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  <front>
    <journal-meta><journal-id journal-id-type="publisher">GMD</journal-id><journal-title-group>
    <journal-title>Geoscientific Model Development</journal-title>
    <abbrev-journal-title abbrev-type="publisher">GMD</abbrev-journal-title><abbrev-journal-title abbrev-type="nlm-ta">Geosci. Model Dev.</abbrev-journal-title>
  </journal-title-group><issn pub-type="epub">1991-9603</issn><publisher>
    <publisher-name>Copernicus Publications</publisher-name>
    <publisher-loc>Göttingen, Germany</publisher-loc>
  </publisher></journal-meta>
    <article-meta>
      <article-id pub-id-type="doi">10.5194/gmd-16-3873-2023</article-id><title-group><article-title>The Fire Inventory from NCAR version 2.5: an updated global fire emissions model for climate and chemistry applications</article-title><alt-title>The Fire Inventory from NCAR version 2.5</alt-title>
      </title-group><?xmltex \runningtitle{The Fire Inventory from NCAR version 2.5}?><?xmltex \runningauthor{C.~Wiedinmyer et al.}?>
      <contrib-group>
        <contrib contrib-type="author" corresp="yes" rid="aff1">
          <name><surname>Wiedinmyer</surname><given-names>Christine</given-names></name>
          <email>christine.wiedinmyer@colorado.edu</email>
        <ext-link>https://orcid.org/0000-0001-9738-6592</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff2">
          <name><surname>Kimura</surname><given-names>Yosuke</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff2">
          <name><surname>McDonald-Buller</surname><given-names>Elena C.</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff3">
          <name><surname>Emmons</surname><given-names>Louisa K.</given-names></name>
          
        <ext-link>https://orcid.org/0000-0003-2325-6212</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff3">
          <name><surname>Buchholz</surname><given-names>Rebecca R.</given-names></name>
          
        <ext-link>https://orcid.org/0000-0001-8124-2455</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff3">
          <name><surname>Tang</surname><given-names>Wenfu</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-0107-4496</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Seto</surname><given-names>Keenan</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1 aff4">
          <name><surname>Joseph</surname><given-names>Maxwell B.</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff5 aff3">
          <name><surname>Barsanti</surname><given-names>Kelley C.</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-6065-8643</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff6">
          <name><surname>Carlton</surname><given-names>Annmarie G.</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-8574-1507</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff7">
          <name><surname>Yokelson</surname><given-names>Robert</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-8415-6808</ext-link></contrib>
        <aff id="aff1"><label>1</label><institution>Cooperative Institute for Research in Environmental Sciences,
University of Colorado, Boulder, Boulder, CO, USA</institution>
        </aff>
        <aff id="aff2"><label>2</label><institution>Center for Energy and Environmental Resources, The University of Texas at Austin, Austin, TX, USA</institution>
        </aff>
        <aff id="aff3"><label>3</label><institution>Atmospheric Chemistry Observations and Modeling Laboratory, National Center for Atmospheric Research, <?xmltex \hack{\break}?>Boulder, CO, USA</institution>
        </aff>
        <aff id="aff4"><label>4</label><institution>Earth Lab, University of Colorado Boulder, Boulder, CO, USA</institution>
        </aff>
        <aff id="aff5"><label>5</label><institution>Department of Chemical and Environmental Engineering, Center for
Environmental Research and Technology, <?xmltex \hack{\break}?>University of California, Riverside, Riverside, CA, USA</institution>
        </aff>
        <aff id="aff6"><label>6</label><institution>Department of Chemistry, University of California Irvine, Irvine, CA, USA</institution>
        </aff>
        <aff id="aff7"><label>7</label><institution>Department of Chemistry, University of Montana, Missoula, MT, USA</institution>
        </aff>
      </contrib-group>
      <author-notes><corresp id="corr1">Christine Wiedinmyer (christine.wiedinmyer@colorado.edu)</corresp></author-notes><pub-date><day>12</day><month>July</month><year>2023</year></pub-date>
      
      <volume>16</volume>
      <issue>13</issue>
      <fpage>3873</fpage><lpage>3891</lpage>
      <history>
        <date date-type="received"><day>30</day><month>January</month><year>2023</year></date>
           <date date-type="rev-request"><day>27</day><month>February</month><year>2023</year></date>
           <date date-type="rev-recd"><day>16</day><month>May</month><year>2023</year></date>
           <date date-type="accepted"><day>1</day><month>June</month><year>2023</year></date>
      </history>
      <permissions>
        <copyright-statement>Copyright: © 2023 Christine Wiedinmyer et al.</copyright-statement>
        <copyright-year>2023</copyright-year>
      <license license-type="open-access"><license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri" xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p></license></permissions><self-uri xlink:href="https://gmd.copernicus.org/articles/16/3873/2023/gmd-16-3873-2023.html">This article is available from https://gmd.copernicus.org/articles/16/3873/2023/gmd-16-3873-2023.html</self-uri><self-uri xlink:href="https://gmd.copernicus.org/articles/16/3873/2023/gmd-16-3873-2023.pdf">The full text article is available as a PDF file from https://gmd.copernicus.org/articles/16/3873/2023/gmd-16-3873-2023.pdf</self-uri>
      <abstract><title>Abstract</title>

      <p id="d1e219">We present the Fire Inventory from National Center for Atmospheric Research (NCAR) version 2.5 (FINNv2.5), a fire emissions inventory that provides publicly available emissions of trace gases and aerosols for various applications, including use in global and regional atmospheric chemistry modeling. FINNv2.5 includes numerous updates to the FINN version 1 framework to better represent burned area, vegetation burned, and chemicals emitted. Major changes include the use of active fire detections from the Visible Infrared Imaging Radiometer Suite (VIIRS) at 375 m spatial resolution, which allows smaller fires to be included in the emissions processing. The calculation of burned area has been updated such that a more rigorous approach is used to aggregate fire detections, which better accounts for larger fires and enables using multiple satellite products simultaneously for emissions estimates. Fuel characterization and emissions factors have also been updated in FINNv2.5. Daily fire emissions for many trace gases and aerosols are determined for 2002–2019 (Moderate Resolution Imaging Spectroradiometer (MODIS)-only fire detections) and 2012–2019 (MODIS <inline-formula><mml:math id="M1" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> VIIRS fire detections). The non-methane organic gas emissions are allocated to the species of several commonly used chemical mechanisms. We compare FINNv2.5 emissions against other widely used fire emissions inventories. The performance of FINNv2.5 emissions as inputs to a chemical transport model is assessed with satellite observations. Uncertainties in the emissions estimates remain, particularly in Africa and South America during August–October and in southeast and equatorial Asia in March and April. Recommendations for future evaluation and use are given.</p>
  </abstract>
    
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<award-group id="gs1">
<funding-source>Climate Program Office</funding-source>
<award-id>NA17OAR4310103</award-id>
</award-group>
<award-group id="gs2">
<funding-source>National Science Foundation</funding-source>
<award-id>1822406</award-id>
<award-id>AGS-1748266</award-id>
<award-id>AGS-1349976</award-id>
<award-id>1852977</award-id>
</award-group>
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<funding-source>National Aeronautics and Space Administration</funding-source>
<award-id>80NSSC18K0681</award-id>
<award-id>NNX14AP45G</award-id>
</award-group>
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<funding-source>National Oceanic and Atmospheric Administration</funding-source>
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<award-id>NA22OAR4320151</award-id>
<award-id>NA17OAR4310007</award-id>
<award-id>NA16OAR4310100</award-id>
</award-group>
</funding-group>
</article-meta>
  </front>
<body>
      

<sec id="Ch1.S1" sec-type="intro">
  <label>1</label><title>Introduction</title>
      <p id="d1e238">Open fires, such as wildfires, prescribed burns, agricultural fires, and
land-clearing fires, are sources of atmospheric pollutants. Fire activity
contributes to local, regional, and global emissions of greenhouse gases
including carbon dioxide (CO<inline-formula><mml:math id="M2" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>) and methane (CH<inline-formula><mml:math id="M3" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">4</mml:mn></mml:msub></mml:math></inline-formula>), reactive gases
such as non-methane organic gases (NMOGs) and nitrogen oxides (NO<inline-formula><mml:math id="M4" display="inline"><mml:msub><mml:mi/><mml:mi>x</mml:mi></mml:msub></mml:math></inline-formula>)
that form ozone, dioxins and other air toxics, and particulate matter (PM). Fire emissions and their transport change the atmospheric composition to cause impacts at many scales, with implications for air quality (e.g., Burke et al., 2021; Jaffe et al., 2020; Liu et al., 2017; Tang et al., 2022;
Bourgeois et al., 2021; Xu et al., 2020, 2021), regional and global<?pagebreak page3874?> climate (e.g., Dintwe et al., 2017; Jin et al., 2012; Liu et al., 2019), visibility (e.g., Ford et al., 2018; Jaffe et al., 2020; Val Martin et al., 2015), and human health outcomes (e.g., Liu et al., 2017; Reid et al., 2016; Xu et al., 2020). Many factors contribute to the spatial and temporal patterns and severity of fires and their emissions, including agricultural, forest, and waste management practices, land use change, climatic factors such as temperature, rainfall, and drought conditions, and ecosystem diversity and health (e.g., Armenteras et al., 2021; Kelly et al., 2020; Pausas and Keeley, 2021). Future climate, policy, and human development patterns, including in the wildland–urban interface (WUI), will have complex interactions on the effects of fires that may require adaptive strategies for communities (Schoennagel et al., 2017).</p>
      <p id="d1e268">Accurate estimates of fire emissions are required to understand chemistry
and climate, to assess ambient pollutant concentrations and population exposure, and to evaluate the effectiveness of emissions control programs for air quality planning and management. The FINN (Fire INventory from NCAR; Wiedinmyer et al., 2011; <uri>https://www2.acom.ucar.edu/modeling/finn-fire-inventory-ncar</uri>, last access: 7 July 2023) inventory was developed more than 10 years ago to provide daily global estimates of pollutant emissions from open fires with a high spatial and temporal resolution for use in air quality, atmospheric composition, and climate modeling applications. The National Center for Atmospheric Research (NCAR) has served as the central repository for FINN global emissions files spanning
2002–2020 (<uri>https://www.acom.ucar.edu/Data/fire/</uri>, last access: 6 July 2023). FINN estimates
have been downloaded more than 13 450 times since 29 August 2013, as of 10 July 2023, and the original model has been cited 998 times (Clarivate Web of Science, <uri>http://www.webofscience.com</uri>, last access: 10 July 2023). FINN emissions estimates have been applied in regions of the world that experience high fire activity to evaluate the influences on air quality and public health (e.g., Crippa et al., 2016; Kulkarni et al., 2020; Nawaz and Henze, 2020; Nuryanto, 2015; Pimonsree and Vongruang, 2018; Takami et al., 2020), to assess emissions trends (e.g., Ma et al., 2018; Shen et al., 2019), to examine the effects of changing climate and development patterns on wildfire emissions (e.g., Hurteau et al., 2014), and in comparisons with surface, aircraft, and satellite-based observations (e.g., Reddington et al., 2019; Stavrakou et al., 2016), as well as with inventories developed using other fire emissions modeling systems (e.g., Bray et al., 2018; Faulstich et al., 2022; Kiely et al., 2019; Koplitz et al., 2018; Larkin et al., 2014; Liu et al., 2020; Pereira et al., 2016; Urbanski et al., 2018). Real-time emissions estimates from FINN version 1 (FINNv1) are currently used in the NCAR Whole Atmosphere Community Climate Model (WACCM) chemistry and aerosol forecasts (<uri>http://www.acom.ucar.edu/waccm/forecast/</uri>, last access: 6 July 2023).</p>
      <p id="d1e283">The FINNv1 model is based on a bottom-up approach to estimate the emissions
described by Wiedinmyer et al. (2011). In FINNv1, global observations from
the Moderate Resolution Imaging Spectroradiometer (MODIS) sensors on board
the National Aeronautics and Space Administration's (NASA) Terra and Aqua
satellites are used to detect fire activity, beginning with the MODIS Rapid
Response (MRR) system or the MODIS Adaptive Processing System (MODAPS) Collection 5 (NASA/University of Maryland, 2002; Davies et al., 2009). Fuel characterization in FINNv1 is based on the Collection 5 MODIS Land Cover Type (LCT) product for 2005 (Friedl et al., 2010), with land cover classifications defined by the International Geosphere–Biosphere Programme (IGBP) and the Collection 3 MODIS Vegetation Continuous Fields (VCF) product for 2001 (Carroll et al., 2011; Hansen et al., 2003, 2005). Fuel loadings are assigned from Hoelzemann (2004) or Akagi et al. (2011). Estimates of fuel burned use the approach of Ito and Penner (2004). Emissions factors by land cover classification for trace gases and particulate air pollutants in FINNv1 are based on the published literature at the time (Akagi et al., 2011; Andreae and Merlet, 2001; Andreae and Rosenfeld, 2008; McMeeking, 2008).</p>
      <p id="d1e286">FINN version 2.5 (FINNv2.5) has extensive updates to the input data and processing used for the detection of fire activity, characterization of
annual land use and/or land cover and vegetation density, determination of area burned, and the application of fuel loadings by global region compared to the FINNv1 configuration. FINNv2.5 also includes revisions to emissions
factors based on the current literature. Here we describe the development of
FINNv2.5, released in 2022 (Wiedinmyer and Emmons, 2022). Global emissions
for 2002 through 2021 have been created and are online for public use, for
inclusion in emissions inventories and chemical and climate modeling
applications, and for comparisons with previous versions of FINN and results
from other fire emissions models.</p>
</sec>
<sec id="Ch1.S2">
  <label>2</label><title>Methods</title>
      <p id="d1e297">FINNv2.5 uses the same FINNv1 bottom-up methodology (Seiler and Crutzen,
1980; Wiedinmyer et al., 2011) as defined by the following overall equation:
          <disp-formula id="Ch1.E1" content-type="numbered"><label>1</label><mml:math id="M5" display="block"><mml:mrow><mml:msub><mml:mi>E</mml:mi><mml:mi>i</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mi>A</mml:mi><mml:mo>(</mml:mo><mml:mi>x</mml:mi><mml:mo>,</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo><mml:mo>×</mml:mo><mml:mi>B</mml:mi><mml:mo>(</mml:mo><mml:mi>x</mml:mi><mml:mo>)</mml:mo><mml:mo>×</mml:mo><mml:mtext>FB</mml:mtext><mml:mo>×</mml:mo><mml:msub><mml:mtext>EF</mml:mtext><mml:mi>i</mml:mi></mml:msub><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>
        where the emissions (<inline-formula><mml:math id="M6" display="inline"><mml:mi>E</mml:mi></mml:math></inline-formula>; mass of pollutant <inline-formula><mml:math id="M7" display="inline"><mml:mi>i</mml:mi></mml:math></inline-formula>) are the product of the area
burned at location <inline-formula><mml:math id="M8" display="inline"><mml:mi>x</mml:mi></mml:math></inline-formula> and time <inline-formula><mml:math id="M9" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> [<inline-formula><mml:math id="M10" display="inline"><mml:mrow><mml:mi>A</mml:mi><mml:mo>(</mml:mo><mml:mi>x</mml:mi><mml:mo>,</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>], the biomass at location <inline-formula><mml:math id="M11" display="inline"><mml:mi>x</mml:mi></mml:math></inline-formula> [<inline-formula><mml:math id="M12" display="inline"><mml:mrow><mml:mi>B</mml:mi><mml:mo>(</mml:mo><mml:mi>x</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>], the fraction of biomass that is burned (FB), and an emissions factor (EF<inline-formula><mml:math id="M13" display="inline"><mml:msub><mml:mi/><mml:mi>i</mml:mi></mml:msub></mml:math></inline-formula>; mass of pollutant <inline-formula><mml:math id="M14" display="inline"><mml:mi>i</mml:mi></mml:math></inline-formula> per biomass burned).</p>
      <p id="d1e433">The FINNv2.5 model framework has the following three components: (1) burned area and land cover determination (Sect. 2.1–2.3), (2) fuel consumption and emissions calculation (Sect. 2.4), and (3) speciation of the non-methane organic gases (NMOGs; Sect. 2.5).</p>
<?pagebreak page3875?><sec id="Ch1.S2.SS1">
  <label>2.1</label><title>Fire location and timing</title>
      <p id="d1e443">FINNv2.5 first determines the burned area from daily satellite detections of
active fires. FINNv2.5 uses MODIS detections (nominal 1 km<inline-formula><mml:math id="M15" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula> resolution; Giglio et al., 2006), as in FINNv1, and adds the option to use active fire
detections at 375 m resolution from the Visible Infrared Imaging Radiometer
Suite (VIIRS; Csiszar et al., 2014), on board the Suomi National
Polar-orbiting Partnership (Suomi-NPP) satellite, alone or in combination
with MODIS active fire data. The use of VIIRS 375 m detections is a major
advancement from the use of MODIS-only fire detections, as this product
better captures small fires. VIIRS detections are available from 2012 to the
current year.</p>
      <p id="d1e455">The MODIS Collection 6 (MCD14DL) and VIIRS active fire products are obtained
from NASA's Fire Information for Resource Management System (FIRMS) data
portal (<uri>https://firms.modaps.eosdis.nasa.gov/download/</uri>, last access: 19 June 2022). The MODIS product provides the location, overpass time (Coordinated Universal Time, UTC), and confidence of daily fire detections. Data confidence in the MODIS product is specified by a numerical scale of 0 % to 100 %. Detections with a confidence
specification of less than 20 % are eliminated from our calculation in
FINNv2.5, as was done in earlier FINN versions. Daily global coverage is not
accomplished at latitudes between approximately 23.5<inline-formula><mml:math id="M16" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N and
23.5<inline-formula><mml:math id="M17" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> S, due to the observational swath width. To account for the
lack of daily observations, fire detections in these equatorial regions only
are counted for a 2 d period; each fire is assumed to continue into the
next day. Regardless of whether the detection is from MODIS or VIIRS, the
intent is to repeat the fire at the same location, since there is not a clear
alternative at this time in these global regions, as described by Wiedinmyer
et al. (2011).</p>
      <p id="d1e479">With its improved spatial resolution of 375 m, the VIIRS product provides a
more sensitive detection of the fires of relatively small areas, fully global
coverage, improved mapping of large fire perimeters, and improved nighttime
performance relative to MODIS fire detections (Schroeder et al., 2014). The
higher detection rates of small fires can be particularly important for
areas of the world such as southeast Asia, where burning of agriculture is
common, and in the southeastern USA, where there is a large amount of managed
burning. Detection confidence is provided by the VIIRS product and is
specified by three categories, namely low, nominal, and high. In the FINNv2.5
preprocessor, detections with a confidence specification identified as
low are eliminated from the analysis. We only include data attributed to
thermal anomalies from vegetation fires (type <inline-formula><mml:math id="M18" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0; i.e., other thermal
anomaly types associated with active volcanos or other static land sources
are filtered from the product).</p>
      <p id="d1e489">The processing of the two simultaneous fire products in FINNv2.5 does not
lead to double-counting of the fires; the FINNv2.5 method determines the spatial union of all adjacent detections for a given day as the daily burned area of a fire, as described below in Sect. 2.2. The identity of the sensor is not relevant for the determination of the burned area, as long as the pixel size for each detection is correctly represented (i.e., 0.14 km<inline-formula><mml:math id="M19" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula> for VIIRS and 1 km<inline-formula><mml:math id="M20" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula> for MODIS). FINNv2.5 and earlier versions do not account for the effects of burning from earlier days for fire detections at the same location; i.e., the fraction burned is consistent with unperturbed
vegetation on the first day, regardless of the persistence of fire activity,
and emissions scale directly with the detection of a thermal anomaly in the
same location over multiple days.</p>
      <p id="d1e511">The active fire products report the time of acquisition in Coordinated
Universal Time (UTC). In contrast to previous versions of the model, the
FINNv2.5 preprocessor uses local time in the specification of the date of a
fire detection in order to facilitate comparisons of emissions estimates
with observational data.
            <disp-formula id="Ch1.E2" content-type="numbered"><label>2</label><mml:math id="M21" display="block"><mml:mrow><mml:mtext>Local time</mml:mtext><mml:mo>=</mml:mo><mml:mtext>UTC</mml:mtext><mml:mo>+</mml:mo><mml:mtext>Nearest_Integer</mml:mtext><mml:mo>(</mml:mo><mml:mtext>Longitude</mml:mtext><mml:mo>/</mml:mo><mml:mn mathvariant="normal">15</mml:mn><mml:mo>)</mml:mo></mml:mrow></mml:math></disp-formula></p>
</sec>
<sec id="Ch1.S2.SS2">
  <label>2.2</label><title>Burned area</title>
      <p id="d1e547">FINNv1 estimates burned area for each fire pixel identified individually,
and the nominal pixel size for the MODIS fire detections, 1 km<inline-formula><mml:math id="M22" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula>, is
assumed per detection. Spatially overlapping detections are eliminated from
further analysis. It was recognized that for large fires in forested regions, an array of multiple discrete detections is typically reported, and an estimate of a contiguous area that represents the total area burned by a
fire is needed. We improved the burned area estimate in FINNv2 to better
represent the area associated with each fire.</p>
      <p id="d1e559">A fire event in the western USA is shown in Fig. 1a to illustrate the new approach for estimating the area burned. For FINNv2.5, each reported active fire detection (Fig. 1b) is assigned a square area of 0.14 km<inline-formula><mml:math id="M23" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula> from VIIRS or 1 km<inline-formula><mml:math id="M24" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula> from MODIS (Fig. 1c), based on the nominal horizontal resolution of the data (denoted as the instrument resolution square). Detections determined to be in proximity with one another are aggregated by two different approaches, depending on the land cover type and forest cover. Initially, it is assumed that multiple detections by adjacent pixels in a satellite sensor array are part of a larger fire, and these detections are merged. The scan and track sizes of the satellite pixel are provided by the fire detection product and define the actual resolution of the fire detection. The scan and track sizes for each fire detection are used for identifying groups of records that represent contiguous or overlapping detections. A rectangle with easterly and northerly sizes equal to 110 % of the scan and track sizes is established for each detection (denoted as the detection rectangle; Fig. 1d), with the objective of identifying adjacent neighboring detections but not for direct application to the burned area estimation. Fire detections are identified as being from one larger fire when any of the satellite detection rectangles overlap. To minimize an overestimation of<?pagebreak page3876?> the burned area, a convex hull is generated between corresponding pairs of detection rectangles that directly intersect. The union of pairwise convex hulls from a cluster forms an extended fire
polygon that represents the tentative estimated burned area for a single
fire event or group of nearby fires for the day (Fig. 1d). This approach
effectively fills any gap between instrument resolution squares.</p>
      <p id="d1e580">For each of the extended polygons, the MOD44B v006 MODIS/Terra VCF annual
product (<uri>https://lpdaac.usgs.gov/products/mod44bv006/</uri>, last access: 13 July 2022) is overlaid (Sect. 2.3), and the average tree cover fraction is determined (Fig. 1e). For forested areas with tree cover <inline-formula><mml:math id="M25" display="inline"><mml:mrow><mml:mo>≥</mml:mo><mml:mn mathvariant="normal">50</mml:mn></mml:mrow></mml:math></inline-formula> %, as determined by the VCF product, the merged polygons are accepted as the final burned area estimate. Otherwise, the merging is not used, and instead, an alternative, more conservative, approach is applied to determine the burned area for the region. This alternative approach is used to prevent overestimation of emissions in regions with many small fires, as in the savanna fires in sub-Saharan Africa. The alternative polygon aggregation is achieved by aggregating nearby detections only when the instrument pixels themselves are intersecting (Fig. 1c) and therefore not with the extended detection footprints (Fig. 1d). The result is an aggregation algorithm that is repeated with a smaller set of detections to determine the alternative conservative set of polygons (denoted as the conservative fire polygon). The final burned area polygons in Fig. 1f show examples of a composite of polygons based on these two different aggregation approaches. Note that at the bottom of Fig. 1f there is a region with less than 50 % tree cover that has a smaller final burned area polygon estimate than the extended polygon (blue). In contrast, the polygon in the center of Fig. 1f, which is a forested area with more than 50 % tree cover, uses the extended polygon determined in Fig. 1d (further information about this aggregation is given in Sect. S1 in the Supplement).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F1" specific-use="star"><?xmltex \currentcnt{1}?><?xmltex \def\figurename{Figure}?><label>Figure 1</label><caption><p id="d1e599">Illustration of the burned area determination used in the FINNv2.5
preprocessor for 11 August 2018 when both MODIS and VIIRS fire detections
are applied. <bold>(a)</bold> Example fire location, <bold>(b)</bold> active fire detections, <bold>(c)</bold> burned area per detection based on instrument resolution, <bold>(d)</bold> detection clusters joined for the determination of the extended burned area, <bold>(e)</bold> determination of the average percent of tree cover (labeled as VCF) for merged polygons, and <bold>(f)</bold> final burned area polygons reflecting either extended or conservative polygons based on the percent of tree cover.</p></caption>
          <?xmltex \igopts{width=483.69685pt}?><graphic xlink:href="https://gmd.copernicus.org/articles/16/3873/2023/gmd-16-3873-2023-f01.png"/>

        </fig>

      <p id="d1e627">Subsequently, the final burned area polygons are subdivided using a Voronoi
tessellation algorithm in order to develop emissions estimates by land cover
classification, as described in Sect. 2.3 and 2.4. Each of the undivided final burned area polygons are assigned a unique fire ID to enable users to group emissions estimates from a presumed single fire event.</p>
</sec>
<sec id="Ch1.S2.SS3">
  <label>2.3</label><title>Fuel loading and vegetation inputs</title>
      <p id="d1e639">The NASA MODIS VCF product provides estimates of the percentage of bare
surface, herbaceous, and forested cover at a horizontal resolution of 250 m
(Fig. S1). For each fire area, the subdivided polygons described in Sect. 2.2 (Fig. 1g) are overlaid on the vegetation cover data from the MOD44B v006 MODIS/Terra VCF annual product  (<uri>https://lpdaac.usgs.gov/products/mod44bv006/</uri>, last access: 13 July 2022; Fig. 1e). The VCF data for the prior year are chosen, so that the VCF before any land cover changes
due to fire are used in the emissions estimation process. The VCF raster is
clipped to the geometry of the fire polygon, and the averages of the VCF
tree, herbaceous, and bare cover are calculated for each fire polygon.</p>
      <p id="d1e645">FINNv2.5 uses the Terra and Aqua combined MODIS LCT MCD12Q1 Version 6 data
product with the International Geosphere–Biosphere Programme (IGBP) classification scheme (<uri>https://lpdaac.usgs.gov/products/mcd12q1v006/</uri>, last access: 13 July 2022) as its default land cover information. Figure 2 shows the global distribution of land cover applied as the default in FINNv2.5. Each subdivided polygon (for example, in Fig. 3) is assigned the factional coverage of 1 of 16 land cover  classifications (Table 1). Similar to the application of the VCF information, land use data from the previous year are used.</p>
      <p id="d1e651">Use of the LCT and VCF products in FINNv2.5 is an improvement on FINNv1. FINNv1 used one static map of LCT and VCF (from 2002) for any year processed. FINNv2.5 employs year-specific MODIS LCT and VCF maps that change annually. Furthermore, the specific vegetation assignments for each subdivided polygon enable different vegetation types and coverage to be represented across larger fires. These input data and processes enable better representation of the vegetation that is burned.</p>
      <p id="d1e654">All fire polygons are assigned to 1 of 13 global regions (Wiedinmyer et
al., 2011) used to assign fuel loadings (Sect. 2.4). This completes the first component of the FINNv2.5 modeling framework and results in a file of daily burned areas and associated land cover information.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F2" specific-use="star"><?xmltex \currentcnt{2}?><?xmltex \def\figurename{Figure}?><label>Figure 2</label><caption><p id="d1e660">MCD12Q1 Version 6 data product with the International Geosphere–Biosphere Programme (IGBP) classification scheme.</p></caption>
          <?xmltex \igopts{width=483.69685pt}?><graphic xlink:href="https://gmd.copernicus.org/articles/16/3873/2023/gmd-16-3873-2023-f02.png"/>

        </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F3" specific-use="star"><?xmltex \currentcnt{3}?><?xmltex \def\figurename{Figure}?><label>Figure 3</label><caption><p id="d1e671">Illustration of the burned area determination used in the FINNv2.5
preprocessor for 11 August 2018 (continued from Fig. 1), showing the subdivision of the burned area polygons to develop emissions estimates by the MODIS IGBP land cover classification.</p></caption>
          <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://gmd.copernicus.org/articles/16/3873/2023/gmd-16-3873-2023-f03.png"/>

        </fig>

</sec>
<sec id="Ch1.S2.SS4">
  <label>2.4</label><title>Emissions calculation</title>
      <p id="d1e688">The next step of the model framework is the emissions calculation. In this
step, the daily burned area and associated vegetation information (described
above) are assigned associated fuel loadings. Using the same process described by Wiedinmyer et al. (2011), where the biomass burned is assigned
based on land cover type and global region (B), the fraction of the biomass
that is burned (FB) is assigned as a function of tree and herbaceous cover,
emissions factors (EFs) are determined based on land cover, and daily
pollutant emissions estimates are calculated following Eq. (1). Overall,
the emissions calculation process follows this framework, as described by
Wiedinmyer et al. (2011), with the following exceptions.</p>
      <p id="d1e691">Similar to earlier FINN versions (Wiedinmyer et al., 2011), the 16 IGBP land
cover classifications of the LCT product are mapped to consolidated
vegetation types, depending on the land cover class and latitude that
distinguish tropical, temperate, and boreal forests (Table 1). The consolidated vegetation types used in FINNv2.5 are grassland and savanna,
woody savanna or shrubs, tropical forest, temperate forest, boreal forest,
temperate evergreen forest, and crops.</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T1" specific-use="star"><?xmltex \currentcnt{1}?><label>Table 1</label><caption><p id="d1e697">LCT IGBP and generic vegetation type descriptions.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="4">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="right"/>
     <oasis:colspec colnum="3" colname="col3" align="justify" colwidth="6cm"/>
     <oasis:colspec colnum="4" colname="col4" align="right"/>
     <oasis:thead>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">IGBP LCT description</oasis:entry>
         <oasis:entry colname="col2">LCT value</oasis:entry>
         <oasis:entry colname="col3">Generic vegetation type</oasis:entry>
         <oasis:entry colname="col4">Generic vegetation value</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">Evergreen needleleaf forests</oasis:entry>
         <oasis:entry colname="col2">1</oasis:entry>
         <oasis:entry colname="col3">If latitude <inline-formula><mml:math id="M30" display="inline"><mml:mrow><mml:mo>&gt;</mml:mo><mml:mn mathvariant="normal">50</mml:mn></mml:mrow></mml:math></inline-formula>, then boreal forest; otherwise, temperate evergreen forest</oasis:entry>
         <oasis:entry colname="col4">5,6</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">Evergreen broadleaf forests</oasis:entry>
         <oasis:entry colname="col2">2</oasis:entry>
         <oasis:entry colname="col3">If latitude <inline-formula><mml:math id="M31" display="inline"><mml:mrow><mml:mo>&gt;</mml:mo><mml:mo>-</mml:mo><mml:mn mathvariant="normal">23.5</mml:mn></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M32" display="inline"><mml:mrow><mml:mo>&lt;</mml:mo><mml:mn mathvariant="normal">23.5</mml:mn></mml:mrow></mml:math></inline-formula>, then tropical forest; otherwise, temperate forest</oasis:entry>
         <oasis:entry colname="col4">3, 4</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">Deciduous needleleaf forests</oasis:entry>
         <oasis:entry colname="col2">3</oasis:entry>
         <oasis:entry colname="col3">If latitude <inline-formula><mml:math id="M33" display="inline"><mml:mrow><mml:mo>&gt;</mml:mo><mml:mn mathvariant="normal">50</mml:mn></mml:mrow></mml:math></inline-formula>, then boreal forest; otherwise, temperate forest</oasis:entry>
         <oasis:entry colname="col4">5,4</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">Deciduous broadleaf forests</oasis:entry>
         <oasis:entry colname="col2">4</oasis:entry>
         <oasis:entry colname="col3">Temperate forest</oasis:entry>
         <oasis:entry colname="col4">4</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">Mixed forests</oasis:entry>
         <oasis:entry colname="col2">5</oasis:entry>
         <oasis:entry colname="col3">If latitude <inline-formula><mml:math id="M34" display="inline"><mml:mrow><mml:mo>&gt;</mml:mo><mml:mn mathvariant="normal">5</mml:mn></mml:mrow></mml:math></inline-formula>, then boreal forest; if latitude <inline-formula><mml:math id="M35" display="inline"><mml:mrow><mml:mo>&gt;</mml:mo><mml:mo>-</mml:mo><mml:mn mathvariant="normal">23.5</mml:mn></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M36" display="inline"><mml:mrow><mml:mo>&lt;</mml:mo><mml:mn mathvariant="normal">23.5</mml:mn></mml:mrow></mml:math></inline-formula>, then tropical forest; otherwise, temperate forest</oasis:entry>
         <oasis:entry colname="col4">5, 3, 4</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">Closed shrublands</oasis:entry>
         <oasis:entry colname="col2">6</oasis:entry>
         <oasis:entry colname="col3">Woody savanna or shrubs</oasis:entry>
         <oasis:entry colname="col4">2</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">Open shrublands</oasis:entry>
         <oasis:entry colname="col2">7</oasis:entry>
         <oasis:entry colname="col3">Woody savanna or shrubs</oasis:entry>
         <oasis:entry colname="col4">2</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">Woody savannas</oasis:entry>
         <oasis:entry colname="col2">8</oasis:entry>
         <oasis:entry colname="col3">Woody savanna or shrubs</oasis:entry>
         <oasis:entry colname="col4">2</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">Savannas</oasis:entry>
         <oasis:entry colname="col2">9</oasis:entry>
         <oasis:entry colname="col3">Grassland and savanna</oasis:entry>
         <oasis:entry colname="col4">1</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">Grasslands</oasis:entry>
         <oasis:entry colname="col2">10</oasis:entry>
         <oasis:entry colname="col3">Grassland and savanna</oasis:entry>
         <oasis:entry colname="col4">1</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">Permanent wetlands</oasis:entry>
         <oasis:entry colname="col2">11</oasis:entry>
         <oasis:entry colname="col3">Grassland and savanna</oasis:entry>
         <oasis:entry colname="col4">1</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">Croplands</oasis:entry>
         <oasis:entry colname="col2">12</oasis:entry>
         <oasis:entry colname="col3">Croplands</oasis:entry>
         <oasis:entry colname="col4">9</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">Urban and built-up lands</oasis:entry>
         <oasis:entry colname="col2">13</oasis:entry>
         <oasis:entry colname="col3">If tree cover <inline-formula><mml:math id="M37" display="inline"><mml:mrow><mml:mo>&lt;</mml:mo><mml:mn mathvariant="normal">40</mml:mn></mml:mrow></mml:math></inline-formula>, then reassign to 10; if tree cover <inline-formula><mml:math id="M38" display="inline"><mml:mrow><mml:mo>&gt;</mml:mo><mml:mn mathvariant="normal">40</mml:mn></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M39" display="inline"><mml:mrow><mml:mo>&lt;</mml:mo><mml:mn mathvariant="normal">60</mml:mn></mml:mrow></mml:math></inline-formula>, then reassign to 8; if tree <inline-formula><mml:math id="M40" display="inline"><mml:mrow><mml:mo>&gt;</mml:mo><mml:mn mathvariant="normal">60</mml:mn></mml:mrow></mml:math></inline-formula>, then assign based on latitude</oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M41" display="inline"><mml:msup><mml:mi/><mml:mo>*</mml:mo></mml:msup></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">Cropland/natural vegetation mosaics</oasis:entry>
         <oasis:entry colname="col2">14</oasis:entry>
         <oasis:entry colname="col3">Grassland and savanna</oasis:entry>
         <oasis:entry colname="col4">1</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">Permanent snow and ice</oasis:entry>
         <oasis:entry colname="col2">15</oasis:entry>
         <oasis:entry colname="col3">Remove</oasis:entry>
         <oasis:entry colname="col4"/>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">Barren</oasis:entry>
         <oasis:entry colname="col2">16</oasis:entry>
         <oasis:entry colname="col3">Grassland and savanna</oasis:entry>
         <oasis:entry colname="col4">1</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">Waterbodies</oasis:entry>
         <oasis:entry colname="col2">17</oasis:entry>
         <oasis:entry colname="col3">Remove</oasis:entry>
         <oasis:entry colname="col4"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Unclassified</oasis:entry>
         <oasis:entry colname="col2">255</oasis:entry>
         <oasis:entry colname="col3">Remove</oasis:entry>
         <oasis:entry colname="col4"/>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table><table-wrap-foot><p id="d1e700"><inline-formula><mml:math id="M26" display="inline"><mml:msup><mml:mi/><mml:mo>*</mml:mo></mml:msup></mml:math></inline-formula> If latitude <inline-formula><mml:math id="M27" display="inline"><mml:mrow><mml:mo>&gt;</mml:mo><mml:mn mathvariant="normal">50</mml:mn></mml:mrow></mml:math></inline-formula>, then boreal forest; if latitude <inline-formula><mml:math id="M28" display="inline"><mml:mrow><mml:mo>&gt;</mml:mo><mml:mo>-</mml:mo><mml:mn mathvariant="normal">30</mml:mn></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M29" display="inline"><mml:mrow><mml:mo>&lt;</mml:mo><mml:mn mathvariant="normal">30</mml:mn></mml:mrow></mml:math></inline-formula>, then tropical forest; otherwise, temperate forest.</p></table-wrap-foot><?xmltex \gdef\@currentlabel{1}?></table-wrap>

      <p id="d1e1170">The fuel loading, or the potential maximum amount of biomass available to be
burned (<inline-formula><mml:math id="M42" display="inline"><mml:mrow><mml:mi>B</mml:mi><mml:mo>(</mml:mo><mml:mi>x</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> in Eq. 1), is assigned by generic vegetation type and global region (Table 2). Selected<?pagebreak page3877?> values were updated for FINNv2.5 from earlier versions of FINN, based on van Leeuwen et al. (2014). The fuel loading for crops was updated to 902 g m<inline-formula><mml:math id="M43" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>, based on an average from the literature (Akagi et al., 2011; van Leeuwen et al., 2014; Pouliot et al., 2017). Specific crop types are not identified in the version described here.</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T2" specific-use="star"><?xmltex \currentcnt{2}?><label>Table 2</label><caption><p id="d1e1202">Fuel loadings (g m<inline-formula><mml:math id="M44" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>) assigned by generic land cover type and
global region. These values are as described by Wiedinmyer et al. (2011),
unless noted otherwise. Values in bold indicate those updated for FINNv2.5,
based on van Leeuwen et al. (2014).</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="6">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="right"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:colspec colnum="4" colname="col4" align="right"/>
     <oasis:colspec colnum="5" colname="col5" align="right"/>
     <oasis:colspec colnum="6" colname="col6" align="right"/>
     <oasis:thead>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">Global region</oasis:entry>
         <oasis:entry colname="col2">Tropical forest</oasis:entry>
         <oasis:entry colname="col3">Temperate forest</oasis:entry>
         <oasis:entry colname="col4">Boreal forest</oasis:entry>
         <oasis:entry colname="col5">Woody savanna/shrublands</oasis:entry>
         <oasis:entry colname="col6">Savanna and grasslands<inline-formula><mml:math id="M50" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">e</mml:mi></mml:msup></mml:math></inline-formula></oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
         <oasis:entry colname="col1">North America</oasis:entry>
         <oasis:entry colname="col2">28 076<inline-formula><mml:math id="M51" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">a</mml:mi></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><bold>10 661</bold><inline-formula><mml:math id="M52" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">c</mml:mi></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4"><bold>17 875</bold><inline-formula><mml:math id="M53" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">c</mml:mi></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col5">4762</oasis:entry>
         <oasis:entry colname="col6">976</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Central America</oasis:entry>
         <oasis:entry colname="col2"><bold>26 500</bold><inline-formula><mml:math id="M54" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">c</mml:mi></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">11 000</oasis:entry>
         <oasis:entry colname="col4"/>
         <oasis:entry colname="col5">2224</oasis:entry>
         <oasis:entry colname="col6">418</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">South America</oasis:entry>
         <oasis:entry colname="col2"><bold>26 755</bold><inline-formula><mml:math id="M55" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">c</mml:mi></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">7400</oasis:entry>
         <oasis:entry colname="col4"/>
         <oasis:entry colname="col5">3077</oasis:entry>
         <oasis:entry colname="col6"><bold>624</bold><inline-formula><mml:math id="M56" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">c</mml:mi></mml:msup></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Northern Africa</oasis:entry>
         <oasis:entry colname="col2">25 366</oasis:entry>
         <oasis:entry colname="col3">3497</oasis:entry>
         <oasis:entry colname="col4"/>
         <oasis:entry colname="col5">2501</oasis:entry>
         <oasis:entry colname="col6"><bold>382</bold><inline-formula><mml:math id="M57" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">c</mml:mi></mml:msup></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Southern Africa</oasis:entry>
         <oasis:entry colname="col2">25 295</oasis:entry>
         <oasis:entry colname="col3">6100</oasis:entry>
         <oasis:entry colname="col4"/>
         <oasis:entry colname="col5">2483</oasis:entry>
         <oasis:entry colname="col6"><bold>411</bold><inline-formula><mml:math id="M58" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">c</mml:mi></mml:msup></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Western Europe</oasis:entry>
         <oasis:entry colname="col2">28 076<inline-formula><mml:math id="M59" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">a</mml:mi></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">7120</oasis:entry>
         <oasis:entry colname="col4">6228</oasis:entry>
         <oasis:entry colname="col5">4523</oasis:entry>
         <oasis:entry colname="col6">1321</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Eastern Europe</oasis:entry>
         <oasis:entry colname="col2">28 076<inline-formula><mml:math id="M60" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">a</mml:mi></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">11 386</oasis:entry>
         <oasis:entry colname="col4">8146</oasis:entry>
         <oasis:entry colname="col5">7752</oasis:entry>
         <oasis:entry colname="col6">1612</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">North central Asia</oasis:entry>
         <oasis:entry colname="col2">6181<inline-formula><mml:math id="M61" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">b</mml:mi></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">20 807</oasis:entry>
         <oasis:entry colname="col4"><bold>14 925</bold><inline-formula><mml:math id="M62" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">c</mml:mi></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col5">11 009</oasis:entry>
         <oasis:entry colname="col6">2170</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Near East</oasis:entry>
         <oasis:entry colname="col2">6181<inline-formula><mml:math id="M63" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">b</mml:mi></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">10 316</oasis:entry>
         <oasis:entry colname="col4"/>
         <oasis:entry colname="col5">2946</oasis:entry>
         <oasis:entry colname="col6">655</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">East Asia</oasis:entry>
         <oasis:entry colname="col2"><bold>14 941</bold><inline-formula><mml:math id="M64" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">c</mml:mi></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">7865</oasis:entry>
         <oasis:entry colname="col4"/>
         <oasis:entry colname="col5">4292</oasis:entry>
         <oasis:entry colname="col6">722</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Southern Asia</oasis:entry>
         <oasis:entry colname="col2"><bold>26 546</bold><inline-formula><mml:math id="M65" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">c</mml:mi></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">14 629</oasis:entry>
         <oasis:entry colname="col4"/>
         <oasis:entry colname="col5">5028</oasis:entry>
         <oasis:entry colname="col6">1445</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Oceania</oasis:entry>
         <oasis:entry colname="col2">16 376</oasis:entry>
         <oasis:entry colname="col3"><bold>13 535</bold><inline-formula><mml:math id="M66" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">c</mml:mi></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4"/>
         <oasis:entry colname="col5"><bold>2483</bold><inline-formula><mml:math id="M67" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">d</mml:mi></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col6"><bold>552</bold><inline-formula><mml:math id="M68" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">c</mml:mi></mml:msup></mml:math></inline-formula></oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table><table-wrap-foot><p id="d1e1217"><inline-formula><mml:math id="M45" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">a</mml:mi></mml:msup></mml:math></inline-formula> Tropical forest class added for North America and Europe (in LCT). <inline-formula><mml:math id="M46" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">b</mml:mi></mml:msup></mml:math></inline-formula> All of Asia is assigned equal tropical forest values. <inline-formula><mml:math id="M47" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">c</mml:mi></mml:msup></mml:math></inline-formula> Taken from van Leeuwen et al. (2014). <inline-formula><mml:math id="M48" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">d</mml:mi></mml:msup></mml:math></inline-formula> Taken as the same for African woody savanna from van Leeuwen
et al. (2014). <inline-formula><mml:math id="M49" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">e</mml:mi></mml:msup></mml:math></inline-formula> Croplands are assigned the same fuel loading as grasslands.</p></table-wrap-foot><?xmltex \gdef\@currentlabel{2}?></table-wrap>

      <p id="d1e1733">For North America, FINNv2.5 utilizes the fuel loadings for coarse/woody and
herbaceous vegetation by land cover type derived from the Fuel Characteristic Classification System (FCCS) of the U.S. Department of Agriculture Forest Service (<uri>https://www.landfire.gov/fccs.php</uri>, last access: 23 December 2018), as described by McDonald-Buller et al. (2015). These fuel loadings (Table 3) have priority over the regional default fuel loadings (Table 2).</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T3"><?xmltex \currentcnt{3}?><label>Table 3</label><caption><p id="d1e1742">North American fuel loadings (g m<inline-formula><mml:math id="M69" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>) by land cover type for
coarse/woody and herbaceous vegetation. These values are based on the Fuel
Characteristic Classification System  (FCCS; <uri>https://www.landfire.gov/fccs.php</uri>, last access: 23 December 2018), with the exception of
croplands<inline-formula><mml:math id="M70" display="inline"><mml:msup><mml:mi/><mml:mo>∗</mml:mo></mml:msup></mml:math></inline-formula>.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="3">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="right"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:thead>
       <oasis:row>
         <oasis:entry colname="col1">Land cover type</oasis:entry>
         <oasis:entry namest="col2" nameend="col3" align="center">Fuel loading </oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry rowsep="1" namest="col2" nameend="col3" align="center">(g m<inline-formula><mml:math id="M72" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>) </oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">Coarse/woody</oasis:entry>
         <oasis:entry colname="col3">Herbaceous</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
         <oasis:entry colname="col1">Water</oasis:entry>
         <oasis:entry colname="col2">0</oasis:entry>
         <oasis:entry colname="col3">0</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Evergreen needleleaf forest</oasis:entry>
         <oasis:entry colname="col2">28 930</oasis:entry>
         <oasis:entry colname="col3">437</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Evergreen broadleaf forest</oasis:entry>
         <oasis:entry colname="col2">19 917</oasis:entry>
         <oasis:entry colname="col3">650</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Deciduous needleleaf forest</oasis:entry>
         <oasis:entry colname="col2">15 653</oasis:entry>
         <oasis:entry colname="col3">541</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Deciduous broadleaf forest</oasis:entry>
         <oasis:entry colname="col2">19 982</oasis:entry>
         <oasis:entry colname="col3">964</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Mixed forests</oasis:entry>
         <oasis:entry colname="col2">20 339</oasis:entry>
         <oasis:entry colname="col3">766</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Closed shrublands</oasis:entry>
         <oasis:entry colname="col2">5136</oasis:entry>
         <oasis:entry colname="col3">229</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Open shrublands</oasis:entry>
         <oasis:entry colname="col2">2889</oasis:entry>
         <oasis:entry colname="col3">169</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Woody savannas</oasis:entry>
         <oasis:entry colname="col2">12 907</oasis:entry>
         <oasis:entry colname="col3">668</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Savannas</oasis:entry>
         <oasis:entry colname="col2">10 907</oasis:entry>
         <oasis:entry colname="col3">764</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Grasslands</oasis:entry>
         <oasis:entry colname="col2">2822</oasis:entry>
         <oasis:entry colname="col3">407</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Permanent wetlands</oasis:entry>
         <oasis:entry colname="col2">8509</oasis:entry>
         <oasis:entry colname="col3">712</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Croplands</oasis:entry>
         <oasis:entry colname="col2">0</oasis:entry>
         <oasis:entry colname="col3">902<inline-formula><mml:math id="M73" display="inline"><mml:msup><mml:mi/><mml:mo>∗</mml:mo></mml:msup></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Urban and built-up areas</oasis:entry>
         <oasis:entry colname="col2">0</oasis:entry>
         <oasis:entry colname="col3">0</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Cropland/natural vegetation</oasis:entry>
         <oasis:entry colname="col2">9080</oasis:entry>
         <oasis:entry colname="col3">822</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Snow and ice</oasis:entry>
         <oasis:entry colname="col2">0</oasis:entry>
         <oasis:entry colname="col3">0</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Barren or sparsely vegetated</oasis:entry>
         <oasis:entry colname="col2">1355</oasis:entry>
         <oasis:entry colname="col3">104</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table><table-wrap-foot><p id="d1e1769"><inline-formula><mml:math id="M71" display="inline"><mml:msup><mml:mi/><mml:mo>∗</mml:mo></mml:msup></mml:math></inline-formula> Taken as an average from van Leeuwen et al. (2014), Akagi et al. (2011), and McCarty et al. (2012).</p></table-wrap-foot><?xmltex \gdef\@currentlabel{3}?></table-wrap>

      <p id="d1e2051">Emissions factors are assigned based on the generic vegetation type. Since
the original release of FINNv1 in 2011, there have been many studies to
measure emissions factors from wildland fires. We have updated the emissions
factors<?pagebreak page3878?> from FINNv1.5 with the results from recent publications (Table 4).</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T4" specific-use="star"><?xmltex \currentcnt{4}?><label>Table 4</label><caption><p id="d1e2058">Emissions factors (g kg<inline-formula><mml:math id="M74" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>) for FINNv2.5.</p></caption><oasis:table frame="topbot"><?xmltex \begin{scaleboxenv}{.90}[.90]?><oasis:tgroup cols="8">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="right"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:colspec colnum="4" colname="col4" align="right"/>
     <oasis:colspec colnum="5" colname="col5" align="right"/>
     <oasis:colspec colnum="6" colname="col6" align="right"/>
     <oasis:colspec colnum="7" colname="col7" align="right"/>
     <oasis:colspec colnum="8" colname="col8" align="right"/>
     <oasis:thead>
       <oasis:row>
         <oasis:entry colname="col1">Chemical species</oasis:entry>
         <oasis:entry rowsep="1" namest="col2" nameend="col8" align="center">Generic vegetation index and type </oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry rowsep="1" colname="col2">1</oasis:entry>
         <oasis:entry rowsep="1" colname="col3">2</oasis:entry>
         <oasis:entry rowsep="1" colname="col4">3</oasis:entry>
         <oasis:entry rowsep="1" colname="col5">4</oasis:entry>
         <oasis:entry rowsep="1" colname="col6">5</oasis:entry>
         <oasis:entry rowsep="1" colname="col7">6</oasis:entry>
         <oasis:entry rowsep="1" colname="col8">9</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">Savanna</oasis:entry>
         <oasis:entry colname="col3">Woody</oasis:entry>
         <oasis:entry colname="col4">Tropical</oasis:entry>
         <oasis:entry colname="col5">Temperate</oasis:entry>
         <oasis:entry colname="col6">Boreal<inline-formula><mml:math id="M80" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">c</mml:mi></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col7">Temperate</oasis:entry>
         <oasis:entry colname="col8">Crops<inline-formula><mml:math id="M81" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">d</mml:mi></mml:msup></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">grasslands<inline-formula><mml:math id="M82" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">a</mml:mi></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">savanna/</oasis:entry>
         <oasis:entry colname="col4">forest</oasis:entry>
         <oasis:entry colname="col5">forest<inline-formula><mml:math id="M83" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">b</mml:mi></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col6"/>
         <oasis:entry colname="col7">evergreen</oasis:entry>
         <oasis:entry colname="col8"/>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2"/>
         <oasis:entry colname="col3">shrubs</oasis:entry>
         <oasis:entry colname="col4"/>
         <oasis:entry colname="col5"/>
         <oasis:entry colname="col6"/>
         <oasis:entry colname="col7">forest<inline-formula><mml:math id="M84" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">b</mml:mi></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col8"/>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
         <oasis:entry colname="col1">Carbon dioxide (CO<inline-formula><mml:math id="M85" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col2">1686</oasis:entry>
         <oasis:entry colname="col3">1681</oasis:entry>
         <oasis:entry colname="col4">1643</oasis:entry>
         <oasis:entry colname="col5">1510</oasis:entry>
         <oasis:entry colname="col6">1565</oasis:entry>
         <oasis:entry colname="col7">1623</oasis:entry>
         <oasis:entry colname="col8">1444</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Carbon monoxide (CO)</oasis:entry>
         <oasis:entry colname="col2">63</oasis:entry>
         <oasis:entry colname="col3">67</oasis:entry>
         <oasis:entry colname="col4">93</oasis:entry>
         <oasis:entry colname="col5">122</oasis:entry>
         <oasis:entry colname="col6">111</oasis:entry>
         <oasis:entry colname="col7">112</oasis:entry>
         <oasis:entry colname="col8">91</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Methane (CH<inline-formula><mml:math id="M86" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">4</mml:mn></mml:msub></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col2">2</oasis:entry>
         <oasis:entry colname="col3">3</oasis:entry>
         <oasis:entry colname="col4">5.1</oasis:entry>
         <oasis:entry colname="col5">5.61</oasis:entry>
         <oasis:entry colname="col6">6</oasis:entry>
         <oasis:entry colname="col7">3.4</oasis:entry>
         <oasis:entry colname="col8">5.82</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Non-methane organic gases (NMOGs)<inline-formula><mml:math id="M87" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">e</mml:mi></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">28.2</oasis:entry>
         <oasis:entry colname="col3">24.8</oasis:entry>
         <oasis:entry colname="col4">51.9</oasis:entry>
         <oasis:entry colname="col5">56</oasis:entry>
         <oasis:entry colname="col6">48.5</oasis:entry>
         <oasis:entry colname="col7">49.3</oasis:entry>
         <oasis:entry colname="col8">51.4</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Hydrogen (H<inline-formula><mml:math id="M88" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col2">1.7</oasis:entry>
         <oasis:entry colname="col3">0.97</oasis:entry>
         <oasis:entry colname="col4">3.4</oasis:entry>
         <oasis:entry colname="col5">2.03</oasis:entry>
         <oasis:entry colname="col6">2.3</oasis:entry>
         <oasis:entry colname="col7">2</oasis:entry>
         <oasis:entry colname="col8">2.59</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Nitrogen oxides (NO<inline-formula><mml:math id="M89" display="inline"><mml:msub><mml:mi/><mml:mi>x</mml:mi></mml:msub></mml:math></inline-formula> as NO)</oasis:entry>
         <oasis:entry colname="col2">3.9</oasis:entry>
         <oasis:entry colname="col3">3.65</oasis:entry>
         <oasis:entry colname="col4">2.6</oasis:entry>
         <oasis:entry colname="col5">1.04</oasis:entry>
         <oasis:entry colname="col6">0.95</oasis:entry>
         <oasis:entry colname="col7">1.96</oasis:entry>
         <oasis:entry colname="col8">2.43</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Sulfur dioxide (SO<inline-formula><mml:math id="M90" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col2">0.9</oasis:entry>
         <oasis:entry colname="col3">0.68</oasis:entry>
         <oasis:entry colname="col4">0.4</oasis:entry>
         <oasis:entry colname="col5">1.1</oasis:entry>
         <oasis:entry colname="col6">1</oasis:entry>
         <oasis:entry colname="col7">1.1</oasis:entry>
         <oasis:entry colname="col8">0.4</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Particulate matter with diameters less than 2.5 <inline-formula><mml:math id="M91" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula> (PM<inline-formula><mml:math id="M92" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">25</mml:mn></mml:msub></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col2">7.17</oasis:entry>
         <oasis:entry colname="col3">7.1</oasis:entry>
         <oasis:entry colname="col4">9.9</oasis:entry>
         <oasis:entry colname="col5">15</oasis:entry>
         <oasis:entry colname="col6">18.4</oasis:entry>
         <oasis:entry colname="col7">17.9</oasis:entry>
         <oasis:entry colname="col8">6.43</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Total particulate matter (TPM)</oasis:entry>
         <oasis:entry colname="col2">8.3</oasis:entry>
         <oasis:entry colname="col3">15.4</oasis:entry>
         <oasis:entry colname="col4">18.5</oasis:entry>
         <oasis:entry colname="col5">18</oasis:entry>
         <oasis:entry colname="col6">18.4</oasis:entry>
         <oasis:entry colname="col7">18</oasis:entry>
         <oasis:entry colname="col8">13</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Total particulate carbon (TPC)</oasis:entry>
         <oasis:entry colname="col2">3</oasis:entry>
         <oasis:entry colname="col3">7.1</oasis:entry>
         <oasis:entry colname="col4">5.2</oasis:entry>
         <oasis:entry colname="col5">9.7</oasis:entry>
         <oasis:entry colname="col6">8.3</oasis:entry>
         <oasis:entry colname="col7">9.7</oasis:entry>
         <oasis:entry colname="col8">4</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Particulate organic carbon (OC)</oasis:entry>
         <oasis:entry colname="col2">2.6</oasis:entry>
         <oasis:entry colname="col3">3.7</oasis:entry>
         <oasis:entry colname="col4">4.7</oasis:entry>
         <oasis:entry colname="col5">7.6</oasis:entry>
         <oasis:entry colname="col6">7.8</oasis:entry>
         <oasis:entry colname="col7">7.6</oasis:entry>
         <oasis:entry colname="col8">2.66</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Particulate black carbon (BC)</oasis:entry>
         <oasis:entry colname="col2">0.37</oasis:entry>
         <oasis:entry colname="col3">1.31</oasis:entry>
         <oasis:entry colname="col4">0.52</oasis:entry>
         <oasis:entry colname="col5">0.56</oasis:entry>
         <oasis:entry colname="col6">0.2</oasis:entry>
         <oasis:entry colname="col7">0.56</oasis:entry>
         <oasis:entry colname="col8">0.51</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Ammonia (NH<inline-formula><mml:math id="M93" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col2">0.56</oasis:entry>
         <oasis:entry colname="col3">1.2</oasis:entry>
         <oasis:entry colname="col4">1.3</oasis:entry>
         <oasis:entry colname="col5">2.47</oasis:entry>
         <oasis:entry colname="col6">1.8</oasis:entry>
         <oasis:entry colname="col7">1.17</oasis:entry>
         <oasis:entry colname="col8">2.12</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Nitrogen oxide (NO)</oasis:entry>
         <oasis:entry colname="col2">2.16</oasis:entry>
         <oasis:entry colname="col3">0.77</oasis:entry>
         <oasis:entry colname="col4">0.9</oasis:entry>
         <oasis:entry colname="col5">0.95</oasis:entry>
         <oasis:entry colname="col6">0.83</oasis:entry>
         <oasis:entry colname="col7">0.95</oasis:entry>
         <oasis:entry colname="col8">1.18</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Nitrogen dioxide (NO<inline-formula><mml:math id="M94" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col2">3.22</oasis:entry>
         <oasis:entry colname="col3">2.58</oasis:entry>
         <oasis:entry colname="col4">3.6</oasis:entry>
         <oasis:entry colname="col5">2.34</oasis:entry>
         <oasis:entry colname="col6">0.63</oasis:entry>
         <oasis:entry colname="col7">2.34</oasis:entry>
         <oasis:entry colname="col8">2.99</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Non-methane hydrocarbons (NMHCs)</oasis:entry>
         <oasis:entry colname="col2">3.4</oasis:entry>
         <oasis:entry colname="col3">3.4</oasis:entry>
         <oasis:entry colname="col4">1.7</oasis:entry>
         <oasis:entry colname="col5">5.7</oasis:entry>
         <oasis:entry colname="col6">5.7</oasis:entry>
         <oasis:entry colname="col7">5.7</oasis:entry>
         <oasis:entry colname="col8">7</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Particulate matter with diameters less than 10 <inline-formula><mml:math id="M95" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula> (PM<inline-formula><mml:math id="M96" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">10</mml:mn></mml:msub></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col2">7.2</oasis:entry>
         <oasis:entry colname="col3">11.4</oasis:entry>
         <oasis:entry colname="col4">18.5</oasis:entry>
         <oasis:entry colname="col5">16.97</oasis:entry>
         <oasis:entry colname="col6">18.4</oasis:entry>
         <oasis:entry colname="col7">18.4</oasis:entry>
         <oasis:entry colname="col8">7.02</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup><?xmltex \end{scaleboxenv}?></oasis:table><?xmltex \begin{scaleboxenv}{.90}[.90]?><table-wrap-foot><p id="d1e2073"><inline-formula><mml:math id="M75" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">a</mml:mi></mml:msup></mml:math></inline-formula> Emissions factors for tropical forests, savannah/grasslands, and woody savannah/shrubs are updated to the average values from Akagi et al. (2011; updated in February 2015). <inline-formula><mml:math id="M76" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">b</mml:mi></mml:msup></mml:math></inline-formula> Emissions factors for temperate forest and temperate evergreen forests are the average values from Akagi et al. (2011; updated February 2015), and the results are from Liu et al. (2017), Paton-Walsh et al. (2014), and Urbanski (2014). For temperate evergreen forest, only the results from evergreen forests are included. <inline-formula><mml:math id="M77" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">c</mml:mi></mml:msup></mml:math></inline-formula> Boreal forest emissions factors are the average of Akagi et al. (2011), with the emissions factors from boreal forest taken from Urbanski (2014). <inline-formula><mml:math id="M78" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">d</mml:mi></mml:msup></mml:math></inline-formula> Crop emissions factors are updated with the average values from Akagi et al. (2011) and results from Fang et al. (2017), Liu et al. (2016), Santiago-De La Rosa et al. (2018), and Stockwell et al. (2015; Table S3). <inline-formula><mml:math id="M79" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">e</mml:mi></mml:msup></mml:math></inline-formula> NMOG emissions factors now include identified and unidentified compounds.</p></table-wrap-foot><?xmltex \end{scaleboxenv}?><?xmltex \gdef\@currentlabel{4}?></table-wrap>

</sec>
<sec id="Ch1.S2.SS5">
  <label>2.5</label><title>Allocation of non-methane organic gases to chemical mechanisms</title>
      <?pagebreak page3879?><p id="d1e2893">Wiedinmyer et al. (2011) provided mappings from the total mass NMOG emissions
values calculated by the FINN model to the surrogate species of three
chemical mechanisms commonly used in chemical transport models, namely MOZART (Model for Ozone and Related chemical Tracers), SAPRC99 (Statewide Air Pollution Research Center Mechanism), and GEOS-Chem (Goddard Earth Observing System with Chemistry). The mapping of NMOG emissions to the MOZART-T1 chemical mechanism was created for FINNv2.5, based on recent published emissions data and updates in the chemical mechanisms (Table 5). To convert the total NMOC to the individual mechanism species, the total NMOG mass estimated by FINN should be multiplied by the mapping value (mole species in kg NMOG<inline-formula><mml:math id="M97" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>; e.g., Table 5) to assign the molar emissions of the surrogate species. The mappings to the SAPRC99 and GEOS-Chem have not been updated and are the same as those described by Wiedinmyer et al. (2011).</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T5" specific-use="star"><?xmltex \currentcnt{5}?><label>Table 5</label><caption><p id="d1e2911">Factors to map the total NMOG mass emissions to the MOZART-T1
chemical species (mole species in kg NMOG<inline-formula><mml:math id="M98" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>). MOZART-T1 species are defined in Emmons et al. (2020; their Table S1).</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="8">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="right"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:colspec colnum="4" colname="col4" align="right"/>
     <oasis:colspec colnum="5" colname="col5" align="right"/>
     <oasis:colspec colnum="6" colname="col6" align="right"/>
     <oasis:colspec colnum="7" colname="col7" align="right"/>
     <oasis:colspec colnum="8" colname="col8" align="right"/>
     <oasis:thead>
       <oasis:row>
         <oasis:entry colname="col1">MOZART-T1 chemical species</oasis:entry>
         <oasis:entry rowsep="1" namest="col2" nameend="col8" align="center">Generic vegetation index and type </oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry rowsep="1" colname="col2">1</oasis:entry>
         <oasis:entry rowsep="1" colname="col3">2</oasis:entry>
         <oasis:entry rowsep="1" colname="col4">3</oasis:entry>
         <oasis:entry rowsep="1" colname="col5">4</oasis:entry>
         <oasis:entry rowsep="1" colname="col6">5</oasis:entry>
         <oasis:entry rowsep="1" colname="col7">6</oasis:entry>
         <oasis:entry rowsep="1" colname="col8">9</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">Savanna</oasis:entry>
         <oasis:entry colname="col3">Woody</oasis:entry>
         <oasis:entry colname="col4">Tropical</oasis:entry>
         <oasis:entry colname="col5">Temperate</oasis:entry>
         <oasis:entry colname="col6">Boreal</oasis:entry>
         <oasis:entry colname="col7">Temperate</oasis:entry>
         <oasis:entry colname="col8">Crop</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">grasslands</oasis:entry>
         <oasis:entry colname="col3">savanna/</oasis:entry>
         <oasis:entry colname="col4">forest</oasis:entry>
         <oasis:entry colname="col5">forest</oasis:entry>
         <oasis:entry colname="col6">forest</oasis:entry>
         <oasis:entry colname="col7">evergreen</oasis:entry>
         <oasis:entry colname="col8"/>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2"/>
         <oasis:entry colname="col3">shrubland</oasis:entry>
         <oasis:entry colname="col4"/>
         <oasis:entry colname="col5"/>
         <oasis:entry colname="col6"/>
         <oasis:entry colname="col7">forest</oasis:entry>
         <oasis:entry colname="col8"/>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
         <oasis:entry colname="col1">APIN</oasis:entry>
         <oasis:entry colname="col2">0.009</oasis:entry>
         <oasis:entry colname="col3">0.053</oasis:entry>
         <oasis:entry colname="col4">0.0</oasis:entry>
         <oasis:entry colname="col5">0.261</oasis:entry>
         <oasis:entry colname="col6">0.259</oasis:entry>
         <oasis:entry colname="col7">0.261</oasis:entry>
         <oasis:entry colname="col8">0.010</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">BENZENE</oasis:entry>
         <oasis:entry colname="col2">0.144</oasis:entry>
         <oasis:entry colname="col3">0.442</oasis:entry>
         <oasis:entry colname="col4">0.0</oasis:entry>
         <oasis:entry colname="col5">0.253</oasis:entry>
         <oasis:entry colname="col6">0.290</oasis:entry>
         <oasis:entry colname="col7">0.253</oasis:entry>
         <oasis:entry colname="col8">0.091</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">BIGALK</oasis:entry>
         <oasis:entry colname="col2">0.156</oasis:entry>
         <oasis:entry colname="col3">0.644</oasis:entry>
         <oasis:entry colname="col4">0.219</oasis:entry>
         <oasis:entry colname="col5">0.415</oasis:entry>
         <oasis:entry colname="col6">1.821</oasis:entry>
         <oasis:entry colname="col7">0.415</oasis:entry>
         <oasis:entry colname="col8">0.246</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">BIGENE</oasis:entry>
         <oasis:entry colname="col2">1.467</oasis:entry>
         <oasis:entry colname="col3">1.274</oasis:entry>
         <oasis:entry colname="col4">0.662</oasis:entry>
         <oasis:entry colname="col5">1.393</oasis:entry>
         <oasis:entry colname="col6">0.627</oasis:entry>
         <oasis:entry colname="col7">1.393</oasis:entry>
         <oasis:entry colname="col8">0.674</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">BPIN</oasis:entry>
         <oasis:entry colname="col2">0.0</oasis:entry>
         <oasis:entry colname="col3">0.004</oasis:entry>
         <oasis:entry colname="col4">0.0</oasis:entry>
         <oasis:entry colname="col5">0.008</oasis:entry>
         <oasis:entry colname="col6">0.209</oasis:entry>
         <oasis:entry colname="col7">0.008</oasis:entry>
         <oasis:entry colname="col8">0.0</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">BZALD</oasis:entry>
         <oasis:entry colname="col2">0.791</oasis:entry>
         <oasis:entry colname="col3">0.272</oasis:entry>
         <oasis:entry colname="col4">0.120</oasis:entry>
         <oasis:entry colname="col5">0.298</oasis:entry>
         <oasis:entry colname="col6">0.166</oasis:entry>
         <oasis:entry colname="col7">0.298</oasis:entry>
         <oasis:entry colname="col8">0.325</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">C<inline-formula><mml:math id="M99" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>H<inline-formula><mml:math id="M100" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">2.103</oasis:entry>
         <oasis:entry colname="col3">1.975</oasis:entry>
         <oasis:entry colname="col4">0.672</oasis:entry>
         <oasis:entry colname="col5">2.513</oasis:entry>
         <oasis:entry colname="col6">1.167</oasis:entry>
         <oasis:entry colname="col7">2.513</oasis:entry>
         <oasis:entry colname="col8">1.701</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">C<inline-formula><mml:math id="M101" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>H<inline-formula><mml:math id="M102" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">4</mml:mn></mml:msub></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">1.218</oasis:entry>
         <oasis:entry colname="col3">2.886</oasis:entry>
         <oasis:entry colname="col4">1.505</oasis:entry>
         <oasis:entry colname="col5">1.930</oasis:entry>
         <oasis:entry colname="col6">1.407</oasis:entry>
         <oasis:entry colname="col7">1.930</oasis:entry>
         <oasis:entry colname="col8">1.412</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">C<inline-formula><mml:math id="M103" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>H<inline-formula><mml:math id="M104" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">6</mml:mn></mml:msub></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">0.859</oasis:entry>
         <oasis:entry colname="col3">0.641</oasis:entry>
         <oasis:entry colname="col4">0.939</oasis:entry>
         <oasis:entry colname="col5">0.611</oasis:entry>
         <oasis:entry colname="col6">1.168</oasis:entry>
         <oasis:entry colname="col7">0.611</oasis:entry>
         <oasis:entry colname="col8">0.673</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">C<inline-formula><mml:math id="M105" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula>H<inline-formula><mml:math id="M106" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">6</mml:mn></mml:msub></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">0.647</oasis:entry>
         <oasis:entry colname="col3">0.557</oasis:entry>
         <oasis:entry colname="col4">0.603</oasis:entry>
         <oasis:entry colname="col5">0.487</oasis:entry>
         <oasis:entry colname="col6">0.499</oasis:entry>
         <oasis:entry colname="col7">0.487</oasis:entry>
         <oasis:entry colname="col8">0.457</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">C<inline-formula><mml:math id="M107" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula>H<inline-formula><mml:math id="M108" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">8</mml:mn></mml:msub></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">0.090</oasis:entry>
         <oasis:entry colname="col3">0.561</oasis:entry>
         <oasis:entry colname="col4">0.114</oasis:entry>
         <oasis:entry colname="col5">0.149</oasis:entry>
         <oasis:entry colname="col6">0.194</oasis:entry>
         <oasis:entry colname="col7">0.149</oasis:entry>
         <oasis:entry colname="col8">0.142</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">CH<inline-formula><mml:math id="M109" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O</oasis:entry>
         <oasis:entry colname="col2">1.532</oasis:entry>
         <oasis:entry colname="col3">2.285</oasis:entry>
         <oasis:entry colname="col4">2.299</oasis:entry>
         <oasis:entry colname="col5">2.181</oasis:entry>
         <oasis:entry colname="col6">1.361</oasis:entry>
         <oasis:entry colname="col7">2.181</oasis:entry>
         <oasis:entry colname="col8">1.716</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">CH<inline-formula><mml:math id="M110" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula>CH<inline-formula><mml:math id="M111" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>OH</oasis:entry>
         <oasis:entry colname="col2">0.0</oasis:entry>
         <oasis:entry colname="col3">0.055</oasis:entry>
         <oasis:entry colname="col4">0.0</oasis:entry>
         <oasis:entry colname="col5">0.066</oasis:entry>
         <oasis:entry colname="col6">0.023</oasis:entry>
         <oasis:entry colname="col7">0.066</oasis:entry>
         <oasis:entry colname="col8">0.0</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">CH<inline-formula><mml:math id="M112" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula>CHO</oasis:entry>
         <oasis:entry colname="col2">1.037</oasis:entry>
         <oasis:entry colname="col3">0.792</oasis:entry>
         <oasis:entry colname="col4">1.404</oasis:entry>
         <oasis:entry colname="col5">0.758</oasis:entry>
         <oasis:entry colname="col6">0.416</oasis:entry>
         <oasis:entry colname="col7">0.758</oasis:entry>
         <oasis:entry colname="col8">0.929</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">CH<inline-formula><mml:math id="M113" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula>CN</oasis:entry>
         <oasis:entry colname="col2">0.117</oasis:entry>
         <oasis:entry colname="col3">0.130</oasis:entry>
         <oasis:entry colname="col4">0.399</oasis:entry>
         <oasis:entry colname="col5">0.088</oasis:entry>
         <oasis:entry colname="col6">0.176</oasis:entry>
         <oasis:entry colname="col7">0.088</oasis:entry>
         <oasis:entry colname="col8">0.142</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">CH<inline-formula><mml:math id="M114" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula>COCH<inline-formula><mml:math id="M115" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">0.201</oasis:entry>
         <oasis:entry colname="col3">0.242</oasis:entry>
         <oasis:entry colname="col4">0.433</oasis:entry>
         <oasis:entry colname="col5">0.297</oasis:entry>
         <oasis:entry colname="col6">0.242</oasis:entry>
         <oasis:entry colname="col7">0.297</oasis:entry>
         <oasis:entry colname="col8">0.162</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">CH<inline-formula><mml:math id="M116" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula>COOH</oasis:entry>
         <oasis:entry colname="col2">2.371</oasis:entry>
         <oasis:entry colname="col3">1.353</oasis:entry>
         <oasis:entry colname="col4">2.029</oasis:entry>
         <oasis:entry colname="col5">1.292</oasis:entry>
         <oasis:entry colname="col6">1.360</oasis:entry>
         <oasis:entry colname="col7">1.292</oasis:entry>
         <oasis:entry colname="col8">2.349</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">CH<inline-formula><mml:math id="M117" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula>OH</oasis:entry>
         <oasis:entry colname="col2">1.451</oasis:entry>
         <oasis:entry colname="col3">1.650</oasis:entry>
         <oasis:entry colname="col4">3.031</oasis:entry>
         <oasis:entry colname="col5">1.744</oasis:entry>
         <oasis:entry colname="col6">1.608</oasis:entry>
         <oasis:entry colname="col7">1.744</oasis:entry>
         <oasis:entry colname="col8">2.328</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">CRESOL</oasis:entry>
         <oasis:entry colname="col2">0.059</oasis:entry>
         <oasis:entry colname="col3">0.058</oasis:entry>
         <oasis:entry colname="col4">0.0</oasis:entry>
         <oasis:entry colname="col5">0.059</oasis:entry>
         <oasis:entry colname="col6">0.040</oasis:entry>
         <oasis:entry colname="col7">0.059</oasis:entry>
         <oasis:entry colname="col8">0.074</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">GLYALD</oasis:entry>
         <oasis:entry colname="col2">0.390</oasis:entry>
         <oasis:entry colname="col3">0.128</oasis:entry>
         <oasis:entry colname="col4">1.886</oasis:entry>
         <oasis:entry colname="col5">0.210</oasis:entry>
         <oasis:entry colname="col6">0.233</oasis:entry>
         <oasis:entry colname="col7">0.210</oasis:entry>
         <oasis:entry colname="col8">0.800</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">HCN</oasis:entry>
         <oasis:entry colname="col2">0.559</oasis:entry>
         <oasis:entry colname="col3">0.927</oasis:entry>
         <oasis:entry colname="col4">0.625</oasis:entry>
         <oasis:entry colname="col5">0.684</oasis:entry>
         <oasis:entry colname="col6">0.846</oasis:entry>
         <oasis:entry colname="col7">0.684</oasis:entry>
         <oasis:entry colname="col8">0.416</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">HCOOH</oasis:entry>
         <oasis:entry colname="col2">0.206</oasis:entry>
         <oasis:entry colname="col3">0.134</oasis:entry>
         <oasis:entry colname="col4">0.683</oasis:entry>
         <oasis:entry colname="col5">0.259</oasis:entry>
         <oasis:entry colname="col6">0.254</oasis:entry>
         <oasis:entry colname="col7">0.259</oasis:entry>
         <oasis:entry colname="col8">0.426</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">HONO</oasis:entry>
         <oasis:entry colname="col2">0.298</oasis:entry>
         <oasis:entry colname="col3">0.643</oasis:entry>
         <oasis:entry colname="col4">1.001</oasis:entry>
         <oasis:entry colname="col5">0.326</oasis:entry>
         <oasis:entry colname="col6">0.228</oasis:entry>
         <oasis:entry colname="col7">0.326</oasis:entry>
         <oasis:entry colname="col8">0.187</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">HYAC</oasis:entry>
         <oasis:entry colname="col2">0.309</oasis:entry>
         <oasis:entry colname="col3">0.118</oasis:entry>
         <oasis:entry colname="col4">0.609</oasis:entry>
         <oasis:entry colname="col5">0.223</oasis:entry>
         <oasis:entry colname="col6">0.149</oasis:entry>
         <oasis:entry colname="col7">0.223</oasis:entry>
         <oasis:entry colname="col8">1.548</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">ISOP</oasis:entry>
         <oasis:entry colname="col2">0.069</oasis:entry>
         <oasis:entry colname="col3">0.138</oasis:entry>
         <oasis:entry colname="col4">0.029</oasis:entry>
         <oasis:entry colname="col5">0.129</oasis:entry>
         <oasis:entry colname="col6">0.085</oasis:entry>
         <oasis:entry colname="col7">0.129</oasis:entry>
         <oasis:entry colname="col8">0.062</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">LIMON</oasis:entry>
         <oasis:entry colname="col2">0.0</oasis:entry>
         <oasis:entry colname="col3">0.013</oasis:entry>
         <oasis:entry colname="col4">0.0</oasis:entry>
         <oasis:entry colname="col5">0.158</oasis:entry>
         <oasis:entry colname="col6">0.0</oasis:entry>
         <oasis:entry colname="col7">0.158</oasis:entry>
         <oasis:entry colname="col8">0.0</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">MACR</oasis:entry>
         <oasis:entry colname="col2">0.0</oasis:entry>
         <oasis:entry colname="col3">0.147</oasis:entry>
         <oasis:entry colname="col4">0.222</oasis:entry>
         <oasis:entry colname="col5">0.113</oasis:entry>
         <oasis:entry colname="col6">0.024</oasis:entry>
         <oasis:entry colname="col7">0.113</oasis:entry>
         <oasis:entry colname="col8">0.0</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">MEK</oasis:entry>
         <oasis:entry colname="col2">0.370</oasis:entry>
         <oasis:entry colname="col3">0.286</oasis:entry>
         <oasis:entry colname="col4">0.666</oasis:entry>
         <oasis:entry colname="col5">0.274</oasis:entry>
         <oasis:entry colname="col6">0.104</oasis:entry>
         <oasis:entry colname="col7">0.274</oasis:entry>
         <oasis:entry colname="col8">0.387</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">MGLY</oasis:entry>
         <oasis:entry colname="col2">0.347</oasis:entry>
         <oasis:entry colname="col3">0.094</oasis:entry>
         <oasis:entry colname="col4">0.0</oasis:entry>
         <oasis:entry colname="col5">0.135</oasis:entry>
         <oasis:entry colname="col6">0.090</oasis:entry>
         <oasis:entry colname="col7">0.135</oasis:entry>
         <oasis:entry colname="col8">0.171</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">MVK</oasis:entry>
         <oasis:entry colname="col2">0.317</oasis:entry>
         <oasis:entry colname="col3">0.301</oasis:entry>
         <oasis:entry colname="col4">0.222</oasis:entry>
         <oasis:entry colname="col5">0.247</oasis:entry>
         <oasis:entry colname="col6">0.087</oasis:entry>
         <oasis:entry colname="col7">0.247</oasis:entry>
         <oasis:entry colname="col8">0.193</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">MYRC</oasis:entry>
         <oasis:entry colname="col2">0.0</oasis:entry>
         <oasis:entry colname="col3">0.003</oasis:entry>
         <oasis:entry colname="col4">0.0</oasis:entry>
         <oasis:entry colname="col5">0.002</oasis:entry>
         <oasis:entry colname="col6">0.0</oasis:entry>
         <oasis:entry colname="col7">0.002</oasis:entry>
         <oasis:entry colname="col8">0.0</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">PHENOL</oasis:entry>
         <oasis:entry colname="col2">0.472</oasis:entry>
         <oasis:entry colname="col3">0.457</oasis:entry>
         <oasis:entry colname="col4">0.191</oasis:entry>
         <oasis:entry colname="col5">0.345</oasis:entry>
         <oasis:entry colname="col6">0.517</oasis:entry>
         <oasis:entry colname="col7">0.345</oasis:entry>
         <oasis:entry colname="col8">0.408</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">TOLUENE</oasis:entry>
         <oasis:entry colname="col2">0.457</oasis:entry>
         <oasis:entry colname="col3">0.531</oasis:entry>
         <oasis:entry colname="col4">0.769</oasis:entry>
         <oasis:entry colname="col5">0.605</oasis:entry>
         <oasis:entry colname="col6">1.327</oasis:entry>
         <oasis:entry colname="col7">0.605</oasis:entry>
         <oasis:entry colname="col8">0.375</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">XYLENE</oasis:entry>
         <oasis:entry colname="col2">0.385</oasis:entry>
         <oasis:entry colname="col3">0.355</oasis:entry>
         <oasis:entry colname="col4">0.040</oasis:entry>
         <oasis:entry colname="col5">0.422</oasis:entry>
         <oasis:entry colname="col6">0.238</oasis:entry>
         <oasis:entry colname="col7">0.422</oasis:entry>
         <oasis:entry colname="col8">0.295</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">XYLOL</oasis:entry>
         <oasis:entry colname="col2">0.108</oasis:entry>
         <oasis:entry colname="col3">0.046</oasis:entry>
         <oasis:entry colname="col4">0.0</oasis:entry>
         <oasis:entry colname="col5">0.088</oasis:entry>
         <oasis:entry colname="col6">0.056</oasis:entry>
         <oasis:entry colname="col7">0.088</oasis:entry>
         <oasis:entry colname="col8">0.130</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table><?xmltex \gdef\@currentlabel{5}?></table-wrap>

</sec>
</sec>
<sec id="Ch1.S3">
  <label>3</label><title>Results</title>
<sec id="Ch1.S3.SS1">
  <label>3.1</label><title>Emissions estimates</title>
      <p id="d1e4231">The FINNv2.5 model was run in two ways to produce emissions for evaluation
and assessment, namely (1) for comparison with the previous version of FINN
(FINNv1.5) using MODIS-only fire detections and calculated starting in 2002
(FINNv2.5(MODIS)) and (2) by using both MODIS and VIIRS fire detections and
calculated starting in 2012 (FINNv2.5(MODIS <inline-formula><mml:math id="M118" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> VIIRS). The FINNv2.5 emissions files are freely available for use by the community (Wiedinmyer and Emmons, 2022). Results through 2019 are presented in this work.</p>
      <p id="d1e4241">Estimates from several versions of FINN are compared to other emissions
inventories, such as the Global Fire Emissions Database (GFED; van der Werf et al., 2017), Fire Energetics and Emissions Research (FEER; Ichoku and Ellison, 2014), the Global Fire Assimilation System (GFAS; Kaiser et al., 2012), and the Quick Fire Emissions Dataset (QFED) version 2.5 (Darmenov and da Silva, 2015; Fig. 4). The comparisons are done by the global region that follows (Giglio et al., 2010; Fig. 4).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F4" specific-use="star"><?xmltex \currentcnt{4}?><?xmltex \def\figurename{Figure}?><label>Figure 4</label><caption><p id="d1e4246">Annually averaged (2012–2019) emissions of CO<inline-formula><mml:math id="M119" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>, CO,
formaldehyde (CH<inline-formula><mml:math id="M120" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O), particulate black carbon (BC) plus organic carbon
(OC), ammonia (NH<inline-formula><mml:math id="M121" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula>), ethane (C<inline-formula><mml:math id="M122" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>H<inline-formula><mml:math id="M123" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">6</mml:mn></mml:msub></mml:math></inline-formula>), sulfur dioxide
(SO<inline-formula><mml:math id="M124" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>), and nitrogen oxide (NO<inline-formula><mml:math id="M125" display="inline"><mml:msub><mml:mi/><mml:mi>x</mml:mi></mml:msub></mml:math></inline-formula>) from the Fire Inventory from NCAR
version 2.5 (FINNv2.5(MODIS <inline-formula><mml:math id="M126" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> VIIRS), FINNv2.5MODIS-only version (FINNv2.5 (MODIS)), FINNv1.5, Global Fire Emissions Database (GFED), Fire Energetics and Emissions Research (FEER), Global Fire Assimilation System (GFAS), and Quick Fire Emissions Dataset (QFED). Bars show global totals broken up into regional totals by color (Giglio et al., 2010). The regions are shown in the global map here, namely boreal North America (BONA), temperate North America (TENA), central America (CEAM), Northern Hemisphere South America (NHSA), Southern Hemisphere South America (SHSA), Europe (EURO), the Middle East (MIDE), Northern Hemisphere Africa (NHAF), Southern Hemisphere Africa (SHAF), boreal Asia (BOAS), central Asia (CEAS), Southeast Asia (SEAS), equatorial Asia (EQAS), and Australia and New Zealand (AUST). For comparisons with earlier versions of FINN, see Fig. S2.</p></caption>
          <?xmltex \igopts{width=426.791339pt}?><graphic xlink:href="https://gmd.copernicus.org/articles/16/3873/2023/gmd-16-3873-2023-f04.png"/>

        </fig>

      <p id="d1e4327">Figure 4 compares the annual averaged (2012–2019) emissions of key pollutants from several versions of FINN and the other inventories by region. For all emitted species, FINNv2.5(MODIS <inline-formula><mml:math id="M127" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> VIIRS) global emissions are higher than, and approximately double, those predicted by<?pagebreak page3880?> FINNv1.5. This is the case, even when only MODIS fire detections are considered. The increase in emissions from previous versions is primarily due to the new processing of the area burned. In previous versions, the fire area was determined from a
satellite detection pixel only; the updated version here also includes the
composite of many detections into larger areas of fire activity (Sect. 2.1). The inclusion of VIIRS into the FINNv2.5(MODIS <inline-formula><mml:math id="M128" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> VIIRS) inventory
globally adds approximately 25 % above the FINNv2.5(MODIS) processing for
all emitted species. Further, emissions of NMOGs and the individual species
that make up NMOGs (e.g., CH<inline-formula><mml:math id="M129" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O and C<inline-formula><mml:math id="M130" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>H<inline-formula><mml:math id="M131" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">6</mml:mn></mml:msub></mml:math></inline-formula> in Fig. 4) are increased
significantly due to the use of updated emissions factors from recent field
campaigns. Previous studies have shown low biases in FINN regional and
species-specific estimates; for example, CO in the western USA (Pfister et
al., 2011) and Australia (Desservettaz et al., 2022) and particulate carbon
in North America (Carter et al., 2020). The updated version is expected to
correct some of these prior biases.</p>
      <p id="d1e4371">FINNv2.5(MODIS <inline-formula><mml:math id="M132" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> VIIRS) emissions estimates are overall at the higher end of the range of annual global total emissions provided by our sample of other
commonly used emissions inventories, likely due to a combination of the
aggregated burned areas and the fact that FINNv2.5(MODIS <inline-formula><mml:math id="M133" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> VIIRS) includes fire information from VIIRS, which captures more small fires. However, depending on the pollutant emitted, a comparison across different emissions inventories shows varied results. For example, both CO<inline-formula><mml:math id="M134" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula> and CO global annual emissions from FINNv2.5 (MODIS and MODIS <inline-formula><mml:math id="M135" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> VIIRS) are higher than QFED, but black carbon (BC) and ammonia (NH<inline-formula><mml:math id="M136" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula>) are lower in FINNv2.5 than QFED. The primary drivers of these differences are the assumed fuel type burned and associated emissions factors. This difference in emissions amounts between inventories is more variable when looking regionally and year to year (e.g., Figs. 5 and S4).</p>
      <p id="d1e4413">In general, the year-to-year variabilities in the annual fire emissions are
consistent between different inventories, and mainly the magnitudes of the
emissions differ (Figs. 5, S5, and S6). FINNv2.5(MODIS <inline-formula><mml:math id="M137" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> VIIRS) is often among the inventories that produces the highest CO emissions in<?pagebreak page3881?> all 14 global
regions. Some notable exceptions are boreal North America and boreal Asia,
where GFAS and sometimes GFED estimate higher emissions. This is likely due
to the representation of smoldering peat fires in the high latitudes that
are represented as a specific vegetation type in the GFED and GFAS
inventories but not in FINNv2.5. (Note that Kiely et al., 2019, developed a
parameterization used in FINNv2 to represent regional peat emissions in Indonesia, but this was not included in FINNv2.5.) Similarly, in equatorial Asia, GFED and GFAS estimate the highest CO emissions for the years when much of the tropical peatland burned. The magnitude of FINNv2.5(MODIS <inline-formula><mml:math id="M138" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> VIIRS) CO emissions in Australia and New Zealand has increased relative to FINNv1.5, which compares better to downwind surface measurements of instantaneous mixing ratios (Desservettaz et al., 2022). However, regional FINNv2.5(MODIS <inline-formula><mml:math id="M139" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> VIIRS and MODIS) emissions remain lower than three other emissions inventories (GFAS, QFED, and FEER) in Australia and New Zealand. A similar result is seen over the Middle East, which suggests a potential role of extremely dry landscapes in causing inter-inventory differences. For most other regions, FEER is the only inventory that produces emissions that are as high in magnitude, or sometimes higher, as FINNv2.5(MODIS <inline-formula><mml:math id="M140" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> VIIRS).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F5" specific-use="star"><?xmltex \currentcnt{5}?><?xmltex \def\figurename{Figure}?><label>Figure 5</label><caption><p id="d1e4446">Annual total emissions of CO by region between 2012 and 2019 from
the Fire Inventory from NCAR version 2.5 with MODIS and VIIRS (FINNv2.5
modvrs; black symbols), FINNv2.5 MODIS-only version (FINNv2.5 mod; gray symbols), FINNv1.5, Global Fire Emissions Database (GFED), Fire Energetics and Emissions Research (FEER), Global Fire Assimilation System (GFAS), and Quick Fire Emissions Dataset (QFED). Regions are defined in Giglio et al. (2010; refer to Fig. 4). For comparisons with earlier versions of FINN, see Fig. S3. For comparisons of CH<inline-formula><mml:math id="M141" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O and PM<inline-formula><mml:math id="M142" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2.5</mml:mn></mml:msub></mml:math></inline-formula> emissions, see Figs. S4 and S5, respectively.</p></caption>
          <?xmltex \igopts{width=483.69685pt}?><graphic xlink:href="https://gmd.copernicus.org/articles/16/3873/2023/gmd-16-3873-2023-f05.png"/>

        </fig>

      <p id="d1e4473">The seasonal change in the regional fire emissions for CO in FINNv2.5(MODIS <inline-formula><mml:math id="M143" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> VIIRS) is shown in Fig. 6, with other inventories in
Fig. S4. Globally, fire emissions peak in August–September, with the
largest emissions in Southern Hemisphere Africa and Southern Hemisphere
South America. As mentioned above, GFED and GFAS show an increase in boreal
North America in July and August that is not as prevalent in FINNv2.5(MODIS <inline-formula><mml:math id="M144" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> VIIRS).</p>
      <p id="d1e4491">FINNv2.5(MODIS <inline-formula><mml:math id="M145" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> VIIRS) also has an emissions peak in March, which is driven primarily by emissions in Southeast Asia. March–April is a peak fire season in the Northern Hemisphere tropics, and in mainland Southeast Asia, the season is driven primarily by small, agricultural fires. FINNv2.5(MODIS <inline-formula><mml:math id="M146" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> VIIRS) uses VIIRS fire detections, which detect these small fires to a greater extent than MODIS. Most inventories show this second peak in emissions during March and April; however, it is not seen in GFED, nor is it as pronounced in the other inventories (Fig. S6). Consequently, determining the cause of different fire emissions in Southeast Asia is a target for future research. Although the magnitude of the regional emissions
in FINNv2.5(MODIS <inline-formula><mml:math id="M147" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> VIIRS) is 2–3 times higher than FINNv1.5, the
seasonality is similar.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F6"><?xmltex \currentcnt{6}?><?xmltex \def\figurename{Figure}?><label>Figure 6</label><caption><p id="d1e4517">Seasonal cycle of fire emissions of CO from
FINNv2.5(MODIS <inline-formula><mml:math id="M148" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> VIIRS; averaged for 2012–2019) by global region. Region
definitions follow Giglio et al. (2010) and are described in Fig. 4.</p></caption>
          <?xmltex \igopts{width=236.157874pt}?><graphic xlink:href="https://gmd.copernicus.org/articles/16/3873/2023/gmd-16-3873-2023-f06.png"/>

        </fig>

</sec>
<sec id="Ch1.S3.SS2">
  <label>3.2</label><title>Model simulation using FINNv2.5 compared to satellite products</title>
      <p id="d1e4541">As shown above, the emissions estimates from the different fire emissions
models can vary substantially in time and space. It is difficult to know
which emissions estimates most closely represent reality. One way to assess
the emissions is<?pagebreak page3882?> to use them as input to an atmospheric chemistry model and
calculate pollutant concentrations that can then be compared to in situ
measurements and satellite observations. To further evaluate FINNv2.5(MODIS <inline-formula><mml:math id="M149" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> VIIRS) and understand its uncertainties and limitations, we performed a simulation with the Community Atmosphere Model with Chemistry
(CAM-chem), a component of the Community Earth System Model (CESM2.2.0; Emmons et al., 2020). For this simulation, the temperature and winds of
CAM-chem are nudged to the Modern-Era Retrospective analysis for Research
and Applications, version 2 (MERRA-2) reanalysis fields. Anthropogenic
emissions are from the Copernicus Atmosphere Monitoring Service (CAMS) v5.1
inventory (Soulie et al., 2023), and biogenic emissions are calculated online with the Model of Emissions of Gases and Aerosols from Nature (MEGAN) version 2.1 (described in Emmons et al., 2020). Results for the year 2018, after several years of spin-up, are shown here.</p>
      <p id="d1e4551">The model results with FINNv2.5 emissions are compared to the CO column density from the Measurement of Pollution in the Troposphere (MOPITT) instrument retrievals (version 8, Level 3, gridded monthly joint product;<?pagebreak page3883?> MOP03J.008; Deeter et al., 2019), and aerosol optical depth (AOD) from MODIS (Level 3 gridded monthly global product; MOD08_M3 and
MYD08_M3; MODIS Atmosphere Science Team, 2017; Figs. 7 and 8). For the comparisons to the MOPITT retrievals, the model CO profiles are transformed with the MOPITT averaging kernels and an a priori profile. The joint retrieval product combines the thermal-infrared (TIR) and near-infrared (NIR) radiances to provide greater sensitivity to the boundary layer than the TIR retrievals alone.</p>
      <p id="d1e4554">Overall, CAM-chem driven with FINNv2.5(MODIS <inline-formula><mml:math id="M150" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> VIIRS) overestimates
satellite-observed AOD and CO over the Amazon basin and central Africa
during the 2018 fire season (Figs. 7–9). This result suggests that
FINNv2.5(MODIS <inline-formula><mml:math id="M151" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> VIIRS) overestimates fire emissions over the Amazon basin and central Africa in the 2018 fire season. This overestimation could be due<?pagebreak page3884?> to a number of reasons, including inaccurate ecosystem identification (e.g., tropical forest rather than shrublands or less wooded landscapes) and/or fuel loading assignments. The model also overestimates AOD, but not CO, over Australia and northern Africa. These discrepancies are likely due to
overestimated dust emissions in the model simulation rather than overestimated fire emissions from FINNv2.5(MODIS <inline-formula><mml:math id="M152" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> VIIRS).</p>
      <p id="d1e4578">There are important fire regions in which the model predictions and observations agree. For example, the CAM-chem results using FINNv2.5(MODIS <inline-formula><mml:math id="M153" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> VIIRS) simulate column-measured CO in August 2018 (Fig. 9) for the Pacific Northwest well. This is consistent with a previous study, which evaluated CAM-chem with regional refinement over the Pacific Northwest with aircraft observations during the Western wildfire Experiment for Cloud chemistry, Aerosol absorption and Nitrogen (WE-CAN; Tang et al., 2022) and found that simulated CO concentrations agreed reasonably with aircraft measurements.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F7"><?xmltex \currentcnt{7}?><?xmltex \def\figurename{Figure}?><label>Figure 7</label><caption><p id="d1e4591">Global distribution of CO column density from the Measurement of
Pollution in the Troposphere (MOPITT) averaged for 2018, and the corresponding Community Atmosphere Model with Chemistry (CAM-chem) model
simulation bias (model minus observations) for CO column density. The CAM-chem simulation used FINNv2.5(MODIS <inline-formula><mml:math id="M154" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> VIIRS) for fire emissions.</p></caption>
          <?xmltex \igopts{width=236.157874pt}?><graphic xlink:href="https://gmd.copernicus.org/articles/16/3873/2023/gmd-16-3873-2023-f07.png"/>

        </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F8"><?xmltex \currentcnt{8}?><?xmltex \def\figurename{Figure}?><label>Figure 8</label><caption><p id="d1e4609">Global distribution of aerosol optical depth (AOD) from the
Moderate Resolution Imaging Spectroradiometer (MODIS) averaged for 2018 and
the corresponding Community Atmosphere Model with Chemistry (CAM-chem) model
simulation bias (model minus observation) for AOD. The CAM-chem simulation
used FINNv2.5(MODIS <inline-formula><mml:math id="M155" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> VIIRS) for fire emissions.</p></caption>
          <?xmltex \igopts{width=236.157874pt}?><graphic xlink:href="https://gmd.copernicus.org/articles/16/3873/2023/gmd-16-3873-2023-f08.png"/>

        </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F9" specific-use="star"><?xmltex \currentcnt{9}?><?xmltex \def\figurename{Figure}?><label>Figure 9</label><caption><p id="d1e4627">Community Atmosphere Model with Chemistry (CAM-chem) model
simulation bias from the MOPITT CO column density <bold>(a, c, e)</bold> and MODIS AOD <bold>(b, d, f)</bold> for three regions. <bold>(a, b)</bold> The Pacific Northwest, USA, in August 2018. <bold>(c, d)</bold> Amazon basin in  September 2018. <bold>(e, f)</bold> Central Africa in August 2018. The months are selected to represent the fire season in each region. Absolute values modeled with CAM-chem are shown in Fig. S7.</p></caption>
          <?xmltex \igopts{width=483.69685pt}?><graphic xlink:href="https://gmd.copernicus.org/articles/16/3873/2023/gmd-16-3873-2023-f09.png"/>

        </fig>

</sec>
<sec id="Ch1.S3.SS3">
  <label>3.3</label><title>Uncertainties</title>
      <p id="d1e4659">Despite updates to the input data, parameters, and processing, FINNv2.5
emissions estimates remain uncertain. Uncertainties are caused by the natural
variability associated with the various inputs to the model and the model
assumptions and processes used to create the estimates. Uncertainties may
arise due to missed fire detections caused by cloud or smoke cover, timing,
and incomplete global coverage from the polar orbiting satellite paths. Furthermore, the assumed vegetation type in active fires is highly variable,
and the use of different vegetation maps can introduce large changes in the
predicted emissions. The assumed fuel loading, fraction burned,<?pagebreak page3885?> and
resulting fuel consumption can be highly variable in space and time, whereas
the model assumes best-guess average values for generic ecosystems by global
region. The emissions factors used also add some uncertainty to the estimates, which is particularly highlighted in the emissions estimates of particles and reactive gases. Other issues arise when VIIRS and MODIS are used in combination to drive the emissions estimates, compared to the MODIS-only version. We recognize that the addition of a second dataset from VIIRS increases the emissions compared to those estimated using MODIS only.</p>
      <p id="d1e4662">Wiedinmyer et al. (2011) estimated an uncertainty that is a factor of 2 in the FINNv1 estimates. Other efforts have assigned uncertainty to fire emissions estimates (e.g., Kennedy et al., 2020; Soares et al., 2015; Urbanski et al., 2011); however, limitations in our ability to directly measure fire emissions (fluxes) prevent a comprehensive, global evaluation of existing inventories. Discrepancies between model predictions and evaluations with model output, in situ measurements, and satellite observations can help
identify the processes in the models that drive the uncertainties and the
regions across the globe that are the most important and uncertain. Results
from the evaluation presented here suggest that high uncertainties in emissions occur in South America and southern Africa and in southeast and
equatorial Asia. Emissions across boreal North America should also be assessed; wide variations in organic carbon (OC) and BC emissions in this
region lead to significant uncertainty in the ability to estimate air
quality and climate impacts from biomass burning (Carter et al., 2020). Furthermore, while CO and AOD are often used to assess aerosol and CO emissions estimates, the emissions of other important pollutants are more highly variable across inventories and should be further constrained.</p>
</sec>
</sec>
<sec id="Ch1.S4" sec-type="conclusions">
  <label>4</label><title>Conclusions</title>
      <?pagebreak page3886?><p id="d1e4674">FINN version 2.5 was created by updating multiple processes and parameters
of the original FINN model framework. This version includes an improved area
burned calculation, uses year-specific land cover and vegetation datasets, updates the fuel loading and emissions factors, and enables the use of multiple fire detection satellite inputs (for example, MODIS and VIIRS). The Python code to process the burned area and overlaid land cover, in addition to the IDL (Interactive Data Language) code to calculate the emissions and speciate the NMOGs, is freely available to the community for use as is or can be further developed (<uri>https://github.com/NCAR/finn-preprocessor</uri>, last access: 7 July 2023; the current code is archived at <ext-link xlink:href="https://doi.org/10.5065/XNPA-AF09" ext-link-type="DOI">10.5065/XNPA-AF09</ext-link>; Wiedynmyer and Emmons, 2022). The resulting emissions files for 2002–2021 are also freely available in several volatile organic compound (VOC) speciation types and gridded formats (Wiedinmyer and Emmons, 2022).</p>
      <p id="d1e4683">Specific, one-time modifications to FINN have included emissions from peat
in Southeast Asia (Kiely et al., 2019) and the consideration of burn severity in the emissions calculations from California (Xu et al., 2022). These may be incorporated into future versions of FINN. Future efforts will also improve emissions estimates for fires in the wildland–urban interface.</p>
      <p id="d1e4686">The FINNv2.5(MODIS <inline-formula><mml:math id="M156" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> VIIRS) emissions estimates remain uncertain, and more evaluations and model comparisons are recommended, especially in Southern Hemisphere South America and Africa during August–October, in addition to southeastern and equatorial Asia in March–April. FINNv2.5(MODIS <inline-formula><mml:math id="M157" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> VIIRS) does, however, appear to simulate emissions in the western USA better, compared to earlier versions (e.g., Pfister et al., 2011). The vegetation type and associated fuel loading and consumption are large sources of uncertainty; the use of a different global vegetation map, other than the MODIS LCT, can lead to large variations in the<?pagebreak page3887?> predicted emissions. Future efforts to improve fire emissions estimates should focus on these components of the model.</p>
</sec>

      
      </body>
    <back><notes notes-type="codeavailability"><title>Code availability</title>

      <p id="d1e4708">The code to process the burned area and overlaid land cover, and to calculate the emissions and speciate the NMOGs, is available at <uri>https://github.com/NCAR/finn-preprocessor</uri> (last access: 7 July 2023) for updated versions, and the
current version (v2.5.2) is archived at <ext-link xlink:href="https://doi.org/10.5281/zenodo.7860860" ext-link-type="DOI">10.5281/zenodo.7860860</ext-link> (Wiedynmyer and Emmons, 2023).</p>
  </notes><notes notes-type="dataavailability"><title>Data availability</title>

      <p id="d1e4720">Emissions calculated from the FINNv2.5 algorithms, for MODIS and MODIS <inline-formula><mml:math id="M158" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> VIIRS fire detections with MOZART VOC speciation types, are archived at <ext-link xlink:href="https://doi.org/10.5065/XNPA-AF09" ext-link-type="DOI">10.5065/XNPA-AF09</ext-link> (Wiedinmyer and Emmons, 2022) and <ext-link xlink:href="https://doi.org/10.5281/zenodo.7868652" ext-link-type="DOI">10.5281/zenodo.7868652</ext-link> (Wiedinmyer and Emmons, 2023). The FINNv2.5 emissions, including emissions files for SAPRC and GEOS-Chem VOC speciation, in addition to tools for subsetting, are available from the NCAR Research Data Archive (<uri>https://rda.ucar.edu/datasets/ds312.9/</uri>, last access: 7 July 2023; <ext-link xlink:href="https://doi.org/10.5065/XNPA-AF09" ext-link-type="DOI">10.5065/XNPA-AF09</ext-link>; Wiedinmyer and Emmons, 2022). Files are provided with emissions for each fire (ungridded; zipped text files) and are also gridded to <inline-formula><mml:math id="M159" display="inline"><mml:mrow><mml:mn mathvariant="normal">0.1</mml:mn><mml:mo>×</mml:mo><mml:mn mathvariant="normal">0.1</mml:mn></mml:mrow></mml:math></inline-formula><inline-formula><mml:math id="M160" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> (netCDF files). Both sets of files are available for emissions from MODIS-only and MODIS <inline-formula><mml:math id="M161" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> VIIRS fire detections at <ext-link xlink:href="https://doi.org/10.5065/XNPA-AF09" ext-link-type="DOI">10.5065/XNPA-AF09</ext-link> (Wiedinmyer and Emmons, 2022).</p>
  </notes><app-group>
        <supplementary-material position="anchor"><p id="d1e4773">The supplement related to this article is available online at: <inline-supplementary-material xlink:href="https://doi.org/10.5194/gmd-16-3873-2023-supplement" xlink:title="pdf">https://doi.org/10.5194/gmd-16-3873-2023-supplement</inline-supplementary-material>.</p></supplementary-material>
        </app-group><notes notes-type="authorcontribution"><title>Author contributions</title>

      <p id="d1e4782">CW contributed to all aspects of the project, from the model design, management, and resource acquisition to the model development and evaluation. CW prepared the paper, with contributions from all co-authors. LKE, WT, and RRB assisted with the implementation and evaluation and led the deployment of the emissions files online. ECMB acquired resources for the development and advised on the model development and evaluation. YK led the model development. MBJ and KS provided technical support for the model development and model simulations. KCB, AGC, and RY provided key input to the model development and evaluation.</p>
  </notes><notes notes-type="competinginterests"><title>Competing interests</title>

      <p id="d1e4788">The contact author has declared that none of the authors has any competing interests.</p>
  </notes><notes notes-type="disclaimer"><title>Disclaimer</title>

      <p id="d1e4794">The findings, opinions and conclusions are the work of the authors and do not necessarily represent findings, opinions, or conclusions of the State of Texas Air Quality Research Program (AQRP) or the Texas Commission on Environmental Quality (TCEQ). <?xmltex \hack{\newline}?><?xmltex \hack{\newline}?>Publisher's note: Copernicus Publications remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.</p>
  </notes><ack><title>Acknowledgements</title><p id="d1e4803">The authors thank the many users of the FINN emissions estimates for their support in the evaluation and quality assurance and quality control efforts.</p></ack><notes notes-type="financialsupport"><title>Financial support</title>

      <p id="d1e4808">The development of the FINNv2.5 model framework, the estimates, and the
evaluation have been supported through several different funding sources,
including the NOAA Climate Program Office (CPO; grant no. NA17OAR4310103), U.S. National Science Foundation (NSF; grant no. 1822406), and NASA (grant no. 80NSSC18K0681). Funding has also been provided by the Texas Air Quality Research Program (AQRP; project nos. 14-011 and 18-022) at The University of Texas at Austin through the Texas Emission Reduction Program and the Texas Commission on Environmental Quality (TCEQ). Support for most Cooperative Institute for Research in Environmental Sciences (CIRES) employees is from NOAA (grant nos. NA17OAR4320101 and NA22OAR4320151). Support for Kelley C. Barsanti was also from NOAA CPO (grant no. NA17OAR4310007). Robert Yokelson has been supported by the NSF (grant nos. AGS-1748266 and AGS-1349976), NOAA CPO (grant no. NA16OAR4310100), and NASA (grant no. NNX14AP45G). This material is based upon work supported by the National Center for Atmospheric Research, which is a major facility sponsored by the NSF (grant no. 1852977).</p>
  </notes><notes notes-type="reviewstatement"><title>Review statement</title>

      <p id="d1e4814">This paper was edited by Samuel Remy and reviewed by Johannes Kaiser and two anonymous referees.</p>
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