">1.4</oasis:entry>
         <oasis:entry colname="col4">2.0</oasis:entry>
         <oasis:entry colname="col5">1.586</oasis:entry>
         <oasis:entry colname="col6">0.405</oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M231" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>1.908</oasis:entry>
         <oasis:entry colname="col8">6.738</oasis:entry>
         <oasis:entry colname="col9">0.962</oasis:entry>
         <oasis:entry colname="col10">0.019</oasis:entry>
         <oasis:entry colname="col11">0.001</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">36.2</oasis:entry>
         <oasis:entry colname="col3">1.6</oasis:entry>
         <oasis:entry colname="col4">2.2</oasis:entry>
         <oasis:entry colname="col5">1.431</oasis:entry>
         <oasis:entry colname="col6">0.479</oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M232" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>1.795</oasis:entry>
         <oasis:entry colname="col8">6.326</oasis:entry>
         <oasis:entry colname="col9">0.954</oasis:entry>
         <oasis:entry colname="col10">0.020</oasis:entry>
         <oasis:entry colname="col11">0.002</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">40.34</oasis:entry>
         <oasis:entry colname="col3">1.0</oasis:entry>
         <oasis:entry colname="col4">2.4</oasis:entry>
         <oasis:entry colname="col5">1.699</oasis:entry>
         <oasis:entry colname="col6">0.392</oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M233" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>1.924</oasis:entry>
         <oasis:entry colname="col8">6.948</oasis:entry>
         <oasis:entry colname="col9">0.948</oasis:entry>
         <oasis:entry colname="col10">0.020</oasis:entry>
         <oasis:entry colname="col11">0.002</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">45.07</oasis:entry>
         <oasis:entry colname="col3">0.0</oasis:entry>
         <oasis:entry colname="col4">2.8</oasis:entry>
         <oasis:entry colname="col5">2.772</oasis:entry>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M234" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.009</oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M235" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>2.420</oasis:entry>
         <oasis:entry colname="col8">9.426</oasis:entry>
         <oasis:entry colname="col9">0.945</oasis:entry>
         <oasis:entry colname="col10">0.021</oasis:entry>
         <oasis:entry colname="col11">0.001</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">49.25</oasis:entry>
         <oasis:entry colname="col3">0.8</oasis:entry>
         <oasis:entry colname="col4">2.8</oasis:entry>
         <oasis:entry colname="col5">1.747</oasis:entry>
         <oasis:entry colname="col6">0.384</oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M236" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>1.757</oasis:entry>
         <oasis:entry colname="col8">6.801</oasis:entry>
         <oasis:entry colname="col9">0.938</oasis:entry>
         <oasis:entry colname="col10">0.022</oasis:entry>
         <oasis:entry colname="col11">0.001</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">57.06</oasis:entry>
         <oasis:entry colname="col3">0.2</oasis:entry>
         <oasis:entry colname="col4">3.4</oasis:entry>
         <oasis:entry colname="col5">2.316</oasis:entry>
         <oasis:entry colname="col6">0.188</oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M237" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>1.390</oasis:entry>
         <oasis:entry colname="col8">7.026</oasis:entry>
         <oasis:entry colname="col9">0.936</oasis:entry>
         <oasis:entry colname="col10">0.023</oasis:entry>
         <oasis:entry colname="col11">0.001</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">All</oasis:entry>
         <oasis:entry colname="col3">–</oasis:entry>
         <oasis:entry colname="col4">–</oasis:entry>
         <oasis:entry colname="col5">–</oasis:entry>
         <oasis:entry colname="col6">–</oasis:entry>
         <oasis:entry colname="col7">–</oasis:entry>
         <oasis:entry colname="col8">–</oasis:entry>
         <oasis:entry colname="col9">0.952</oasis:entry>
         <oasis:entry colname="col10">0.019</oasis:entry>
         <oasis:entry colname="col11">0.001</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">MARMIT-2</oasis:entry>
         <oasis:entry colname="col2">0</oasis:entry>
         <oasis:entry colname="col3">–</oasis:entry>
         <oasis:entry colname="col4">–</oasis:entry>
         <oasis:entry colname="col5">–</oasis:entry>
         <oasis:entry colname="col6">–</oasis:entry>
         <oasis:entry colname="col7">–</oasis:entry>
         <oasis:entry colname="col8">–</oasis:entry>
         <oasis:entry colname="col9">–</oasis:entry>
         <oasis:entry colname="col10">–</oasis:entry>
         <oasis:entry colname="col11">–</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">14.45</oasis:entry>
         <oasis:entry colname="col3">–</oasis:entry>
         <oasis:entry colname="col4">–</oasis:entry>
         <oasis:entry colname="col5">0.030</oasis:entry>
         <oasis:entry colname="col6">0.01</oasis:entry>
         <oasis:entry colname="col7">0.3</oasis:entry>
         <oasis:entry colname="col8">–</oasis:entry>
         <oasis:entry colname="col9">0.995</oasis:entry>
         <oasis:entry colname="col10">0.007</oasis:entry>
         <oasis:entry colname="col11">0.001</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">27.34</oasis:entry>
         <oasis:entry colname="col3">–</oasis:entry>
         <oasis:entry colname="col4">–</oasis:entry>
         <oasis:entry colname="col5">0.000</oasis:entry>
         <oasis:entry colname="col6">0.03</oasis:entry>
         <oasis:entry colname="col7">0.3</oasis:entry>
         <oasis:entry colname="col8">–</oasis:entry>
         <oasis:entry colname="col9">0.984</oasis:entry>
         <oasis:entry colname="col10">0.013</oasis:entry>
         <oasis:entry colname="col11"><inline-formula><mml:math id="M238" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.002</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">31.6</oasis:entry>
         <oasis:entry colname="col3">–</oasis:entry>
         <oasis:entry colname="col4">–</oasis:entry>
         <oasis:entry colname="col5">0.000</oasis:entry>
         <oasis:entry colname="col6">0.03</oasis:entry>
         <oasis:entry colname="col7">0.3</oasis:entry>
         <oasis:entry colname="col8">–</oasis:entry>
         <oasis:entry colname="col9">0.957</oasis:entry>
         <oasis:entry colname="col10">0.019</oasis:entry>
         <oasis:entry colname="col11"><inline-formula><mml:math id="M239" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.002</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">36.2</oasis:entry>
         <oasis:entry colname="col3">–</oasis:entry>
         <oasis:entry colname="col4">–</oasis:entry>
         <oasis:entry colname="col5">0.000</oasis:entry>
         <oasis:entry colname="col6">0.02</oasis:entry>
         <oasis:entry colname="col7">0.4</oasis:entry>
         <oasis:entry colname="col8">–</oasis:entry>
         <oasis:entry colname="col9">0.955</oasis:entry>
         <oasis:entry colname="col10">0.021</oasis:entry>
         <oasis:entry colname="col11"><inline-formula><mml:math id="M240" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.008</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">40.34</oasis:entry>
         <oasis:entry colname="col3">–</oasis:entry>
         <oasis:entry colname="col4">–</oasis:entry>
         <oasis:entry colname="col5">0.000</oasis:entry>
         <oasis:entry colname="col6">0.03</oasis:entry>
         <oasis:entry colname="col7">0.4</oasis:entry>
         <oasis:entry colname="col8">–</oasis:entry>
         <oasis:entry colname="col9">0.970</oasis:entry>
         <oasis:entry colname="col10">0.018</oasis:entry>
         <oasis:entry colname="col11"><inline-formula><mml:math id="M241" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.008</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">45.07</oasis:entry>
         <oasis:entry colname="col3">–</oasis:entry>
         <oasis:entry colname="col4">–</oasis:entry>
         <oasis:entry colname="col5">0.000</oasis:entry>
         <oasis:entry colname="col6">0.03</oasis:entry>
         <oasis:entry colname="col7">0.4</oasis:entry>
         <oasis:entry colname="col8">–</oasis:entry>
         <oasis:entry colname="col9">0.956</oasis:entry>
         <oasis:entry colname="col10">0.018</oasis:entry>
         <oasis:entry colname="col11"><inline-formula><mml:math id="M242" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.003</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">49.25</oasis:entry>
         <oasis:entry colname="col3">–</oasis:entry>
         <oasis:entry colname="col4">–</oasis:entry>
         <oasis:entry colname="col5">0.000</oasis:entry>
         <oasis:entry colname="col6">0.04</oasis:entry>
         <oasis:entry colname="col7">0.4</oasis:entry>
         <oasis:entry colname="col8">–</oasis:entry>
         <oasis:entry colname="col9">0.969</oasis:entry>
         <oasis:entry colname="col10">0.017</oasis:entry>
         <oasis:entry colname="col11"><inline-formula><mml:math id="M243" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.005</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">57.06</oasis:entry>
         <oasis:entry colname="col3">–</oasis:entry>
         <oasis:entry colname="col4">–</oasis:entry>
         <oasis:entry colname="col5">0.000</oasis:entry>
         <oasis:entry colname="col6">0.05</oasis:entry>
         <oasis:entry colname="col7">0.4</oasis:entry>
         <oasis:entry colname="col8">–</oasis:entry>
         <oasis:entry colname="col9">0.957</oasis:entry>
         <oasis:entry colname="col10">0.018</oasis:entry>
         <oasis:entry colname="col11"><inline-formula><mml:math id="M244" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.002</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">All</oasis:entry>
         <oasis:entry colname="col3">–</oasis:entry>
         <oasis:entry colname="col4">–</oasis:entry>
         <oasis:entry colname="col5">–</oasis:entry>
         <oasis:entry colname="col6">–</oasis:entry>
         <oasis:entry colname="col7">–</oasis:entry>
         <oasis:entry colname="col8">–</oasis:entry>
         <oasis:entry colname="col9">0.971</oasis:entry>
         <oasis:entry colname="col10">0.016</oasis:entry>
         <oasis:entry colname="col11"><inline-formula><mml:math id="M245" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.003</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Hapke-HSR <inline-formula><mml:math id="M246" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> MARMIT-2</oasis:entry>
         <oasis:entry colname="col2">0</oasis:entry>
         <oasis:entry colname="col3">2.0</oasis:entry>
         <oasis:entry colname="col4">0.30</oasis:entry>
         <oasis:entry colname="col5">0.000</oasis:entry>
         <oasis:entry colname="col6">0.00</oasis:entry>
         <oasis:entry colname="col7">0.0</oasis:entry>
         <oasis:entry colname="col8">–</oasis:entry>
         <oasis:entry colname="col9">1.000</oasis:entry>
         <oasis:entry colname="col10">0.001</oasis:entry>
         <oasis:entry colname="col11">0.000</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">14.45</oasis:entry>
         <oasis:entry colname="col3">2.2</oasis:entry>
         <oasis:entry colname="col4">0.29</oasis:entry>
         <oasis:entry colname="col5">0.018</oasis:entry>
         <oasis:entry colname="col6">0.01</oasis:entry>
         <oasis:entry colname="col7">0.3</oasis:entry>
         <oasis:entry colname="col8">–</oasis:entry>
         <oasis:entry colname="col9">0.994</oasis:entry>
         <oasis:entry colname="col10">0.006</oasis:entry>
         <oasis:entry colname="col11"><inline-formula><mml:math id="M247" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.001</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">27.34</oasis:entry>
         <oasis:entry colname="col3">3.1</oasis:entry>
         <oasis:entry colname="col4">0.24</oasis:entry>
         <oasis:entry colname="col5">0.011</oasis:entry>
         <oasis:entry colname="col6">0.02</oasis:entry>
         <oasis:entry colname="col7">0.4</oasis:entry>
         <oasis:entry colname="col8">–</oasis:entry>
         <oasis:entry colname="col9">0.991</oasis:entry>
         <oasis:entry colname="col10">0.008</oasis:entry>
         <oasis:entry colname="col11">0.000</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">31.6</oasis:entry>
         <oasis:entry colname="col3">4.0</oasis:entry>
         <oasis:entry colname="col4">0.21</oasis:entry>
         <oasis:entry colname="col5">0.006</oasis:entry>
         <oasis:entry colname="col6">0.02</oasis:entry>
         <oasis:entry colname="col7">0.5</oasis:entry>
         <oasis:entry colname="col8">–</oasis:entry>
         <oasis:entry colname="col9">0.989</oasis:entry>
         <oasis:entry colname="col10">0.009</oasis:entry>
         <oasis:entry colname="col11"><inline-formula><mml:math id="M248" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.001</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">36.2</oasis:entry>
         <oasis:entry colname="col3">3.3</oasis:entry>
         <oasis:entry colname="col4">0.23</oasis:entry>
         <oasis:entry colname="col5">0.000</oasis:entry>
         <oasis:entry colname="col6">0.02</oasis:entry>
         <oasis:entry colname="col7">0.5</oasis:entry>
         <oasis:entry colname="col8">–</oasis:entry>
         <oasis:entry colname="col9">0.986</oasis:entry>
         <oasis:entry colname="col10">0.010</oasis:entry>
         <oasis:entry colname="col11">0.000</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">40.34</oasis:entry>
         <oasis:entry colname="col3">4.0</oasis:entry>
         <oasis:entry colname="col4">0.21</oasis:entry>
         <oasis:entry colname="col5">0.006</oasis:entry>
         <oasis:entry colname="col6">0.03</oasis:entry>
         <oasis:entry colname="col7">0.5</oasis:entry>
         <oasis:entry colname="col8">–</oasis:entry>
         <oasis:entry colname="col9">0.987</oasis:entry>
         <oasis:entry colname="col10">0.009</oasis:entry>
         <oasis:entry colname="col11">0.000</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">45.07</oasis:entry>
         <oasis:entry colname="col3">3.3</oasis:entry>
         <oasis:entry colname="col4">0.23</oasis:entry>
         <oasis:entry colname="col5">0.001</oasis:entry>
         <oasis:entry colname="col6">0.03</oasis:entry>
         <oasis:entry colname="col7">0.5</oasis:entry>
         <oasis:entry colname="col8">–</oasis:entry>
         <oasis:entry colname="col9">0.987</oasis:entry>
         <oasis:entry colname="col10">0.009</oasis:entry>
         <oasis:entry colname="col11">0.002</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">49.25</oasis:entry>
         <oasis:entry colname="col3">4.0</oasis:entry>
         <oasis:entry colname="col4">0.21</oasis:entry>
         <oasis:entry colname="col5">0.005</oasis:entry>
         <oasis:entry colname="col6">0.04</oasis:entry>
         <oasis:entry colname="col7">0.5</oasis:entry>
         <oasis:entry colname="col8">–</oasis:entry>
         <oasis:entry colname="col9">0.986</oasis:entry>
         <oasis:entry colname="col10">0.009</oasis:entry>
         <oasis:entry colname="col11">0.001</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">57.06</oasis:entry>
         <oasis:entry colname="col3">3.7</oasis:entry>
         <oasis:entry colname="col4">0.22</oasis:entry>
         <oasis:entry colname="col5">0.000</oasis:entry>
         <oasis:entry colname="col6">0.05</oasis:entry>
         <oasis:entry colname="col7">0.5</oasis:entry>
         <oasis:entry colname="col8">–</oasis:entry>
         <oasis:entry colname="col9">0.984</oasis:entry>
         <oasis:entry colname="col10">0.009</oasis:entry>
         <oasis:entry colname="col11"><inline-formula><mml:math id="M249" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.001</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">All</oasis:entry>
         <oasis:entry colname="col3">–</oasis:entry>
         <oasis:entry colname="col4">–</oasis:entry>
         <oasis:entry colname="col5">–</oasis:entry>
         <oasis:entry colname="col6">–</oasis:entry>
         <oasis:entry colname="col7">–</oasis:entry>
         <oasis:entry colname="col8">–</oasis:entry>
         <oasis:entry colname="col9">0.991</oasis:entry>
         <oasis:entry colname="col10">0.008</oasis:entry>
         <oasis:entry colname="col11">0.000</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

      <p id="d2e5799">Figure 5 shows that the Hapke-HSR, MARMIT-2 and HM models fit the typical measured SSR (bab16_014-008) at SMC <inline-formula><mml:math id="M250" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0 %, 5 %, 10.7 %, 16 %, 21.1 %, 30.8 %, and 45.5 %, respectively. This set of typical data is suspected to have a specular reflection effect when SMC <inline-formula><mml:math id="M251" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 30.8 % and 45.5 %. Therefore, we further validate the capacity of the HM model for describing the relevant SSR attributes. The outcomes of the Hapke-HSR, MARMIT-2 and HM models match the typical measured SSR when the SMC <inline-formula><mml:math id="M252" display="inline"><mml:mo>&lt;</mml:mo></mml:math></inline-formula> 30 %. The Hapke-HSR and MARMIT-2 models cannot effectively consider the specular reflectance characteristics at high SMCs (SMC <inline-formula><mml:math id="M253" display="inline"><mml:mo>≥</mml:mo></mml:math></inline-formula> 30 %), and the results of the HM model display greater consistency with the measured SSR values. When the SMC is high and there is a specular reflectance effect, the fitting capability of the Hapke-HSR model is significantly underestimated in the range of 0.5–1.2 <inline-formula><mml:math id="M254" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula> and two strong water absorption bands; moreover, there is a slight overestimation in the range of 1.5–1.9 <inline-formula><mml:math id="M255" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula>. The outcomes of the MARMIT-2 model are marginally underestimated across the 0.4–1.36 <inline-formula><mml:math id="M256" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula> interval, and there is a slight overestimation across the spectral interval of 1.36–2.5 <inline-formula><mml:math id="M257" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula>, particularly in the strong water absorption region. The HM model can match the measured SSR well, especially at SMC <inline-formula><mml:math id="M258" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 30.8 % and 45.5 %, possibly because this model accounts for the specular scattering characteristics of high SMCs (SMC <inline-formula><mml:math id="M259" display="inline"><mml:mo>≥</mml:mo></mml:math></inline-formula> 30 %) on the basis of the coefficient (<inline-formula><mml:math id="M260" display="inline"><mml:mi>b</mml:mi></mml:math></inline-formula>) and soil particle shape-dependent parameter (<inline-formula><mml:math id="M261" display="inline"><mml:mi>M</mml:mi></mml:math></inline-formula>). To better show the differences between the SSR values simulated with these three models and the measured SSR values, we calculate the bias between them, as shown in Appendix Fig. A2. The results indicate that the HM model can describe SSR features effectively at SMC <inline-formula><mml:math id="M262" display="inline"><mml:mo>≥</mml:mo></mml:math></inline-formula> 30 %, and the simulated values exhibit very high consistency with the measured SSR values.</p>
      <p id="d2e5907">Table 5 shows that the Hapke-HSR, MARMIT-2 and HM models fit to the SSR parameters and statistical results. The overall precision of the Hapke-HSR and MARMIT-2 models in terms of fitting measured SSR was high (<inline-formula><mml:math id="M263" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.943</mml:mn></mml:mrow></mml:math></inline-formula>–0.946, RMSE <inline-formula><mml:math id="M264" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.006–0.022), especially at SMC <inline-formula><mml:math id="M265" display="inline"><mml:mo>&lt;</mml:mo></mml:math></inline-formula> 30 %; however, these two models were not suitable at SMC <inline-formula><mml:math id="M266" display="inline"><mml:mo>≥</mml:mo></mml:math></inline-formula> 30 %, which needs to be improved by accounting for specular reflectance. The HM model shows greater accuracy in fitting the variation in the SMC than the Hapke-HSR and MARMIT-2 models; the overall <inline-formula><mml:math id="M267" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula> is 0.995, the RMSE is 0.009, and the bias is negligible. When SMC <inline-formula><mml:math id="M268" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 30.8 % and 45.5 %, the measured SSR are suspected to have a specular reflection effect, and the HM model maintains a higher fitting precision (<inline-formula><mml:math id="M269" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.990</mml:mn></mml:mrow></mml:math></inline-formula>–0.993, RMSE <inline-formula><mml:math id="M270" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.009) than the Hapke-HSR and MARMIT-2 models (<inline-formula><mml:math id="M271" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.846</mml:mn></mml:mrow></mml:math></inline-formula>–0.973, RMSE <inline-formula><mml:math id="M272" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.019–0.053). These results indicate that these two models can be combined by coupling the Hapke-HSR and MARMIT-2 models (i.e., HM model), which can effectively determine the variation in SSR with increasing SMC, particularly in the presence of specular reflectance.</p>

      <fig id="F5" specific-use="star"><label>Figure 5</label><caption><p id="d2e6011">The Hapke-HSR (red), MARMIT-2 (blue) and Hapke-HSR <inline-formula><mml:math id="M273" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> MARMIT-2 (HM) (lime) models fit the measured soil reflectance (black) at SMC <inline-formula><mml:math id="M274" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0 % <bold>(a)</bold>, 5 % <bold>(b)</bold>, 10.7 % <bold>(c)</bold>, 16 % <bold>(d)</bold>, 21.1 % <bold>(e)</bold>, 30.8 % <bold>(f)</bold>, and 45.5 % <bold>(g)</bold>, respectively. </p></caption>
          <graphic xlink:href="https://gmd.copernicus.org/articles/19/4775/2026/gmd-19-4775-2026-f05.png"/>

        </fig>

<table-wrap id="T5" specific-use="star"><label>Table 5</label><caption><p id="d2e6059">The Hapke-HSR, MARMIT-2 and Hapke-HSR <inline-formula><mml:math id="M275" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> MARMIT-2 (HM) models fit to the soil reflectance parameters and statistical results.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="11">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="right"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:colspec colnum="4" colname="col4" align="right"/>
     <oasis:colspec colnum="5" colname="col5" align="right"/>
     <oasis:colspec colnum="6" colname="col6" align="right"/>
     <oasis:colspec colnum="7" colname="col7" align="right"/>
     <oasis:colspec colnum="8" colname="col8" align="right"/>
     <oasis:colspec colnum="9" colname="col9" align="right"/>
     <oasis:colspec colnum="10" colname="col10" align="right"/>
     <oasis:colspec colnum="11" colname="col11" align="right"/>
     <oasis:thead>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">Models</oasis:entry>
         <oasis:entry colname="col2">SMC (%)</oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M276" display="inline"><mml:mi>b</mml:mi></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M277" display="inline"><mml:mrow><mml:mi>f</mml:mi><mml:mo>/</mml:mo><mml:mi>M</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M278" display="inline"><mml:mrow><mml:msub><mml:mi>A</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub><mml:mo>/</mml:mo><mml:mi mathvariant="italic">δ</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M279" display="inline"><mml:mrow><mml:msub><mml:mi>A</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub><mml:mo>/</mml:mo><mml:mi>L</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M280" display="inline"><mml:mrow><mml:msub><mml:mi>A</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mo>/</mml:mo><mml:mi mathvariant="italic">ε</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col8"><inline-formula><mml:math id="M281" display="inline"><mml:mrow><mml:msub><mml:mi>A</mml:mi><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col9"><inline-formula><mml:math id="M282" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col10">RMSE</oasis:entry>
         <oasis:entry colname="col11">bias</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
         <oasis:entry colname="col1">Hapke-HSR</oasis:entry>
         <oasis:entry colname="col2">0.0</oasis:entry>
         <oasis:entry colname="col3">1.4</oasis:entry>
         <oasis:entry colname="col4">0.6</oasis:entry>
         <oasis:entry colname="col5">2.447</oasis:entry>
         <oasis:entry colname="col6">0.180</oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M283" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>4.150</oasis:entry>
         <oasis:entry colname="col8">12.010</oasis:entry>
         <oasis:entry colname="col9">0.974</oasis:entry>
         <oasis:entry colname="col10">0.014</oasis:entry>
         <oasis:entry colname="col11">0.000</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">5.0</oasis:entry>
         <oasis:entry colname="col3">1.4</oasis:entry>
         <oasis:entry colname="col4">1.0</oasis:entry>
         <oasis:entry colname="col5">2.016</oasis:entry>
         <oasis:entry colname="col6">0.322</oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M284" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>3.477</oasis:entry>
         <oasis:entry colname="col8">10.222</oasis:entry>
         <oasis:entry colname="col9">0.971</oasis:entry>
         <oasis:entry colname="col10">0.014</oasis:entry>
         <oasis:entry colname="col11"><inline-formula><mml:math id="M285" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.001</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">10.7</oasis:entry>
         <oasis:entry colname="col3">0.0</oasis:entry>
         <oasis:entry colname="col4">1.6</oasis:entry>
         <oasis:entry colname="col5">2.685</oasis:entry>
         <oasis:entry colname="col6">0.091</oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M286" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>5.119</oasis:entry>
         <oasis:entry colname="col8">14.339</oasis:entry>
         <oasis:entry colname="col9">0.960</oasis:entry>
         <oasis:entry colname="col10">0.015</oasis:entry>
         <oasis:entry colname="col11"><inline-formula><mml:math id="M287" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.002</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">16.0</oasis:entry>
         <oasis:entry colname="col3">0.2</oasis:entry>
         <oasis:entry colname="col4">2.0</oasis:entry>
         <oasis:entry colname="col5">2.506</oasis:entry>
         <oasis:entry colname="col6">0.189</oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M288" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>4.601</oasis:entry>
         <oasis:entry colname="col8">13.129</oasis:entry>
         <oasis:entry colname="col9">0.944</oasis:entry>
         <oasis:entry colname="col10">0.018</oasis:entry>
         <oasis:entry colname="col11">0.001</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">21.1</oasis:entry>
         <oasis:entry colname="col3">0.0</oasis:entry>
         <oasis:entry colname="col4">2.2</oasis:entry>
         <oasis:entry colname="col5">3.144</oasis:entry>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M289" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.023</oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M290" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>5.618</oasis:entry>
         <oasis:entry colname="col8">15.939</oasis:entry>
         <oasis:entry colname="col9">0.941</oasis:entry>
         <oasis:entry colname="col10">0.020</oasis:entry>
         <oasis:entry colname="col11">0.000</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">30.8</oasis:entry>
         <oasis:entry colname="col3">0.2</oasis:entry>
         <oasis:entry colname="col4">2.4</oasis:entry>
         <oasis:entry colname="col5">3.544</oasis:entry>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M291" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.173</oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M292" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>6.051</oasis:entry>
         <oasis:entry colname="col8">17.081</oasis:entry>
         <oasis:entry colname="col9">0.936</oasis:entry>
         <oasis:entry colname="col10">0.023</oasis:entry>
         <oasis:entry colname="col11">0.003</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">45.5</oasis:entry>
         <oasis:entry colname="col3">1.0</oasis:entry>
         <oasis:entry colname="col4">4.0</oasis:entry>
         <oasis:entry colname="col5">2.377</oasis:entry>
         <oasis:entry colname="col6">0.439</oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M293" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>4.292</oasis:entry>
         <oasis:entry colname="col8">12.350</oasis:entry>
         <oasis:entry colname="col9">0.884</oasis:entry>
         <oasis:entry colname="col10">0.037</oasis:entry>
         <oasis:entry colname="col11">0.004</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">All</oasis:entry>
         <oasis:entry colname="col3">–</oasis:entry>
         <oasis:entry colname="col4">–</oasis:entry>
         <oasis:entry colname="col5">–</oasis:entry>
         <oasis:entry colname="col6">–</oasis:entry>
         <oasis:entry colname="col7">–</oasis:entry>
         <oasis:entry colname="col8">–</oasis:entry>
         <oasis:entry colname="col9">0.943</oasis:entry>
         <oasis:entry colname="col10">0.022</oasis:entry>
         <oasis:entry colname="col11">0.001</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">MARMIT-2</oasis:entry>
         <oasis:entry colname="col2">0.0</oasis:entry>
         <oasis:entry colname="col3">–</oasis:entry>
         <oasis:entry colname="col4">–</oasis:entry>
         <oasis:entry colname="col5">–</oasis:entry>
         <oasis:entry colname="col6">–</oasis:entry>
         <oasis:entry colname="col7">–</oasis:entry>
         <oasis:entry colname="col8">–</oasis:entry>
         <oasis:entry colname="col9">–</oasis:entry>
         <oasis:entry colname="col10">–</oasis:entry>
         <oasis:entry colname="col11">–</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">5.0</oasis:entry>
         <oasis:entry colname="col3">–</oasis:entry>
         <oasis:entry colname="col4">–</oasis:entry>
         <oasis:entry colname="col5">0.000</oasis:entry>
         <oasis:entry colname="col6">0.01</oasis:entry>
         <oasis:entry colname="col7">0.2</oasis:entry>
         <oasis:entry colname="col8">–</oasis:entry>
         <oasis:entry colname="col9">0.996</oasis:entry>
         <oasis:entry colname="col10">0.006</oasis:entry>
         <oasis:entry colname="col11"><inline-formula><mml:math id="M294" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.001</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">10.7</oasis:entry>
         <oasis:entry colname="col3">–</oasis:entry>
         <oasis:entry colname="col4">–</oasis:entry>
         <oasis:entry colname="col5">0.020</oasis:entry>
         <oasis:entry colname="col6">0.01</oasis:entry>
         <oasis:entry colname="col7">0.5</oasis:entry>
         <oasis:entry colname="col8">–</oasis:entry>
         <oasis:entry colname="col9">0.993</oasis:entry>
         <oasis:entry colname="col10">0.006</oasis:entry>
         <oasis:entry colname="col11"><inline-formula><mml:math id="M295" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.001</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">16.0</oasis:entry>
         <oasis:entry colname="col3">–</oasis:entry>
         <oasis:entry colname="col4">–</oasis:entry>
         <oasis:entry colname="col5">0.010</oasis:entry>
         <oasis:entry colname="col6">0.03</oasis:entry>
         <oasis:entry colname="col7">0.4</oasis:entry>
         <oasis:entry colname="col8">–</oasis:entry>
         <oasis:entry colname="col9">0.991</oasis:entry>
         <oasis:entry colname="col10">0.009</oasis:entry>
         <oasis:entry colname="col11"><inline-formula><mml:math id="M296" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.005</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">21.1</oasis:entry>
         <oasis:entry colname="col3">–</oasis:entry>
         <oasis:entry colname="col4">–</oasis:entry>
         <oasis:entry colname="col5">0.000</oasis:entry>
         <oasis:entry colname="col6">0.02</oasis:entry>
         <oasis:entry colname="col7">0.4</oasis:entry>
         <oasis:entry colname="col8">–</oasis:entry>
         <oasis:entry colname="col9">0.988</oasis:entry>
         <oasis:entry colname="col10">0.009</oasis:entry>
         <oasis:entry colname="col11">0.002</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">30.8</oasis:entry>
         <oasis:entry colname="col3">–</oasis:entry>
         <oasis:entry colname="col4">–</oasis:entry>
         <oasis:entry colname="col5">0.000</oasis:entry>
         <oasis:entry colname="col6">0.04</oasis:entry>
         <oasis:entry colname="col7">0.3</oasis:entry>
         <oasis:entry colname="col8">–</oasis:entry>
         <oasis:entry colname="col9">0.973</oasis:entry>
         <oasis:entry colname="col10">0.019</oasis:entry>
         <oasis:entry colname="col11"><inline-formula><mml:math id="M297" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.009</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">45.5</oasis:entry>
         <oasis:entry colname="col3">–</oasis:entry>
         <oasis:entry colname="col4">–</oasis:entry>
         <oasis:entry colname="col5">0.000</oasis:entry>
         <oasis:entry colname="col6">0.04</oasis:entry>
         <oasis:entry colname="col7">0.4</oasis:entry>
         <oasis:entry colname="col8">–</oasis:entry>
         <oasis:entry colname="col9">0.846</oasis:entry>
         <oasis:entry colname="col10">0.053</oasis:entry>
         <oasis:entry colname="col11"><inline-formula><mml:math id="M298" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.024</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">All</oasis:entry>
         <oasis:entry colname="col3">–</oasis:entry>
         <oasis:entry colname="col4">–</oasis:entry>
         <oasis:entry colname="col5">–</oasis:entry>
         <oasis:entry colname="col6">–</oasis:entry>
         <oasis:entry colname="col7">–</oasis:entry>
         <oasis:entry colname="col8">–</oasis:entry>
         <oasis:entry colname="col9">0.946</oasis:entry>
         <oasis:entry colname="col10">0.022</oasis:entry>
         <oasis:entry colname="col11"><inline-formula><mml:math id="M299" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.005</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Hapke-HSR <inline-formula><mml:math id="M300" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> MARMIT-2</oasis:entry>
         <oasis:entry colname="col2">0.0</oasis:entry>
         <oasis:entry colname="col3">2.0</oasis:entry>
         <oasis:entry colname="col4">0.30</oasis:entry>
         <oasis:entry colname="col5">0.000</oasis:entry>
         <oasis:entry colname="col6">0.00</oasis:entry>
         <oasis:entry colname="col7">0.0</oasis:entry>
         <oasis:entry colname="col8">–</oasis:entry>
         <oasis:entry colname="col9">1.000</oasis:entry>
         <oasis:entry colname="col10">0.001</oasis:entry>
         <oasis:entry colname="col11">0.000</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">5.0</oasis:entry>
         <oasis:entry colname="col3">2.3</oasis:entry>
         <oasis:entry colname="col4">0.28</oasis:entry>
         <oasis:entry colname="col5">0.020</oasis:entry>
         <oasis:entry colname="col6">0.01</oasis:entry>
         <oasis:entry colname="col7">0.2</oasis:entry>
         <oasis:entry colname="col8">–</oasis:entry>
         <oasis:entry colname="col9">0.997</oasis:entry>
         <oasis:entry colname="col10">0.005</oasis:entry>
         <oasis:entry colname="col11">0.002</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">10.7</oasis:entry>
         <oasis:entry colname="col3">1.3</oasis:entry>
         <oasis:entry colname="col4">0.38</oasis:entry>
         <oasis:entry colname="col5">0.001</oasis:entry>
         <oasis:entry colname="col6">0.02</oasis:entry>
         <oasis:entry colname="col7">0.3</oasis:entry>
         <oasis:entry colname="col8">–</oasis:entry>
         <oasis:entry colname="col9">0.994</oasis:entry>
         <oasis:entry colname="col10">0.006</oasis:entry>
         <oasis:entry colname="col11">0.000</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">16.0</oasis:entry>
         <oasis:entry colname="col3">1.7</oasis:entry>
         <oasis:entry colname="col4">0.33</oasis:entry>
         <oasis:entry colname="col5">0.000</oasis:entry>
         <oasis:entry colname="col6">0.02</oasis:entry>
         <oasis:entry colname="col7">0.4</oasis:entry>
         <oasis:entry colname="col8">–</oasis:entry>
         <oasis:entry colname="col9">0.991</oasis:entry>
         <oasis:entry colname="col10">0.007</oasis:entry>
         <oasis:entry colname="col11"><inline-formula><mml:math id="M301" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.001</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">21.1</oasis:entry>
         <oasis:entry colname="col3">2.4</oasis:entry>
         <oasis:entry colname="col4">0.27</oasis:entry>
         <oasis:entry colname="col5">0.009</oasis:entry>
         <oasis:entry colname="col6">0.03</oasis:entry>
         <oasis:entry colname="col7">0.4</oasis:entry>
         <oasis:entry colname="col8">–</oasis:entry>
         <oasis:entry colname="col9">0.992</oasis:entry>
         <oasis:entry colname="col10">0.007</oasis:entry>
         <oasis:entry colname="col11">0.000</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">30.8</oasis:entry>
         <oasis:entry colname="col3">3.0</oasis:entry>
         <oasis:entry colname="col4">0.24</oasis:entry>
         <oasis:entry colname="col5">0.002</oasis:entry>
         <oasis:entry colname="col6">0.03</oasis:entry>
         <oasis:entry colname="col7">0.4</oasis:entry>
         <oasis:entry colname="col8">–</oasis:entry>
         <oasis:entry colname="col9">0.990</oasis:entry>
         <oasis:entry colname="col10">0.009</oasis:entry>
         <oasis:entry colname="col11">0.002</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">45.5</oasis:entry>
         <oasis:entry colname="col3">5.8</oasis:entry>
         <oasis:entry colname="col4">0.17</oasis:entry>
         <oasis:entry colname="col5">0.002</oasis:entry>
         <oasis:entry colname="col6">0.05</oasis:entry>
         <oasis:entry colname="col7">0.6</oasis:entry>
         <oasis:entry colname="col8">–</oasis:entry>
         <oasis:entry colname="col9">0.993</oasis:entry>
         <oasis:entry colname="col10">0.009</oasis:entry>
         <oasis:entry colname="col11"><inline-formula><mml:math id="M302" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.002</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">All</oasis:entry>
         <oasis:entry colname="col3">–</oasis:entry>
         <oasis:entry colname="col4">–</oasis:entry>
         <oasis:entry colname="col5">–</oasis:entry>
         <oasis:entry colname="col6">–</oasis:entry>
         <oasis:entry colname="col7">–</oasis:entry>
         <oasis:entry colname="col8">–</oasis:entry>
         <oasis:entry colname="col9">0.995</oasis:entry>
         <oasis:entry colname="col10">0.007</oasis:entry>
         <oasis:entry colname="col11">0.000</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

      <p id="d2e7206">Figure 6 presents a comparison of the SSR results obtained from the Hapke-HSR, MARMIT-2 and HM models and the measured SSR values from eight databases. These three models are generally highly accurate in terms of capturing SSR features. However, the HM and MARMIT-2 models (<inline-formula><mml:math id="M303" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mo>=</mml:mo><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">0.993</mml:mn></mml:mrow></mml:math></inline-formula>) fit the measured SSR data with slightly greater correlation accuracy than did the Hapke-HSR model (<inline-formula><mml:math id="M304" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.957</mml:mn></mml:mrow></mml:math></inline-formula>), and the RMSE values of the HM (RMSE <inline-formula><mml:math id="M305" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.010) and MARMIT-2 (RMSE <inline-formula><mml:math id="M306" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.012) models were significantly lower than the RMSE of the Hapke-HSR (RMSE <inline-formula><mml:math id="M307" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.027) model. Additionally, the MRE values of the HM and MARMIT-2 models are approximately 5.74 % and 6.43 % lower than that of the Hapke-HSR model, respectively. These findings indicate that the HM model yields the highest level of accuracy in fitting the measured SSR, followed by the MARMIT-2 model, whereas the Hapke-HSR model has the worst fitting effect on the basis of the measured SSR. The main reason is that the Hapke-HSR model includes a simple assumption regarding the effect of the SMC on SSR. In addition, the SSR simulated by the Hapke-HSR and MARMIT-2 models is considerably uncertain at high SMCs (e.g., Fig. 5f–g), whereas the HM model results display greater consistency with the fitted SSR value. In general, the HM and MARMIT-2 models excellently characterize the SSR attributes of soil and yield greater accuracy than the Hapke-HSR model for the eight soil databases does, and the SSR estimates produced by the HM model are marginally more accurate than those of the MARMIT-2 model are.</p>

      <fig id="F6" specific-use="star"><label>Figure 6</label><caption><p id="d2e7264">Comparison results of the all soil reflectance simulated by the Hapke-HSR <bold>(a)</bold>, MARMIT-2 <bold>(b)</bold> and Hapke-HSR <inline-formula><mml:math id="M308" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> MARMIT-2 (HM) <bold>(c)</bold> models with all measured soil reflectance.</p></caption>
          <graphic xlink:href="https://gmd.copernicus.org/articles/19/4775/2026/gmd-19-4775-2026-f06.jpg"/>

        </fig>

</sec>
<sec id="Ch1.S4.SS3">
  <label>4.3</label><title>Validating the Hapke-HSR <inline-formula><mml:math id="M309" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> MARMIT-2 model for high SMC</title>
      <p id="d2e7305">The MARMIT-2 and HM models achieve excellent fitting accuracy at SMC levels ranging from 0 %-30 %, whereas the Hapke-HSR and MARMIT-2 models exhibit moderate fitting capability at SMC <inline-formula><mml:math id="M310" display="inline"><mml:mo>≥</mml:mo></mml:math></inline-formula> 30 % (e.g., Figs. 3 and 4). Therefore, focus is placed on comparing the fitting results of the above three models under the condition of an SMC <inline-formula><mml:math id="M311" display="inline"><mml:mo>≥</mml:mo></mml:math></inline-formula> 30 %. Figure 7 shows the comprehensive results obtained with the Hapke-HSR, MARMIT-2 and HM models at SMC <inline-formula><mml:math id="M312" display="inline"><mml:mo>≥</mml:mo></mml:math></inline-formula> 30 %, and these three models exhibit strong agreement with the measured SSR (<inline-formula><mml:math id="M313" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mo>&gt;</mml:mo><mml:mn mathvariant="normal">0.90</mml:mn></mml:mrow></mml:math></inline-formula>), with RMSE values ranging from 0.007–0.028. However, the accuracy of the HM model (<inline-formula><mml:math id="M314" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.993</mml:mn></mml:mrow></mml:math></inline-formula>, RMSE <inline-formula><mml:math id="M315" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.007) for fitting SSR data is slightly better than that of the MARMIT-2 model (<inline-formula><mml:math id="M316" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.983</mml:mn></mml:mrow></mml:math></inline-formula>, RMSE <inline-formula><mml:math id="M317" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.012) and significantly greater than that of the Hapke-HSR model (<inline-formula><mml:math id="M318" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.909</mml:mn></mml:mrow></mml:math></inline-formula>, RMSE <inline-formula><mml:math id="M319" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.028). Compared with those of the MARMIT-2 and Hapke-HSR models, the RMSE values of the HM model are 41.7 % and 66.7 % lower, and the MRE values are 2.158 % and 9.702 % lower, respectively. Moreover, the HM model has the ability to improved the inadequate fitting outcomes of the Hapke-HSR model. These findings show that the HM model can describe SSR attributes more effectively than the other models can, especially at SMC <inline-formula><mml:math id="M320" display="inline"><mml:mo>≥</mml:mo></mml:math></inline-formula> 30 %. The key factor is that the HM model combines the strengths of both the Hapke-HSR and MARMIT-2 models to better describe the changes in SSR with increasing SMC. The MARMIT-2 model also exhibits higher accuracy at SMC <inline-formula><mml:math id="M321" display="inline"><mml:mo>≥</mml:mo></mml:math></inline-formula> 30 % since it fully considers the effect of the SMC on SSR.</p>

      <fig id="F7" specific-use="star"><label>Figure 7</label><caption><p id="d2e7428">Comparison results of the soil reflectance values simulated by the Hapke-HSR <bold>(a)</bold>, MARMIT-2 <bold>(b)</bold> and Hapke-HSR <inline-formula><mml:math id="M322" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> MARMIT-2 (HM) <bold>(c)</bold> models with the measured soil reflectance at SMC <inline-formula><mml:math id="M323" display="inline"><mml:mo>≥</mml:mo></mml:math></inline-formula> 30 %.</p></caption>
          <graphic xlink:href="https://gmd.copernicus.org/articles/19/4775/2026/gmd-19-4775-2026-f07.jpg"/>

        </fig>

      <p id="d2e7460">Next, we further evaluate the ability of the Hapke-HSR, MARMIT-2 and HM models to fit the measured SSR for different bands (0.4–2.5 <inline-formula><mml:math id="M324" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula>) at SMC <inline-formula><mml:math id="M325" display="inline"><mml:mo>≥</mml:mo></mml:math></inline-formula> 30 %. Figure 8 shows the comparison results between the simulated SSR values of the three models and the measured SSR values. The results of these three models are highly consistent with the measured values. The <inline-formula><mml:math id="M326" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula> values of these three models are generally very high, in the range of 0.4–2.5 <inline-formula><mml:math id="M327" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula>. The <inline-formula><mml:math id="M328" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula> value of the HM model is the largest, followed by those of the MARMIT-2 model and, finally, the Hapke-HSR model. However, the consistency between the outcomes of these three models and the measured values in the strong absorption band of water (centred at 1.90 <inline-formula><mml:math id="M329" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula>) is significantly lower than that for the other bands. The RMSE results from the HM model were the smallest, followed by those of the MARMIT-2 model. The maximum RMSE value of the Hapke-HSR model was approximately 0.05 because the Hapke-HSR model uses a simplistic assumption to reflect the effect of the SMC. However, the HM and MARMIT-2 models significantly outperform the Hapke-HSR model, specifically at two major absorption bands of water (centred at 1.47 and 1.90 <inline-formula><mml:math id="M330" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula>), since the HM and MARMIT-2 models fully consider the changes in SSR characteristics with variations in the SMC. The MRE trends of the three models are basically similar to the RMSE trends, and the HM model demonstrates the highest level of accuracy, with the MARMIT-2 model following closely behind. The MRE value of the Hapke-HSR model is approximately 60 % at the major absorption band of water (centred at 1.90 <inline-formula><mml:math id="M331" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula>), which is significantly greater than that of the MARMIT-2 model (28 %) and the HM model (15 %). The bias values of the HM model approach 0.4–2.5 <inline-formula><mml:math id="M332" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula>, whereas those of the Hapke-HSR model exhibit a large range of variation. These studies indicate that the HM model results are more in line with the fitted SSR, whereas the Hapke-HSR model results are more different from the measured SSR values. In general, the variations between the outputs of these three models and the measured values are in the wavelength ranges of 0.4–0.6  and 2.4–2.5 <inline-formula><mml:math id="M333" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula> and represent the two major absorption bands of water. The soil reflectance is low over the spectral region from 0.40.6 <inline-formula><mml:math id="M334" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula>, and the soil reflectance variation remains insignificant in this wavelength range as the SMC increases. The soil measurements have great uncertainty in the range of 2.4–2.5 <inline-formula><mml:math id="M335" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula>, resulting in poor correlations between the fitting results of these three models and the measured values. The SSR changes rapidly in the strong absorption band of water, which leads to great uncertainty in the fitting results of these models. Compared with the observed SSR model, the Hapke-HSR model has the lowest accuracy, followed by the MARMIT-2 model. The HM and MARMIT-2 models are better than the Hapke-HSR model at SMC <inline-formula><mml:math id="M336" display="inline"><mml:mo>≥</mml:mo></mml:math></inline-formula> 30 % because these two models fully consider the variation in SSR characteristics with the variation in SMC.</p>

      <fig id="F8" specific-use="star"><label>Figure 8</label><caption><p id="d2e7594">Evaluation of the Hapke-HSR (red), MARMIT-2 (blue) and Hapke-HSR <inline-formula><mml:math id="M337" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> MARMIT-2 (HM) (lime) models in fitting measured soil reflectance at SMC <inline-formula><mml:math id="M338" display="inline"><mml:mo>≥</mml:mo></mml:math></inline-formula> 30 %. The assessment indices are the <inline-formula><mml:math id="M339" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula> <bold>(a)</bold>, RMSE <bold>(b)</bold>, MRE <bold>(c)</bold>, and bias <bold>(d)</bold> values.</p></caption>
          <graphic xlink:href="https://gmd.copernicus.org/articles/19/4775/2026/gmd-19-4775-2026-f08.png"/>

        </fig>

      <p id="d2e7641">Finally, we analysed the fitting performance of the Hapke-HSR, MARMIT-2, and HM models across eight soil spectral databases, as shown in Fig. 9. All three models achieve high accuracy (NRMSE <inline-formula><mml:math id="M340" display="inline"><mml:mo>&lt;</mml:mo></mml:math></inline-formula> 9 %), with the HM model generally outperforming the individual models. The performance varies across datasets, reflecting differences in soil properties, reflectance levels, and sensitivity to soil moisture. The HM model shows clear improvements for most datasets (e.g., Bab16, Dup20, Hum15, Liu02, Mar12, and Phil14), indicating the effectiveness of coupling directional scattering and moisture-related processes. However, the improvement is less pronounced for certain datasets. For example, the MARMIT-2 model already achieves high accuracy for the Les08 dataset, resulting in limited additional improvement. For the Lob02 dataset, the relatively low reflectance leads to larger NRMSE values, which reduces the apparent gain. Overall, these results demonstrate the robustness of the proposed framework across diverse datasets, while also highlighting its dependence on dataset characteristics.</p>

      <fig id="F9"><label>Figure 9</label><caption><p id="d2e7653">The NRMSE values of the measured soil reflectance fit with the Hapke-HSR (red), MARMIT-2 (blue) and Hapke-HSR <inline-formula><mml:math id="M341" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> MARMIT-2 (HM) (lime) models for eight different databases.</p></caption>
          <graphic xlink:href="https://gmd.copernicus.org/articles/19/4775/2026/gmd-19-4775-2026-f09.png"/>

        </fig>


</sec>
</sec>
<sec id="Ch1.S5">
  <label>5</label><title>Discussion</title>
<sec id="Ch1.S5.SS1">
  <label>5.1</label><title>Analysis of the variation in the parameter <inline-formula><mml:math id="M342" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">χ</mml:mi><mml:mi mathvariant="normal">soil</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula></title>
      <p id="d2e7699">In this section, we analyse the imaginary component of the soil index (<inline-formula><mml:math id="M343" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">χ</mml:mi><mml:mi mathvariant="normal">soil</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> parameter) calculated from the dry soil reflectance for eight different databases with the wavelengths shown in Fig. 10. For different soil databases, the change trend of the <inline-formula><mml:math id="M344" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">χ</mml:mi><mml:mi mathvariant="normal">soil</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> parameter is basically the same. The <inline-formula><mml:math id="M345" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">χ</mml:mi><mml:mi mathvariant="normal">soil</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> parameter increases with wavelength, and there is an obvious peak at the two strong absorption bands of water (i.e., centred at 1.47 and 1.90 <inline-formula><mml:math id="M346" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula>). However, there are still some differences between different soil databases. The values of the parameter <inline-formula><mml:math id="M347" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">χ</mml:mi><mml:mi mathvariant="normal">soil</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> are greater in the strong absorption band of water for the Bab16 and Liu02 databases, whereas the parameter values <inline-formula><mml:math id="M348" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">χ</mml:mi><mml:mi mathvariant="normal">soil</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> are lower for the Hum15, Lob02 and Phil14 databases in the strong absorption band of water; moreover, the influence of the SMC on these three databases is small. For the same soil database, the change in the parameter <inline-formula><mml:math id="M349" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">χ</mml:mi><mml:mi mathvariant="normal">soil</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is small, and only the difference between the Bab16 database results is large. In addition, the parameter <inline-formula><mml:math id="M350" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">χ</mml:mi><mml:mi mathvariant="normal">soil</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is obviously greater in the two water absorption bands, and the overall change range also decreases. This decrease may further affect the accuracy of fitting the measured SSR. Therefore, the method of determining the parameter <inline-formula><mml:math id="M351" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">χ</mml:mi><mml:mi mathvariant="normal">soil</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> in each soil database should be theoretically feasible. The parameter <inline-formula><mml:math id="M352" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">χ</mml:mi><mml:mi mathvariant="normal">soil</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is derived based on the assumption that the spectral shape of dry soil reflectance is similar to that of the single scattering albedo. Therefore, this approach depends on the availability of dry soil reflectance, which is often difficult to obtain from field measurements or satellite observations. Providing a representative dry soil reflectance remains an important challenge for future work. In addition, the use of an averaged <inline-formula><mml:math id="M353" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">χ</mml:mi><mml:mi mathvariant="normal">soil</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> does not explicitly account for variability in soil properties within the same soil type, such as differences in organic carbon content or texture, which may influence spectral absorption. This simplification may contribute to the observed decrease in model accuracy. In future work, the definition of <inline-formula><mml:math id="M354" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">χ</mml:mi><mml:mi mathvariant="normal">soil</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> could be refined by incorporating soil-specific properties or by grouping spectrally similar soils, which is expected to provide a more accurate representation of absorption characteristics and further improve model performance.</p>

      <fig id="F10" specific-use="star"><label>Figure 10</label><caption><p id="d2e7837">Analysis of the imaginary component of the soil index (parameter <inline-formula><mml:math id="M355" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">χ</mml:mi><mml:mi mathvariant="normal">soil</mml:mi></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> for eight different databases (i.e., Bab16 <bold>(a)</bold>, Dup20 <bold>(b)</bold>, Hum15 <bold>(c)</bold>, Les08 <bold>(d)</bold>, Liu02 <bold>(e)</bold>, Lob02 <bold>(f)</bold>, Mar12 <bold>(g)</bold>, and Phil14 <bold>(h)</bold>) with wavelengths.</p></caption>
          <graphic xlink:href="https://gmd.copernicus.org/articles/19/4775/2026/gmd-19-4775-2026-f10.png"/>

        </fig>

</sec>
<sec id="Ch1.S5.SS2">
  <label>5.2</label><title>Validating the Hapke-HSR <inline-formula><mml:math id="M356" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> MARMIT-2 model using the average parameter <inline-formula><mml:math id="M357" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">χ</mml:mi><mml:mi mathvariant="normal">soil</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula></title>
      <p id="d2e7910">We used the average parameter <inline-formula><mml:math id="M358" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">χ</mml:mi><mml:mi mathvariant="normal">soil</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> (i.e., Fig. 10a) to validate the HM model to characterize the SSR attributes; this model is called the HM_mean model in the following section. Figure 11 shows that the HM and HM_mean models fit the influence of the typical measured SSR value (i.e., bab16_056-051) at SMC <inline-formula><mml:math id="M359" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0 %, 9.1 %, 17 %, 29.9 %, 39.3 %, and 52.4 %, respectively. This set of typical data is thought to have a specular reflection effect when SMC <inline-formula><mml:math id="M360" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 52.4 %. The HM and HM_mean models match well with the typical measured SSR values. However, the HM model shows greater consistency with the fitted SSR value than does the HM_mean model, especially at SMC <inline-formula><mml:math id="M361" display="inline"><mml:mo>&lt;</mml:mo></mml:math></inline-formula> 10 %. The HM_mean model results in significant underestimation and overestimation at SMC <inline-formula><mml:math id="M362" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0 % and 9.1 %, respectively, because the average parameter <inline-formula><mml:math id="M363" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">χ</mml:mi><mml:mi mathvariant="normal">soil</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is obviously greater in the water absorption band (Fig. 10a), which further affects the accuracy of the HM_mean model. The HM and HM_mean model fitting results can capture the change in SSR with increasing SMC and are highly in line with the measured SSR values at high SMCs, which may be caused by the obvious SSR broadening in the strong absorption band of water with increasing SMC. In general, the HM model, which uses the average parameter <inline-formula><mml:math id="M364" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">χ</mml:mi><mml:mi mathvariant="normal">soil</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, can still effectively describe the SSR characteristics, especially at high SMCs. However, the average parameter <inline-formula><mml:math id="M365" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">χ</mml:mi><mml:mi mathvariant="normal">soil</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> leads to a significant broadening of the strong absorption band of water at low SMCs, which further leads to obvious overestimation or underestimation of the SSR fitted by the HM_mean model in the strong absorption band of water.</p>

      <fig id="F11" specific-use="star"><label>Figure 11</label><caption><p id="d2e7988">The HM (red) and HM_mean (blue) models fit the measured soil reflectance (black) at SMC <inline-formula><mml:math id="M366" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0 % <bold>(a)</bold>, 9.1 % <bold>(b)</bold>, 17 % <bold>(c)</bold>, 29.9 % <bold>(d)</bold>, 39.3 % <bold>(e)</bold>, and 52.4 % <bold>(f)</bold>.</p></caption>
          <graphic xlink:href="https://gmd.copernicus.org/articles/19/4775/2026/gmd-19-4775-2026-f11.png"/>

        </fig>

<table-wrap id="T6" specific-use="star"><label>Table 6</label><caption><p id="d2e8027">The HM and HM_mean models fit the soil reflectance variables and statistical outputs.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="10">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="right"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:colspec colnum="4" colname="col4" align="right"/>
     <oasis:colspec colnum="5" colname="col5" align="right"/>
     <oasis:colspec colnum="6" colname="col6" align="right"/>
     <oasis:colspec colnum="7" colname="col7" align="right"/>
     <oasis:colspec colnum="8" colname="col8" align="right"/>
     <oasis:colspec colnum="9" colname="col9" align="right"/>
     <oasis:colspec colnum="10" colname="col10" align="right"/>
     <oasis:thead>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">Models</oasis:entry>
         <oasis:entry colname="col2">SMC</oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M367" display="inline"><mml:mi>b</mml:mi></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M368" display="inline"><mml:mi>M</mml:mi></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M369" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M370" display="inline"><mml:mi>L</mml:mi></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M371" display="inline"><mml:mi mathvariant="italic">ε</mml:mi></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col8"><inline-formula><mml:math id="M372" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col9">RMSE</oasis:entry>
         <oasis:entry colname="col10">bias</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
         <oasis:entry colname="col1">HM model</oasis:entry>
         <oasis:entry colname="col2">0.0</oasis:entry>
         <oasis:entry colname="col3">2.0</oasis:entry>
         <oasis:entry colname="col4">0.30</oasis:entry>
         <oasis:entry colname="col5">0.00</oasis:entry>
         <oasis:entry colname="col6">0.00</oasis:entry>
         <oasis:entry colname="col7">0.0</oasis:entry>
         <oasis:entry colname="col8">1.000</oasis:entry>
         <oasis:entry colname="col9">0.001</oasis:entry>
         <oasis:entry colname="col10">0.000</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">9.1</oasis:entry>
         <oasis:entry colname="col3">3.6</oasis:entry>
         <oasis:entry colname="col4">0.22</oasis:entry>
         <oasis:entry colname="col5">0.14</oasis:entry>
         <oasis:entry colname="col6">0.01</oasis:entry>
         <oasis:entry colname="col7">0.2</oasis:entry>
         <oasis:entry colname="col8">0.996</oasis:entry>
         <oasis:entry colname="col9">0.007</oasis:entry>
         <oasis:entry colname="col10">0.003</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">17.0</oasis:entry>
         <oasis:entry colname="col3">1.8</oasis:entry>
         <oasis:entry colname="col4">0.32</oasis:entry>
         <oasis:entry colname="col5">0.05</oasis:entry>
         <oasis:entry colname="col6">0.01</oasis:entry>
         <oasis:entry colname="col7">0.6</oasis:entry>
         <oasis:entry colname="col8">0.993</oasis:entry>
         <oasis:entry colname="col9">0.006</oasis:entry>
         <oasis:entry colname="col10">0.000</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">29.9</oasis:entry>
         <oasis:entry colname="col3">2.2</oasis:entry>
         <oasis:entry colname="col4">0.28</oasis:entry>
         <oasis:entry colname="col5">0.07</oasis:entry>
         <oasis:entry colname="col6">0.02</oasis:entry>
         <oasis:entry colname="col7">0.6</oasis:entry>
         <oasis:entry colname="col8">0.990</oasis:entry>
         <oasis:entry colname="col9">0.006</oasis:entry>
         <oasis:entry colname="col10">0.001</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">39.3</oasis:entry>
         <oasis:entry colname="col3">1.2</oasis:entry>
         <oasis:entry colname="col4">0.38</oasis:entry>
         <oasis:entry colname="col5">0.06</oasis:entry>
         <oasis:entry colname="col6">0.02</oasis:entry>
         <oasis:entry colname="col7">0.6</oasis:entry>
         <oasis:entry colname="col8">0.990</oasis:entry>
         <oasis:entry colname="col9">0.006</oasis:entry>
         <oasis:entry colname="col10">0.001</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">52.4</oasis:entry>
         <oasis:entry colname="col3">1.8</oasis:entry>
         <oasis:entry colname="col4">0.32</oasis:entry>
         <oasis:entry colname="col5">0.01</oasis:entry>
         <oasis:entry colname="col6">0.05</oasis:entry>
         <oasis:entry colname="col7">0.9</oasis:entry>
         <oasis:entry colname="col8">0.991</oasis:entry>
         <oasis:entry colname="col9">0.005</oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M373" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.002</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">All</oasis:entry>
         <oasis:entry colname="col3">–</oasis:entry>
         <oasis:entry colname="col4">–</oasis:entry>
         <oasis:entry colname="col5">–</oasis:entry>
         <oasis:entry colname="col6">–</oasis:entry>
         <oasis:entry colname="col7">–</oasis:entry>
         <oasis:entry colname="col8">0.998</oasis:entry>
         <oasis:entry colname="col9">0.005</oasis:entry>
         <oasis:entry colname="col10">0.001</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">HM_mean model</oasis:entry>
         <oasis:entry colname="col2">0.0</oasis:entry>
         <oasis:entry colname="col3">2.2</oasis:entry>
         <oasis:entry colname="col4">0.18</oasis:entry>
         <oasis:entry colname="col5">0.04</oasis:entry>
         <oasis:entry colname="col6">0.00</oasis:entry>
         <oasis:entry colname="col7">0.9</oasis:entry>
         <oasis:entry colname="col8">0.989</oasis:entry>
         <oasis:entry colname="col9">0.012</oasis:entry>
         <oasis:entry colname="col10">0.001</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">9.1</oasis:entry>
         <oasis:entry colname="col3">2.2</oasis:entry>
         <oasis:entry colname="col4">0.18</oasis:entry>
         <oasis:entry colname="col5">0.14</oasis:entry>
         <oasis:entry colname="col6">0.00</oasis:entry>
         <oasis:entry colname="col7">1.0</oasis:entry>
         <oasis:entry colname="col8">0.977</oasis:entry>
         <oasis:entry colname="col9">0.016</oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M374" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.001</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">17.0</oasis:entry>
         <oasis:entry colname="col3">0.6</oasis:entry>
         <oasis:entry colname="col4">0.34</oasis:entry>
         <oasis:entry colname="col5">0.13</oasis:entry>
         <oasis:entry colname="col6">0.01</oasis:entry>
         <oasis:entry colname="col7">0.6</oasis:entry>
         <oasis:entry colname="col8">0.980</oasis:entry>
         <oasis:entry colname="col9">0.009</oasis:entry>
         <oasis:entry colname="col10">0.002</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">29.9</oasis:entry>
         <oasis:entry colname="col3">0.6</oasis:entry>
         <oasis:entry colname="col4">0.34</oasis:entry>
         <oasis:entry colname="col5">0.09</oasis:entry>
         <oasis:entry colname="col6">0.02</oasis:entry>
         <oasis:entry colname="col7">0.6</oasis:entry>
         <oasis:entry colname="col8">0.981</oasis:entry>
         <oasis:entry colname="col9">0.008</oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M375" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.001</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">39.3</oasis:entry>
         <oasis:entry colname="col3">1.0</oasis:entry>
         <oasis:entry colname="col4">0.26</oasis:entry>
         <oasis:entry colname="col5">0.10</oasis:entry>
         <oasis:entry colname="col6">0.03</oasis:entry>
         <oasis:entry colname="col7">0.6</oasis:entry>
         <oasis:entry colname="col8">0.981</oasis:entry>
         <oasis:entry colname="col9">0.008</oasis:entry>
         <oasis:entry colname="col10">0.000</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">52.4</oasis:entry>
         <oasis:entry colname="col3">2.6</oasis:entry>
         <oasis:entry colname="col4">0.16</oasis:entry>
         <oasis:entry colname="col5">0.03</oasis:entry>
         <oasis:entry colname="col6">0.06</oasis:entry>
         <oasis:entry colname="col7">0.9</oasis:entry>
         <oasis:entry colname="col8">0.988</oasis:entry>
         <oasis:entry colname="col9">0.006</oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M376" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.002</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">All</oasis:entry>
         <oasis:entry colname="col3">–</oasis:entry>
         <oasis:entry colname="col4">–</oasis:entry>
         <oasis:entry colname="col5">–</oasis:entry>
         <oasis:entry colname="col6">–</oasis:entry>
         <oasis:entry colname="col7">–</oasis:entry>
         <oasis:entry colname="col8">0.993</oasis:entry>
         <oasis:entry colname="col9">0.011</oasis:entry>
         <oasis:entry colname="col10">0.000</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

      <p id="d2e8621">Table 6 shows that the HM and HM_mean models fit the SSR parameters and statistical outputs. The overall accuracy of the HM and HM_mean models in terms of fitting the measured SSR is high (<inline-formula><mml:math id="M377" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.991</mml:mn></mml:mrow></mml:math></inline-formula>–0.993, RMSE <inline-formula><mml:math id="M378" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.005–0.011). According to the simulation results, the HM model is more accurate with respect to the measured SSR than the HM_mean model is, especially at SMC <inline-formula><mml:math id="M379" display="inline"><mml:mo>&lt;</mml:mo></mml:math></inline-formula> 10 %, because the average parameter <inline-formula><mml:math id="M380" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">χ</mml:mi><mml:mi mathvariant="normal">soil</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is obviously greater in the water absorption band. The HM and HM_mean models can effectively describe SSR features, especially high SMCs (<inline-formula><mml:math id="M381" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M382" display="inline"><mml:mo>&gt;</mml:mo></mml:math></inline-formula> 0.98 and RMSE <inline-formula><mml:math id="M383" display="inline"><mml:mo>&lt;</mml:mo></mml:math></inline-formula> 0.01). When SMC <inline-formula><mml:math id="M384" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 52.4 %, the measured soil spectral data are suspected to have a specular reflection effect, and the HM model maintains a higher fitting accuracy (<inline-formula><mml:math id="M385" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.991</mml:mn></mml:mrow></mml:math></inline-formula>, RMSE <inline-formula><mml:math id="M386" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.005) than does the Hapke_mean model (<inline-formula><mml:math id="M387" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.988</mml:mn></mml:mrow></mml:math></inline-formula>, RMSE <inline-formula><mml:math id="M388" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.006). These results indicate that the method of assuming an average parameter <inline-formula><mml:math id="M389" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">χ</mml:mi><mml:mi mathvariant="normal">soil</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> in each soil database should be theoretically feasible. However, all the soil types may have large differences in the parameter <inline-formula><mml:math id="M390" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">χ</mml:mi><mml:mi mathvariant="normal">soil</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>. How to select the parameter <inline-formula><mml:math id="M391" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">χ</mml:mi><mml:mi mathvariant="normal">soil</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> of each soil type will be particularly important in our subsequent study.</p>
      <p id="d2e8775">Finally, we calculate the overall average parameter <inline-formula><mml:math id="M392" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">χ</mml:mi><mml:mi mathvariant="normal">soil</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> to determine the dependence of the HM model on the dry SSR. First, we normalize all <inline-formula><mml:math id="M393" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">χ</mml:mi><mml:mi mathvariant="normal">soil</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> parameters to the same order of magnitude and then average these indices in each band. Finally, we use all the SSR data to verify the accuracy of this method. Table 7 shows that the HM_mean model fit the statistical results for all the SSR data. Compared with the measured SSR, the HM_mean model has high fitting accuracy. The <inline-formula><mml:math id="M394" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula> value of the HM_mean model is 0.988, and the RMSE is 0.014, indicating negligible bias. However, the fitting accuracy of the overall SSR data of the HM_mean model is lower than that of the MARMIT-2 and HM models (i.e., Fig. 6b–c). The main reason is that there are notable discrepancies in the parameter <inline-formula><mml:math id="M395" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">χ</mml:mi><mml:mi mathvariant="normal">soil</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> among various soil types (Fig. 10). The model operation can be simplified by averaging all the <inline-formula><mml:math id="M396" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">χ</mml:mi><mml:mi mathvariant="normal">soil</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> parameters of the soil, but this approach also results in an accuracy decline for the HM_mean model. For SMC values <inline-formula><mml:math id="M397" display="inline"><mml:mo>≥</mml:mo></mml:math></inline-formula> 30 %, the HM_mean model results in a lower RMSE than that for SMC values <inline-formula><mml:math id="M398" display="inline"><mml:mo>&lt;</mml:mo></mml:math></inline-formula> 30 %, which is consistent with the findings illustrated in Fig. 11 and Table 6. However, the NRMSE and MRE values of the HM_mean model at SMC <inline-formula><mml:math id="M399" display="inline"><mml:mo>≥</mml:mo></mml:math></inline-formula> 30 % were lower than those at SMC <inline-formula><mml:math id="M400" display="inline"><mml:mo>&lt;</mml:mo></mml:math></inline-formula> 30 %, possibly because the dry SSR is greater than that of wet soil. In conclusion, the HM_mean model demonstrates proficiency in describing SSR attributes, and the overall average parameter <inline-formula><mml:math id="M401" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">χ</mml:mi><mml:mi mathvariant="normal">soil</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> of the soil can be used to determine the dependence of the HM model on the SSR. In this study, we based our analysis solely on the soil databases, which has limitations. In future research, we will consider soil properties or spectrally similar soils and account for more factors affecting the <inline-formula><mml:math id="M402" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">χ</mml:mi><mml:mi mathvariant="normal">soil</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> parameter to improve the accuracy of the Hapke-HSR <inline-formula><mml:math id="M403" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> MARMIT-2 model.</p>

<table-wrap id="T7" specific-use="star"><label>Table 7</label><caption><p id="d2e8895">The HM_mean model fit the statistical results for all the soil reflectance data.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="7">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="right"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:colspec colnum="4" colname="col4" align="right"/>
     <oasis:colspec colnum="5" colname="col5" align="right"/>
     <oasis:colspec colnum="6" colname="col6" align="right"/>
     <oasis:colspec colnum="7" colname="col7" align="right"/>
     <oasis:thead>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">Data</oasis:entry>
         <oasis:entry colname="col2">Number</oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M404" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4">RMSE</oasis:entry>
         <oasis:entry colname="col5">NRMSE (%)</oasis:entry>
         <oasis:entry colname="col6">MRE (%)</oasis:entry>
         <oasis:entry colname="col7">bias</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
         <oasis:entry colname="col1">SMC <inline-formula><mml:math id="M405" display="inline"><mml:mo>&lt;</mml:mo></mml:math></inline-formula> 30 %</oasis:entry>
         <oasis:entry colname="col2">2257585</oasis:entry>
         <oasis:entry colname="col3">0.989</oasis:entry>
         <oasis:entry colname="col4">0.015</oasis:entry>
         <oasis:entry colname="col5">1.811</oasis:entry>
         <oasis:entry colname="col6">5.117</oasis:entry>
         <oasis:entry colname="col7">0.000</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">SMC <inline-formula><mml:math id="M406" display="inline"><mml:mo>≥</mml:mo></mml:math></inline-formula> 30 %</oasis:entry>
         <oasis:entry colname="col2">1082887</oasis:entry>
         <oasis:entry colname="col3">0.980</oasis:entry>
         <oasis:entry colname="col4">0.013</oasis:entry>
         <oasis:entry colname="col5">1.858</oasis:entry>
         <oasis:entry colname="col6">6.988</oasis:entry>
         <oasis:entry colname="col7">0.000</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">All</oasis:entry>
         <oasis:entry colname="col2">3340472</oasis:entry>
         <oasis:entry colname="col3">0.988</oasis:entry>
         <oasis:entry colname="col4">0.014</oasis:entry>
         <oasis:entry colname="col5">1.743</oasis:entry>
         <oasis:entry colname="col6">5.723</oasis:entry>
         <oasis:entry colname="col7">0.000</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

</sec>
<sec id="Ch1.S5.SS3">
  <label>5.3</label><title>Analysing the Parameter Influence of the Hapke-HSR <inline-formula><mml:math id="M407" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> MARMIT-2 model on the soil BRDF shape</title>
      <p id="d2e9063">Finally, we analyse the impact of the soil parameters on the BRDF shape obtained with the Hapke-HSR <inline-formula><mml:math id="M408" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> MARMIT-2 model. Considering that we previously used various BRDF data sources to examine the role of the Hapke-HSR model in modelling soil BRDF features, we analyse how the model parameters affect the shape of the BRDF curve (Ding et al., 2022). Figure 12 shows the effects of parameters <inline-formula><mml:math id="M409" display="inline"><mml:mi>b</mml:mi></mml:math></inline-formula>, <inline-formula><mml:math id="M410" display="inline"><mml:mi>M</mml:mi></mml:math></inline-formula>, <inline-formula><mml:math id="M411" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula>, <inline-formula><mml:math id="M412" display="inline"><mml:mi>L</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math id="M413" display="inline"><mml:mi mathvariant="italic">ε</mml:mi></mml:math></inline-formula> in the Hapke-HSR <inline-formula><mml:math id="M414" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> MARMIT-2 (HM) model on the soil BRDF shape in the principal plane (PP). With increasing parameter <inline-formula><mml:math id="M415" display="inline"><mml:mi>b</mml:mi></mml:math></inline-formula>, the soil reflectance gradually decreases in the forwards direction but increases in the backwards reflection direction. The parameter <inline-formula><mml:math id="M416" display="inline"><mml:mi>b</mml:mi></mml:math></inline-formula> has a relatively large contribution to the anisotropy characteristics of the soil. When the parameter <inline-formula><mml:math id="M417" display="inline"><mml:mi>M</mml:mi></mml:math></inline-formula> increases, the soil reflectance continuously decreases. The soil anisotropy is strongest when the parameter <inline-formula><mml:math id="M418" display="inline"><mml:mi>M</mml:mi></mml:math></inline-formula> is relatively small. With the increase in the parameter <inline-formula><mml:math id="M419" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula>, the impact of the parameter <inline-formula><mml:math id="M420" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula> on the soil reflectance is relatively large in the range of 0–0.01, and the anisotropy of the soil is strong; however, the influence of the parameter <inline-formula><mml:math id="M421" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula> on the SSR is relatively low, and the soil anisotropy is significantly weak. As the parameter <inline-formula><mml:math id="M422" display="inline"><mml:mi>L</mml:mi></mml:math></inline-formula> increases, <inline-formula><mml:math id="M423" display="inline"><mml:mi>L</mml:mi></mml:math></inline-formula> does not impact the soil reflectance, which corresponds with the results in Fig. 3g. With increasing value of the parameter <inline-formula><mml:math id="M424" display="inline"><mml:mi mathvariant="italic">ε</mml:mi></mml:math></inline-formula>, the equal interval of the soil reflectance decreases since the influence of the surface coverage fraction of water is proportionally related to this factor. In summary, the variation in the parameters <inline-formula><mml:math id="M425" display="inline"><mml:mi>b</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math id="M426" display="inline"><mml:mi>M</mml:mi></mml:math></inline-formula> in the Hapke-HSR model has a notable effect on the soil BRDF shape, whereas the parameters of the MARMIT-2 model have a relatively minimal effect on the soil BRDF shape. Therefore, the ability of the HM model to describe the features of the soil BRDF is basically consistent with that of the Hapke-HSR model. This occurs because the MARMIT-2 model does not include additional BRDF-related information, whereas the Hapke-HSR model includes input parameters for angle-related information. In future studies, we will comprehensively assess the ability of the HM model to represent soil BRDF features, especially in the forwards direction for wet soil.</p>
      <p id="d2e9202">Compared with existing models, the proposed Hapke-HSR <inline-formula><mml:math id="M427" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> MARMIT-2 model provides a physically consistent integration of directional scattering and moisture-related processes. Semi-empirical models such as the BSM and general spectral vectors (GSV) capture spectral variability but lack explicit representation of angular effects (Ding et al., 2022; Jiang  and Fang, 2019), which is critical for multi-angular observations and physically based parameter inversion. Moreover, soil reflectance acts as a key background component in canopy reflectance and influences vegetation parameter retrieval. By improving its spectral and directional representation under varying moisture conditions, the proposed framework can provide more reliable inputs for coupled soil–vegetation models (e.g., PROSAIL), thereby reducing uncertainties in vegetation parameter inversion. This study has certain limitations. To simplify the analysis, the effects of surface roughness and porosity are not explicitly considered (Ding et al., 2023; Ding, 2026). Despite this, the model achieves high accuracy, indicating its effectiveness in representing soil reflectance. The evaluation is conducted under a fixed observation geometry due to dataset limitations, which may constrain the characterization of angular effects. Nevertheless, the framework inherently accounts for viewing geometry through the Hapke formulation and can be extended to varying observation conditions. Future work will incorporate multi-angular datasets to further evaluate model performance.</p>

      <fig id="F12" specific-use="star"><label>Figure 12</label><caption><p id="d2e9214">Influence of the coefficient of <inline-formula><mml:math id="M428" display="inline"><mml:mi>b</mml:mi></mml:math></inline-formula> <bold>(a)</bold>, soil particle size and shape-dependent <inline-formula><mml:math id="M429" display="inline"><mml:mi>M</mml:mi></mml:math></inline-formula> <bold>(b)</bold>, volume fraction <inline-formula><mml:math id="M430" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula> <bold>(c)</bold>, thickness <inline-formula><mml:math id="M431" display="inline"><mml:mi>L</mml:mi></mml:math></inline-formula> <bold>(d)</bold> and surface coverage fraction of water <inline-formula><mml:math id="M432" display="inline"><mml:mi mathvariant="italic">ε</mml:mi></mml:math></inline-formula> <bold>(e)</bold> parameters of the Hapke-HSR <inline-formula><mml:math id="M433" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> MARMIT-2 (HM) model on the soil BRDF shape in the red band (0.67 <inline-formula><mml:math id="M434" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula>).</p></caption>
          <graphic xlink:href="https://gmd.copernicus.org/articles/19/4775/2026/gmd-19-4775-2026-f12.png"/>

        </fig>

</sec>
</sec>
<sec id="Ch1.S6" sec-type="conclusions">
  <label>6</label><title>Conclusions</title>
      <p id="d2e9301">This study develops a unified soil radiative transfer framework by refining the improved Hapke-HSR model and dynamically coupling it with the MARMIT-2 model to improve the representation of soil reflectance under varying soil moisture conditions. The primary objective is to overcome the limitations of the Hapke-HSR model in wet soils and the dependence of MARMIT-2 model on externally prescribed dry reflectance, thereby extending the applicability of both models.</p>
      <p id="d2e9304">First, dry SSR is used to estimate the imaginary part of the soil refractive index (<inline-formula><mml:math id="M435" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">χ</mml:mi><mml:mi mathvariant="normal">soil</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>), which alleviates the piecewise fitting limitation of the Hapke-HSR model by establishing a continuous statistical relationship between single scattering albedo and wavelength. The improved Hapke-HSR is then coupled with MARMIT-2 to integrate particle scattering and moisture-dependent absorption processes within a physically consistent framework. The proposed Hapke-HSR <inline-formula><mml:math id="M436" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> MARMIT-2 (HM) model is evaluated using multiple independent soil spectral databases. The results show that all three models reproduce measured SSR with reasonable accuracy, whereas the coupled HM model achieves consistently higher performance (<inline-formula><mml:math id="M437" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.993</mml:mn></mml:mrow></mml:math></inline-formula>, RMSE <inline-formula><mml:math id="M438" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.007) than MARMIT-2 (<inline-formula><mml:math id="M439" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.983</mml:mn></mml:mrow></mml:math></inline-formula>, RMSE <inline-formula><mml:math id="M440" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.012) and Hapke-HSR (<inline-formula><mml:math id="M441" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.909</mml:mn></mml:mrow></mml:math></inline-formula>, RMSE <inline-formula><mml:math id="M442" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.028), with particularly pronounced improvements at high soil moisture levels (SMC <inline-formula><mml:math id="M443" display="inline"><mml:mo>≥</mml:mo></mml:math></inline-formula> 30 %). This study does not aim to replace the MARMIT-2 model, which already provides an effective description of moisture effects, but rather to improve the overall physical consistency of soil reflectance modeling through the integration of complementary mechanisms. The coupled framework provides a robust basis for future developments in soil parameter inversion, particularly for soil moisture, and for improved representation of soil background effects in land-surface radiative transfer modeling.  In summary, this work addresses two key modeling challenges: (1) improving the hyperspectral consistency of the Hapke-HSR using dry soil reflectance, and (2) establishing a unified coupling strategy that jointly represents spectral behavior and moisture-dependent effects. The proposed framework contributes to the theoretical and methodological foundation of soil radiative transfer modeling and supports future advances in optical remote sensing of land-surface parameters. </p>
</sec>

      
      </body>
    <back><app-group>

<app id="App1.Ch1.S1">
  <label>Appendix A</label><title/>

      <fig id="FA1"><label>Figure A1</label><caption><p id="d2e9414">The bias (i.e., simulated reflectance of these models – measured reflectance) between the simulated spectral reflectance of the Hapke-HSR (red), MARMIT-2 (blue) and Hapke-HSR <inline-formula><mml:math id="M444" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> MARMIT-2 (HM) (lime) models and the fitted soil reflectance at SMC <inline-formula><mml:math id="M445" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0 % <bold>(a)</bold>, 14.45 % <bold>(b)</bold>, 27.34 % <bold>(c)</bold>, 31.6 % <bold>(d)</bold>, 36.2 % <bold>(e)</bold>, 40.34 % <bold>(f)</bold>, 45.07 % <bold>(g)</bold>, 49.25 % <bold>(h)</bold>, and 57.06 % <bold>(i)</bold>.</p></caption>
        
        <graphic xlink:href="https://gmd.copernicus.org/articles/19/4775/2026/gmd-19-4775-2026-f13.png"/>

      </fig>

<fig id="FA2"><label>Figure A2</label><caption><p id="d2e9470">The bias (i.e., simulated reflectance of these models – measured reflectance) between the simulated reflectance of the Hapke-HSR (red), MARMIT-2 (blue) and Hapke-HSR <inline-formula><mml:math id="M446" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> MARMIT-2 (HM) (lime) models and the fitted soil reflectance at SMC <inline-formula><mml:math id="M447" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0 % <bold>(a)</bold>, 5 % <bold>(b)</bold>, 10.7 % <bold>(c)</bold>, 16 % <bold>(d)</bold>, 21.1 % <bold>(e)</bold>, 30.8 % <bold>(f)</bold>, and 45.5 % <bold>(g)</bold>.</p></caption>
        
        <graphic xlink:href="https://gmd.copernicus.org/articles/19/4775/2026/gmd-19-4775-2026-f14.png"/>

      </fig>

</app>
  </app-group><notes notes-type="codedataavailability"><title>Code and data availability</title>

      <p id="d2e9521">The Hapke-HSR <inline-formula><mml:math id="M448" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> MARMIT-2 model code and example datasets used in this study are archived on Zenodo (Ding, 2026, <ext-link xlink:href="https://doi.org/10.5281/zenodo.18366791" ext-link-type="DOI">10.5281/zenodo.18366791</ext-link>). The original soil databases are derived from the MARMIT framework (<uri>https://pss-gitlab.math.univ-paris-diderot.fr/marmit/marmit</uri>, last access:  12 March 2026).</p>
  </notes><notes notes-type="authorcontribution"><title>Author contributions</title>

      <p id="d2e9540">Conceptualization, A.D. and S.L.; methodology, A.D., H.M., S.L., Z.J., and A.K.; formal analysis, A.D., H.M., and R.X.; data curation, H.M., Z.J., and R.X.; software, H.M.; investigation, Z.J.; theoretical support, A.K.; data processing and validation, H.S.; supervision, S.L.; writing – original draft, A.D.; writing – review and editing, H.M., S.L., Z.J., H.S., A.K., and R.X.</p>
  </notes><notes notes-type="competinginterests"><title>Competing interests</title>

      <p id="d2e9546">The contact author has declared that none of the authors has any competing interests.</p>
  </notes><notes notes-type="disclaimer"><title>Disclaimer</title>

      <p id="d2e9552">Publisher's note: Copernicus Publications remains neutral with regard to jurisdictional claims made in the text, published maps, institutional affiliations, or any other geographical representation in this paper. The authors bear the ultimate responsibility for providing appropriate place names. Views expressed in the text are those of the authors and do not necessarily reflect the views of the publisher.</p>
  </notes><ack><title>Acknowledgements</title><p id="d2e9561">We gratefully acknowledge Stéphane Jacquemoud and his team for sharing the implementation of the MARMIT-2 model, which provided valuable support for this study.</p></ack><notes notes-type="financialsupport"><title>Financial support</title>

      <p id="d2e9566">This study was supported by the National Natural Science Foundation of China (grant no. 42301363), the Open Fund of State Key Laboratory of Remote Sensing Science (no. OFSLRSS202412) and the Anhui Province Youth Science and Technology Talent Lift Program (grant no. RCTJ202404).</p>
  </notes><notes notes-type="reviewstatement"><title>Review statement</title>

      <p id="d2e9572">This paper was edited by Cenlin He and reviewed by two anonymous referees.</p>
  </notes><ref-list>
    <title>References</title>

      <ref id="bib1.bib1"><label>1</label><mixed-citation> Ångström, A.: The albedo of various surfaces of ground, Geogr. Ann. A, 7, 323–342, 1925.</mixed-citation></ref>
      <ref id="bib1.bib2"><label>2</label><mixed-citation>Bablet, A., Vu, P. V. H., Jacquemoud, S., Viallefont-Robinet, F., Fabre, S., Briottet, X., Sadeghi, M., Whiting, M. L., Baret, F., and Tian, J.: MARMIT: a multilayer radiative transfer model of soil reflectance to estimate surface SMC in the solar domain 400–2500 nm, Remote Sens. Environ., 217, 1–17, <ext-link xlink:href="https://doi.org/10.1016/j.rse.2018.07.031" ext-link-type="DOI">10.1016/j.rse.2018.07.031</ext-link>, 2018.</mixed-citation></ref>
      <ref id="bib1.bib3"><label>3</label><mixed-citation>Bach, H. and Mauser, W.: Modeling and model verification of the spectral reflectance of soils under varying moisture conditions, IGARSS, 4, 2354–2356, <ext-link xlink:href="https://doi.org/10.1109/IGARSS.1994.399735" ext-link-type="DOI">10.1109/IGARSS.1994.399735</ext-link>, 1994.</mixed-citation></ref>
      <ref id="bib1.bib4"><label>4</label><mixed-citation>Cheng, J., Wen, J., Xiao, Q., Wu, S., Hao, D., and Liu, Q.: Extending the GOSAILT model to simulate sparse woodland bidirectional reflectance with soil reflectance anisotropy consideration, Remote Sens., 14, 1001, <ext-link xlink:href="https://doi.org/10.3390/rs14041001" ext-link-type="DOI">10.3390/rs14041001</ext-link>, 2022.</mixed-citation></ref>
      <ref id="bib1.bib5"><label>5</label><mixed-citation>Ding, A.: Hapke-HSR <inline-formula><mml:math id="M449" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> MARMIT-2 soil reflectance model (v1.0), Zenodo [code], <ext-link xlink:href="https://doi.org/10.5281/zenodo.18366791" ext-link-type="DOI">10.5281/zenodo.18366791</ext-link>, 2026.</mixed-citation></ref>
      <ref id="bib1.bib6"><label>6</label><mixed-citation>Ding, A., Yao, Y., Song, H., Geng, J., Zhao, P., Peng, P., and Jiao, Z.: The coupling GSV and MARMIT-2 models to characterize reflectance properties of dry and wet soils, IEEE Geosci. Remote S., 22, 1–5, <uri>https://ieeexplore.ieee.org/document/10938195</uri> (last access: 12 March 2026), 2025.</mixed-citation></ref>
      <ref id="bib1.bib7"><label>7</label><mixed-citation>Ding, A., Ma, H., Liang, S., and He, T.: Extension of the Hapke model to the spectral domain to characterize soil physical properties, Remote Sens. Environ., 269, 112843, <ext-link xlink:href="https://doi.org/10.1016/j.rse.2021.112843" ext-link-type="DOI">10.1016/j.rse.2021.112843</ext-link>, 2022.</mixed-citation></ref>
      <ref id="bib1.bib8"><label>8</label><mixed-citation>Ding, A., Jiao, Z., Zhang, X., Dong, Y., Kokhanovsky, A. A., Guo, J., and Jiang, H.:  A practical approach to improve the MODIS MCD43A products in snow-covered areas, J. Remote Sens., 3, 0057, <ext-link xlink:href="https://doi.org/10.34133/remotesensing.0057" ext-link-type="DOI">10.34133/remotesensing.0057</ext-link>, 2023.</mixed-citation></ref>
      <ref id="bib1.bib9"><label>9</label><mixed-citation>Dupiau, A., Jacquemoud, S., Briottet, X., Fabre, S., Viallefont-Robinet, F., Philpot, W., Di Biagio, C., Hébert, M., and Formenti, P.: MARMIT-2: an improved version of the MARMIT model to predict soil reflectance as a function of surface water content in the solar domain, Remote Sens. Environ., 272, 112951, <ext-link xlink:href="https://doi.org/10.1016/j.rse.2022.112951" ext-link-type="DOI">10.1016/j.rse.2022.112951</ext-link>, 2022.</mixed-citation></ref>
      <ref id="bib1.bib10"><label>10</label><mixed-citation>Fan, D., Zhao, T., Jiang, X., García-García, A., Schmidt, T., Samaniego, L., Attinger, S., Wu, H., Jiang, Y., Shi, J., Fan, L., Tang, B. H., Wagner, W., Dorigo, W., Gruber, A., Mattia, F., Balenzano, A., Brocca, L., Jagdhuber, T., Wigneron, J. P., Montzka, C., and Peng, J.: A Sentinel-1 SAR-based global 1 km resolution soil moisture data product: algorithm and preliminary assessment, Remote Sens. Environ., 318, 114579, <ext-link xlink:href="https://doi.org/10.1016/j.rse.2024.114579" ext-link-type="DOI">10.1016/j.rse.2024.114579</ext-link>, 2025.</mixed-citation></ref>
      <ref id="bib1.bib11"><label>11</label><mixed-citation>Gao, S., Yan, K., Liu, J., Pu, J., Zou, D., Qi, J., and Yan, G.: Assessment of remote-sensed vegetation indices for estimating forest chlorophyll concentration, Ecol. Indic., 162, 112001, <ext-link xlink:href="https://doi.org/10.1016/j.ecolind.2024.112001" ext-link-type="DOI">10.1016/j.ecolind.2024.112001</ext-link>, 2024.</mixed-citation></ref>
      <ref id="bib1.bib12"><label>12</label><mixed-citation>Gholami, B. N. and Mobasheri, M. R.: Influence of soil texture on the estimation of bare soil moisture content using MODIS images, Eur. J. Remote Sens., 51, 911–920, 2018.</mixed-citation></ref>
      <ref id="bib1.bib13"><label>13</label><mixed-citation>Hapke, B.: Bidirectional reflectance spectroscopy 7: the single particle phase function hockey stick relation, Icarus, 221, 1079–1083, <ext-link xlink:href="https://doi.org/10.1016/j.icarus.2012.10.022" ext-link-type="DOI">10.1016/j.icarus.2012.10.022</ext-link>, 2012.</mixed-citation></ref>
      <ref id="bib1.bib14"><label>14</label><mixed-citation>Jacquemoud, S.: Modeling spectral and bidirectional soil reflectance, Remote Sens. Environ., 41, 123–132, <ext-link xlink:href="https://doi.org/10.1016/0034-4257(92)90072-R" ext-link-type="DOI">10.1016/0034-4257(92)90072-R</ext-link>, 1992.</mixed-citation></ref>
      <ref id="bib1.bib15"><label>15</label><mixed-citation>Jiang, C. and Fang, H.: GSV: a general model for hyperspectral soil reflectance simulation, Int. J. Appl. Earth Obs., 83, 101932, <ext-link xlink:href="https://doi.org/10.1016/j.jag.2019.101932" ext-link-type="DOI">10.1016/j.jag.2019.101932</ext-link>, 2019.</mixed-citation></ref>
      <ref id="bib1.bib16"><label>16</label><mixed-citation>Jiang, H., Wei, X., Chen, Z., Zhu, M., Yao, Y., Zhang, X., and Jia, K.: Influence of different soil reflectance schemes on the retrieval of vegetation LAI and FVC from PROSAIL in agricultural regions, Comput. Electron. Agric., 12, 108165, <ext-link xlink:href="https://doi.org/10.1016/j.compag.2023.108165" ext-link-type="DOI">10.1016/j.compag.2023.108165</ext-link>, 2023.</mixed-citation></ref>
      <ref id="bib1.bib17"><label>17</label><mixed-citation>Kimmel, B. W. and Baranoski, G. V. G.: A novel approach for simulating light interaction with particulate materials: application to the modeling of sand spectral properties, Opt. Express, 15, 9755–9777, 2007.</mixed-citation></ref>
      <ref id="bib1.bib18"><label>18</label><mixed-citation>Labarre, S., Jacquemoud, S., Ferrari, C., Delorme, A., Derrien, A., Grandin, R., Jalludin, M., Lemaître, F., Métois, M., Pierrot-Deseilligny, M., Rupnik, E., and Tanguy, B.: Retrieving soil surface roughness with the Hapke photometric model: confrontation with the ground truth, Remote Sens. Environ., 225, 1–15, 2019.</mixed-citation></ref>
      <ref id="bib1.bib19"><label>19</label><mixed-citation>Lekner, J. and Dorf, M. C.: Why some things are darker when wet, Appl. Optics, 27, 1278–1280, 1988.</mixed-citation></ref>
      <ref id="bib1.bib20"><label>20</label><mixed-citation>Lei, T. and Bailey, B. N.: A text-based, generative deep learning model for soil reflectance spectrum simulation in the solar range (400–2499 nm), Remote Sens. Environ., 318, 114527, <ext-link xlink:href="https://doi.org/10.1016/j.rse.2024.114527" ext-link-type="DOI">10.1016/j.rse.2024.114527</ext-link>, 2025.</mixed-citation></ref>
      <ref id="bib1.bib21"><label>21</label><mixed-citation>Li, L., Mu, X., Qi, J., Pisek, J., Roosjen, P., Yan, G., Huang, H., Liu, S., and Baret, F.: Characterizing reflectance anisotropy of background soil in open-canopy plantations using UAV-based multiangular images, ISPRS J. Photogramm. Remote Sens., 177, 263–278, 2021.</mixed-citation></ref>
      <ref id="bib1.bib22"><label>22</label><mixed-citation>Liang, S. and Townshend, J. R. G.: A parametric soil BRDF model: a four-stream approximation for multiple scattering, Int. J. Remote Sens., 17, 1303–1315, 1996a.</mixed-citation></ref>
      <ref id="bib1.bib23"><label>23</label><mixed-citation>Liang, S. and Townshend, J. R. G.: A modified Hapke model for soil bidirectional reflectance, Remote Sens. Environ., 55, 1–10, 1996b.</mixed-citation></ref>
      <ref id="bib1.bib24"><label>24</label><mixed-citation>Ma, H., Liang, S., Xiao, Z., and Shi, H.: Simultaneous inversion of multiple land surface parameters from MODIS optical-thermal observations, ISPRS J. Photogramm. Remote Sens., 128, 240–254, <ext-link xlink:href="https://doi.org/10.1016/j.isprsjprs.2017.04.007" ext-link-type="DOI">10.1016/j.isprsjprs.2017.04.007</ext-link>, 2017a.</mixed-citation></ref>
      <ref id="bib1.bib25"><label>25</label><mixed-citation>Ma, H., Liu, Q., Liang, S., and Xiao, Z.: Simultaneous estimation of leaf area index, fraction of absorbed photosynthetically active radiation, and surface albedo from multiple-satellite data, IEEE T. Geosci. Remote Sens., 55, 4334–4354, 2017b.</mixed-citation></ref>
      <ref id="bib1.bib26"><label>26</label><mixed-citation>Ni, W. and Li, X.: A coupled vegetation–soil bidirectional reflectance model for a semiarid landscape, Remote Sens. Environ., 74, 113–124, 2000.</mixed-citation></ref>
      <ref id="bib1.bib27"><label>27</label><mixed-citation>Nolin, A. W. and Liang, S.: Progress in bidirectional reflectance modeling and applications for surface particulate media: snow and soils, Remote Sens. Rev., 18, 307–342, 2000.</mixed-citation></ref>
      <ref id="bib1.bib28"><label>28</label><mixed-citation>Rizzo, R., Wadoux, A. M. J.-C., Demattê, J. A. M., Minasny, B., Barrón, V., Ben-Dor, E., Francos, N., Savin, I., Poppiel, R., Silvero, N. E. Q., Terra, F. S., Rosin, N. A., Rosas, J. T. F., Greschuk, L. T., Ballester, M. R. V., Gómez, A. M. R., Belllinaso, H., Safanelli, J. L., Chabrillat, S., Fiorio, P. R., Das, B. S., Malone, B. P., Zalidis, G., Tziolas, N., Tsakiridis, N., Karyotis, K., Samarinas, N., Kalopesa, E., Gholizadeh, A., Shepherd, K. D., Milewski, R., Vaudour, E., Wang, C., and Salama, E. S. M.: Remote sensing of the Earth's soil color in space and time, Remote Sens. Environ., 299, 113845, <ext-link xlink:href="https://doi.org/10.1016/j.rse.2023.113845" ext-link-type="DOI">10.1016/j.rse.2023.113845</ext-link>, 2023.</mixed-citation></ref>
      <ref id="bib1.bib29"><label>29</label><mixed-citation>Sadeghi, M., Babaeian, E., Tuller, M., and Jones, S. B.: The optical trapezoid model: a novel approach to remote sensing of soil moisture applied to Sentinel-2 and Landsat-8 observations, Remote Sens. Environ., 198, 52–68, <ext-link xlink:href="https://doi.org/10.1016/j.rse.2017.05.041" ext-link-type="DOI">10.1016/j.rse.2017.05.041</ext-link>, 2017.</mixed-citation></ref>
      <ref id="bib1.bib30"><label>30</label><mixed-citation>Sheng, Y., Sun, Z., Lu, S., and Omasa, K.: Ratio of physical model parameters can retrieve aggregate size from different types of soil in cultivated regions, Soil Tillage Res., 244, 106262, <ext-link xlink:href="https://doi.org/10.1016/j.still.2024.106262" ext-link-type="DOI">10.1016/j.still.2024.106262</ext-link>, 2024.</mixed-citation></ref>
      <ref id="bib1.bib31"><label>31</label><mixed-citation>Shoshany, M., Roitberg, E., Goldshleger, N., and Kizel, F.: Universal quadratic soil spectral reflectance line and its deviation patterns' relationships with chemical and textural properties: a global database analysis, Remote Sens. Environ., 155, 198–230, <ext-link xlink:href="https://doi.org/10.1016/j.rse.2022.113182" ext-link-type="DOI">10.1016/j.rse.2022.113182</ext-link>, 2022.</mixed-citation></ref>
      <ref id="bib1.bib32"><label>32</label><mixed-citation>Sun, Z., Lu, S., and Omasa, K.: MART-soil: A modified analytical radiative transfer model for simulating multi-angular reflection of soils with different particle size, Geoderma, 431, 116366, <ext-link xlink:href="https://doi.org/10.1016/j.geoderma.2023.116366" ext-link-type="DOI">10.1016/j.geoderma.2023.116366</ext-link>, 2023.</mixed-citation></ref>
      <ref id="bib1.bib33"><label>33</label><mixed-citation>Verhoef, W. and Bach, H.: Coupled soil–leaf–canopy and atmosphere radiative transfer modeling to simulate hyperspectral multi-angular surface reflectance and TOA radiance data, Remote Sens. Environ., 109, 166–182, <ext-link xlink:href="https://doi.org/10.1016/j.rse.2006.12.013" ext-link-type="DOI">10.1016/j.rse.2006.12.013</ext-link>, 2007.</mixed-citation></ref>
      <ref id="bib1.bib34"><label>34</label><mixed-citation>Verhoef, W., Van der Tol, C., and Middleton, E. M.: Hyperspectral radiative transfer modeling to explore the combined retrieval of biophysical parameters and canopy fluorescence from FLEX–Sentinel-3 tandem mission multi-sensor data, Remote Sens. Environ., 204, 942–963, <ext-link xlink:href="https://doi.org/10.1016/j.rse.2017.08.006" ext-link-type="DOI">10.1016/j.rse.2017.08.006</ext-link>, 2018.</mixed-citation></ref>
      <ref id="bib1.bib35"><label>35</label><mixed-citation>Xu, H., Sun, H., Xu, Z., Wang, Y., Zhang, T., Wu, D., and Gao, J.: kNDMI: a kernel normalized difference moisture index for remote sensing of soil and vegetation moisture, Remote Sens. Environ., 319, 114621, <ext-link xlink:href="https://doi.org/10.1016/j.rse.2025.114621" ext-link-type="DOI">10.1016/j.rse.2025.114621</ext-link>, 2025. </mixed-citation></ref>
      <ref id="bib1.bib36"><label>36</label><mixed-citation>Yang, G.-J., Zhao, C.-J., Huang, W.-J., and Wang, J.-H.: Extension of the Hapke bidirectional reflectance model to retrieve soil water content, Hydrol. Earth Syst. Sci., 15, 2317–2326, <ext-link xlink:href="https://doi.org/10.5194/hess-15-2317-2011" ext-link-type="DOI">10.5194/hess-15-2317-2011</ext-link>, 2011.</mixed-citation></ref>
      <ref id="bib1.bib37"><label>37</label><mixed-citation>Yang, P.: Exploring the interrelated effects of soil background, canopy structure, and sun–observer geometry on canopy photochemical reflectance index, Remote Sens. Environ., 279, 113133, <ext-link xlink:href="https://doi.org/10.1016/j.rse.2022.113133" ext-link-type="DOI">10.1016/j.rse.2022.113133</ext-link>, 2022.</mixed-citation></ref>
      <ref id="bib1.bib38"><label>38</label><mixed-citation>Yang, P., van der Tol, C., Liu, J., and Liu, Z.: Separation of the direct reflection of soil from canopy spectral reflectance, Remote Sens. Environ., 316, 114500, <ext-link xlink:href="https://doi.org/10.1016/j.rse.2024.114500" ext-link-type="DOI">10.1016/j.rse.2024.114500</ext-link>, 2025.</mixed-citation></ref>
      <ref id="bib1.bib39"><label>39</label><mixed-citation>Zeng, Y., Hao, D., Badgley, G., Damm, A., Rascher, U., Ryu, Y., Johnson, J., Krieger, V., Wu, S., Qiu, H., Liu, Y., Berry, J. A., and Chen, M.: Estimating near-infrared reflectance of vegetation from hyperspectral data, Remote Sens. Environ., 267, 112723, <ext-link xlink:href="https://doi.org/10.1016/j.rse.2021.112723" ext-link-type="DOI">10.1016/j.rse.2021.112723</ext-link>, 2021.</mixed-citation></ref>
      <ref id="bib1.bib40"><label>40</label><mixed-citation>Zhao, X., Qi, J., Xu, H., Yu, Z., Yuan, L., Chen, Y., and Huang, H.: Evaluating the potential of airborne hyperspectral LiDAR for assessing forest insects and diseases with 3D radiative transfer modeling, Remote Sens. Environ., 297, 113759, <ext-link xlink:href="https://doi.org/10.1016/j.rse.2023.113759" ext-link-type="DOI">10.1016/j.rse.2023.113759</ext-link>, 2023.</mixed-citation></ref>

  </ref-list></back>
    <!--<article-title-html>A unified Hapke-HSR + MARMIT-2 soil radiative transfer model for reflectance simulation under varying moisture conditions</article-title-html>
<abstract-html/>
<ref-html id="bib1.bib1"><label>1</label><mixed-citation>
      
Ångström, A.: The albedo of various surfaces of ground, Geogr.
Ann. A, 7, 323–342, 1925.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib2"><label>2</label><mixed-citation>
      Bablet, A., Vu, P. V. H., Jacquemoud, S., Viallefont-Robinet, F., Fabre, S.,
Briottet, X., Sadeghi, M., Whiting, M. L., Baret, F., and Tian, J.: MARMIT:
a multilayer radiative transfer model of soil reflectance to estimate
surface SMC in the solar domain 400–2500&thinsp;nm, Remote Sens. Environ., 217,
1–17, <a href="https://doi.org/10.1016/j.rse.2018.07.031" target="_blank">https://doi.org/10.1016/j.rse.2018.07.031</a>, 2018.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib3"><label>3</label><mixed-citation>
      Bach, H. and Mauser, W.: Modeling and model verification of the spectral
reflectance of soils under varying moisture conditions, IGARSS, 4,
2354–2356, <a href="https://doi.org/10.1109/IGARSS.1994.399735" target="_blank">https://doi.org/10.1109/IGARSS.1994.399735</a>, 1994.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib4"><label>4</label><mixed-citation>
      Cheng, J., Wen, J., Xiao, Q., Wu, S., Hao, D., and Liu, Q.: Extending the
GOSAILT model to simulate sparse woodland bidirectional reflectance with
soil reflectance anisotropy consideration, Remote Sens., 14, 1001, <a href="https://doi.org/10.3390/rs14041001" target="_blank">https://doi.org/10.3390/rs14041001</a>, 2022.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib5"><label>5</label><mixed-citation>
      Ding, A.: Hapke-HSR + MARMIT-2 soil reflectance model (v1.0), Zenodo [code],
<a href="https://doi.org/10.5281/zenodo.18366791" target="_blank">https://doi.org/10.5281/zenodo.18366791</a>, 2026.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib6"><label>6</label><mixed-citation>
      Ding, A., Yao, Y., Song, H., Geng, J., Zhao, P., Peng, P., and Jiao, Z.: The coupling GSV and MARMIT-2 models to characterize reflectance properties of dry and wet soils, IEEE Geosci. Remote S., 22, 1–5, <a href="https://ieeexplore.ieee.org/document/10938195" target="_blank"/> (last access: 12 March 2026), 2025.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib7"><label>7</label><mixed-citation>
      Ding, A., Ma, H., Liang, S., and He, T.: Extension of the Hapke model to the
spectral domain to characterize soil physical properties, Remote Sens.
Environ., 269, 112843, <a href="https://doi.org/10.1016/j.rse.2021.112843" target="_blank">https://doi.org/10.1016/j.rse.2021.112843</a>, 2022.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib8"><label>8</label><mixed-citation>
      Ding, A., Jiao, Z., Zhang, X., Dong, Y., Kokhanovsky, A. A., Guo, J., and
Jiang, H.:  A practical approach to improve the MODIS MCD43A products in
snow-covered areas, J. Remote Sens., 3, 0057, <a href="https://doi.org/10.34133/remotesensing.0057" target="_blank">https://doi.org/10.34133/remotesensing.0057</a>, 2023.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib9"><label>9</label><mixed-citation>
      Dupiau, A., Jacquemoud, S., Briottet, X., Fabre, S., Viallefont-Robinet, F.,
Philpot, W., Di Biagio, C., Hébert, M., and Formenti, P.: MARMIT-2: an
improved version of the MARMIT model to predict soil reflectance as a
function of surface water content in the solar domain, Remote Sens.
Environ., 272, 112951, <a href="https://doi.org/10.1016/j.rse.2022.112951" target="_blank">https://doi.org/10.1016/j.rse.2022.112951</a>, 2022.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib10"><label>10</label><mixed-citation>
      Fan, D., Zhao, T., Jiang, X., García-García, A., Schmidt, T.,
Samaniego, L., Attinger, S., Wu, H., Jiang, Y., Shi, J., Fan, L., Tang, B.
H., Wagner, W., Dorigo, W., Gruber, A., Mattia, F., Balenzano, A., Brocca,
L., Jagdhuber, T., Wigneron, J. P., Montzka, C., and Peng, J.: A Sentinel-1
SAR-based global 1 km resolution soil moisture data product: algorithm and
preliminary assessment, Remote Sens. Environ., 318, 114579,
<a href="https://doi.org/10.1016/j.rse.2024.114579" target="_blank">https://doi.org/10.1016/j.rse.2024.114579</a>, 2025.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib11"><label>11</label><mixed-citation>
      Gao, S., Yan, K., Liu, J., Pu, J., Zou, D., Qi, J., and Yan, G.: Assessment
of remote-sensed vegetation indices for estimating forest chlorophyll
concentration, Ecol. Indic., 162, 112001,
<a href="https://doi.org/10.1016/j.ecolind.2024.112001" target="_blank">https://doi.org/10.1016/j.ecolind.2024.112001</a>, 2024.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib12"><label>12</label><mixed-citation>
      Gholami, B. N. and Mobasheri, M. R.: Influence of soil texture on the
estimation of bare soil moisture content using MODIS images, Eur. J. Remote
Sens., 51, 911–920, 2018.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib13"><label>13</label><mixed-citation>
      Hapke, B.: Bidirectional reflectance spectroscopy 7: the single particle
phase function hockey stick relation, Icarus, 221, 1079–1083,
<a href="https://doi.org/10.1016/j.icarus.2012.10.022" target="_blank">https://doi.org/10.1016/j.icarus.2012.10.022</a>, 2012.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib14"><label>14</label><mixed-citation>
      Jacquemoud, S.: Modeling spectral and bidirectional soil reflectance, Remote
Sens. Environ., 41, 123–132, <a href="https://doi.org/10.1016/0034-4257(92)90072-R" target="_blank">https://doi.org/10.1016/0034-4257(92)90072-R</a>,
1992.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib15"><label>15</label><mixed-citation>
      Jiang, C. and Fang, H.: GSV: a general model for hyperspectral soil
reflectance simulation, Int. J. Appl. Earth Obs., 83, 101932,
<a href="https://doi.org/10.1016/j.jag.2019.101932" target="_blank">https://doi.org/10.1016/j.jag.2019.101932</a>, 2019.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib16"><label>16</label><mixed-citation>
      Jiang, H., Wei, X., Chen, Z., Zhu, M., Yao, Y., Zhang, X., and Jia, K.:
Influence of different soil reflectance schemes on the retrieval of
vegetation LAI and FVC from PROSAIL in agricultural regions, Comput.
Electron. Agric., 12, 108165, <a href="https://doi.org/10.1016/j.compag.2023.108165" target="_blank">https://doi.org/10.1016/j.compag.2023.108165</a>,
2023.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib17"><label>17</label><mixed-citation>
      Kimmel, B. W. and Baranoski, G. V. G.: A novel approach for simulating light
interaction with particulate materials: application to the modeling of sand
spectral properties, Opt. Express, 15, 9755–9777, 2007.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib18"><label>18</label><mixed-citation>
      Labarre, S., Jacquemoud, S., Ferrari, C., Delorme, A., Derrien, A., Grandin,
R., Jalludin, M., Lemaître, F., Métois, M., Pierrot-Deseilligny,
M., Rupnik, E., and Tanguy, B.: Retrieving soil surface roughness with the
Hapke photometric model: confrontation with the ground truth, Remote Sens.
Environ., 225, 1–15, 2019.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib19"><label>19</label><mixed-citation>
      Lekner, J. and Dorf, M. C.: Why some things are darker when wet, Appl. Optics,
27, 1278–1280, 1988.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib20"><label>20</label><mixed-citation>
      Lei, T. and Bailey, B. N.: A text-based, generative deep learning model for
soil reflectance spectrum simulation in the solar range (400–2499&thinsp;nm),
Remote Sens. Environ., 318, 114527, <a href="https://doi.org/10.1016/j.rse.2024.114527" target="_blank">https://doi.org/10.1016/j.rse.2024.114527</a>, 2025.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib21"><label>21</label><mixed-citation>
      Li, L., Mu, X., Qi, J., Pisek, J., Roosjen, P., Yan, G., Huang, H., Liu, S.,
and Baret, F.: Characterizing reflectance anisotropy of background soil in
open-canopy plantations using UAV-based multiangular images, ISPRS J.
Photogramm. Remote Sens., 177, 263–278, 2021.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib22"><label>22</label><mixed-citation>
      Liang, S. and Townshend, J. R. G.: A parametric soil BRDF model: a
four-stream approximation for multiple scattering, Int. J. Remote Sens., 17,
1303–1315, 1996a.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib23"><label>23</label><mixed-citation>
      Liang, S. and Townshend, J. R. G.: A modified Hapke model for soil
bidirectional reflectance, Remote Sens. Environ., 55, 1–10, 1996b.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib24"><label>24</label><mixed-citation>
      Ma, H., Liang, S., Xiao, Z., and Shi, H.: Simultaneous inversion of multiple
land surface parameters from MODIS optical-thermal observations, ISPRS J.
Photogramm. Remote Sens., 128, 240–254,
<a href="https://doi.org/10.1016/j.isprsjprs.2017.04.007" target="_blank">https://doi.org/10.1016/j.isprsjprs.2017.04.007</a>, 2017a.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib25"><label>25</label><mixed-citation>
      Ma, H., Liu, Q., Liang, S., and Xiao, Z.: Simultaneous estimation of leaf
area index, fraction of absorbed photosynthetically active radiation, and
surface albedo from multiple-satellite data, IEEE T. Geosci. Remote
Sens., 55, 4334–4354, 2017b.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib26"><label>26</label><mixed-citation>
      Ni, W. and Li, X.: A coupled vegetation–soil bidirectional reflectance
model for a semiarid landscape, Remote Sens. Environ., 74, 113–124, 2000.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib27"><label>27</label><mixed-citation>
      Nolin, A. W. and Liang, S.: Progress in bidirectional reflectance modeling
and applications for surface particulate media: snow and soils, Remote Sens.
Rev., 18, 307–342, 2000.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib28"><label>28</label><mixed-citation>
      Rizzo, R., Wadoux, A. M. J.-C., Demattê, J. A. M., Minasny, B.,
Barrón, V., Ben-Dor, E., Francos, N., Savin, I., Poppiel, R., Silvero,
N. E. Q., Terra, F. S., Rosin, N. A., Rosas, J. T. F., Greschuk, L. T.,
Ballester, M. R. V., Gómez, A. M. R., Belllinaso, H., Safanelli, J. L.,
Chabrillat, S., Fiorio, P. R., Das, B. S., Malone, B. P., Zalidis, G.,
Tziolas, N., Tsakiridis, N., Karyotis, K., Samarinas, N., Kalopesa, E.,
Gholizadeh, A., Shepherd, K. D., Milewski, R., Vaudour, E., Wang, C., and
Salama, E. S. M.: Remote sensing of the Earth's soil color in space and
time, Remote Sens. Environ., 299, 113845,
<a href="https://doi.org/10.1016/j.rse.2023.113845" target="_blank">https://doi.org/10.1016/j.rse.2023.113845</a>, 2023.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib29"><label>29</label><mixed-citation>
      Sadeghi, M., Babaeian, E., Tuller, M., and Jones, S. B.: The optical
trapezoid model: a novel approach to remote sensing of soil moisture applied
to Sentinel-2 and Landsat-8 observations, Remote Sens. Environ., 198,
52–68, <a href="https://doi.org/10.1016/j.rse.2017.05.041" target="_blank">https://doi.org/10.1016/j.rse.2017.05.041</a>, 2017.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib30"><label>30</label><mixed-citation>
      Sheng, Y., Sun, Z., Lu, S., and Omasa, K.: Ratio of physical model
parameters can retrieve aggregate size from different types of soil in
cultivated regions, Soil Tillage Res., 244, 106262,
<a href="https://doi.org/10.1016/j.still.2024.106262" target="_blank">https://doi.org/10.1016/j.still.2024.106262</a>, 2024.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib31"><label>31</label><mixed-citation>
      Shoshany, M., Roitberg, E., Goldshleger, N., and Kizel, F.: Universal
quadratic soil spectral reflectance line and its deviation patterns'
relationships with chemical and textural properties: a global database
analysis, Remote Sens. Environ., 155, 198–230,
<a href="https://doi.org/10.1016/j.rse.2022.113182" target="_blank">https://doi.org/10.1016/j.rse.2022.113182</a>, 2022.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib32"><label>32</label><mixed-citation>
      Sun, Z., Lu, S., and Omasa, K.: MART-soil: A modified analytical radiative transfer model for simulating multi-angular reflection of soils with different particle size, Geoderma, 431, 116366, <a href="https://doi.org/10.1016/j.geoderma.2023.116366" target="_blank">https://doi.org/10.1016/j.geoderma.2023.116366</a>, 2023.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib33"><label>33</label><mixed-citation>
      Verhoef, W. and Bach, H.: Coupled soil–leaf–canopy and atmosphere
radiative transfer modeling to simulate hyperspectral multi-angular surface
reflectance and TOA radiance data, Remote Sens. Environ., 109, 166–182,
<a href="https://doi.org/10.1016/j.rse.2006.12.013" target="_blank">https://doi.org/10.1016/j.rse.2006.12.013</a>, 2007.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib34"><label>34</label><mixed-citation>
      Verhoef, W., Van der Tol, C., and Middleton, E. M.: Hyperspectral radiative
transfer modeling to explore the combined retrieval of biophysical
parameters and canopy fluorescence from FLEX–Sentinel-3 tandem mission
multi-sensor data, Remote Sens. Environ., 204, 942–963,
<a href="https://doi.org/10.1016/j.rse.2017.08.006" target="_blank">https://doi.org/10.1016/j.rse.2017.08.006</a>, 2018.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib35"><label>35</label><mixed-citation>
      Xu, H., Sun, H., Xu, Z., Wang, Y., Zhang, T., Wu, D., and Gao, J.: kNDMI: a
kernel normalized difference moisture index for remote sensing of soil and
vegetation moisture, Remote Sens. Environ., 319, 114621,
<a href="https://doi.org/10.1016/j.rse.2025.114621" target="_blank">https://doi.org/10.1016/j.rse.2025.114621</a>, 2025.


    </mixed-citation></ref-html>
<ref-html id="bib1.bib36"><label>36</label><mixed-citation>
      Yang, G.-J., Zhao, C.-J., Huang, W.-J., and Wang, J.-H.: Extension of the Hapke bidirectional reflectance model to retrieve soil water content, Hydrol. Earth Syst. Sci., 15, 2317–2326, <a href="https://doi.org/10.5194/hess-15-2317-2011" target="_blank">https://doi.org/10.5194/hess-15-2317-2011</a>, 2011.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib37"><label>37</label><mixed-citation>
      Yang, P.: Exploring the interrelated effects of soil background, canopy
structure, and sun–observer geometry on canopy photochemical reflectance
index, Remote Sens. Environ., 279, 113133,
<a href="https://doi.org/10.1016/j.rse.2022.113133" target="_blank">https://doi.org/10.1016/j.rse.2022.113133</a>, 2022.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib38"><label>38</label><mixed-citation>
      Yang, P., van der Tol, C., Liu, J., and Liu, Z.: Separation of the direct
reflection of soil from canopy spectral reflectance, Remote Sens. Environ.,
316, 114500, <a href="https://doi.org/10.1016/j.rse.2024.114500" target="_blank">https://doi.org/10.1016/j.rse.2024.114500</a>, 2025.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib39"><label>39</label><mixed-citation>
      Zeng, Y., Hao, D., Badgley, G., Damm, A., Rascher, U., Ryu, Y., Johnson, J.,
Krieger, V., Wu, S., Qiu, H., Liu, Y., Berry, J. A., and Chen, M.:
Estimating near-infrared reflectance of vegetation from hyperspectral data,
Remote Sens. Environ., 267, 112723,
<a href="https://doi.org/10.1016/j.rse.2021.112723" target="_blank">https://doi.org/10.1016/j.rse.2021.112723</a>, 2021.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib40"><label>40</label><mixed-citation>
      Zhao, X., Qi, J., Xu, H., Yu, Z., Yuan, L., Chen, Y., and Huang, H.:
Evaluating the potential of airborne hyperspectral LiDAR for assessing
forest insects and diseases with 3D radiative transfer modeling, Remote
Sens. Environ., 297, 113759, <a href="https://doi.org/10.1016/j.rse.2023.113759" target="_blank">https://doi.org/10.1016/j.rse.2023.113759</a>,
2023.

    </mixed-citation></ref-html>--></article>
